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Abstract
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MOSFET: metaloxide-semiconductor
eld-effect transistor
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is bulk material without any surface connement effect. In 1968, Colman et al. (21) measured the
-coefcients in p-type inversion layers for the rst time. Two decades later, the rst Si n- and
pMOSFETs with biaxial stress induced by a Si1x Gex buffer layer (Figure 1a) were demonstrated
by Wesler et al. (22) in 1992 and by Nayak et al. (23, 24) in 1993, respectively. A 2.2-times
enhancement in electron mobility and a 1.5-times enhancement in hole mobility were reported.
Uniaxial stress
Tensile nitride
Compressive nitride
Gate
Gate
Stress
Stress
NMOS
Strained Si
STI
PMOS
Biaxial stress
Gate
Source
Drain
Relaxed SiGe
Substrate
Relaxed SiGe
Uniaxial stress
Biaxial stress
Figure 1
(a) Illustration of process-induced uniaxial stress on MOSFETs with a nitride capping layer and biaxial stress
with a relaxed SiGe layer. (b) Four-point and concentric ring wafer bending setup for applying uniaxial and
biaxial stress on the upper surface of the wafer.
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Rim et al. (25) investigated pMOSFET drive current enhancement versus Ge content in Si1x Gex
layers in 1995 and measured the current enhancement for short-channel nMOSFETs in 1998 (26).
In 2005, Lee et al. (27) published a review of the history of and progress in high-mobility biaxially
strained Si, SiGe, and Ge channel MOSFETs.
Even though the predominant focus of the industry in the 1980s and 1990s was on biaxially
stressed devices, the current focus has shifted to uniaxial stress. Uniaxial stress has several advantages over biaxial stress, such as larger mobility enhancements and a smaller shift in threshold
voltage (28). Incorporating uniaxial stress to enhance MOSFET performance was rst introduced
by Ito et al. (29) and Shimizu et al. (30), who used etch-stop nitride (Figure 1a), and by Gannavaram et al. (31), who used SiGe source/drain (S/D) regions, in the early 2000s. Starting at the
90-nm technology node (32), uniaxial stress was successfully integrated into the mainstream MOSFET process ow to improve device performance (3336). Encouraged by the strain-enhanced
planar MOSFETs, researchers recently applied uniaxial stress to multigate devices (3742) with
metal gate and high-k dielectric (43, 44) as a performance booster.
These studies demonstrate that strain achieves higher device performance with extensive industrial application. In the future, the viability of novel structures and channel materials will depend
on their ability to provide device enhancement comparable to strained-Si planar MOSFETs. Thus,
strain will remain a necessary enhancement option even in these devices.
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Unstrained
15:5
<110> uniaxial
compression
Bulk p-type Si
Bulk n-type Si
Unstrained
4
Heavy holes
Light holes
Split-off holes
<110> uniaxial
compression
Unstrained
E
4
2
2
Si pMOSFET
e
Si nMOSFET
Unstrained
Heavy holes
E
k
Light holes
Split-off holes
Figure 2
(a) Simplied conduction band structure change under <110> uniaxial tensile stress for bulk n-type Si and Si (100)-nMOSFETs.
(b) Simplied valence band structure change under <110> uniaxial compressive stress for bulk p-type Si and Si (100)-pMOSFETs. In
the <110> direction, the heavy-hole band (top band ) becomes light-hole like around the point, and the light-hole band (bottom band )
becomes heavy-hole like. The top band is lower in energy and has smaller conductivity effective mass (0.11 m0 for 1 GPa), whereas the
bottom band is higher in energy and has larger conductivity effective mass (0.2 m0 for 1 GPa). Most of the holes repopulate into the top
band, and the mobility is thus enhanced.
occupy the lower-energy 2 valley. Thus, the effective mass change under stress is smaller than
that for bulk Si. Furthermore, surface roughness scattering dominates under typical commercialuse conditions for two-dimensional (2-D) carrier transport, which makes the current transport
in nMOSFETs more difcult to predictably model (56, 57). As a result, the electron mobility
enhancement in strained nMOSFETs is often signicantly different from that in bulk Si.
