FISA TEHNICA DE SECURITATE conform directivei 2001/

58/CE

DuPont™ SUVA® 404A Refrigerant

Versiune 2.1
Data revizuirii 12.04.2006 Ref. 130000000494

$FHDVW ILú FX1RUPHGH7HKQLFDúL6HFXULWDWHD0XQFLLDIRVWHODERUDW FRQIRUPOHJLVOD LHLURPkQHúLDUSXWHDV QX

vQGHSOLQHDVF UHJOHPHQW ULOHGLQDOWH UL

,'(17,),&$5($68%67$1 (,35(3$5$78/8,&+,0,&3(5,&8/26ù,$),50(,6$8,175(35,1'(5,,

,QIRUPD LLGHVSUHSURGXV
™ ®
Denumirea produsului : DuPont SUVA 404A Refrigerant

Types : ASHRAE Refrigerant number designation: R-404A

Folosirea : refrigerent
VXEVWDQ HLSUHSDUDUH

Societatea : Du Pont de Nemours (Nederland) B.V.

Baanhoekweg 22
NL-3313 LA Dordrecht
The Netherlands

Telefon : +31-78-630.1011

Fax : +31-78-630.1181

Telefon îQFD]GHXUJHQ : +44-(0)8456-006.640

&2032=, ,$,1)250$ ,,'(635(,1*5(',(17(

'HQXPLUHFKLPLF Nr. CAS Nr.CE Clasificare &RQFHQWUD LH [%]

1,1,1-Trifluoroethane (R143a) 420-46-2 206-996-5 F+; R12 52

Pentafluoroethane (R125) 354-33-6 206-557-8 44

1,1,1,2-Tetrafluoroethane (R134a) 811-97-2 212-377-0 4
3HQWUXWH[WXOFRPSOHWDOIUD]HORU5PHQ LRQDWHvQDFHVWSDUDJUDIVHYDFRQVXOWDSDUDJUDIXO

3. IDENTIFICAREA PERICOLELOR

(YDSRUDUHDUDSLG DOLFKLGXOXLSRDWHSURYRFDGHJHU WXUL

9DSRULLVXQWPDLJUHLGHFkWDHUXOúLSRWSURYRFDVXIRFDUHDSULQUHGXFHUHDR[LJHQXOXLQHFHVDUUHVSLUD LHL

0 685,'(35,0$-8725

,QGLFD LLJHQHUDOH : ÌQFD]GHLQFRQúWLHQ VHYDFXOFDSHUVRDQDvQSR]L LHODWHUDO VWDELO úLVHYD

consulta un medic. 1LFLRGDW QXVHYDvQFHUFDV VHIRU H]HRSHUVRDQ 
LQFRQVWLHQW V vQJKLW  ÌQFD]GHUHVSLUD LHQHUHJXODW VDXGHVWRSUHVSLUDWRULX
VHYDDSOLFDUHVSLUD LHDUWLILFLDO  'DF VLPSWRPHOHSHUVLVW Ve va chema un
medic.

Inhalare : 6HYDLHúLODDHUFXUDW 6HYDFXOFDSHUVRDQDUHVSHFWLY úLVHYD LQHODF OGXU 

5HVSLUD LHDUWLILFLDO úLVDXDGPLQLVWUDUHDGHR[LJHQSRWILQHFHVDUH

Contact cu pielea : 6HYDVS ODFXDS FDOG  Se vor scoate imediat toate hainele contaminate.

1/5
FISA TEHNICA DE SECURITATE conform directivei 2001/
58/CE

DuPont™ SUVA® 404A Refrigerant

Versiune 2.1
Data revizuirii 12.04.2006 Ref. 130000000494

Contact cu ochii : 6HYDVS ODELQHFXPXOW DS LQFOXVLYVXESOHRDSH Se va consulta un medic.

,QGLFD LLSHQWUXPHGLFL
Tratament : 1XVHYDDGPLQLVWUDDGUHQDOLQ VDXPHGLFDPHQWHVLPLODUH

0 685,'(&20%$7(5($,1&(1',,/25

Riscuri specifice în timpul : FUHúWHUHGHSUHVLXQH

luptei împotriva incendiilor

(FKLSDPHQWGHSURWHF LH : În cazul unui incendiu, se va purta un aparat respirator autonom.

special pentru pompieri

,QIRUPD LLVXSOLPHQWDUH : 6HYRUIRORVLPHWRGHGHVWLQJHUHDGHFYDWHFRQGL LLORUORFDOHúLPHGLXOXL

vQFRQMXU WRU 6HYRUU FLUHFLSLHQWHOHUH]HUYRDUHOHFXMHWGHDS 

0 685,,03OTRIVA PIERDERILOR ACCIDENTALE

0 VXULGHSUHYHGHUH : Se va evacua personalul în zone sigure. 6HYDYHQWLOD]RQDUHVSHFWLY  A se

individuale YHGHDP VXULOHGHSURWHF LHGLQFDSLWROHOHúL

0 VXULGHSUHYHGHUHSHQWUX : 1XYDILHOLEHUDWLQPHGLXOvQFRQMXU WRU

mediu

0HWRGHGHFXU LUH : 6HHYDSRU 

0$1,38/$5(ù,'(32=,7$5(

Manipulare
Sfaturi de manipulare în : 6HYD SUHYHGHDRUHvPSURVS WDUH DDHUXOXLúLVDXR YHQWLOD LHFRUHVSXQ] toare
FRQGL LLGHVHFXULWDWH ODORFXOGHPXQF  3HQWUXSURWHF LDLQGLYLGXDO DVHYHGHDSDUDJUDIXO

