This document provides all the basics regarding Mole Concept in Science that are intended for class IX and X students under CBSE curriculum in a very interactive manner with rich examples and exercises.

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This document provides all the basics regarding Mole Concept in Science that are intended for class IX and X students under CBSE curriculum in a very interactive manner with rich examples and exercises.

Attribution Non-Commercial ShareAlike (BY-NC-SA)

- Electrochemistry
- Notes on Mole Concept
- Mole Concept empirical & molecular formula by S.K.sinha See Chemistry Animations at sinhalab.com
- MOLE CONCEPT
- IONIC EQUILLIBRIUM FOR IIT-JEE ENTRANCE TEST by S.K.sinha See Chemistry Animations at http://openchemistry.in
- Mole Concept
- Stoichiometry and the Mole Concept Notes
- Mole Concept
- Mole Concept Exercise
- ATOMIC STRUCTURE STUDY MATERIAL & ASSIGNMENT
- STOICHIOMETRY
- Mole Concept
- Calculus for iit jee.pdf
- Organic Nomenclature http://openchemistry.in/
- Revision Class Ix Mole Concept
- Mole Concept Solution Practice Set 1 Objective by S.K.sinha See Chemistry Animations at sinhalab.com
- MOLE CONCEPT-JEE(MAIN+ADVANCED)
- Chemistry iit TMH 2012
- Chemestry for JEE
- Numerical Chemistry

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BASICS OF MOLE CONCEPT - Parishkrit Jain

If you have ever visited in a bank then you might have observed that people working

there have large number of coins of various denominations. As you can imagine, it

would really be very tedious to count such large number of coins. Then how do these

people count them? Well, the simple method is to weigh the coins. Sounds strange! But

it is true. Think of simpler example related to your life. We use to have grains (wheat,

rice, etc.) or sugar in our houses. Do we really count each and every grain or sugar

particle? Surely no. We just weigh them. It is often convenient to do so, especially in the

case of grains and sugar. Let us go back to our example of banks. A simple question may

arise in your mind: Knowing the weight of some coins of given denomination how can

be count the total number of coins? The method is indeed very interesting and requires

some simple math. You know that a fixed number of coins (of same denomination) will

have the same mass. Let us, for an example, think that 10, ₹ 5 coins weigh 50 grams

then you can know the weight of a single coin easily. Yes, it would be 5 grams. Now they

put some coins on a weighing machine which shows their weight to be 550 grams. Can

you figure out the number of coins on the weighing machine? We have the following

relation:

This was rather simple but using this simple concept scientists count the ‘number’ of

atoms or molecules present in elements and compounds (i.e. from their mass). In fact

this ‘number’ is referred to as mole. But a simple question may arise in your mind:

Well, let us answer this question for you. Consider a simple chemical reaction, involved

in formation of water:

2H2 + O2 → 2H2O

1

BASICS OF MOLE CONCEPT - Parishkrit Jain

You can observe from this equation that in a chemical equation the number of

molecules or atoms taking part in the reaction is indicated. Here, 2 molecules of

Hydrogen combine with a single molecule of Oxygen to form 2 molecules of water. Thus,

a chemical reaction directly indicates the number of atoms taking part in the reaction.

So, it is more convenient to refer to the quantity of a substance in terms of the number

of atoms taking part in the reaction, rather than their masses. Chemists need the

number of atoms and molecules while carrying out reactions, and for this they need to

relate the mass in grams to the number. Thus, a mole is the chemist’s counting unit. It

has the unit symbol mol. Now let us move back to our previous discussion to see how

they relate mass in grams to the number.

The answer is simple: by weighing them. Experimentally it has been found that if we

weigh an element equal to its atomic mass in grams, then it contains 6.022 X 10 23 atoms

of the element. Recall that mole is actually a number. For example, 1 dozen apples

always means only and only 12 apples, irrespective of their shape and size. Similarly:

Gram atomic mass (of anything) = 1 mole (of anything) = 6.022 X 1023 in number

You can also observe the advantage of using mole rather than dozen or gross that mass

of 1 mole of a particular substance is always fixed. It is always equal to the relative

atomic mass or molecular mass in grams.

