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D Electrochemical Series
Electrochemical
Series
K
MORE ELECTROPOSITIVE
Na
Easier to release electrons to form a
Ca positive ion (cation)
Mg
Al
Zn
Fe
Sn
Pb
Cu
Ag
Metal X Metal Y
Electrolyte
Chapter 6 39 Electrochemistry
4541 CHEMISTRY Chapter 6
Positive
Pair of metal Voltage Negative
Termina
X/Y (V) Terminal
l
Mg / Cu 2.7 Cu Mg
Zn / Cu 1.1 Cu Zn
Fe / Cu 0.8 Cu Fe
Pb / Cu 0.5 Cu Pb
Cu / Cu 0.0 - -
• The greater the voltage produced, the further is the separation of the paired metals in the
Electrochemical Series.
• Metals which have a higher tendency to ionise (higher position in the Electrochemical Series)
will be the negative terminal.
• Metals which have a lower tendency to ionise (lower position in the Electrochemical Series)
will be the positive terminal.
Mg
2.7 V
Zn
The tendency
for metals to
ionise is Fe 1.1 V
increase
0.8 V
Pb
0.5 V
Cu
Sample question :
Table below shows the voltage and positive terminal of three chemical cells.
Which of the following is the correct arrangment of the metals in the Electrochemical Series
starting with the most electropositive metal?
A P, Q, R, S
B Q, P, R, S
C Q, R, S, P
Chapter 6 40 Electrochemistry
4541 CHEMISTRY Chapter 6
D S, R, P, Q
II : The capability of metals to displace other metals from its salt solution.
(Displacement reaction)
Metal P
Activity 19 :-
By using the Electrochemical Series, complete the table below :
Metal
Solution
Cu Pb Fe Zn Mg
Cu(NO3)2
Pb(NO3)2
FeSO4
ZnSO4
MgSO4
Total √
Chapter 6 41 Electrochemistry
4541 CHEMISTRY Chapter 6
Activity 20 :-
Experiment I II III
Set up of
apparatus L M M
• Grey • Grey • No
deposit deposit change
Observation
• Colour • Light
less solution blue solution
Inferences :
Experiment I :
(a) L can/cannot* displace silver from silver nitrate solution.
(b) L is more/less* electropositive than silver.
(c) The position of L is higher/lower* than silver in the Electrochemical Series.
Experiment II :
(d) M can/cannot* displace silver from silver nitrate solution.
(e) M is more/less* electropositive than silver.
(f) The position of M is higher/lower* than silver in the Electrochemical Series.
Experiment III :
(g) M can/cannot* displace L from silver nitrate solution.
(h) M is more/less* electropositive than L.
(i) The position of M is higher/lower* than L in the Electrochemical Series.
Conclusion :
The order of the three metals is :
Increasing of electropositivity
P, Q, R, S
Decreasing order of electropositivity
Chapter 6 42 Electrochemistry
4541 CHEMISTRY Chapter 6
Activity 21 :-
Predict and mark the positive and negative terminals for the following cells :
V V
Ag Zn Mg Cu
Chapter 6 43 Electrochemistry
AgNO3(aq) CuSO4(aq)
4541 CHEMISTRY Chapter 6
The further the distance between two metals in the Electrochemical Series, the
higher the voltage of the chemical cell.
Activity 22 :-
Compare the voltage produced (V1, V2, V3 and V4) by the voltaic cell below :
V1 V2
Cu Pb Zn Cu
V3 V4
Cu Ag Ag Mg
More electropositive metal can displace a less electropositive metal from its salt
solution.
[ Metals placed higher up in the Electrochemical Series is able to displace metals
placed below them from their salt solutions ]
Example :
Zn plate
(i) zinc metal + copper(II) sulphate solution
CuSO4(aq)
Zn + CuSO4 → Zn SO4 + Cu
Observation :
2+ Zinc is more electropositive than copper
Zn → Zn + 2e Zinc plate becomes
Zinc corrodes
thinner
Brown solid formed
Chapter 6 44 Electrochemistry
Blue solution
becomes colourless
4541 CHEMISTRY Chapter 6
Zn + Cu2+ → Zn2+ + Cu
Activity 23 :-
Chapter 6 45 Electrochemistry
4541 CHEMISTRY Chapter 6
Activity 24 :-
Analyse the electrolysis of 0.1 mol dm-3 sodium nitrate solution, using carbon electrodes.
Carbon electrode
Chapter 6 46 Electrochemistry
4541 CHEMISTRY Chapter 6
Activity 25 :-
Importance
of
Electrochemical Series
Chapter 6 47 Electrochemistry
4541 CHEMISTRY Chapter 6
Activity 26 :-
State the example of pollution caused by industries processes involving electrolysis.
Pollution
endanger our health. Therefore, these wastes must be ……………. ……………… and
Chapter 6 48 Electrochemistry
4541 CHEMISTRY Chapter 6
END OF CHAPTER 6
Chapter 6 49 Electrochemistry