Propiedades Fsicas de Gases

Componente

Frmula

Tf
(K)

Tb
(K)

Tc
(K)

Pc
(bar)

Vc
(cm /mol)
3

Zc

Cp=A+BT+CT2+DT3 [=]jul/molK; T[=]K

A
B
C
D

28.01

68.10

81.61

133.40

35.0

93.10 0.294 0.066

30.8424 -1.284E-02

Dixido de Carbono

CO
CO2

44.01

216.56

194.65

304.20

73.9

94.80 0.275 0.239

19.7740

Nitrgeno

N2

28.01

63.30

77.40

126.20

33.9

89.80 0.290 0.039

31.1500 -1.357E-02

2.680E-05 -1.168E-08

Agua

H2O

18.02

273.20

373.20

647.30

221.2

57.10 0.235 0.344

32.2400

1.924E-03

1.055E-05 -3.596E-09

Oxgeno

O2

32.00

54.40

90.20

154.60

50.4

73.40 0.288 0.025

28.1100 -3.680E-06

1.746E-05 -1.065E-08

Acido sulfhdrico

H2S

34.08

189.60

213.50

373.20

89.4

98.60 0.284 0.081

31.9400

1.432E-05

2.432E-05 -1.176E-08

Metano

CH4

16.04

90.70

111.62

190.70

46.3

98.90 0.288 0.011

25.3596

1.687E-02

7.131E-05 -4.084E-08

Etano

C2H6

30.07

89.90

184.63

305.40

48.8

145.70 0.285 0.099

8.1814

Propano

C3H8

44.10

85.50

231.14

369.70

42.5

198.60 0.279 0.153

-5.3379

3.102E-01 -1.646E-04

3.469E-08

n-Butano

n-C4H10

58.12

134.80

272.98

425.60

37.6

255.00 0.274 0.199

-1.7792

3.870E-01 -1.933E-04

3.483E-08

i-Butano

i-C4H10

58.12

113.60

261.52

407.70

36.8

263.10 0.283 0.183 -10.8533

4.305E-01 -2.516E-04

5.945E-08

n-Pentano

n-C5H12

72.15

143.40

309.22

470.00

33.6

310.60 0.267 0.251

-3.4107

4.850E-01 -2.519E-04

4.868E-08

i-Pentano

i-C5H12

72.15

113.30

301.15

461.10

33.4

307.40 0.270 0.227 -11.2901

5.161E-01 -2.880E-04

6.386E-08

n-Hexano

n-C6H14

86.18

177.80

341.93

507.90

30.2

368.40 0.264 0.299

-4.7384

5.824E-01 -3.106E-04

6.292E-08

n-Heptano

n-C7H16

100.20

182.60

371.56

540.10

27.4

428.10 0.262 0.349

-5.6191

6.769E-01 -3.639E-04

7.407E-08

Monx. de Carbono

Componente

Frmula

LnP=VPA-VPB/(VPC+T); P=mmHg, T=K

VPA

VPB

VPC

Tmx

Tmn

ZrA

CO
CO2

14.3686

530.22

-13.15

108

63

0.2896

Dixido de Carbono

22.5898

3103.39

-0.16

204

154

0.2722

Nitrgeno

N2

14.9542

580.72

-6.60

90

54

0.2900

Agua

H2O

18.3036

3816.44

-46.13

441

284

0.2338

Oxgeno

O2

15.4075

734.55

-6.45

100

63

0.2905

Acido sulfhdrico

H2S

16.1040

1768.69

-26.06

230

190

0.2855

Metano

CH4

15.2243

597.84

-7.16

120

93

0.2892

Etano

C2H6

15.6637

1511.42

-17.16

199

130

0.2808

Propano

C3H8

15.7260

1872.46

-25.16

249

164

0.2766

n-Butano

