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Isopropyl Alcohol evaporates very quickly to leave a dry and clean surface while being flammable and harmful if swallowed - in sensible hands it is an
amazingly useful and versatile product.
Oxygenates
Published octane values vary a lot because the rating conditions are
significantly different to standard conditions, for example the API
Project
45 numbers used above for the hydrocarbons, reported in 1957, gave
MTBE
blending RON as 148 and MON as 146, however that was partly based on
the
lead response, whereas today we use MTBE in place of lead.
methanol
ethanol
iso propyl alcohol
methyl tertiary butyl ether
ethyl tertiary butyl ether
tertiary amyl methyl ether
133
129
118
116
118
111
:
:
:
:
:
:
105
102
98
103
102
98
:
:
:
:
:
:
65
78
82
55
72
86
:
:
:
:
:
:
0.796
0.794
0.790
0.745
0.745
0.776
: 385
: 365
: 399
:
:
:
of the VOC emissions when they react with NOx, and is being
introduced as a
regulatory means of ensuring that automobile emissions do actually
reduce
smog formation. The ozone-forming potential of chemicals is defined
as the
number of molecules of ozone formed per VOC carbon atom, and this is
called
the Incremental Reactivity. Typical values ( big is bad :-) ) are
[74]:
Maximum Incremental Reactivities as mg Ozone / mg VOC
alkanes
olefins
aromatics
oxygenates
carbon monoxide
methane
ethane
propane
n-butane
ethylene
propylene
1,3 butadiene
benzene
toluene
meta-xylene
1,3,5-trimethyl benzene
methanol
ethanol
MTBE
ETBE
0.054
0.0148
0.25
0.48
1.02
7.29
9.40
10.89
0.42
2.73
8.15
10.12
0.56
1.34
0.62
1.98
and 91 unleaded will give 94. Some blends of oxygenated fuels with
ordinary
gasoline can result in undesirable increases in volatility due to
volatile
azeotropes, and some oxygenates can have negative lead responses.
The octane
requirement of some engines is determined by the need to avoid runon, not
to avoid knock.
6.16 What happens if I use the wrong octane fuel?
If you use a fuel with an octane rating below the requirement of the
engine,
the management system may move the engine settings into an area of
less
efficient combustion, resulting in reduced power and reduced fuel
economy.
You will be losing both money and driveability. If you use a fuel
with an
octane rating higher than what the engine can use, you are just
wasting
money by paying for octane that you can not utilise. The additive
packages
are matched to the engines using the fuel, for example intake valve
deposit
control additive concentrations may be increased in the premium
octane grade.
If your vehicle does not have a knock sensor, then using a fuel with
an
octane rating significantly below the octane requirement of the
engine means
that the little men with hammers will gleefully pummel your engine
to pieces.
You should initially be guided by the vehicle manufacturer's
recommendations,
however you can experiment, as the variations in vehicle tolerances
can
mean that Octane Number Requirement for a given vehicle model can
range
over 6 Octane Numbers. Caution should be used, and remember to
compensate
if the conditions change, such as carrying more people or driving in
different ambient conditions. You can often reduce the octane of the
fuel
you use in winter because the temperature decrease and possible
humidity
changes may significantly reduce the octane requirement of the
engine.
Recent
in both
methane
(MJ/kg)
(MJ/kg)
120
120
0.5094
50.0
propane
112
97
0.4253
46.2
iso100
100
1950
0.45
1925
0.45
0.30
0.26
5.0
2.1
15.0
9.5
540 - 630
450
1980
415
Over 2 million tonnes of IPA are produced annually, mainly in the US, Europe and
Japan.
Refineries can produce considerable quantities of propylene and this can be the
immediate precursor to the production of IPA.
IPA is identified as an acceptable additive for Euro-3 and Euro-4 fuel specifications.
Modelling in the literature review and analysis report identified ethanol and IPA (at
10%)
as the best alcohols for approaching the 95 RON target. There has been no visible
18
interest expressed by Australian Petroleum Industry members to use IPA, with lack
of
infrastructure a particular problem.
Environmental and health issues
While IPA is suspected as having a range of health effects, no pertinent data on the
fate
of IPA in the environment is available. However, as a secondary alcohol IPA is likely
to
degrade more slowly than ethanol (a primary alcohol) but faster than TBA (a tertiary
alcohol).
Spectrum Laboratories Inc reports that IPA would not be very long lived in natural
waters, and if released to this environment would volatilise (estimated half-life
approximately 5.4 days) and biodegrade. IPA would not be expected to adsorb to
sediment or bioconcentrate.
Vehicle operability issues
No data presented.
Effect on fuel specifications
No data presented.
Proposed management
Based on the information at hand, the Commonwealth proposes not to regulate the
use of
It is likely that the use of higher alcohols (propanols, butanols) in Australian petrol
will
be constrained by supply. However, they may make an occasional contribution in
selected instances.
Environmental and health issues
The literature review and analysis found no pertinent data available on the
environmental
fate of these chemicals. However, if released to soil they would be expected to leach
to
groundwater or to biodegrade. Volatilisation from the soil surface may also occur.
None of these alcohols are expected to bind strongly to soil and would be expected to
move into the water compartment where they would biodegrade.