p-type devices. For unstrained bulk Si, the valence band minimum is located at the point, where
the heavy-hole and light-hole bands are degenerated. The spin-orbit split-off band is located
44 meV below and is thus not important for hole transport (46). In unstressed Si, 80% of the
holes occupy the heavy-hole band, which has an effective mass of 0.59 m0 along the <110>
direction (versus 0.15 m0 for the light-hole band). Under <110> uniaxial compression, which
can be theoretically shown to have the largest enhancement, the degeneracy is lifted, and band
warping occurs, as shown in Figure 2b. At room temperature, band warpinginduced effective
mass reduction is the dominant factor for mobility enhancement in p-type Si under uniaxial
stress (<1 GPa) (9) because the splitting between the top band and the bottom band is small
compared with the Si optical phonon energy (61.3 meV). Thus, the phonon-scattering rate change
is negligible (58).
For unstrained pMOSFETs, however, the degeneracy of the heavy hole and the light hole
is lifted by the surface electric eld connement, as shown in Figure 2b. The splitting between
the heavy-hole band and the light-hole band increases with an increasing gate eld. With typical
device operation (surface effective eld E eff 1 MV cm1 ), the summation of connement-induced
band splitting and strain-induced band splitting can be larger than the optical phonon energy. As
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a result, the optical phonon-scattering reduction under strain becomes signicant and must be
considered. A detailed study on the stress-altered scattering rate is discussed further below.
<110> uniaxial
compression
<100> uniaxial
tension
Biaxial tension
<110> uniaxial
compression
Biaxial tension
Ec
Ec
Ev
Ev
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connement-induced splitting, whereas the <100> uniaxial tension is more complicated because
the 4 valley splits into two energy levels, as shown in Figure 3a. For valence bands, the splitting
due to <110> uniaxial compression is additive to the (100) connement effect, and biaxial tension
is subtractive.
If the stress-induced splitting is subtractive to connement-induced splitting, the mobility
enhancement for MOSFETs is lower than for bulk Si. Thus, for MOSFETs operating under a
high electric eld to benet from strain, it is critical that the chosen stress produce splitting that
is additive to the connement effect.
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b
0.28
0.22
0.2
0.19
0.18
ky
0.17
0.15
m110
110
0.16
0
<110> transverse
tension
0.24
0.5
1.5
Band warping
not considered
0.22
0.2
0.18
<110> longitudinal
tension
0.16
kx
0.14
0.5
1.5
Figure 4
(a) The longitudinal and transverse effective mass of conduction band 2 valley as a function of <110> uniaxial tension. The
intersection shows the 2 subband warping under this stress, which is the reason for the change of effective mass. (b) Conduction band
average transport effective mass change under uniaxial <110> and <110> stress. The blue curve is calculated without the band
warping effect. In this case, both the longitudinal and the transverse stresses cause the same effective mass change.
(1). The potential in the quantum well is simulated by solving the Schrodinger
and Poisson equations self-consistently (62). Figure 6 shows the procedure. First, a reasonable starting potential
such as triangular potential is assumed. This potential is then substituted in the Schrodinger
equation to solve for the wave functions and energy levels, which are used to calculate carrier density.
The resulting carrier density is incorporated into the Poisson equation to get the potential. If the
difference between the calculated potential and the original potential is within a specic criterion,
0.05
Energy (meV)
0.26
m110
Effective mass, m0
Effective mass, m0
0.21
Channel direction
<110>
<110>
0 MPa
0.05
500 MPa
1 GPa
0.1
1.5 GPa
<110> uniaxial compression
0.15
0.1
0.1
Figure 5
Valence band ground-state warping under <110> uniaxial compressive stress. The curves have been
normalized to align at the point for easy comparison of their difference.
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h2
2mx*
n(x) =
n
No
d2
+ Hstrain + qV(x) n(x) = Enn(x)
dx2
m*d kB T
h 2
q
d2
V(x) =
[p(x) n(x) + ND(x)]
dx2
si
n(x), V'(x)
Final result
Figure 6
Introduction of the self-consistence calculation procedure. This method can be used to calculate with greater
accuracy the connement potential, carrier energy level, wave function, and carrier density.
the calculation is nished. If not, the calculated potential is set as the new starting potential, and
the whole process repeats. We use the self-consistent simulation procedure here to produce the
results of the following subsections.