This 6.022 X 1023 is actually called the Avogadro number or Avogadro constant

(represented by NA or NO) in honour of Italian scientist Amadeo Avogadro.

2

BASICS OF MOLE CONCEPT - Parishkrit Jain

Before moving further let us first see what is gram atomic mass or molar mass. Mass of

1 mole of particles is called molar mass or gram atomic mass. To get it, we take the

numerical value of the atomic mass and simply write gram (g) after that or in other

words, we write the atomic mass but place ‘g’ instead of ‘u’. For example, atomic mass

of hydrogen=1u. So, gram atomic mass of hydrogen = 1g. So, can you tell now what the

gram atomic mass of Sodium is? (Remember that the atomic mass of Sodium is 23u).

Yes, it is 23g.

Now, we know that 1u of hydrogen has 1 atom of hydrogen. So, 1g of hydrogen has 1

mole of atoms that is 6.022 X 1023 atoms of Hydrogen. Let us consider one more

example. 16u oxygen has only 1 atom of oxygen, 16 g oxygen has 1 mole atoms, that is,

6.022×1023 atoms of oxygen. Before moving on, there is a question for you:

What do you understand from this? 18u water has only 1 molecule of water, 18g water

has 1 mole molecules of water, that is, 6.022×1023 molecules of water.

1896 by Wilhelm Ostwald who derived

TO the term from the Latin word moles

meaning a „heap‟ or „pile‟. A substance

may be considered as a heap of atoms

K NOW ???

or molecules. The unit mole was

accepted in 1967 to provide a simple

way of reporting a large number- the

massive heap of atoms and molecules in

a sample.

Wilhelm Ostwald

3

BASICS OF MOLE CONCEPT - Parishkrit Jain

The illustration given below shows the relationship between mole, Avogadro number

and mass:

Let us now try to define the important terms we have learnt so far:

‘Mole is the amount of substance that contains the same number of particles.’

having a mass equal to its atomic mass or molecular mass in grams.’

grams of Carbon-12.’

4

BASICS OF MOLE CONCEPT - Parishkrit Jain

Before moving further we need to know the following symbols used while solving

numerical problems:

Number of moles =n

Given mass =m

Molar mass =M

Given number of particles =N

Avogadro number = NO

Let us now suppose that we need to find number of moles (i.e. n) in a given mass (m) of

element x, given that the molar mass of the element is M.

So, =

In other words, =

Solution. We know that, Atomic mass of He = 4u

So, its molar mass = 4 g

That is, 4 g of He contains 1 mole of He.

Or, 4 g of He = 1 mole of He

So, 52 grams of Helium = X 52 mole

= 13 moles

Therefore, there are 13 moles in 52 g of He.

5

BASICS OF MOLE CONCEPT - Parishkrit Jain

From the 5th step of this example you could have easily observed that 52 grams (i.e.

given mass) of Helium contains number of moles. Thus, we verify

our relationship.

Now, Let us try to find number of moles (i.e. n) for given number of particles (N) of an

element x.

i.e., 1 mole of x = NO

=> =

In other words, =

Now let us look at some sample problems to illustrate the use of above formulas.

Sample Problem 2. Calculate the number of moles for 12.044 X 1023 atoms of Helium.

Solution. We know that,

=

Or, =

=

=2

Therefore, there are 2 moles in 12.044 X 1023 atoms of He.

Before moving further we have got a simple exercise for you to let you apply the

concepts you have learned so far.

6

BASICS OF MOLE CONCEPT - Parishkrit Jain

1. In 1896, William Ostwald, introduced a term mole which

can be defined as…………………………...........……………..………………

………………………………………………………………………………………………

………………………………………………………………………………………………

n ……………………………………………………

N …………………………………………………..

