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DPP No. # 39
Total Marks : 86
1.
(3 marks, 2 min.)
(4 marks, 2 min.)
[66, 44]
[20, 10]
The following structures represent various silicate anions. Their formulas are respectively
fuEu lajpuk, fofHkUu flfydsV _.kk;uksa dks iznf'kZr djrh gSA muds lw=k e'k% fuEu gSa&
O
O = Oxygen
= Silicon
O
(1) SiO44 & Si3O88
(1) SiO44 o Si3O88
2.
O
(2*) SiO44 & Si3O108
(2*) SiO44 o Si3O108
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PAGE NO.- 1
Sol.
gy %
3.
Sol.
4.
Sol.
Which gas is formed when CaC2 is allowed to react with dilute HCl ?
(1) Ethane
(2) Ethene
(3*) Ethyne
tc CaC2 dks ruq HCl ds lkFk vfHkr fd;k tkrk gS] rks dkSulh xSl curh
(1) ,sFksu
(2) ,Fkhu
(3*) ,Fkkbu
(4) Methane
gS \
(4) esFksu
Ethyne
,Fkkbu
6.
The function of fluorspar in the electrolytic reduction of alumina dissolved in fused cryolite (Na3AlF6) is
(1) as a catalyst
(2*) to lower the temperature of the melt and to make the fused mixture very conducting
(3) to decrease the rate of oxidation of carbon at the anode
(4) none of these above
laxfyr k;ksykbV (Na3AlF6) esa ?kqfyr ,sY;qfeuk ds oS|qr vi?kVuh; viPk;u esa yksjLikj dk dk;Z gksrk gSA
(1) mRizsjd ds :i esa gSA
(2*) xfyr dk rki de djuk rFkk laxfyr feJ.k dks vfrpkyd cukuk
(3) ,uksM+ ij dkcZu dh vkWDlhdj.k dh nj dks ?kVkuk
(4) buesa ls dksbZ ugha
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PAGE NO.- 2
7.
(2) AlCl3
Which of the following oxidation states are the most characterstics for lead and tin, respectively ?
ySM o fVu ds fy, fuEu esa ls dkSulh vkWDlhdj.k voLFkk e'k% lokZf/kd :i ls vfHkyk{kf.kd gSa \
(1*) + 2 , + 4
9.
(2) + 4 , + 4
(3) + 2 , + 2
(4) + 4 , + 2
flfydsV dh J`a[kyk lajpuk esa fuEu esa ls dkSulk _.kk;u mifLFkr gksrk gS \
(1) (Si2 O52 )n
10.
11.
(2*) (SiO32 )n
curk gSA
(3) SiO 4
4
(3) Na3AlF6
(4*) H2SiF6
gy12.
Sol.
(1*) CO2
(2) CO
(3) SO2
(4) Both (1) & (3) nksuks (1)
CO2 can not act as reducing agent because carbon is in its highest oxidation state, i.e., +4.
CO2 vipk;d ds :i esa dk;Z ugha djrk gS D;ksafd dkcZu bldh mPpre vkWDlhdj.k voLFkk +4 esa gSaA
Aqueous solution of potash alum is :
(1) alkalline
(2*) acidic
(3) neutral
(4) soapy
(3) mnklhu
(4) lkcquhdr
It is acidic because of the hydrolysis of Al2(SO4)3 according to the following reaction.
Al2 (SO4)3 + 6H2O 2Al(OH)3 + 3H2SO4.
gy-
13.
gy-
14.
Sol.
z
rFkk (3)
(3) SrO 2
(4) BaO 2
vfHkf;k
16.
(2) H 2 O 2
B 2 O 3 C Cl 2 A CO . esa A
gS %
BCl 3
(1*)
(2) BCl 2
(3) B 2 Cl 2
(4) CCl 2
Which of the following is formed when aluminium oxide and carbon is strongly heated in dry chlorine gas
Tkc ,Y;qfefu;e vkWDlkbM rFkk dkcZu dks 'kq"d Dyksjhu xSl dh mifLFkfr esa izcy :Ik ls xeZ djrs gS rks fuEu esa ls D;k
curk gS \
(1)
,Y;qfefu;e DyksjkbM
(3*) futZy
(2) ty
,Y;qfefu;e DyksjkbM
(4) buesa
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PAGE NO.- 3
17.
,Y;qfefu;e gkbMksDlkWbM] lksfM;e gkbMksDlkWbM ds vkf/kD; esa foys; gksdj vk;u cukrk gS % ?
(1) AlO 2 3
18.
