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2 MOLE CONCEPT
05/20/16
MATTER
Learning Outcome
At the end of this topic, students should be
able :
(a) Define mole in terms of mass of
carbon-12 and Avogadro constant, NA.
(b) Interconvert between moles, mass, number of
particles, molar volume of gas at s.t.p. and
room temperature.
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MATTER
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MATTER
MATTER
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MATTER
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MATTER
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MATTER
One
The
NA =
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MATTER
Example
1.0 mole of chlorine atom
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Molar Mass
The
Unit
: g mol-1
Example:
molar mass of Mg
molar mass of CH4
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=
=
=
MATTER
24 g mol-1
(12 + 4) gmol-1
16 g mol-1
10
Number of Mole
Mass
(g)
Mass
(g)
Number
Number of
of mole
mole
-1-1
Molar
Mass
(g
mol
Molar Mass (g mol ))
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MATTER
11
Example 1
In
In 14
14ggof
of N
N22 ,,calculate;
calculate;
-1-1
i.i. Number
of
moles
molecule
if
molar
mass
28
g
mol
Number of moles molecule if molar mass 28 g mol
ii.
ii.Number
Numberof
of molecule
molecule
iii.
iii.Number
Numberof
of atoms
atoms
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MATTER
12
Solution
Solution::
-1-1
i.i. Number
of
moles
molecule
if
molar
mass
28
gmol
Number of moles molecule if molar mass 28 gmol
Mass
(g)
Mass
(g)
Number
of
mole
molecules
N
-1-1
28
g
mol
28 g mol
0.5
0.5mol
mol
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MATTER
13
Example 1 (cont)
ii.
ii.Number
Numberof
ofmolecule
molecule
Number
N
Numberof
of molecules
molecules
N22Number
Numberof
ofmole
mole xxN
NAA
23
0.5
x
6.022
x
10
0.5x 6.022x 1023
23
3.011
x
10
3.011x 1023 molecules
molecules
iii.
of
iii.Number
Number
ofatoms
atoms
11 molecule
moleculeof
ofN
N22 contains
contains22 atoms
atomsof
of N
N
23
23
23moleculeofN contains2 x 3.011
3.011
x
10
x
10
3.011x 10 moleculeofN22 contains2 x 3.011x 1023atoms
atomsof
of N
N
23
6.022
x
10
6.022x 1023 atoms
atoms
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MATTER
14
Example 2
Calculate
33
Calculate the
thenumber
numberH
Hatom
atomin
in11mole
moleof
ofNH
NH
11 mole
33 contains
moleof
ofNH
NH
contains33 moles
molesof
ofH
H atoms
atoms
Number
of
atoms
Number
of
atoms
Number
Numberof
ofmoles
moles
N
NA
A
23
Number
of
atoms
3
x
6.022
x
10
Numberof atoms 3 x 6.022x 1023
24
1.807
x
10
1.807x 1024atoms
atoms
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MATTER
15
Example 3
Calculate
Calculate the
the number
number of
of bromide
bromide ions
ions in
in 22 moles
moles of
of CaBr
CaBr22
11 mole
mole of
of CaBr
CaBr22 contains
contains 22 moles
moles of
of bromide
bromide ions
ions
22 mole
mole of
of CaBr
CaBr22 contains
contains 44 moles
moles of
of bromide
bromide ions
ions
so,
so,
23
Number
of
bromide
ions
4
x
6.022
x
10
Number of bromide ions 4 x 6.022 x 10 23
24
1.2046
x
10
1.2046 x 10 24ions
ions
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MATTER
16
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MATTER
17
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MATTER
18
Example 1
AA balloon
balloon isis filled
filled with
with hydrogen
hydrogen gas
gas atat s.t.p.
s.t.p.
33
IfIf the
volume
of
the
ballon
is
2.24
dm
the volume of the ballon is 2.24 dm ,, calculate
calculate
the
the amount
amount (mole)
(mole) of
of hydrogen
hydrogen gas.
gas.