M ………………………………………………….

M ………………………………………………….

represented as …………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

7

BASICS OF MOLE CONCEPT - Parishkrit Jain

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

phosphorous?

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

8

BASICS OF MOLE CONCEPT - Parishkrit Jain

and, =

So, we can now easily find the number of moles in a given mass of element or given

number of particles. But have you ever thought how can we find the mass of an element

or the number of particles of an element that contains given number of moles?

That’s rather simple! In fact, we can do so and many other related things using just

these basic key concepts. Let us do so.

Suppose we need to find mass of an element x that contains given mole of atoms.

We know that, =

Or, =

Or,

Let us now suppose that we need to find number of particles (N) of an element in a

given mole of atoms.

We know that,

Or, =

Or,

Can you find the mass (m) of an element if the number of particles (N) is known? Or, can

you find the number of particles (N) in a given mass (m) of an element?

9

BASICS OF MOLE CONCEPT - Parishkrit Jain

Let us now suppose that we need to determine mass (m) of an element when the

number of particles (N) is known.

We have, =

Or, m=MXn

We get, m=MX

... Mass =

Let us now suppose that we need to determine the number of atoms (N) in a given mass

(m) of an element.

We have, =

Or, = ………...……………… (i)

Or,

We get, N=

10

BASICS OF MOLE CONCEPT - Parishkrit Jain

So, we a seen a lot many number of derivations from two simple key formulas. Let us

now look at all of them for once.

b) Number of particles = Number of moles X Avogadro number

c) Mass =

d) Number of particles =

The following sample problems illustrate the use of all these formulas.

Solution. We know that,

Mass = Number of moles X Molar mass

Or,

= 0.5 X 14

=7g

Sample Problem 4. What is the mass of 3.011 X 1023 number of Nitrogen atoms?

Solution. We know that,

Mass =

Or, m=MX

= 14 X

=7g

11

BASICS OF MOLE CONCEPT - Parishkrit Jain

(i) 0.1 mole of Carbon atoms

(ii) 46 grams of Sodium atoms.

Solution. (i) We know that,

Number of particles = Number of moles X Avogadro number

Or,

= 6.022 X 1022

Number of particles =

Or, N=

= X

= 12.044 X 1023

Thus we see the application of concepts we have learned in the chapter. Now we have

got some exercises for you to work on and learn the things with ease. But before that,

let us revise the key formulas once again:

and, =

12

BASICS OF MOLE CONCEPT - Parishkrit Jain

1. One mole of any species is that quantity in number

………………………….…………………………...........……………..………………

………………………………………………………………………………………………

………………………………………………………………………………………………

mole and in a given mass of elements.

Formula 1 ……………………………………………………….....…………………

……………………………………………………….....………………………………….

Formula 2…………………………………….…………………………………………

………….....……………………………..………………………………………………..

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

13

BASICS OF MOLE CONCEPT - Parishkrit Jain

weighing 2.8 grams.

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

in grams of a single atom of Carbon?

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

…………………………………………………………………………….…………………

14

BASICS OF MOLE CONCEPT - Parishkrit Jain

Here we go looking at some more sample questions to get a better understanding of the

text.

Mass = Number of moles X Molar mass

Or,

= 0.5 X (14+14)

= 14 g

Sample Problem 7. Convert 12.044 X 1022 molecules of Sulphur dioxide into moles?

Solution. We know that,

Number of moles =

Or, n=

=

= 0.2

Sample Problem 8. In which case the number of Hydrogen atoms is more- 2 mol of HCl

or 1 mol of NH3?

Also, NH3 contains 3 moles of H atoms.

Therefore, 1 mole of NH3 contains more number of atoms.

15

BASICS OF MOLE CONCEPT - Parishkrit Jain

Sample Problem 9. An ornament of silver contains 20 gram silver. Calculate the moles of

silver present.