0 VXULGHSURWHF LH : 1XVXQWQHFHVDUHP VXULVSHFLDOHGHOXSW vPSRWULYDLQFHQGLLORU

vPSRWULYDLQFHQGLXOXLúLD
exploziei

Depozitare
&HULQ HSHQWUXVSD iile de : 6HYDS VWUDFRQWDLQHUXOHUPHWLFvQFKLVvQWU-XQORFXVFDWúLELQHYHQWLODW Se va
GHSR]LWDUHúLFRQWDLQHUH depozita în containerul original.

0 VXULGHSURWHF LHvQFD]XO : 1XVXQWGHPHQ LRQDWPDWHULDOHvQ mod special.

GHSR]LW ULLvQORFXULFRPXQH

Clasa de depozitare : 2A : Gaz comprimt, sub presiune sau lichefiat

JHUPDQ

&21752/8/(;381(5,,3527(& ,(3(5621$/$

2/5
FISA TEHNICA DE SECURITATE conform directivei 2001/
58/CE

DuPont™ SUVA® 404A Refrigerant

Versiune 2.1
Data revizuirii 12.04.2006 Ref. 130000000494

0 VXULGHRUGLQWHKQLF
6HYDDVLJXUDYHQWLOD LHFRUHVSXQ] WRDUHvQVSHFLDOvQORFXULOHvQFKLVH

(FKLSDPHQWGHSURWHF LHDSHUVRQDOXOXL
3URWHF LHUHVSLUDWRULH : 6HYDIRORVLXQDSDUDWUHVSLUDWRUDXWRQRPSHQWUXRSHUD LLGHVDOYDUHúL
vQWUH LQHUHvQFXYHOHGHVWRFDUH 9DSRULLVXQWPDLJUHLGHFkWDHUXOúLSRWSURYRFD
sufocarea prin reducerea oxigenului nHFHVDUUHVSLUD LHL

3URWHF LDPkLQLORU : P QXúLDQWLWHUPLFH

3URWHF LDRFKLORU : RFKHODULGHSURWHF LH

0 VXULGHLJLHQ : 6HYDPDQLSXODFRQIRUPQRUPHORUGHLJLHQ LQGXVWULDOHúLDQRUPHORUGH

securitate.

35235,(7 I FIZICO-CHIMICE

)RUP : Gaz lichefiat,

Culoare : incolor,

Miros : eterat,

pH : neutru

Punct/domeniu de fierbere : -46,7 °C

Punct de aprindere : QXVWU OXFHúWH

'HVFRPSXQHUHWHUPLF : 728 °C,

Presiune de vapori : 12 340 hPa la 25 °C

Presiune de vapori : 23 100 hPa la 50 °C

Densitate : 1,05 g/cm3 la 25 °C, VXEIRUP GHOLFKLG

67$%,/,7$7(ù,5($&7,9,7$7(

&RQGL LLGHHYLWDW : 3URGXVXOQXHVWHLQIODPDELOvQDHUODWHPSHUDWXU úLSUHVLXQHQRUPDOH

,QIRUPD LLGHVSUHSURGXúLGH : halogenuri de hidrogen, bioxid de carbon (CO2), Monoxid de carbon,

GHVFRPSXQHUHSRWHQ LDO florocarburi, halogenuri de carbonil
SHULFXORúL

,1)250$ ,,72;,&2/2*,&(
7R[LFLWDWHDFXW ODLQKDODUH
• 1,1,1-Trifluoroethane : LC50/ 4 h/ úRERODQ : > 1 855 mg/l
(R143a)
• Pentafluoroethane (R125) : ALC/ 4 h/ úRERODQ : > 3 480 mg/l

3/5
FISA TEHNICA DE SECURITATE conform directivei 2001/
58/CE

DuPont™ SUVA® 404A Refrigerant

Versiune 2.1
Data revizuirii 12.04.2006 Ref. 130000000494

• 1,1,1,2-Tetrafluoroethane : LC50/ 4 h/ úRERODQ : > 2 085 mg/l

(R134a)
(YDOXDUHDFDUFLQRJHQLFLW LL : Nu a prezentat efecte cancerigene în decursul experimentelor pe animale.

