precipitation because the diffusion rate is very slow.
Here the rate of the reaction is controlled
by the rate at which atoms can migrate. The rate of precipitation is also very slow at temperatures just below the solvus line (point e, Fig. 16.1). In this case, the solution is only slightly oversaturated and the free-energy decrease resulting from precipitation is very small. Nucleation is, accordingly, slow, and precipitation is controlled by the rate at which nuclei can form. The high diffusion rates that exist at these temperatures can do little if nuclei do not form. At intermediate temperatures, between the two abovementioned extremes, the precipitation rate increases to a maximum, so that the time to complete the precipitation is very short. In this range, the combination include: aluminum, copper, silicon, phosphorus, nickel, and zirconium. Other elements are found in both the ferrite and the carbides. A number of these elements in the order of their tendency to form carbides (manganese having the least and titanium the greatest) are: manganese, chromium, tungsten, molybdenum, vanadium, and titanium. Most alloying elements in steels tend to increase the resistance of the steel to softening when it is heated, which means that for a given time and temperature of tempering, an alloy steel will possess a greater hardness after tempering