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qV .
(2.1.1)
33
dA dA ext
V
dv
Figure 2.1.1
If the electric charge from domain V has the volume distribution
density a v (see Figure 2.1.1), then relation (2.1.1) can be explicitly written:
D dA D dAext v dv
(2.1.2)
D dA div D dv v dv,
(2.1.3)
div D v ,
(2.1.4)
expression which represents the local form the electric flux law for continuity
domains.
Electric flux law emphasizes one of the causes that generates electric
field, namely charged bodies.
div D 0
div D 0
div D 0
Figure 2.1.2
34
It is well-known that, for any field vector, the points from the space in
which the divergence is nonzero represent end points of field lines (starting
point if the divergence is positive, and, respectively, end points if the divergence
is negative). It results that the lines of the electric field produced by charges
are open curves, starting from the positive charged bodies and ending on the
negative charged bodies (see Figure 2.1.2).
0.
(2.2.1)
Because this relation is valid for any space domain V , it results the
local form for continuity domains of the magnetic flux law:
(2.2.3)
div B 0.
35
dA j dAext
S , j
dA k dAext
S ,k
dl
Figure 2.2.1
integral on S , j and S, k :
S , j
S , j
S , k
S , k
(2.2.4)
Therefore
B dA j B dAk B dAk
S , j
S , k
(2.2.5)
for any open surface S which sits on the closed curve , which shows that
the magnetic flux has a unique value through all open surfaces bounded by
the same closed curve.
Moreover, the vector identity
div curl A 0
(2.2.6)
allows the introduction of a new quantity, called magnetic vector potential and
denoted by A with relation:
curl A B .
36
(2.2.7)
div A 0
such that the field vector A to be a solenoidal one too.
Applying the Stokes theorem, the magnetic flux which flows through an
arbitrary open surface S , which sits on a closed curve , can be expressed
by the line integral of the of the magnetic potential vector on the curve :
B dA curl A dA A dl .
(2.2.9)
This shows that the magnetic flux through an open surface depends
only on the closed curve that bounds it.
B 0 H M .
(2.3.1)
B 0 H 0 M t 0 M p
(2.3.2)
37
Mt Mt H .
(2.4.1)
M t m H,
(2.4.2)
B 0 H 0 M t 0 M p 0 H 0 m H 0 M p
0 1 m H 0 M p .
(2.4.3)
r 1 m
(2.4.4)
o r
(2.4.5)
H I p,
(2.4.6)
Ip
B H I p
Figure 2.4.1, a
Figure 2.4.1, b
0 and, respectively, as in
Hydrogen
1-0,06310-6
Copper
1-08,810-6
Water
1-910-6
Zinc
1-1210-6
39
Halite
1-12,610-6
Silver
1-1910-6
Mercury
1-2510-6
Bismuth
1-17610-6
Azoth
1+0,01310-6
Air
1+0,410-6
Oxygen
1+1,910-6
Aluminum
1+2310-6
Platinum
1+36010-6
M t M t x i M t y j M t z k and B Bx i B y j Bz k , then
M t m H x m H y m H z
xx
xy
xz
x
M t y m yx H x m yy H y m yz H z
M t z m zx H x m zy H y m zz H z .
(2.4.7)
40
m
xx
m yx
m
zx
m xy
m yy
m zy
m xz
m yz ,
m zz
(2.4.8)
M t m H
B 0 H 0 M t 0 M p 0 H 0 m H 0 M p
(2.4.10)
0 1 m H 0 M p 0 r H 0 M p H I p ,
where r 1 m is he relative permeability tensor, and 0 r is the
absolute permeability tensor.
Ip
B H I p
B H
H
H
H
Figure 2.4.2, a
Figure 2.4.2, b
Relation (2.4.10) has the vector interpretation from Figure 2.4.2,a with
the particular case in Figure 2.4.2,b corresponding in which M p 0.