(YDOXDUHDFDUFLQRJHQLFLW LL
• 1,1,1-Trifluoroethane : 7HVWHOHSHDQLPDOHQXDXDU WDWQLFLXQIHOGHHIHFWHFDQFHULJHQH
(R143a)
7R[LFLWDWHvQFD]XOHYDOX ULL : ([SHULPHQWHOHSHDQLPDOHQXDXHYLGHQ iat efecte mutagene sau teratogene.
reproducerii

7R[LFLWDWHvQFD]XOHYDOX ULLUHSURGXFHULL
• 1,1,1-Trifluoroethane : ([SHULPHQWHOHSHDQLPDOHQXDXHYLGHQ LDWHIHFWHPXWDJHQHVDXWHUDWRJHQH
(R143a)
([SHULHQ DXPDQ : ([SXQHUHDH[FHVLY SRDWHDIHFWDV Q WDWHDXPDQ GXS FXPXUPHD] 

Inhalare
LQVXILFLHQ UHVSLUDWRULHJUDY QDUFR] $FWLYLWDWHFDUGLDF QHUHJXODW

,QIRUPD LLVXSOLPHQWDUH : (YDSRUDUHDUDSLG DOLFKLGXOXLSRDWHSURYRFDGHJHU WXUL

,1)250$ ,,(&2/2*,&(

7R[LFLWDWHSHQWUXSHúWL
• 1,1,1,2-Tetrafluoroethane : LC50 / 96 h/ 2QFRUK\QFKXVP\NLVV3 VWU YFXUFXEHX : 450 mg/l
(R134a)

7R[LFLWDWHDFYDWLF
• 1,1,1,2-Tetrafluoroethane : / EC50/ 48 h/ Daphnae: 980 mg/l
(R134a)

(IHFWGHVHU SRWHQ ial : 3 748

(ESP)

&216,'(5$ ,,5(/$7,9(/$(/,0,1$5(

Produs : 3RDWHILIRORVLWGXS UHFRQGL LRQDUH

Ambalaje contaminate : &LOLQGULLVXESUHVLXQHJRLYRUILUHWXUQD LIXUQL]RUXOXL

,1)250$ ,,35,9,1'75$1632578/

ADR
Clasa: 2
Cod de clasificare: 2A
HI Nr.: 20
Nr. ONU: 3337

4/5
FISA TEHNICA DE SECURITATE conform directivei 2001/
58/CE

DuPont™ SUVA® 404A Refrigerant

Versiune 2.1
Data revizuirii 12.04.2006 Ref. 130000000494

Eticheta Nr.: 2.2

Nume corect de expediere: Refrigerant gas R 404A

IATA_C
Clasa: 2.2
Nr. ONU: 3337
Eticheta Nr.: 2.2
Nume corect de expediere: Refrigerant gas R 404A

IMDG
Clasa: 2.2
Nr. ONU: 3337
Eticheta Nr.: 2.2
Nume corect de expediere: Refrigerant gas R 404A

,1)250$ ,,35,9,1'5(*/(0(17 5,/(63(&,),&($3/,&$%,/(

(WLFKHWDUHFRQIRUP FX'LUHFWLYHOH&(
ÌQFRQIRUPLWDWHFXGLUHFWLYHOH&(VDXOHJLOHQD LRQDOHUHVSHFWLYHSURGXVXOQXWUHEXLHV SRDUWHHWLFKHW 

$/7(,1)250$ ,,

7H[WXOIUD]HORU5PHQ LRQDWHODDUWLFROXO
R12 Extrem de inflamabil.

,QIRUPD LLVXSOLPHQWDUH
,QDLQWHGHIRORVLUHVHYDFLWLLQIRUPD LDGHSURWHF LH'X3RQW3HQWUXLQIRUPD LLXOWHULRDUHFRQVXOWD LELURXOORFDO'X3RQW
VDXGLVWULEXWRULLDXWRUL]D L'X3RQW0DUF vQUHJLVWUDW 'X3RQW®

,QIRUPD LLOHFRQ LQXWHvQDFHVWH1RUPHGH7HKQLFDúL6HFXULWDWHD0XQFLLDXIRVWVWDELOLWHSHED]DFRQRúWLLQ HORU

LQIRUPD LLORUúLSUHVXSXQHULORUQRDVWUHODGDWDSXEOLF ULLDFHVWXLGRFXPHQW$FHVWHLQIRUPD LLVXQWGDWHFXVFRS
informativ pentru a permite mDQLSXODUHDIDEULFDUHDGHSR]LWDUHDWUDQVSRUWXOGLVWULEX LDXWLOL]DUHDVLHOLPLQDUHDvQ
FRQGL LLFRUHVSXQ] WRDUHGHVHFXULWDWHúLGHDFHHDQXSRWILFRQVLGHUDWHGUHSWXQFHUWLILFDWGHFDOLWDWHVDXGH
JDUDQ LH,QIRUPD LLOHVHUHIHUDQXPDLODSURGXVXOVSHFLILFDWúLQXSRWILYDODELOHFkQGDFHVWSURGXVVHJ VHúWHvQ
FRPELQD LHFXRULFHDOWSURGXVVDXvQRULFHSURFHVGHIDEULFD LHI U VSHFLILFD LHH[SUHV 

5/5