Solution
Solution 1,
1,
33
22.4
dm
22.4 dm consists
consists 11 mol
mol of
of hydrogen
hydrogen gas
gas
11
33
2.24
xx2.24
2.24dm
dm consists
consists
2.24 mol
mol of
of hydrogen
hydrogen gas
gas
22.4
22.4
so,
so,
Number
Number of
of mole
mole00..11 mol
mol
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MATTER
19
3
1
22.4 dm mol
0.1 mol
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MATTER
20
Exercise
A sample of CO2 has a volume of 56 cm3 at STP. Calculate:
a.
b.
c.
MATTER
21
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MATTER
22
MATTER
23
Example
A sample of hydrocarbon contains 85.7%
carbon and 14.3% hydrogen by mass. Its
molar mass is 56. Determine the empirical
formula and molecular formula of the
compound.
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MATTER
24
Solution :
C
85.7
14.3
Number of mol
85.7
12
7.1417
14.3
1
14.3
Simplest ratio
mass
MATTER
25
n = 56
14
= 4
MATTER
26
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MATTER
27
Exercise
A combustion of 0.202 g of an organic sample that
contains carbon, hydrogen and oxygen produce
0.361g carbon dioxide and 0.147 g water. If the
relative molecular mass of the sample is 148,
what is the molecular formula.
Ans : C6H12O4
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MATTER
28
Molarity
Molality
Mole Fraction
Percentage by Mass
Percentage byVolume
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MATTER
29
A. Molarity (M)
moles
of
solute
(mol)
moles
of
solute
(mol)
molarity,
M
molarity, M
33
volume
volume of
of solution
solution (dm
(dm ))
-3-3
-1-1
Unit
:
mol
dm
or
mol
L
Unit : mol dm or mol L or
or molar
molar
Note:
1 dm3 =
1000 cm3
1L
=
1000 mL
05/20/16
MATTER
30
Example
Calculate
Calculate the
the molarity
molarity of
of aa solution
solution of
of 1.71
1.71gg sucrose
sucrose (C
(C1212HH2222OO1111))
ddissolved
issolved in
in aa 0.5
0.5LL of
of water.
water.
[Ar
[Ar HH1,1, CC12,
12, OO16
16 ]]
Solution,
Solution,
Molar
Molar mass
mass of
of sucrose
sucrose(12x2)
(12x2)22
22(11
(11xx16
16))
1
342
g
mol
342 g mol 1
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MATTER
31
Cont
mass
Number of mole of sucrose
molar mass
1.71 g
342 g mol 1
0.005 mol
mole of sucrose
molarity of solution sucrose
volume of solution
0.005 mol
0.5 L
0.01 mol L-1
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MATTER
32
Exercises
How
How many
many grams
grams of
of potassium
potassium dichromate
dichromate,, KK2Cr
2Cr2O7
2O7 required
required
to
to prepare
prepare aa solution
solution of
of 250
250mL
mL with
with 2.16
2.16M?
M?
[Ar
[Ar KK 39
39.1,
.1, Cr
Cr 52,
52, OO16
16 ]]
Ans
Ans::158
158.87
.87
AA ,,matriculat
ion
prepared
by
matriculat
ionstudent
student
preparedaa solution
solution
by dissolving
dissolving
3
0.586
g
of
sodium
carbonate,
Na
CO
in
250
cm
0.586g of sodiumcarbonate,Na22CO33 in 250 cm3 of
of water.
water.
Calculate
Calculateits
itsmolarity?
molarity?
[Ar
,, CC12,
[Ar Na
Na23
23
12, O
O16
16]]
-3
Ans
:
0
.