n-C4H10

15.6782

2154.90

-34.42

290

195

0.2730

i-Butano

i-C4H10

15.5381

2032.73

-33.15

280

187

0.2754

n-Pentano

n-C5H12

15.8333

2477.07

-39.94

330

220

0.2684

i-Pentano

i-C5H12

15.6338

2348.67

-40.05

322

216

0.2717

n-Hexano

n-C6H14

15.8366

2697.55

-48.78

370

245

0.2635

n-Heptano

n-C7H16

15.8737

2911.32

-56.51

400

270

0.2604

Monx. de Carbono

2.788E-05 -1.271E-08

7.337E-02 -5.602E-05

1.716E-08

1.615E-01 -4.007E-05 -6.942E-09

Propiedades Fsicas de Gases

Componente Frmula
Monxido de C CO

=a+bT+cT2+dT3
b

Unidades
de:

0.0322800

4.747E-04 -9.648E-08 =poise, T=K

0.0001210

Dixido de C

CO2

0.0254500

4.549E-04 -8.649E-08 =poise, T=K

-0.0172300

Nitrgeno

N2

0.0304300

4.989E-04 -1.093E-07 =poise, T=K

Agua

H2O

0.0001476

Oxgeno
Benceno

O2

k=a+bT+cT2+dT3
b
c
2.179E-04 -8.416E-08

Unidades
de:

1.958E-11 k=cal/s-cm-K, T=K

1.308E-08

-2.514E-11 k=cal/s-cm-K, T=K

0.0009359

2.344E-04 -1.210E-08

3.591E-11 k=cal/s-cm-K, T=K

4.955E-06 -1.543E-10 =lbf-s/ft ,T=F

0.0084940

2.495E-01

0.0181100
-0.0157600

6.632E-04 -1.879E-07 =poise, T=K

3.245E-04 -7.232E-08 =poise, T=K

-0.0007816
-0.0201900

2.380E-05 -8.939E-08 2.324E-11 k=cal/s-cm-K, T=K

8.640E-06 2.340E-08 -9.690E-12 k=cal/s-cm-K, T=K

1.914E-04

7.891E-05

0.000E+00 k=Btu/hr-ft-R, T=F

Metano

C6H6
CH4

0.0159600

3.439E-04 -8.140E-09 =poise, T=K

-0.0044630

2.084E-04

2.815E-07

-8.631E-11 k=cal/s-cm-K, T=K

Etano

C2H6

0.0055760

3.064E-03 -5.307E-08 =poise, T=K

-0.0000758

5.257E-04 -4.593E-07

3.974E-10 k=cal/s-cm-K, T=K

Propano

C3H8

0.0049120

2.712E-04 -3.806E-08 =poise, T=K

0.0044380

-1.122E-05

n-Butano

n-C4H10

-0.2997100

6.361E-01 -8.318E-05 =lbm/h-ft,T=K

-0.0052197

4.031E-01

2.710E-04

0.000E+00 k=Btu/hr-ft-R, T=K

i-Butano

i-C4H10

3.0891000
0.0033244

6.238E-01 -6.836E-05 =lbm/h-ft,T=K

7.043E-06 -5.602E-09 =lbf-s/ft2,T=K

-0.0089848
0.0133950

6.069E-01 2.578E-05
1.954E-02 0.000E+00

0.000E+00 k=Btu/hr-ft-R, T=K

0.000E+00 k=Btu/hr-ft-R, T=K

Aire
Componente Frmula
Monxido de C CO

cP=a+bT+cT2+dT3
b
c

Unidades
de:

Href

5.198E-07 -2.008E-10 k=cal/s-cm-K, T=K

h=a+bT+cT2+dT3
a
b

Unidades de:
c

0.99921

9.921E-01

8.581E-04

0.000E+00 cP=kJ/kg-K, T=K

-16131(300K)

-17422.0

4.179E-01

4.173E-01 h=Btu/lbm,T=K, a 14.7Psia

Dixido de C

CO2

0.53459

1.187E-03 -4.899E-03

0.000E+00 cP=kJ/kg-K, T=K

61322(500K)