If we explicitly write the relation (2.4.10):
Bx xx
B y yx
B
z zx
xy
yy
zy
xz H x I p x
yz H y I p y ,
zz H z I p
z
(2.4.11)
41
we remark the fact that the matrix corresponding to the tensor is symmetrical
and positive defined. There are three orthogonal directions, called principal
magnetization directions, having the unit vectors u1 , u 2 , u 3 , for which the
scalar
components
of
vectors
B B1 u1 B2 u 2 B3 u 3 ,
H H1 u1 H 2 u 2 H 3 u 3 and I p I p u1 I p u 2 I p u 3 after
1
B1 1 0 0 H1 I p1
B 0 0 H I .
2
2
2 p2
B3 0 0 3 H 3 I p
3
(2.4.12)
B f H .
(2.4.13)
H
0
Figure 2.4.3
One notices there are nonlinear materials (such as for example some
iron, nickel, cobalt alloys) for which the dependence of the relationship
between the magnetic flux density and the magnetic field strength cannot be
expressed (and not even approximated) analytically. These materials present a
specific phenomena called magnetic hysteresis, which expresses the fact that a
functioning point from the curve which gives the dependence B BH has
coordinates dependent on the succession of states followed to arrive in that
specific point, so it depends on the historical realizations of that state.
42
Below we present, from the qualitative point of view, this phenomena (see
Figure 2.4.4). Starting from an initial state in which the material is not
magnetized, state corresponding to point O0;0 in the plane H; B and
applying a magnetic field with increasing magnetic field strength, one notices
first a nonlinear increase of the magnetic flux density followed by a
saturation plateau until point A1 H max ; Bmax . On this plateau, an increase of
the magnetic field strength does not lead to significant increases of the magnetic
flux density. OA1 curve is called the first magnetization curve.
Figure 2.4.4
When the magnetic field strength is decreased, the values of the magnetic
flux density do not coincide to those corresponding to the first magnetization
curve for the same values of H . The decrease of the magnetic flux density is
realized by applying an increasing magnetic field but opposite as direction to the
initial one. To magnetic field cancellation it corresponds a nonzero remanent
magnetic flux density the functioning point A2 0; Br . The magnetic field that
cancels the magnetic flux density is called coercive magnetic field
functioning point A3 H c ;0 .
43
r,s
B
0 H
tg ;
(2.4.14)
B
H 0 0 H
r , d lim
H 0
tg ;
(2.4.15)
B
H 0 0 H
r , rev lim
H 0
with Max ; .
44
tg ,
A
(2.4.16)
Figure 2.4.5
The curves from Figure 2.4.5 gives us only a qualitative information, that
do not make out the real magnitude order of the ratio between the widths of the
hysteresis cycles. For comparison, we present below the values of the remanent
flux density Br and of the coercive field H c for a few of the soft
ferromagnetic materials, respectively for hard magnetic materials.
Br
H c
A / m
0,6
0,4
0,6
Pure Iron
1,4
0,13
10
45
Br
H c
A / m
1,8
40
0,15
20
Steel (cu 1% C)
0,7
5103
1,1
5103
0,73
34103
0,55
65103
Cobalt Ferrite
0,16
90103
Barium Ferrite
0,35
200103
0,45
260103
One can notice that, for both categories, the magnitude order of the
remanent flux densities is the same, while the values of coercive fields are
slightly different. For example, taking into consideration two materials with the
same value of the remanent flux density, manganese zinc ferrite from the soft
materials category and cobalt ferrite from the hard materials category, one can
notice a ratio between the widths of the hysteresis cycles, expressed by the ratio
of their coercive fields, of 1/4.500.
Finally, its important to mention that the completion of a hysteresis
cycle is accompanied by energy transfer from the magnetic field to the
ferromagnetic body, the volume density of this energy being proportional to
the cycles area (as Warburg theorem proves, theorem that will be presented in a
following chapter of this book).
We also remember that the properties of the ferromagnetic material
are greatly influenced by temperature, these properties even disappearing
for certain limit values of temperature, proper for each material, called
Curie points. Curie point for cobalt is 1.1370 C , for iron is 7530 C , and for
0
nickel is 376 C . Increasing the temperature over the Curie point value
leads to the transformation of ferromagnetic materials into paramagnetic
materials.