0221
moldm
Ans: 0.0221moldm-3
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MATTER
33
B. Molality (m)
moles
of
moles
of
molality,
m
molality, m
mass
mass of
of
solute
solute (mol)
(mol)
solvent
solvent (kg)
(kg)
-1-1
unit
unit :: mol
molkg
kg or
or molal
molal or
or m
m
Note:
Mass of solution
Volume
of solution
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mass of solute +
mass of solvent
volume of solvent
MATTER
34
Example 1
Calculate the molality of sulphuric acid
solution containing 24.4 g of sulphuric acid
in 198 g of water?
[molar mass H 2 SO 4 98.08 g mol ]
-1
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MATTER
35
Solution :
n H SO
2
mass
molar mass
24.4 g
98.08 g mol 1
0.2488 mol
0.198 kg
1.26 m
05/20/16
MATTER
36
Example 2
What is the molal concentration of a solution
prepared by dissolving 0.30 mol of CuCl 2 in
40.0 mol of water?
[molar mass H 2 O 18.02 g mol ]
-1
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MATTER
37
Solution :
nH O
2
mass
molar mass
mass of H 2 O
0.7208 kg
0.416 m
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MATTER
38
Exercises
What
What isis the
the molality
molality of
of aa solution
solution containing
containing 7.78
7.78gg
of
of urea
urea [(NH
[(NH22))22CO]
CO] in
in 203
203gg water?
water?
Ans
Ans::00..639
639m
m
05/20/16
MATTER
39
A
A solution
solution containing
containing 121.8
121.8gg of
of Zn(NO
Zn(NO33))22 per
per litre
litre
has
has aa density
density of
of 1.107
1.107 ggmL
mL .. Calculate
Calculate its
its molal
molal
- -1
- -1
concentrat
concentration.
ion.
Ans
Ans::00..653
653 m
m
05/20/16
MATTER
40
moles
of
AA
moles
of
mole
mole fraction
fraction of
of component
component A,
A, XXAA
total
total number
number of
of moles
moles
of
of all
all component
component
nnAA
XXAA
nntotal
total
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MATTER
41
It
The
05/20/16
MATTER
42
Example 1
What is the mole fraction of CuCl 2 in a solution
prepared by dissolving 0.30 mol of CuCl 2 in
40.0 mol of water?
[molar mass H 2 O 18.02 g mol ]
-1
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MATTER
43
Solution :
nCuCl
X CuCl
n total
0.3
0.3 40
0.007
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MATTER
44
XHO
2
nH O
2
n total
40
0.3 40
0.993
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MATTER
45
XCuCl2 XH2O 1
XH2O 1 0.007
0.093
05/20/16
MATTER
46
Example 2
A solution is prepared by mixing 55 g of toluene,
C 7 H 8 and 55 g of bromobenzene C 6 H 5 Br.
What is the mole fraction of each component?
[Ar C 12.01, H 1.01, Br 79.9]
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MATTER
47
Step2 :
Step1:
nC7H8
55
7(12.01)
8(1.01)
55
92.15
0.5969mol
Step3 :
XC7H8
0.5969
0.5969 0.3491
0.63
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nC6H5Br
55
6(12.01)
5(1.01)
79.90
55
157.55
0.3491mol
Step4 :
XC 6H5Br
0.3491
0.5969 0.3491
0.37
MATTER
48
mass
of
solute
mass
of
solutex100
w
%
% ww mass of solution
x100
w massof solution
note
mass
mass
note:: mass
massof
ofsolution
solution
massof
ofsolute
solute
massof
ofsolvent
solvent
05/20/16
MATTER
49
Example 1
A sample of 0.892 g of potassium chloride, KCl is
dissolved in 54.3 g of water. What is percentage by
mass in the solution?
Solution
::
Solution
mass
of
solute
mass
of
solutex100
w
%
% ww mass of solution
x100
w mass of solution
00.892
.892 x100
x100
00.892
.3
.89254
54
.3
1.61%
1.61%
05/20/16
MATTER
50
Example 2
Calculate the amount of water (in grams) that must
be added to 5.00 g of urea in the preparation of a 16.2
percent by mass solution.
