Diagrama Au-CN-H2O

Nombre : Osvaldo Miranda

Reaccion
1. Au(OH)3 (s)+3H++2e=Au++3H2O
2.
Au0
=Au++e
3.
Au(CN)-2
=Au++2CN4.
H++ CN= HCN

Log (K)
45,35
-28,62
-38,10
9,21

Reaccion A0/ Au(CN)-2

Au++e = Au0
Au(CN)-2
=Au++2CNAu(CN)-2 + e = Au0 + 2CN-

28,62
-38,10
-9,48

p= -9,48-2log[CN-]+log[Au(CN)-2]
Reaccion Au(CN)-2 /HCN
Au++2CN- = Au(CN)-2 + e
2HCN
= 2CN- + 2H+

9,48
-18,42

Au++2HCN = Au(CN)-2 + e +2H+

-8,94
p= 8,94 -2pH -2log[HCN] +log[Au(CN)-2]
= 8,94-2pH
Reaccion Au(OH)3 (s)/ Au(CN)-2
Au(OH)3 (s)+3H++2e=Au++3H2O
Au++2CN= Au(CN)-2
Au(OH)3 (s) + 3H++ 2e +2CN- = Au(CN)-2+3H2O
p= 41,725- 1,5 pH

45,35
38,10
83,45

Au(OH)3 (s)

Au(CN)-2

CN-

HCN
Au

pH