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MATERIAL SAFETY DATA SHEET

SECTION I . PRODUCT IDENTIFICATION

-_. - - ---

product Nam!):

Synonym(s):

Product Use:

WHMIS Class:

DOT Classification:

TOG Classification:

ManufacturerlSuppl ier:

RFCCU Equilibrium Catalyst FCC Equilibrium Catalyst FCC Regenerated Catalyst Catalyst

Class D - Division 2A, 2B

Not regulated as dangerous goods. Not regulated as dangerous goods. Irving Oil Refining G.P.

Box 1260

Saint John, NB E2L 4H6 CA Phone: (506) 202-2000 Refinery: (506) 202-3000

Emergency Phone: 1-800-424-9300 (CHEMTREC)

LEGEND HMIS/NFPA

Severe Serious Moderate Slight Minimal

SECTION II - HAZARDOUS INGREDIENTS

Ingredient(s) Mullite

Zeolite

Lanthanum oxide (La203) Titanium oxide

Antimony trioxide Magnesium oxide

Nickel (II) oxide Silica-crystalline, quartz Sodium sulfate

Vanadium pentoxide

Zinc oxide

W.J WCta Q:2I:1A EELS A~~II:HL...'i ~ Q[ill L.C:2!1
1302-93-8 30 - 60 Not established Not established Not available Not available
76774-74-8 30 - 60 Not established .Not established 0.6 mgl1l4h rat Not available
1312-81-8 3-7 Not established Not established Not available 8500.0001 mglkg rat
13463-67-7 0.5-1.5 15 mglm3 - TWA 10 mglm3 - TWA Not available 24000 mglkg rat
1309-64-4 < 1 Not established Not established Not available > 34600 mgJkg rat
1309-48-4 <1 15 mglm3 - TWA 10 mglm3 - TWA Not available Not available
1313-99-1 < 1 Not established Not established Not available 5000,0001 mglkg rat
14808-60- 7 < 1 0.1 mg/m3 - TWA 0.1 mglm3 - TWA Not available SOD mg/kg rat
7757-82-6 < 1 Not established Not established Not available 10000 mgikg ral;
5989 mglkg mouse
1314-62-1 c 1 0.5 mglm3 - CEIL 0.05mglm3 - TW A 2.21 mgll14h rat 23 mg/kg mouse; 10
mg/kg rat
1314-13-2 < 1 5mglm3- TWA 2 mglm3 - TWA; 10 Not available 7950 mg/kg mouse;
mg/m3- STEL 5000 mglkg rat SECTION III . PHYSICAL DATA

BoilinQ Point: Not available Specific Gravity: 0.8 (bulk)
Fraezlna Point: Not available Coefficient of Water/Oil Not applicable
Vapor Pressure: Not available Distribu1ion:
Vapor Densitv: Not available % Volatile: Not applicable
Solubility in Water: Insoluble Evaporation Rate: Not applicable
Physical State: Solid pH: 4 - 7 @ 20·C
Appearance: dark grey Powder Viscosity: Not available
Odor: Mineral-oil-like Odor Threshold: Not available SECTION IV - FIRE AND EXPLOSION DATA.

Flammability:

Flash Point:

Hazardous Combustion Prcducts:

Autoignition Temperature:

Explosion Data:

Not flammable by WHMIS/OSHA criteria.

Not applicable LEL: Not applicable

UEL: Not applicable

May include and are not limited to: Oxides of carbon. Nickel carbonyl. Corrosive vapours.

Not applicable

Sensitivity to Mechanical Impact:

Not expected to be sensitive to rnecnanlcal impact.

Sensitivity to Static Discharge:

Means of Extinction:

Special Fire Hazards:

Not expected to be sensitive to static discharge. Treat for surrounding material.

Firefighters should wear a self-contained breathing apparatus. Some components may burn if heated to very high temperatures.

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SECTION V - REACTIVITY DATA

Incompatible Materials:

conditions for Chemical Instability: Stable under recommended storage conditions.

Reactivity, and Under What Conditions:

Hazardous Decomposition Products:

Acids. Caustics. Oxidizers. Chlorinated products. Fluorinated materials. Bromine trifluoride. lithium

Do not mix with other chemicals.