As linear alcohols, n-propanol and n-butanol are likely to degrade quickly. Isobutanol
and sec-butanol are expected to degrade more slowly than ethanol but faster than
TBA.
Use
Over 2 million tonnes of IPA are produced annually, mainly in the US, Europe and
Japan. Refineries can produce considerable quantities of propylene and this can be the
immediate precursor to the production of IPA.
IPA is identified as an acceptable additive for Euro-3 and Euro-4 fuel specifications.
Modelling in the literature review and analysis report identified ethanol and IPA (at
10%) as the best alcohols for approaching the 95 RON target. There has been no
visible interest expressed by Australian Petroleum Industry members to use IPA, with
"lack of infrastructure" a particular problem.
Environmental and health issues
While IPA is suspected as having a range of health effects, no pertinent data on the
fate of IPA in the environment is available. However, as a secondary alcohol IPA is
likely to degrade more slowly than ethanol (a primary alcohol) but faster than TBA (a
tertiary alcohol).
Spectrum Laboratories Inc reports that IPA would not be very long lived in natural
waters, and if released to this environment would volatilise (estimated half-life
approximately 5.4 days) and biodegrade. IPA would not be expected to adsorb to
sediment or bioconcentrate.
Vehicle operability issues
No data presented.
Dear Bob: R.M. from Overland Park, Kan., asked about adding isopropyl
alcohol in lieu of a dry-gas additive. You mentioned that he could use either
the 50-percent or the 70-percent solution of isopropyl alcohol.
I recommend that you rethink this advice.
I completely agree that isopropyl alcohol is the preferred substitute for dry gas
today, because many -- though not all -- dry-gas compounds contain methyl
alcohol, which can be corrosive. Not so isopropyl alcohol.
But a c
ar owner should never use the isopropyl alcohol sold in drug stores,
because these solutions are made with water, and of course we don't
want to add water to our gasoline. A chemical-supply house would be the
safest way to obtain pure, high-grade isopropyl alcohol for use in the fuel
tank.
Thank you, Bob.
-- Rev. J.M., Kansas City, Mo.
A: Don't thank me, Reverend, thank yourself and others like you for bringing
this to my attention. Read on.
Dear Bob: I find it hard to understand why you are advising people to put
water in their gas tanks! Don't you realize that commercial isopropyl-alcohol
products have water in them?
A 50-percent solution in a 12-ounce bottle would contain 6 ounces of water.
Isn't the purpose of adding a dry-gas product to remove water from the tank,
rather than to add water to it?
Walgreen's sells a 91-percent solution of isopropyl alcohol, which I imagine
would be much better than using a 50-percent solution, as you
recommended.
Sincerely,
-- R.K., Liberty Lake, Wash.
Dear Bob: In a recent article you said that one could use isopropyl alcohol -rubbing alcohol -- to replace commercial dry-gas products.
I thought that alcohol was added to gas to disperse any water that might be
present. Rubbing alcohol is 70 percent alcohol, and a good share of the other
30 percent is water.
Wouldn't adding rubbing alcohol have an adverse effect because of the water
it contains? Am I missing something?
Sincerely,
R.H., via e-mail
A: No, you're not missing something. I goofed! I was careless here: I received
an electronic heads-up alert about this subject, and the recommended
procedure was exactly as I outlined -- mistakenly, as it turns out.
I should have said to use pure isopropyl alcohol (IPA), anhydrous or
waterfree, which normally can't be purchased at a drug store. However, Dick
Baumgart of Valvoline research tells me that Wal-Mart sells a 16-ounce
container of 99-percent-pure IPA -- that's as close to pure as you can get -for $3.74.
Mr. Baumgart also notes that the products sold in auto stores are 100-percent
IPA or methyl alcohol, with nothing added except, in some products, a
corrosion inhibitor. Both IPA and methyl alcohol are soluble in water and,
while they work differently, both prevent the water in the system from freezing.
IPA additives work by holding some water in solution, then burning it off in the
combustion chamber. Methyl-alcohol additives work by drawing the water to
the bottom of the tank, out of harm's way. Fuel-tank sloshing then will permit
small amounts to be drawn into the fuel system, where it will burn off.
With near-pure Wal-Mart or pure chemical-house IPA, you won't be getting
the corrosion inhibitor included in many gas-line antifreeze additives. All told,
therefore, you gain very little by using these, and probably lose by not having
the corrosion inhibitor. My choice: a good IPA additive with corrosion inhibitor.
And with the aches and pains I've endured because of all this, feel free to
send those leftover bottles of 50-percent rubbing alcohol along to me. Lord
knows, I need a good rubdown after all the hassle!
AMERICAN DRIVERS FIGHT BACK
Here's a tip that will help you get better gas mileage while fighting terrorism
and cutting our nation's dependence on Mideastern oil:
The next time you are shopping for a car or truck, consider buying a dieselpowered vehicle. The U.S. Department of Transportation reports that a diesel
is generally much more efficient than a conventional gasoline engine.
The smallest engine that provides adequate performance to meet your needs
-- acceleration, hill climbing, trailer towing -- will also provide the best fuel
economy, the department's advisory says. In general, a 10-percent increase
in the size of the engine increases fuel usage by 6 percent. Diesel engines
can provide as much as a 25-percent increase in fuel economy, compared to
gasoline engines of the same size