46
D 0 E P.
(2.5.1)
As for the magnetic constitutive law, this law has only local form.
Expressing the electric polarization vector P by its two components,
namely the temporary P t and the permanent component P p , the electric
constitutive law has the following form:
D 0 E Pt Pp
(2.5.2)
Pt Pt E .
(2.6.1)
(2.6.2)
47
where the proportionality coefficient e is a material numeric (nondimensional) constant called electric susceptibility, and the electric constitutive
law becomes
D 0 E Pt Pp 0 E 0 e E Pp 0 1 e E Pp .
The numeric quantity
(2.6.3)
r 1 e
is called relative permittivity, and the numeric quantity
(2.6.4)
0 r
is called the absolute permittivity or electric constant.
(2.6.5)
Using these notations, the electric constitutive law has the form
D E P p.
Pp
(2.6.6)
D E Pp
E
E
D E
Figure 2.6.1, a
Figure 2.6.1, b
48
Aggregation state
H2
1,0003
Air
1,0006
O2
1,0006
Gaseous
CO
1,0007
CO2
1,001
CH4
1,001
C2H6
1,0015
Air ( 1910 C )
1,43
2,2
Acetone ( 200 C )
21,2
Ethyl alcohol ( 15 0 C )
26
Liquid
32,5
36
81,1
95
Paraffin
2,2
Polyethylene
2,3
Polyamide
Solid
2,4
Insulant paper
2,4
Bakelite
2,8
Plexiglas
Pressboard
Solid
3,03,6
3,44,3
49
Aggregation state
2,55,0
Rubber
3,06,0
Quartz glass
4,04,2
Porcelain
5,06,5
Solid
ClNa
5,5
Mica
5,07,0
Glass
5,58,0
SO4K2
8,35
Diamond
16,5
For linear and anisotropic materials, one can notice that, if a threeorthogonal coordinate system is taken into consideration, in each point from the
space, each scalar component of temporary electric polarization vector depends,
in principle on all scalar components of electric field strength vector. In a
Cartesian coordinate system, for example, if E E x i E y j E z k ,
P t Pt x i Pt y j Pt z k and
D Dx i D y j D z k , then
Pt 0 e E x 0 e E y 0 e E z
xx
xy
xz
x
Pt y 0 e yx E x 0 e yy E y 0 e yz E z
Pt z 0 e zx E x 0 e zy E y 0 e zz E z .
(2.6.7)
e
xx
e e yx
e
zx
e xy
e yy
e zy
e xz
e yz ,
e zz
(2.6.8)
(2.6.9)
Pt 0 e E
D 0 E Pt P p 0 E 0 e E P p
0
1 E P
e
(2.6.10)
0 r E P p E P p ,
Pp
D E Pp
D E
E
E
Figure 2.6.2, a
Figure 2.6.2, b
D x xx xy xz E x Pp x
P
yy
yz y
py ,
y yx
D
z zx zy zz E z Pp z
(2.6.11)
and it can be noticed that the matrix corresponding got tensor is symmetrical
and positive defined. So, there are three orthogonal directions (called
electrization principal directions), having the unit vectors u1 , u 2 , u 3 for
which the scalar components of the vectors D D1 u1 D2 u 2 D3 u 3 ,
E E1 u1 E2 u 2 E3 u 3 and P p P p u1 P p u 2 P p u 3 with
1
51
D x 1
D y 0
D 0
z
2
0
0 E x Pp x
0 E y Pp y .
3 E z P
pz
(2.6.12)
d S
dt
(2.7.1)
E dl dt B dA.
(2.7.2)
dA
dl
Figure 2.7.1
The electromagnetic induction law has the above form only with the
condition that the reference direction of the closed curve (the reference
direction of the oriented line element dl ) and the direction of the normal to
the surface S (the oriented area element dA ) are associated according to
right corkscrew rule (see Figure 2.7.1).