May include and are not limited to: Nickel carbonyl. Orthophosphoric acid. Oxides of carbon.

SECTION VI - TOXICOLOGICAL PROPERTIES

Route of Entry: Eye, Skin contact, Inhalation, Ingestion.

EFFECTS OF ACUTE EXPOSURE:

May cause irritation.

Contact with skin can cause irritation and allergic reaction (sensitization) in some individuals.

This product may cause metal fume fever with resulting flu-like symptoms. Excessive intentional inhalation may cause respiratory tract irritation and central

nervous system effects (headache, dizziness).

Ingestion: May cause stomach distress, nausea or vomiting.

EFFECTS OF CHRONIC EXPOSURE:

Eye:

Skin:

Inhalation:

Prolonged or repeated exposure can cause drying, defatting and dermatitis.

Prolonged or repeated exposure to fine airborne crystalline silica dust may cause severe 'scarring of the lungs, a disease called silicosis. Early symptoms of silicosis include cough, mucous production and shortness of breath upon exertion.

Skin: Prolonged or repeated exposure can cause drying, defatting and dermatitis.

Irritancy:

Respiratory Tract Sensitization:

Carcinogenicity:

Teratogenicity:

Mutagenicity:

Reproductive Effects:

Synergistic Materials:

Skin. eyes, respiratory tract.

May cause respiratory and skin sensitization. People with asthma or other lung problems may be more susceptible.

Contains potential carcinogens.

High concentrations of pigment-grade (powdered) and ultrafine titanium dioxide (titanium oxide) dust have caused resptratory tract cancer in rats exposed by inhalation and lntratracheal instillation.

Non-hazardous by WHMIS/OSHA criteria.

Contains potential mutagens.

Contains a potential reproductive toxin. Not available

SECTION VII - PREVENTATIVE MEASURES

Gloves:

Eye Protection:

Respiratory Protection:

Other Protective Equipment:

Engi neering Controls:

Leak and Spill Procedure:

Waste Disposal:

Hand!!ng Rsqutrements:

Storage Requirements:

Rubber gloves. Confirm with a reputable supplier first. Wear safety glasses with side shields.

In case of brief exposure or low concentration, use an air-filtering cartridge respirator, For longer exposures or higher concentrations, use an air-supplied respirator. The recommended filter device for short term use is a Pi00 filter.

If clothing or footwear becomes contaminated with the product, remove it and completely decontaminate It before re-use, or discard it.

Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. General ventilation

normally adequate. .

Before attempting clean up, refer to hazard data given above. Use broom or dry vacuum to collect material for proper disposal without raising dust. Rinse area with water. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice.

Dispose in accordance with all applicable regulations.

USE! good industrial hygiene practices in handling this material. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. Although the product is not flammable, when pouring powder into a container of flammable liquid. ground both containers electrically to prevent a static spark.

Keep out of reach of children. Store in a closed container away from incompatible materials.

May be stored at ambient temperatures.

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RFCCO Equilibrium Catalyst (03019)

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SECTION VIII ~ FIRST AID

inhalation:

Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists.

Flush with cool water. Wash with soap and water. Obtain medical attention if irritation persists.

If symptoms develop move victim to fresh air. if symptoms persist, obtain medica! attention.

Eye:

Skin:

Ingestion: .. +De-not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth if victim Is unconscious, or is convulsing. Obtain medical attention.

SECTION IX· PREPARATION INFORMATION

Effective Date: 01-Sep-2009 Expiry Date: 01-Sep-2012 Issue Date: 13-0ct-2009

Prepared By: Dell Tech Laboratories Ltd. (519) 858-5021

For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. .

Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been mace to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to Ihe requlrernents of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses. injuries or consequential damages which may result from the use of or reliance on any information contained in this document.

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RFCCO Equilibrium Catalyst (03019) TlJTAL P.03

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The C~emioaICompany· ...