16148.0

7.857E-01

2.407E+00 h=kJ/kg, T=K, a 0.1MPa

Nitrgeno

N2

10165.0

3.011E-01

1.198E-04

0.000E+00 cP=kJ/kg-K, T=K

46025(300K)

12558.0

1.102E+04

0.000E+00 h=kJ/kg, T=K, a 0.1MPa

Agua

H2O

0.52467 -2.144E+00

2.984E-03

-9.363E-08 cp=Btu/lbm-R,T=F

12793(500F)

10585.0

4.367E-01

3.984E-01 h=Btu/lbm,T=F, a 10Psia

Oxgeno
Benceno

O2

0.81249
-0.25481

3.772E+00 -9.923E-04
5.025E-03 -2.083E-02

0.000E+00 cP=kJ/kg-K, T=K

0.000E+00 cP=kJ/kg-K, T=K

46573(300K)
7607(511k)

2005.0
48293.0

8.444E-01
3.077E-01

1.295E+00 h=kJ/kg, T=K, a 0.1MPa

4.665E+00 h=Btu/lbm,T=K, a 14.7Psia

Metano

C6H6
CH4

10306.0

4.175E-03 -7.159E-03

0.000E+00 cP=kJ/kg-K, T=K

98469(300k)

32524.0

2.221E+04

0.000E+00 h=kJ/kg, T=K, a 0.1MPa

Etano

C2H6

0.23647

5.607E-03 -1.765E-02

0.000E+00 cP=kJ/kg-K, T=K

76174(300K)

41031.0

5.787E-01

1.998E-03 h=kJ/kg, T=K, a 0.1MPa

Propano

C3H8

0.06595

6.040E-03 -2.140E-02

0.000E+00 cP=kJ/kg-K, T=K

52102(300k)

27201.0

4.726E-01

2.087E-03 h=kJ/kg, T=K, a 0.1MPa

n-Butano

n-C4H10

2.43340

1.545E-03 -6.304E-03

0.000E+00 cp=Btu/lbm-R,T=K

59765(300k)

25575.0

5.621E-01

1.976E-03 h=kJ/kg, T=K, a 0.1MPa

i-Butano

i-C4H10

0.02139
0.23878

1.437E-03 -5.093E-04
1.538E-01 0.000E+00

0.000E+00 cp=Btu/lbm-R,T=K
0.000E+00 cp=Btu/lbm-R,T=K

63195(340K)

23212.0
16859.0

4.732E-01
9.394E-01

2.092E-03 h=kJ/kg, T=K, a 0.1MPa

9.666E-01 h=kJ/kg, T=K, a 0.1MPa

Aire

45985(300k)