Scattering Mechanisms
As mentioned above (see subsection: Overview of How Strain Affects Carrier Mobility), phonon
scattering and surface roughness scattering are the major scattering mechanisms in strained Si.
Phonon scattering can be categorized to acoustic phonon scattering and optical phonon scattering
based on the phase of the vibration of the two different atoms in one primitive cell. Acoustic phonon
energy is negligible compared with carrier energy, whereas optical phonon energy is approximately
61.3 meV for Si. When strain is applied, the interband optical phonon scattering reduces owing to
band splitting, and the mobility is enhanced. Surface roughness scattering represents the collision
between carriers and the interface. This interaction depends heavily on the roughness of the
interface and is proportional to the square of the vertical electric eld.
The phonon-scattering and surface roughness scattering rates can be calculated from the band
structure obtained by the self-consistent simulation introduced above. Equipartition approximation (63) and two surface roughness assumptions (64) are applied to reduce the complexity of
modeling. Figure 7 shows the dependence of these scattering rates in pMOSFETs on (a) the applied <110> uniaxial compressive stress and (b) the lattice temperature. Optical phonon scattering
dominates at room temperature and signicantly reduces under high stress beyond 1 GPa. At low
temperature, however, surface roughness scattering becomes more important. The existing surface
roughness model works well for pMOSFETs alone (64). For nMOSFETs, only the assumption
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b
3.0E+13
3.0E+13
2.5E+13
2.5E+13
2.0E+13
1.5E+13
1.0E+13
5.0E+12
0.0E+00
2.0E+13
1.5E+13
1.0E+13
5.0E+12
0.0E+00
77
127
177
227
Temperature (K)
277
of increasing smoother interfaces with increasing strain seems to explain the experimental data
(65). An accurate model for the surface roughness scattering in nMOSFETs is still a complex issue
needing resolution.
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b
Occupation of
two-fold valleys (%)
Electron mobility
enhancement
0.7
0.6
0.5
Reference 61
0.4
0.3
0.2
400
100
350
80
300
250
60
200
40
150
100
20
0.1
0
0.5
Stress (GPa)
1.5
0.8
450
120
0.9
500
140
50
0
0.5
Stress (GPa)
1.5
Biaxial tension
<100> uniaxial
<110> uniaxial
Figure 8
(a) Mobility enhancement factors for (100)-surface nMOSFETs under <100> longitudinal, <110> longitudinal, and biaxial tensile
stress. The solid curves represent simulated results from Reference 66. (b) Stress effect on conduction band edge splitting and
ground-state subband occupation. The stress effect determines how fast the enhancement saturation is.
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Hole mobility
(cm2 Vs1)
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300
(110)/<110> uniaxial
(001)/<110> pMOSFET
200
0.15
100
0.15
0.15
kx
0.15
0.15
No stress
<110>
0.15
<110>
(110)/<110> uniaxial
ky
60
40
ky
(001)/<110> uniaxial
20
0.15
0.15
kx
Uniaxial compression
3E+14
1
(001)/<110> uniaxial
2E+14
1E+14
5E+13
(110)/<110> uniaxial
0.15
0.15
kx
Uniaxial compression
2E+14
0E+00
kx
0.15
No stress
80
<111>
ky
100
<110>
Subband occupation
Subband splitting
(meV)
120
(110)/<110> pMOSFET
0.15
ky
(001)/<110> uniaxial
0
<110>
(001)/<110> uniaxial
0.8
(110)/<110> uniaxial
0.6
0.4
Figure 9
(a) Hole mobility as a function of <110> uniaxial compression. (b) Stress effect on valence band ground-state subband structure.