Material Safety Data Sheet

MSDS Code: EC-1880-3

ALL FLUID CRACKING CATALYSTS (SERIES): 5,OOO-1(),OOO Series, Controlefin™, Dimension™, DynasivTM, EC, Endurance™, Flexeat™, Flex-Tee™, Flex-Tee II, HEZTM, IMP, L Grades, Magnasiv™, Maximum

Propylene Solution, Maxol™, Miliennium™, MPS Series, NaphthaMax™, NaphthaMaxTM II, Octasiv™, Octidyne™, PetroMax™, peG Grades, Preeision™, Reduxion™, Syntec™, Ultrium™, Vektor™, X

I Grades

Revision date:

02108/07

Date Printed:

06/13/07

NFP A Classification:

Health:

Flammability:

Instability:

Special Hazards:

o o o

HMIS Classification:

Health:

Flammability:

Physical Hazard:

Personal Protection:

1 • o

o A

• indicates possible chronic health effects.

Common Name:

Chemical Name:

Clay Processed For Catalyzing Purposes, Processed Clay, Synthetic Clay Chemical Mixture

Product Use:

Petroleum catalyst.

Supplier:

BASF Catalysts LLC 100 Campus Drive Florham Park, NJ 07932

For Chemical Emergency Call:

BASF Hotline: 1-800-832-H ELP CHEMTREC (24 hours):

1-800-424-9300 (US, Canada, Puerto Rico, Virgin islands) 1-703-527-3887 (Outside Above Area)

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MSDS code: EC-1880-3 Revision date: 02108/07

B ASF - The Chemical Company M a terial Safety Data Sheet

1- Ingredient Weight in Percent (%) Notes ]
CAS Number -~ ~-- 1------- - -
kare Earth Oxide 0-9 None.
Calcium Oxide 0-5 None.
1305-78-8
Magnesium Oxide 0-9 None.
1309·48-4
I Phosphorus Compound 0-4 None.
Kaolin 20-80 'Naturally occurring chemical substance per TSCA, 40 CFR
f----. 1332-58-7 710.4{b).
Silica 0-25 None.
7631-86-9
Aluminum Oxide 0-25 None.
1344-28-1 Emergency Overview:

Color:

Form:

Odor:

Flash Point, ·C:

White

Powder Odorless Nonflammable

Most important Hazards: Prolonged Oi repeated exposure to dust may cause pulmonary problems. Contact wilh eyes and skin may result in irritation. Inhalation may result in respiratory irritation. May be harmful if large amounts are swallowed. May cause pain, nausea, vomiting and diarrhea.

Potential Health Effects:

Inhalation:

May cause irritation of the respiratory tract. May result in coughing, difficulty breathing and sore throat.

Ingestion:

May cause irritation if large amounts are ingested. May cause pain, nausea, vomiting and diarrhea.

Skin Contact:

May cause skin irritation.

Eye Contact:

May irritate eyes.

Carcinogenicity:

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BASF - The Chemical Company Material Safety Data Sheet

MSDS code: EC-1880-3 Revision date: 02/08/07

i Ingredient Weight in NTP IARC OSHA ACGIH
CAS Number Percent (YIN) (See Notes) (YIN) (See Notes)
("!o)
Rare Earth Oxide o·g N N N N
Calcium Oxide 0-5 N N N N
1305-78-8
Magnesium Oxide 0-9 N N N A4
1309-48-4
Phosphorus Compound 0-4 N N N N
Kaolin 20-80 N N N A4
1332-58-7
Silica 0-25 N N3 N N
7631-86-9
Aluminum Oxide 0-25 N N N A4
i344-28-1 Notes:

IARC: Y1 =Carcinogenic to humans; Y2A=Probably carcinogenic to humans; Y28=Possibly carcinogenic to humans; N3=Not classifiable as to its carcinogenicity', N=Not studied or probably not carcinogenic.

ACGIH: A1=Canfirmed human carcinogen; A2=Suspected human carcinogen; A3o:Confirmed animal carcinogen; A4=Not classifiable as a human carcinogen; A5=Not suspected as a human carcinogen; N=Not studied.

Chronic Health Hazards:

Prolonged or repeated exposure to dust may cause pulmonary problems, May cause benign pneumoconiosis. Long-term exposure, to extremely high levels of dust, may result in progressive fibrosis with lung function impairment. Chronic exposure to dust, vapor or fume may cause headache, nausea, sensitivity to heat, itching and an increased awareness of odor and taste.