52
For moving media, the integration domains follows the bodies in their
movement, and the derivative with respect to time of the magnetic flux is a
substantial derivative and it is computed using the following relation:
d
B
dA
div
B
curl
B
w
dA,
t
dt S
(2.7.3)
E dl curl E dA
(2.7.4)
rot B w dA B w dl .
(2.7.5)
and
S
Taking into account the local form (2.2.3) of the magnetic flux law, one
obtains a new integral form of the electromagnetic induction law:
E dl
B
dA B w dl.
(2.7.6)
Relation (2.7.6) emphasizes the physical significance of the law: the time
variable magnetic field produces (induces) an electric field by the
electromagnetic induction phenomena. Therefore, the electromagnetic
induction is a physical phenomena, unlike electric displacement D and
magnetic induction B which are physical quantities.
Moreover, relation (2.7.6) allows the decomposition of the emf into two
components:
u ut um ,
(2.7.7)
with
ut
B
dA
B
dA
(2.7.8)
53
u m B w dl
w B dl
(2.7.9)
curl
w
B
t
dA
curl E dA
(2.7.10)
is valid for any surface S and it imposes the equality of the integrands:
curl E
B
curl w B .
t
(2.7.11)
Relation (2.7.11) represents the local form for continuity domains of the
electromagnetic induction law.
54
B
t
(2.7.12)
B
dA.
(2.7.13)
curl E
curl E 0
(2.7.14)
E dl 0.
(2.7.15)
E grad V .
(2.7.16)
Figure 2.7.2
55
Mj
Mk
Mj
E dl E dl E dl E dl E dl 0
Mk
C1
Mj
C 2
Mj
Mj
Mk
C1
Mk
C 2
(2.7.17)
that is
E dl E dl u M k M j .
Mk
C1
(2.7.18)
Mk
C 2
V M j VM j VM 0
Mj
E dl.
(2.7.19)
M0
56
M0
u P j P0
M0
E dl grad V dl
Mj
Mj
M0
V
V
V
k dx i dy j dz k
x y
Mj
M0
0
V
V
V
dx
dy
dz dV V
Mj
Mj
Mj
M0
(2.7.20)
V M j VM 0 ,
uMk M j
M0
Mj
E dl E dl E dl VM 0
Mk
C3
Mk
M 0 (see Figure
VM0
M0
(2.7.21)
Mj
V M 0 E dl V M 0 E dl V M k V M j ,
M0
M0
Mk
relation which represents the expression of the voltage between any two
points function of their potentials.
If one considers VM 0 0 , it is said that point M 0 is grounded or
earthed and in an electric circuit it has a specific symbol (see Figure 2.7.2).
In these conditions
V M j VM j
M0
E dl.
(2.7.22)
Mj
57
um iS
dS
dt
(2.8.1)
H dl
J dA
d
D dA
dt S
(2.8.2)
which has the above presented form only if the association between the
reference direction of the orientation the oriented line element dl and the
oriented area element dA is according to the corkscrew rule (as for the
electromagnetic induction law).
For moving media, the integration domains follows the bodies in their
movement, following a similar path as the one described for the electromagnetic
induction law, and the integral developed form of magnetic circuit law is
obtained:
H dl curl H dA J dA
div
D
curl
D
w
dA
t
J dA
D
dA
w divD dA curlD w dA ,
58
(2.8.3)
respectively,
u m iS id S
iv S
iR S .
(2.8.4)
iS
J dA;
(2.8.5)
D
dA ,
t
S
(2.8.6)
idS
where
D
Jd
t
(2.8.7)
ivS
w div D dA w v dA,
(2.8.8)
where
w v J v
(2.8.9)
iR S
curlD w dA D w dl .
(2.8.10)
The magnetic circuit law emphasizes two causes that can generate the
magnetic field: conducting bodies transited by conduction currents and/or
time variable electric fields (by displacement currents, convection and
Roentgen currents).