(c) Stress effect on valence band splitting between the ground state and the second subband. (d ) Stress effect on the two-dimensional
density of state of the valence band ground-state subband at the point. (e) Stress effect on valence band ground-state subband
occupation for (100)-surface and (110)-surface pMOSFETs.
were presented. The authors results for long-channel-device enhancement match the theoretical
expectation given above. They also concluded that as the channel length is reduced, 2-D S/D electrostatics lead to a reduction in charge connement in the channel. This reduction in connement
reduces the valley splitting at shorter channel lengths, lowering the anisotropy and reducing the
differences between (110) and (100) substrates.
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b
4
80
<100> uniaxial
Mobility enhancement
factor /
Piezoresistance coefficients
(1012 dyne cm2)
90
70
60
50
Biaxial tension
40
30
<110> uniaxial
20
10
0
0.5
0.6
0.7
0.8
0.9
1.1
1.2
3
2
1
0
Figure 10
(a) Effective eld dependence of (100)-oriented nMOSFET piezoresistance coefcients. (b) Inversion layer carrier density dependence
of (100)/<110> hole mobility under uniaxial compression.
Section Summary
This section presents strain effects on Si band structure, effective mass, and scattering mechanism.
On the basis of this understanding, strain-induced carrier mobility enhancement for both n- and
pMOSFETs with different surface orientations and channel directions was studied. The results
show that (100)/<110> uniaxial stress is the most promising stress for n/pMOSFETs operating
under a high stress level.
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Gate
Source
Drain
Si substrate
Bulk MOSFET
Gate
Source
Si
Source
Gate
Drain
Oxide
Si substrate
Drain
SOI MOSFET
FinFET
Figure 11
Si MOSFETs with different device structures: (a) classical bulk MOSFET; (b) SOI MOSFET; (c) 3-D
FinFET.
device structures and channel materials are being considered as possible solutions. In this section,
we focus on the effect of stress on novel devices such as ultrathin body silicon-on-insulator (UTB
SOI) transistors, multigate FinFETs, and Ge and GaAs channel MOSFETs.
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under low stress, but he observed a larger enhancement for UTB SOI devices under large stress.
At low stress, (100)-oriented pMOSFET mobility is enhanced owing mainly to band warping
induced effective mass lowering, which is the same for SOI and bulk devices. At high stress,
however, phonon-scattering rate reduction caused by increasing subband splitting plays the major
role. Because the additional geometrical connement in UTB SOI devices results in extra subband
splitting, there is larger carrier mobility enhancement than for the classical bulk device at high
stress.
Stress effects on multigate FinFETs. Although SOI technology has better scalability than do
classical bulk Si MOSFETs, it is still impractical to scale the SOI device to the deep sub-20-nm
regime because the lateral electric eld at the drain penetrates into the channel (1, 80, 81). To
improve gate control, multigate FinFETs (Figure 11c) have been investigated as perhaps the most
promising candidates for sub-20-nm technology (8284). Recently, strain effects on double-gate
(DG) and trigate (TG) FinFETs have been studied (8587). Collaert and coworkers (39, 8890)
demonstrated performance enhancement of TG FinFET devices, using supercritical strained
SOI (SC-SSOI) and CESL. Irisawa et al. (37, 42, 91) pointed out the difference between top-gate
and side-wall transport and proposed the optimal strain congurations for n- and p-type FinFETs.
Shin and colleagues (43) and Suthram et al. (41), using wafer bending experiments, studied stress
effects on TG FinFET and DG FinFET, respectively.
Both Sun (58) and Suthram et al. (41) show that for DG FinFETs with large n width (>20 nm),
the mobility enhancement is similar to that for bulk devices with the same surface orientation. For
very narrow FinFETs (<20 nm), the bulk inversion effect (92, 93) caused by geometry connement
becomes signicant, and a strong subband modulation is observed, as illustrated in Figure 12.
This gures shows that in FinFETs, band bending at the Si/SiO2 interface is very small and
that the ground-state subband is much closer to the Fermi level than it is in the bulk device.
Furthermore, the second subband is very close to the ground state, which acts like an increasing
DOS of the ground-state subband. As a result, the amount of carriers that can be affected by
the strain increases, which results in a higher enhancement factor (see Reference 58 for a more
detailed discussion). For strained TG FinFETs, contributions from the top gate and the side walls
should be studied separately because the top gate and side walls have different surface orientations,
but the underlying physics is the same. We expect the TG FinFET with small n width to have
similar behavior as DG FinFET and those with large n widths to have similar behavior as the
bulk device.