(2) AlO 23
(3*) AlO 2
(4) AlO 3
Aluminium chloride exists as dimer, Al 2 Cl6 in solid state as well as in solution of non-polar solvents such
as benzene. When dissolved in water, it gives
,Y;qfefu;e DyksjkbM Bksl vOkLFkk ds lkFk&lkFk v/kzqoh; foyk;d tSls csUthu ds foy;u esa f}yd , Al 2 Cl 6 ds :Ik esa
jgrk gSA tc bls ty esa ?kksyk tkrk gS rks ;g nsrk gS %
(1)
19.
[ Al(OH )6 ]3 3 HCl
(4*) Al 2 O3 6 HCl
(3) Al 3 3 Cl
BF3
(2) BCl 3
(3) BBr3
(4*) BH 3
(2)Basic
Alumina is
(1) Acidic
,yqfeuk gS %
(1) vEyh;
21.
(2) {kkjh;
(3*) mHk;/kehZ
(4) buesa
ls dksbZ ugh
fuEu es ls dkSulh /kkrq dks Lo;a dh vkWDlkbM ijr }kjk ifjjf{kr fd;k tkrk gS %
(1*) Al
22.
(2)
Ag
(3) Au
(4) Fe
Aluminium is more reactive than iron. But aluminium is less easily corroded than iron because
(1) Aluminium is a noble metal
(2*) Oxygen forms a protective oxide layer
(3) Iron undergoes reaction easily with water
(4) Iron forms mono and divalent ions
,Y;qfefu;e] vk;ju dh vis{kk vf/kd f;k'khy gksrk gS fdUrq ,Y;qfefu;e] dk la{kkj.k vk;ju dh vis{kk ljyrk ls ugh
gksrk gS D;ksfd&
(1) ,Y;qfefu;e
(2*) vkWDlhtu
(3) vk;ju
(4)
,d vf; /kkrq gS
,d ifjjf{kr vkWDlkbM ijr cukrk gSA
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PAGE NO.- 4
ChemINFO-1.4
HYDROGEN
Properties of Hydrogen
(1) It is colourless, odourless and taste less gas.
(2) It is only slightly soluble in water.
(3) It is lightest of all elements.
(4) certain metals like palladium, platinum etc can adsorb large quantities of hydrogen. The adsorbed hydrogen is
called occluded hydrogen and is more active than ordinary hydrogen.
Combustion : Hydrogen is flammable or combustible gas it burn with blue flame in oxygen atmosphere.
2H2 + O2 2H2O
Combination reaction :
Due to very high bond dissociation energy (436 KJ mol1) hydrogen is not a very active.
(A) Except Beryllium all alkali and alkaline earth metal directly combine with hydrogen and ionic hydride is formed.
2Li + H2 2LiH
2Na + H2 2NaH
Ca + H2 CaH2
Ba + H2 BaH2
X F , Cl , Br , I
(Oil)
(vanaspati ghee)
(E) Synthesis of Ammonia (Habers Process) : A mixture of N2 and H2 in ratio of 1 : 3 at 200 atm, 500C in
presence of Fe catalyst NH3 is formed.
N2 + 3H2
2NH3
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
23.
24.
25.
(3) Red
(4*) None
(3*) Hydrogen
(4) Oxygen
(3) Al
(4) K
26.
(4) I2
27.
(4) Na
(3) Ba
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PAGE NO.- 5
ChemINFO-1.4
HYDROGEN
gkbMkstu ds xq.k/keZ
cukrh gSA
2Li + H2 2LiH
2Na + H2 2NaH
(B)
Ca + H2 CaH2
Ba + H2 BaH2
H2 + X2 2HX
X F , Cl , Br , I
dk laysk.k : ZnO rFkk CrO3 mRizsjd dh mifLFkfr esa 200 ok;qe.Myh; nkc ij CO rFkk H2 tqM+dj
mRizsjd
CO + 2H2
CH3OH
300 C
(D)
vlarIr olk fudy dh mifLFkfr esa larIr olk esa cnyrh gSA
Ni
vlarIr olk + H2
larIr olk
mRizsjd
(rsy)
(ouLifr
?kh)
veksfu;k dk laysk.k (gscj ize) : N2 rFkk H2 dk feJ.k 200 atm rFkk 500C ij Fe mRiszjd dh mifLFkfr esa 1 : 3 ds
vuqikr esa f;k djds NH3 cukrk gSA
(E)
N2 + 3H2
23.
24.
25.
(3) yky
(3*) gkbMkstu
(4*) dksbZ
(3) Al
27.
(1) Zn
26.
2NH3
(2) Cl2
(3*) F2
fuEu esa ls fdl /kkrq ds lkFk gkbMkstu izR;{k :i ls ugh tqM+rh gS&
(1*) Be
(2) Ca
(3) Ba
ugh
(4) vkWDlhtu
(4) K
(4) I2
(4) Na
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PAGE NO.- 6