WATEREXECUTIVE

GAS SHIFT
REACTOR DE
SUMMARY
LI LAN
SIGN
SIMULATION
LIU YI FEI
INTRODUCTION
MA HAOTIAN

CN2116
28
FEATURES
LUOGroup
YU

CONCLUS
SHAN YU
ION

WGS Reactor Design

INTRODUCTION

DESIGN OBJECTIVE
Hydrogen supply for mass ammonia indu
strial synthesis

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

WGS Reactor Design

EXECUTIVE SUMMARY

REACTOR SET-UP
Heat Exchanger I

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

DESIGN SPECIFICATIONS
Feed Composition
Component

Composition (%)

CO

H2O

37

CO2

H2

42

Inert (N2)

10

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

DESIGN SPECIFICATIONS (CO

NT)
Catalyst Properties
Particulars

Properties

Composition (HTS)

Fe3O4-Cr2O3 (90-95%
Fe2O3, 5-10% Cr2O3,
CuO, K2O, ZnO, PbO,
Al2O3)

Composition (LTS)

Cu-Ce(La)Ox (5% Cu)

Particle Size (mm)

Bulk Density (kg/m3)

995

Weight (kg, HTS)

88256.5

Weight (kg, LTS)

18706

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

DESIGN SPECIFICATIONS (CO

NT)
HTS Reactor Dimensions
Dimensions

Values

Inner Diameter (m)

3.8

Cross-sectional Area
(m2)

11.6

Height (m)

7.7

Volume (m3)

88.7

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

DESIGN SPECIFICATIONS (CO

NT)
LTS Reactor Dimensions
Dimensions

Values

Inner Diameter (m)

2.3

Cross-sectional Area
(m2)

4.1

Height (m)

4.6

Volume (m3)

18.8

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

DESIGN SPECIFICATIONS (CO

NT)
Process Specifications
Particulars

HTS

LTS

Inlet Temperature
(OC)

300 500

200 - 300

Outlet Temperature
(OC)

350 - 550

205 310

Inlet Pressure (bar)

10

9.85

Outlet Pressure
(bar)

9.85

9.82

Conversion

0.81

0.99

Hydrogen
Producing Rate
(mol/s)

1467.9

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

WGS Reactor Design

SIMULATION

GOVERNING EQUATIONS

x CO

C (T T0 )
''
p

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

GOVERNING EQUATIONS (CO

NT)
rCO k0 e

E
RT

CCO C H 2O (1 )
n

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

GOVERNING EQUATIONS (CO

NT)
W FCO0

dx
rCO

W
V
bulk

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

ASSUMPTIONS
No deactivation of catalyst

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

METHODOLOGY

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

SIMULATION RESULTS
The highest conversion for HTS inlet temperature 320.000000 Celsius i
s 0.810000 outlet temperature 362.849043 Celsius
The highest conversion for LTS inlet temperature 200.000000 Celsius i
s 0.990500 outlet temperature 208.682034 Celsius
HTS reactor volume is 88.687919 m^3
LTS reactor volume is 18.837752 m^3
Total volume is 107.525670 m^3

HTS reactor pressure drop is 14807.220752 Pa

LTS reactor pressure drop is 2505.309835 Pa
Total pressure drop is 17312.530587 Pa

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

SIMULATION RESULTS

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

WGS Reactor Design

FEATURES

FEATURES

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

FEATURES (CONT)
Reactor Volume

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

FEATURES (CONT)
Operating Temperature

INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION

WGS Reactor Design

CONCLUSION
INTROEXE. SUMMARY
SIMULATION
FEATURES
CONCLUSION