Etop
Ev
Etop
Esecond
Ethird
Esecond
Ev
(110) SG MOSFET
DG MOSFET
Figure 12
Comparison between the connement-induced subband splitting of double-gate (DG) and single-gate (SG)
MOSFETs.
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Table 1 Band and transport parameters for Si, Ge, and some III-V semiconductors. Produced with permission from
Reference 45
Eg (eV)
mn
(cm2 /V s)
mhh /mlh
(cm2 /V s)
gmm (norm.)
EL c
ml /mt
(eV)
(L)a
Si
1.12
0.92/0.19
1450
0.53/0.15
500
Ge
0.67
1.59/0.082
3900
0.33/0.043
2270
0.92
InSb
0.17
0.014
7.7 104
0.45/0.016
850
1.9
0.51
1.56/0.094
InAs
0.35
0.024
23.3 104
0.41/0.026
100450
1.29
0.72
1.56/0.094
GaSb
0.73
0.041
3750
0.40/0.05
680
0.28
0.084
0.95/0.11
InP
1.34
0.08
5370
0.6/0.089
150
0.77
0.59
1.9/0.15
GaAs
1.42
0.063
9200
0.5/0.076
400
1.03
0.29
1.9/0.075
Strained
Si
1.08
2900b
2200c
a
These two columns list the L valley data for selected III-V semiconductors. The other data in the table are taken from Reference 96 and from
http://www.ioffe.rssi.ru/SVA/NSM/Semicond/.
b
See Reference 94.
c
See Reference 95.
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1800
Ge
1500
1200
Si0.25Ge0.75
900
Si0.5Ge0.5
Si0.75Ge0.25
600
Si
300
0
Figure 13
Ge, Si, and Si1x Gex hole mobility enhancement of a (100)-oriented device under <110> uniaxial
compressive stress.
on the In mole fraction (120, 121). Because the valence and conduction bands for GaAs, InAs, and
InGaAs are very similar, this subsection focuses on the stress effect on bulk GaAs MOSFETs.
Suthram et al. (121) applied uniaxial and biaxial stress on GaAs n- and pMOSFETs and extracted
the corresponding -coefcients. Their results show that the enhancement of uniaxially stressed
nMOS saturates at very low stress (with a maximum of 6% enhancement in drive current at
75 MPa), whereas a linear trend is seen under biaxial stress (6% enhancement in drive current
per 100 MPa). This phenomenon can be explained by stress-induced electron repopulation among
different valleys (107). GaAs has energetically adjacent multivalley conduction bands: , L, and
X valleys. Electron mobility in the valley is much higher than that in the L valley or X valley.
Under applied biaxial stress, the conduction band valleys shift as shown in Figure 14a, and the
splitting between the and L valleys increases, causing more electrons to repopulate to the loweffective-mass valley and thus enhance mobility. Uniaxial strain, however, splits the L valleys
into two groups, as shown in Figure 14b. The lower L valleys shift faster downward with the
uniaxial stress than does the valley. Thus, valley occupation turns lower. But the splitting of
the L valley also lowers the DOS of each group to one-half of the original value. As a result, the
band shift and DOS reduction of the lower L valley render a saturation of electron occupation
in the valley at a specic stress. Beyond that value, the occupation of valley decreases. As a
summary, we see a monotonic increase in electron mobility with biaxial stress, whereas we see an
increase, a saturation, and then a decrease in electron mobility with uniaxial stress.
GaAs valence bands have a similar structure to that of Si valence bands. The self-consistent
simulation that uses the k p method shows a similar hole mobility enhancement factor for both
GaAs and Si under <110> uniaxial compression (12), as shown in Figure 15. However, data from
experiment (121) show a two-times-larger enhancement in GaAs than in Si. The discrepancy may
be due to the surface quality of the GaAs MOSFETs, for which the simulation assumes an interface
quality comparable to that of Si/SiO2 .