59
For continuity domains, the equality (2.8.3), true for any surface S ,
leads to:
curl H J
D
w v curl D w ,
t
(2.8.11)
relation that represents the local form of the magnetic circuit law.
rot H J
D
t
(2.8.12)
and it shows that the closed lines of the magnetic field surrounds the
conductors transited by conduction currents, respectively the lines of the
time variable electric field that generate them.
In steady state regime the magnetic circuit law becomes the Ampre
theorem, and it has the local form:
curl H J
(2.8.13)
u m is .
(2.8.14)
In the particular cases of the point from the space for which the vector
field H is non-rotational ( curl H 0 ), according to the vector identity which
states that the curl of the gradient of any scalar field is zero, the scalar quantity
Vm , can be introduced, called scalar magnetic potential, using the relation:
H grad Vm .
(2.8.15)
60
dqV
dt
(2.9.1)
By rewriting the relation (2.9.1) one obtains the integral form of the law:
J dA
J dAext
d
v dv
dt V
(2.9.2)
dv
V
Figure 2.9.1
For moving media, the time derivative from relation (2.9.2) is a
substantial derivative, which is computed using the relation:
d
v dv v div w v
dt V
V t
dv,
(2.9.3)
such that the developed integral form of the electric charge conservation law
becomes:
J dA
v
t div w v
V
dv,
(2.9.4)
61
v
t div w v
V
div J dv
dv ,
(2.9.5)
in which
w v J v
(2.9.6)
div J
v
div J v
t
(2.9.7)
v
.
t
(2.9.8)
or
div J J v
div J
v
.
t
(2.9.9)
div J 0 ,
(2.9.10)
(2.9.11)
and it shows that, in this regime, for any closed surface the electric
conduction current is preserved.
The electric charge conservation law underlines from macroscopic point
of view that the electric convection current is generated by moving bodies.
62
(2.10.1)
JJ E .
J E Ei ,
(2.10.2)
F el q0 E
(2.10.3)
63
F neel
0.
F el F neel q0 E F neel q0 E
q
0
(2.10.4)
The term
F neel
Ei
q0
(2.10.5)
has the dimension of an electric field strength and it is called impressed electric
field strength. Impressed electric field is a quantity that capture from the
electric point of view the non electric nature actions upon the charge
carriers from the conductors, in heterogeneous areas of the chemicalphysical properties.
Function on the cause nature that generates them, the impressed electric
fields can be of mechanical, thermal, chemical, etc nature, and function of
space repartition of heterogeneities, the impressed electric field can be
surface or interface (contact) ones.
Relation (2.10.2) can be also written under the form:
E Ei J,
(2.10.6)
1.
(2.10.7)
0 1 0 ,
(2.10.8)
64
In the table below there are presented the values of the resistivity and
of the resistivity temperature variation coefficient for a few of conducting
materials.
at 200 C
103 between
[ mm2 / m ]
00 C and 1000 C
Silver
0,0161
Technical Cooper
0,0175
4,45
Electrolytic Cooper
0,0175
4,4
Gold
0,0237
3,77
Aluminum
0,0278
4,23
0,08
1,5
Platinum
0,0866
2,47
Iron
0,0918
6,25
Nickel
0,138
6,21
Plumb
0,221
4,11
Cooper Nickel
0,4
0,2
Manganin
0,43
0,6
Constantan
0,45
0,4
Retort carbon
7,25
-0,3
Carbon
40 100
-0,2
Uranium Oxide
50 1000
-1,5
0,05 1000
-2,6
Yellow Cooper
Copper Oxide
65
uf
M2
ub
i
M1
Figure 2.10.1, a
Figure 2.10.1, b
Let consider a section from such a filiform conductor, having the area of
the section constant A (see Figure 2.10.1, a), through which flows a current i .
The module of the current density J will be then
66
i
.