Aggravated Medical Conditions: Pulmonary disorders. Dermal ailments. Allergies.

Inhalation:

Move person to fresh air. If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician.

Procedures normally not needed. If large amounts are ingested, and person is conscious and able to swallow, give large amounts of water to dilute, Get medical attention.

Ingestion:

Skin Contact:

Flush skin with large amounts of water. If irritation persists, get medical attention. Remove contaminated clothing and launder before reuse,

Eye Contact:

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

Flash Point, ·C:

Autoignition Temperature, ·C:

Lower Explosive Limit, %:

Upper Explosive Limit, %:

Nonflammable Not Applicable Not Applicable Not Applicable

Extinguishing Media:

Nona- does not burn. Use extinguishing media appropriate for surrounding fire.

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BASF - The Chemical Company MSDS code: EC-1880-3

Material Safety Data Sheet Revision date: 02108107

~---------~------------.---------------------------------------------------

Fire Fighting Procedures:

None required; however, when fighting chemical fires, self-contained breathing apparatus and protective clothing is recommended.

Not a fire or explosion hazard.

Unusual Fire and Expl<lsion Hazards:

Spill Procedures:

Scoop up or vacuum into a container for reclamation or disposal. Avoid dusting.

Store in a cool, dry location away from incompatible materials.

• Material may be slippery when wet.

• Minimize dust generation and exposure.

• Avoid contact with eyes, skin and clothing.

• Wash thoroughly after handling.

• Use with adequate ventilation.

, 0 "

OSHA PEL

ACGtH TLV

Ingredient CAS Number

Kaie c:artn xice - None sa IS eo ;,one cS\8 liS lEHl
Calcium Oxide 0-5 5 mg/m3 2 mglm3
1305-78-8
Magnesium Oxide 0-9 15 mg/m3 (Total particulate) 10 mglmJ (Inhaiable fraction)
1309-48-4
Phosphorus Compound 0-4 None Established None Established
Kaolin 20-80 15 mg/mJ (Total dust) 2 mg/m3 (Respirable fraction)
1332-58-7 5 mg/mJ (Respirable fraction)
Silica 0-25 20 mppcf or 80 mg/ml + %Si02 10 mgfml (lnhalable fraction)
7631·86·9 3 mg/m3 (Respirable fraction)
\ Aluminum Oxide 0-25 15 mg/m3 (Total dust) 10 mg/m3
1344-28-1 5 mg/m3 (Respirable dust)
I E t bll h .

r- < b" r: r!

Unless otherwise noted. all values are reported as 8-hour Time-Weighted Averages [TWAs) and total dust (particulates only). All ACGIH TLVs refer to the 2006 standards. Unless otherwise noted, all OSHA PEls refer to 29 CFR Part 1910 Air Contaminants: Final Rule, June 30, 1993.

PEL TLV Notes: Toxicology testing has indicated that an exposure limit of 5 mg/m3 (time weighted average) for respirable particles would be appropriate for this material,

Personal Protective Equipment: Safety giasses wilh side shields. Wear suitable gloves,

Respif(!(¢r~y Protection: Use approved respiratory protection if exposure Hmits are exc~ded, or overexposure is likely. If respiratory protection is used, follow Gill requirements for respiratory programs set forth in OSHA regulations (29 CFR 1910.134).

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BASF • The Chemical Company Material Safety Data Sheet

MSDS code: EC-1BBO-3 Revision date: 02/0B/07

Ventilation:

General ventilation. Local exhaust ventilation is recommended to control exposures to within applicabte limits.

Form:

Color:

Odor:

Powder White Odorless

Bulk Density:

Solubility (in water):

O.6-1.1g/cc Insoluble

Stability Data:

Conditions/Hazards to Avoid:

Stable

Temperatures above 250°C.

Strong acids. Strong oxidizing agents. Ammonia. Nitrates.

Incompatibility (Materials to Avoid):

Hazardous Decomposition Products:

Polymerization:

None antlclpated.

