Target : JEE (IITs) Resonance CHEMISTRY COURSE : VIJAY (JR) TOPIC : arfaa 7 (REAL GASES) SOLUTION OF ADVANCED LEVEL PROBLEMS SOLUTIONS Pua Xwo ia _ xx 28 Teo 28x = Pos Peo Xco m= Pe AD al 6 x, 2, Ny FaT CO sls se B aA N, gH CO wT Re Bo AEB 704 2 Noa ten = F=t r 44 H,& sel ah seen = 1 ate aate=dareg . 1 1 " 80, that #ten= f =F erer)et nRT _ 41 0.0821%300 _ BT Ht 4 208211300 «5.64 = 8.7 atm. 3. Ge Peer wr ara = 10.aIm P.+P,+P.= 10 3+1+P- > Py fs 1 a) K 1 mr mre = K+KeaKs10 = f.% = 2K = gt ake = 376 = Me (10) = (2). 33, 5 [go] =10 K=3, ‘om aR fem F= 2.612 a) tei} Perr & qearg sea AA ara P28 | Resonance:9x5 =18«,) 3aim=P, at tet & fem o geaq wet BA aa Pe] PY,=P.V, 6x10 = Pp)s15 4aim=P, el I Gel Ba = 443.= 7 atm Ne PN2 |MMny Hy Pi Ve uy _ 1400, 2 [E 60 ~ 28 * 7000 * \28 ty, = 16 minutes, oye A v Pp, P, 800mm, 680mm 800mm 680mm P, x 2V=P i, x BV) Py x V = Pg x 3V 680 poh = 250 Ad tel = “> = 0.0083 agg = 020 _ B& He = Ge = 0.0044 ge Aa =0.0127 “ge sta = 750mm Ad sa 0.0083 Jas XBAI = Foyo7 x 750 = 400 mm Aw site ara = fare are 2904 7592 Bar sift a= 5 57 x 750 = 260mm. fro an ar ara P 8 ae AI ne corer ey arr ETT PV 40xt RT ~ 00x02 = 1218. 7 CH,+ 50, —> 260, +3H.0. 130 74063 IN Resonance: _secisanonctsnsccaiisanieeciaanmeciincacnninanicccsnin Core ee40. 1. 7 CH, + 5 0, —> 200, +3H,0. 2 He > a CH, +30, —> 20, + 2H,0, a> b z $a+ b= 4.063. (ty atb= 1.2195 2) 3a+ 3b = 3.6585 8) M-@ a= (0.4045), a=0.81, b= 0.4095. . 0.4095 _ CH, a1 tte WHIT = T5ige = 0.94. C,H, por gatas 5 PV=n.RT 4 Phy, = Ni P= 5 atm . v3) 54 w= (i7a+ara) * 3 = 3 atm Py =O. ole: orgaftap. , 500 amet ter vrs (a) = 20 = 40 Tv ev a BT 10 | 00 °° RT’ My ~ P2V2/T2 ny = 800, V 760" 300 10 _ 760 ng ~ 600° fFravah gal het a He = (107.895) x 50 = 105.26 gm cl, == 201 (chy ol Fs) WK (RB ake) P18 = YMy(CL+CD = YM, 838 y(1.16)? IN Resonance: _secisanonciasicacisanieeciaanmciinaniseininanicccsain Core acl, == 201 srt Hirer 1 oO rah B wea Ges Pato AA) (1-») 2x frehor & sea, ge Ae 1-x+ 2x= (1+ x) (1=x)M(Cl,) +2xM(Cl) =6: x) 2.28 1 _ 62.28 _ Text ay 7088 1+xe 44d x= 014 feito %= 14%, AP . Me te. [ie ad ap YM > YM, tb 425 _ fly = 88. FE 5 meses (29) = 704 ma Pm 90x05 = 13, @z= DP = Sete = 0.696. Ans. ART _ 1<0.082%263 wP=7y De atm = 43.132 atm 16. mh RT+ (6+) «052224043 ” (2) RT + (Pray) x1 = 22.3039, (2) =) 15. a 16 ee Rb ~ 0082. 0.0378 ~ K = 521.06 K. Ans. mn a 4 (by > Frm = ele) eS OE.Pv 7 7. 7 am 19. aaa aaa, Pb Pv Zat4 a Zea 18 afore H 20 aioe B Par HI aA ae 4 Za PRBS 2020