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MATTER
51
Solution
::
Solution
mass
massof
ofsolute
solutex100
w
%
w
% w massof solution
x100
w mass of solution
55
16.2
xx100
16.2massof solution
100
massof solution
55
mass
of
solution
mass of solution
16.2xx100
100
16.2
30.86
gg
30.86
mass
mass
mass
massof
ofsolution
solution
massof
ofsolute
solute
massof
ofsolvent
solvent
30.86
5.00
mass
30.86
5.00
massof
ofsolvent
solvent
30.86
--5.00
mass
massof
ofsolvent
solvent
30.86
5.00
25.86
gg
25.86
05/20/16
MATTER
52
Exercises
1.
1.How
Howmany
many grams
grams of
of NaOH
NaOH and
and water
water are
are needed
needed
to
to prepare
prepare 250.0
250.0gg of
of 1.00%
1.00% NaOH
NaOH solution?
solution?
Ans
Ans::22..50
50gg;; 247.5
247.5gg
2.2.Hydrochlor
Hydrochloricic acid
acid can
canbe
be purchased
purchased as
as aa solution
solution of
of 37%
37%
HCl.
HCl. What
Whatisisthe
themass
mass of
of this
this solution
solution contains
contains 7.5
7.5gg of
of HCl?
HCl?
Ans
Ans::20
20.27
.27 gg
05/20/16
MATTER
53
MATTER
54
Example
A 200mL of perfume contains 28 mL of alcohol.
What is the % by volume of alcohol in this solution?
Solution
Solution::
volume of
of alcohol
alcohol (mL)
(mL)x 100
VV volume
%
% V volume of solution (mL) x 100
V volume of solution (mL)
28
28 xx100
100
200
200
14
14%
%
05/20/16
MATTER
55
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MATTER
56
Example:
xA
yB
zC
Reactants
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wD
Products
MATTER
57
Inspection Method
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MATTER
58
Inspection Method
a.
b.
c.
d.
05/20/16
MATTER
59
Example
Balance the chemical equation by applying the
inspection method.
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MATTER
60
Exercise
1.
b.
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MATTER
61
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MATTER
62
Oxidation
The
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MATTER
63
Reduction
The
05/20/16
MATTER
64
1.
Mg
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O2
MATTER
65
2.
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MATTER
66
3.
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MATTER
67
4.
05/20/16
MATTER
68
5.
05/20/16
MATTER
=
=
-2
-2
69
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MATTER
+2
70
6.
05/20/16
MATTER
=
=
0
0
71
7.
-1
-2
-1
05/20/16
MATTER
72
Example :
Assign the oxidation number of Cr in Cr2O72-.
Solution :
Cr2O7 = -2
2 Cr + 7 (-2) = -2
2 Cr = + 12
Cr = + 6
05/20/16
MATTER
73
Exercise
1.
2.
3.
MATTER
74
Follow
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MATTER
75
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MATTER
76
2.
05/20/16
MATTER
77
b.
c.
MATTER
78
05/20/16
MATTER
79
5.
05/20/16
MATTER
80
C2O42- CO2
ii. Reduction
MnO4- Mn2+
2.
i. C2O42- 2CO2
ii. MnO4- + 8H+ Mn2+ + 4H2O
3.
i. C2O42- 2CO2 + 2e
ii. MnO4- + 8H+ + 5e Mn2+ + 4H2O
05/20/16
MATTER
81
4. i.
ii.
5. i.
ii.
_________________________________________________
5C2O42- + 2MnO4- + 16H+ 10CO2 + 2Mn2+ + 8H2O
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MATTER
82
2.
3.
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MATTER
83
Cr(OH)3 CrO32-
ii. Reduction
IO3- I-
2.
3.
MATTER
84
4.
5.
6.
7.