Section Summary
This section reviews strain effects on the carrier mobility of nonclassical MOSFETs. The major
conclusions are as follows:
1. Carrier mobility in UTB SOI devices has a similar enhancement under low stress as bulk Si
devices and a larger enhancement under high stress than bulk Si devices owing to the fact
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a Biaxial tension
b Uniaxial tension
hydro
hydro
hydro
shear
hydro
shear
hydro
80
80
valley
valley
60
40
L valley
20
60
L valley
20
X valley
X valley
0
0.1
0.5
0.5
1.5
0
0.1
0.5
0.5
1.5
Figure 14
Theoretical estimation of the effect of (a) biaxial stress, (b) uniaxial stress on a GaAs conduction band and the predicted carrier
population changes in the , L, and X valleys.
400
hydro
shear
Si
300
200
GaAs
100
Figure 15
Hole mobilities of Si and GaAs as a function of <110> uniaxial compressive stress. Both devices show a
similar mobility enhancement factor.
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that the extra subband splitting caused by geometrical connement in UTB SOI results in
a larger phonon-scattering rate reduction.
2. Wide FinFETs have a similar mobility enhancement as bulk Si devices with the same surface
orientation, whereas narrow FinFETs have a larger enhancement. This is because of the
strong subband modulation caused by geometry connement increasing the amount of
carriers that can be affected by the strain.
3. Ge and Si1x Gex pMOSFETs have the same strained behavior as Si MOSFETs, but the
enhancement saturates at higher stress.
4. n-type GaAs MOSFETs benet from biaxial stress owing to the monotonic increase in
splitting between the and L valleys under biaxial stress. As with the k p method, p-type
GaAs devices have a similar enhancement factor under <110> uniaxial compression to that
of Si channel MOSFETs.
ANRV380-MR39-09
Future
technology node
90-nm node
2003
65-nm node
2005
50-nm length
IEDM 2002
30-nm length
IEDM 2002
32-nm node
2009
22-nm node
2011
Figure 16
222
45-nm node
2007
20-nm length
VLSI 2001
15-nm length
IEDM 2001
10-nm length
ITJ 2002
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by the combination of strain technology with high-k dielectric and a metal gate. Recently, even
35-nm pMOSFETs with strained Si channels have been demonstrated (124).
CONCLUSION
During the past decade, strain has been the dominant technique to successfully enhance device
performance. With its high performance gain and low cost, strain has been introduced into different devices to achieve further improvements in drivability. In this article, we focus on the physical
insights of strain-enhanced carrier mobility and provide key results. We thus demonstrate that
with proper strain, the performance of MOSFETs with different device structures and channel materials can be boosted. On the basis of this knowledge, incorporating high-level strain to improve
novel devices with ultrashort channels is proposed to be the future mission in this eld.
SUMMARY POINTS
1. Owing to surface electric eld connement, the carrier mobility enhancement in
MOSFETs can signicantly differ from that in bulk Si material depending on whether
connement-induced subband splitting and stress-induced subband splitting are additive
or subtractive.
2. For (100)-oriented nMOSFETs under high stress, <110> uniaxial tension yields the
highest mobility enhancement, owing mainly to 2 subband warping.
3. For (100)-oriented pMOSFETs, <110> uniaxial compression is the best stress conguration. (110) pMOSFETs have less enhancement than do (100)-surface devices because
of the smaller change in conductivity effective mass.
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4. Compared with classical bulk MOSFETs, UTB SOI devices and FinFETs have a similar
or larger enhancement under stress. A smaller device geometry results in a larger increase
in mobility.
5. Ge and GaAs channel pMOSFETs have similar strained behavior as their Si counterparts.
Electron mobility in GaAs nMOSFETs increases only under biaxial tensile stress.
FUTURE ISSUES
Annu. Rev. Mater. Res. 2009.39:203-229. Downloaded from www.annualreviews.org
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DISCLOSURE STATEMENT
The authors are not aware of any afliations, memberships, funding, or nancial holdings that
might be perceived as affecting the objectivity of this review.
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Current Interest
Chameleon Coatings: Adaptive Surfaces to Reduce Friction and Wear
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C. Muratore and A.A. Voevodin p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p p 297
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