A
(2.10.9)
Integrating the local form of the constitutive law of the electric conduction
along the axis C of the conducting section, between the extremities M1 and
M 2 of this section, one obtains:
M2
M2
M2
M2
E E i dl E dl E i dl J dl
M1
M1
M1
C
M2
M1
C
M2
J dl
M1
M1
2
i
dl
dl i
A
A
M
(2.10.10)
because the vectors J and dl are omo-parallel, and the electric conduction
current is along the conductor. In this relation appear the following quantities:
electric voltage along the line:
M2
uf
E dl ;
M1
C
(2.10.11)
uei ei e
E i dl ;
M1
C
(2.10.12)
dl
A.
M1
C
(2.10.13)
So, the integral form of the constitutive law of electric conduction for
filiform conductors is:
u f e R i
(2.10.14)
67
ub
E dl
M1
Cb
(2.10.15)
is called the terminals voltage, and the integral form of the constitutive law of
electric conduction becomes
ub e R i .
(2.10.16)
(2.11.1)
We remark that the sign of the dot product shows the real direction of
the transferred power: from the field towards the conducting body if p 0 ,
respectively from the conducting body towards the field if p 0 .
68
From relation (2.10.6) and (2.11.1) one can obtain a new expression of the
local form of the law, for linear and isotropic conductors:
p J Ei J J E i J .
(2.11.2)
The two terms from the right side of equation (2.11.2) have the following
interpretation:
2
E i and J ; if is the smallest angle between the two vectors, then we can
have the following situations: 0; 2 , so E i J 0 and the power is
transferred from the impressed electric field sources (of the conductor) to
the electromagnetic field or ; , so E i J 0 and the power is
2
transferred from the electromagnetic field to impressed electric field
sources (of the conductor) or 2 and there is no power transfer
p dv E J dv,
(2.11.3)
and the corresponding energy to this phenomena between two time moments t1
and t 2 is
t2
t2
W P dt E J dv dt .
t1
t1
V
(2.11.4)
The measure units S.I. for the quantities p , P and W are, respectively,
watt per cubic meter ( W / m 3 ), watt ( W ) and watt multiplied by second ( W s ).
For a filiform conductor in steady state regime (see Figure 2.10.1,a),
taking into account that dv A dl , it results that the integral relation (2.11.3)
takes the particular form
69
E J dv E J dv E J A dl
E dl u f i ub i Pb ,
(2.11.5)
that shows that the power transferred by the electromagnetic field to the
conducting section in the electric conduction process is equal to the power Pb
called received power at its terminals.
Regarding the physical significance, the law characterizes the thermal
effect of the electromagnetic field, referring to heat producing phenomena
(Joule-Lenz effect) which is associated to the electric conduction current
flow through the conductors, that corresponds to the transformation of
electromagnetic energy into caloric energy.
1 A 2
m
i t dt ,
F0 v t
(2.12.1)
where F0 is a universal constant called Faradays constant, that has the value
F0 96 .484 ,6
C
,
ech.gram
(2.12.2)
A is the mols mass of the deposited substance, and v is the valence of a ion
from the deposited substance.
The ratio A / v is called the chemical equivalent, and its value are
presented in the table below.
70
Atomic mass
Valence
Ag
Chemical
equivalent A / v g
Aluminum
Oxygen
16
Aluminum
27
Magnesium
24
12
Iron 3
55,9
18,6
Nickel
58,6
29,3
Cooper 2
63,2
31,6
Zinc
68,8
34,4
39
39
tin
117,4
58,7
Cooper 1
63,2
63,2
Gold
196,1
65,4
Platinum
194,4
97,2
Mercury
199,8
99,9
Plumb
206,4
103,2
Silver
107,7
107,7
Substance
Potassium
The physical significance of the electrolysis law is that it shows the mass
transport phenomena associated to electric current flow through certain
substances.
The electrolysis process has many practical applications such that electrometallurgy (metal extraction from ore, metal refining, substance preparation
etc.) and galvanotechnics (galvanostegy the coating of some object by nickel
plating, chrome plating, cadmium plating a.s.o and galvanoplasty object
shape reproduction).
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