05/20/16
MATTER
85
Exercise
Balance the following redox equations:
a.
In Acidic Solution
i.
Cu + NO3 + H+ Cu2+ + NO2 + H2O
b.
ii.
iii.
In Basic Solution
i.
ClO- + S2O32- Cl- + SO42ii.
iii.
NO2 NO3 + NO
05/20/16
MATTER
86
1.2.5 Stoichiometry
Stoichiometry
05/20/16
MATTER
87
Example:
CaCO3 (s) + 2HCl (aq) CaCl2 (aq) + CO2 (g) + H2O (l)
05/20/16
MATTER
88
Example 1
How many moles of hydrochloric acid, HCl do we need to react
with 0.5 moles of zinc?
05/20/16
MATTER
89
Example 2
How many moles of H2O will be formed when 0.25 moles of
C2H5OH burns in oxygen?
Solution
:
C 2H5OH 3O2 2CO2 3H2O
Fromtheequation,
1mol of C 2H5OH gives 3 molesof H2O
0.25mol of C 2H5OH gives X molesof H2O
0.25x 3
1
05/20/16
MATTER
90
Exercise 1
A 16.50 mL 0.1327 M KMnO4 solution is needed
to oxidise 20.00mL of a FeSO4 solution in an
acidic medium. What is the concentration of the
FeSO4 solution? The net ionic equation is:
5Fe 2+ + MnO4- +8H+
Mn 2+ +5Fe 3+ +4H2O
Answer : 0.5474 M
05/20/16
MATTER
91
Exercise 2
How many mililitres of 0.112 M HCl will react
exactly with the sodium carbonate in 21.2 mL of
0.150 M Na2CO3 according to the following
equation?
2HCl(aq)+Na2CO3(aq)
2NaCl(aq)+CO2(g)+H2O(l)
Answer : 56.8 mL
05/20/16
MATTER
92
An
05/20/16
MATTER
93
Example 1
S + 3F2 SF6
If 4 mol of S reacts with 10 mol of F 2 , which of the two reactants is the
limiting reagent?
Solution :
From the equation,
1 mol of S reacts with 3 moles of F2
4 mol of S reacts with X moles of F2
4x3
X
1
12 mol F2
Compare the n F needed (12 mol) with the n F (10 mol) available
2
MATTER
94
Example 2
C is prepared by reacting A and B :
A + 5B C
In one process, 2 mol of A react with 9 mol of B.
a.
Which is the limiting reactant?
b.
Calculate the number of mole(s) of C?
c.
How much of the excess reactant (in mol) is left at the end of
the reaction?
05/20/16
MATTER
95
Solution A :
Fromtheequation,
1 mol of A reacts with5 molesof B
2 mol of A reacts withX molesof B
2 x5
1
10 mol H2O
Compare thenB needed (10mol) with the nB (9mol) available
in the question.
B is in limit, Bis thelimitingreactant.
05/20/16
MATTER
96
Solution B :
The amountof product formedreliesof themolesof B,
thelimitingreactant.
Fromtheequation,
5 mol of B produce with1 molesof C
9 mol of B produce withX molesof C
9 x1
5
1.8 mol C
05/20/16
MATTER
97
Solution C :
A is theexcess reactant.
Fromtheequation,
5 mol of B produce with1 molesof A
9 mol of B produce withX molesof C
9 x1
X
5
1.8 mol A
The amountexcess reactant 2- 1.8 0.2 mol A
05/20/16
MATTER
98
Percentage yield
The
05/20/16
MATTER
99
Percentage yield
05/20/16
actual yield
x 100%
theoretical yield
MATTER
100
Exercise
In a certain experiment, 14.6g of SbF3 was allowed to react
with CCl4 in excess. After the reaction was finished, 8.62g of
CCl2F2 was obtained.
3 CCl4 +
2 SbF3
3 CCl2F2 +
2 SbCl3
b) 74.31
%
MATTER
101