Information on Product:

Acute Toxlclty- Inhalation: Whole-body inhalation toxicity studies in young adult Sprague-Dawley rats have indicated that the 4-hour LC50 for this material is greater than 5 mg/l.

Information on Components:

Ingredient Weight in Acute Toxicity • Acute Toxlclty- Acute Toxicity- Acute Toxicity-
CAS Number Percent Oral Inhalation Dermal Other
(%)
Rare Earth Oxide 0-9 > 9,968 mg/kg Not Available Not Available Not Available
(rat)
Calcium Oxide 0-5 Not Available Not Available Not Available Not Available
1305-78-8
Magnesium Oxide 0-9 Not Available Not Available Not Available Not Available
1309-48-4
Phosphorus Compound 0-4 > 5 g1kg (mouse) Not Available Not Available Not Available
Kaolin 20-80 > 5,000 mg/kg Not Available Not Available Not Available
1332-58-7 (rat)
Silica 0-25 3,160 mg/kg (rat) Not Available Not Available Not Available
7631-86-9
Aluminum Oxide 0-25 Not Available Not Available Not Available Not Available
1344-28-1 51 8

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I BASF· The Chemical Company Material Safety Data Sheet

MSDS code: EC-1880-3 Revision date: 02/08/07

Information on Product:

Environmental Fate:

No data available.

Mobility:

Ecotoxicological Information:

Not relevant. Insoluble in water.

No data available.

US EPA Waste Number: Not Regulated

Disposal of Waste Method: This product, if disposed as received, is a non-hazardous waste. Spent material may be contaminated and may require special disposal methods. Local disposal laws and regulations will determine the proper waste disposal/recycling/reclamation procedure. Disposal requirements are dependent on the hazard classification and will vary by location and the type of disposal selected.

International Transport Regulations:

ICAO Class: Not Regulated

IMO Class: Not Regulated

US Tr:'\nspnrtation Regulations:

DOT Classification: Not Regulated

Canadian Transportation of Dangerous Goods (TDG):

TOG Classification: Not Regulated

International Inventories; United States:

Canada:

Europe:

Japan:

Australia:

Korea:

Philippines:

China:

This product or Its ingredients are listed on or compliant with the TSCA Inventory. This product or its ingredients are listed on or compliant with the OSLo

This product or its ingredients are listed on or compliant with EINECS.

Not Determined

This product or its ingredients are listed on or compliant with AJCS. This product or its ingredients are listed on or compliant with the EeL. This product or its ingredients are listed on or compliant with PICCS. Not Determined

US Federal Regulations:

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BASF • The Chemical Company
MClterial Safety Data Sheet

Ingredient Weight i
CAS Number
Rare Earth Oxide
Calcium Oxide
1305-78-8
Magnesium Oxide
1309-48·4
Phosphorus Compound
Kaolin
1332-58-7
Silica
7631-86-9
Aluminum Oxide
1344-28-1
SARA 311/312 Hazard Categories:
Acute Health Hazard Chroni
eAA 602 Ozone Oepleting Substanc
This product neither contains nor is ma
requirements of the Clean Air Act Ame
US State Regulations:

VOC Content (CARS): Not Det
QSlnagian B~g!.llaliQns:
WHMIS Classification:
Class D Division 2 Subdivision B
This product has been classified in accordan
MSDS contains all the information required b
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MSDS code: EC-1880-3 Revision date: 02/08/07

n Percent (%)

0-4

Subject to SARA 313 Reporting

No

0-9

No

0-5

No

O-g

No

No

20-80

No

0-25

No

c Health Hazard

es (O~S):

nufactured with an ozone depleting substance subject to the labeling ndments 1990 and 40 CFR Part 82.

ermined

ce with the hazard criteria of the Controlled Products Regulations and the y the Controlled Products Regulations.

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MSDS code: EC-1880-3 Revision date: 02JOaf07

BASF - The Chemical Company Material Safety Data Sheet

Revision number:

37

Section(s) Revised in this Version:

Product Name

Section 1: Chemical Product and Company Identification

Corporate Environmental Health & Safety Group

Prepared By:

IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KINO, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OURTERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS. DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF ·HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESUL TS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.

END OF DATA SHEET

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