COMPOSICIN DEL GAS NATURAL PRODUCIDO EN ALGUNOS CAMPOS BOLIVIANOS

COMPONENTE

RIO
GRANDE

SIRARI

VBORA

CARRASCO

SAN

VUELTA

ROQUE

GRANDE

PORVENIR

PORCENTAJE MOLAR

N2
CO2
C1
C2
C3
i-C4
n-C4
i-C5
n-C5
C6
C7+
TOTAL
Peso Molecular

28.01
44.01
16.04
30.07
44.10
58.12
58.12
72.15
72.15
86.18
100.20

COLPA

LA
VERTIENTE

PIRAYMIRI

CARANDA

1.850
0.941
92.316
4.502
0.349
0.002
0.010
0.005
0.007
0.003
0.015
100.000

0.583
0.079
87.047
7.134
3.088
0.431
0.842
0.262
0.233
0.184
0.117
100.000

2.546
0.623
85.380
6.343
3.103
0.372
0.919
0.215
0.252
0.141
0.106
100.000

0.310
5.790
86.110
7.230
0.510
0.020
0.010
0.010
0.010
0.000
0.000
100.000

1.540
0.010
86.150
7.330
3.200
0.400
0.830
0.190
0.180
0.100
0.070
100.000

1.790
0.060
88.010
9.140
0.930
0.030
0.030
0.010
0.000
0.000
0.000
100.000

1.310
0.110
86.550
6.970
3.240
0.980
0.440
0.150
0.170
0.060
0.020
100.000

0.910
1.300
86.490
7.200
2.850
0.310
0.490
0.190
0.140
0.090
0.030
100.000

2.210
0.060
86.920
6.580
2.860
0.350
0.660
0.150
0.130
0.060
0.020
100.000

0.270
0.000
83.310
10.900
4.030
0.420
0.780
0.130
0.110
0.040
0.010
100.000

1.670
0.800
85.400
8.060
1.650
0.370
0.970
0.160
0.520
0.360
0.040
100.000

17.2835

19.0427

19.2755

18.8804

19.0102

17.8478

18.9531

18.9350

18.6906

19.4108

19.2916

Gravedad Espec.

0.5967

0.6575

0.6655

0.6519

0.6564

0.6162

0.65438

0.65376

0.6453

0.67014

0.66603

GPM, Prepano+

0.11224

1.56370

1.53980

0.15720

1.47910

0.27860

1.49900

1.20950

1.24370

1.59634

1.28773

Valor C Bruto

1022.68

1159.61

1125.98

1012.26

1143.85

1076.4

1142.01

1117.88

1114.37

1190.16

1139.81

H2S

NO EXISTE H2S EN NINGO DE LOS CAMPOS

COMPOSICIN
PROMEDIO

1.363
0.888
86.698
7.399
2.346
0.335
0.544
0.134
0.159
0.094
0.039
100.000
18.7837
0.64850
1.08451
1101.69

Densidad
Lb/pie3 Lbmol/gal

31.636
35.123
36.442
38.981
39.381
41.423
51.380

GPM

0.09591
0.08079
0.08382
0.07223
0.07297
0.06426
0.06855

1000 n xi M i
gal /1000Pie3
379.6 i 3 i

M i Peso Molecular

i Densidad (lb/gal)

PODER CALORIFICO DE COMPONENTES DEL GAS NATURAL

Componente

Frmula

Gravedad

Poder Calorfico
Ideal (60 F,1at)

Goi

Hi (BTU/pie3)

Composicin Especfica Ideal

x

Factor de
Compresibilidad (a
60 F,1at) Z

Nitrgeno

N2

0.0000

0.9672

0.99973

Dixido de Carbono

CO2

0.0000

1.5195

0.99432

Metano

CH4

0.9200

0.5539

1009.7

0.99810

Etano

C2H6

0.0500

1.0382

1768.8

0.99160

Propano

C3H8

0.0200

1.5225

2517.5

0.98200

i-Butano

i-C4H10

0.0000

2.0068

3252.7

0.96960

n-Butano

n-C4H10

0.0100

2.0068

3262.1

0.96670

i-Pentano

i-C5H12

0.0000

2.4911

4000.3

0.94820

n-Pentano

n-C5H12

0.0000

2.4911

4009.6

0.94350

n-Hexano

n-C6H14

0.0000

2.9753

4756.2

0.92000

n-Heptano

n-C7H16

0.0000

3.4596

5502.8

0.92000

Acido sulfhdrico
Total

H2S

1.1765

637.0

0.99030

Ho=

1100.34

Hr=

1103.01

Z=

0.997579

Go=

0.61202

Gr=

0.61326

1.00000

Poder calorfico del gas natural: H 0 xi H 0 i

Poder Calorfico del gas real:

Factor de comprensibilidad:

Hr

H0
Z

Z 1-

i 1

Gravedad especfica del gas ideal: G 0 x iG0i

bi

2 xH xH2 0.0005

G
Gravedad especfica del gas real: G r 0 0.9996
Z

AL
Factor
sumatorio

b
0.0164

0.000

0.0640

0.000

0.0436

89.000

0.89

0.0917

9.000

0.09

0.1342

1.500

0.015

0.1744

0.000

0.1825

0.500

0.005

0.2276

0.000

0.2377

0.000

0.2830

0.000

0.2830

0.000

0.0985

BTU/pie3

9792.05145 Kcal/m3

BTU/pie3

9815.8178 Kcal/m3

0.997139