Solution. We know that,

=

Or, =

=

= 0.185

Therefore, there are 0.185 mol in 20 g of Ag.

Sample Problem 10. If 1 g sulphur dioxide contains x molecules, what will be the number

of molecules in 1 g of methane?

Solution. We have,

1 mol of SO2 = 32 + (16 X 2)

= 64 gram

... 1 g of SO2 = mole

Now, 1 mol of CH4 = 12 + (4 X 1)

= 16 gram

... 1 g of CH4 = mole

= 4x molecules

... If 1 g of SO2 contains x molecules, then 1 g of CH4 contains 4x molecules.

16

BASICS OF MOLE CONCEPT - Parishkrit Jain

1. One mole of oxygen atoms = ………………………….…… oxygen

atoms in number

2. Choose the correct option in the following:

Which of the following has maximum number of molecules?

(a) 4 g of H2 gas (b) 1 mole of H2O gas

(c) 3 mole of CO (d) 22 g of CO 2

3. Choose the correct option in the following:

What is the number of Sulphur atoms in one mole of S8?

(a) 4.818 X 1024 (b) 4.121 X 1024

4. Calculate the number of aluminium ions present in 0.051 g

of aluminium oxide.

……………………………………………………………………………………………...

……………………………………………………………………………………………...

……………………………………………………………………………………………...

……………………………………………………………………………………………...

……………………………………………………………………………………………...

17

BASICS OF MOLE CONCEPT - Parishkrit Jain

atoms as 4 g of calcium?

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

weighing 2.8 grams.

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

18

BASICS OF MOLE CONCEPT - Parishkrit Jain

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

and 3.2 grams of SO2?

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

………………………………………………………………………………………………

19

BASICS OF MOLE CONCEPT - Parishkrit Jain

And that is it! Now, we are in a position to solve a self-evaluation test. It is a question

paper of 50 marks to be solved in 1 hour and contains 20 questions. All the questions

are related to what we have learned in this chapter. It would be like an exam-type test.

It is advised to give the test only after completing the text and reading the summary

given at the end. In this test, as the name suggests, you are going to test yourself. If your

score is less than half the total score (i.e. less than 25), then you must attempt the

practice questions given below. Remember to go through these practice questions also.

PRACTISE QUESTIONS

2. Calculate the number of particles in-

(i) 8 g of O2 molecules (ii) 2.5 mol of calcium atoms.

3. What is the mass of 2.5 mol of Methane?

4. Find the mass of one molecule of water.

5. Calculate the number of water molecules and number of oxygen and

hydrogen atoms in a drop of water containing 0.03 mol of water.

6. Calculate the actual mass of one atom of carbon if 12 grams of Carbon

contain one mole of Carbon.

7. Calculate mass of Nitrogen (N2) which contains same number of molecules

as are present in 4.4 grams of Carbon-di-oxide (CO2).

8. Atomic mass of gold is 197 u. How many moles of gold are present in an

ornament containing 88.65 grams of gold?

9. How many moles of SO2 have same mass as 3 moles of oxygen?

10. A glass of water contains 5 mol of water. How many molecules of water are

present?

11. What is the mass of a formula unit of Na+Cl-?

12. How many atoms of Silver are present in a silver wire weighing 5.4 grams?

13. Calculate the ratio of molecules present in 16 g of methane and 16 g of

oxygen.

14. Convert into mole. (a) 12 g of oxygen gas (b) 20 g of water (c) 22 g of

carbon-dioxide.

15. Determine the number of bromide ion in 0.2 mole of MgBr2.

20

BASICS OF MOLE CONCEPT - Parishkrit Jain

Name

concepts mentioned in the text.

This question-paper contains questions regarding the concepts learned in the

text.

Please check that this question paper contains 20 questions.

Please write down the serial number of the question paper before attempting

it.

15 minutes time has been allotted to read this question paper.

It is required to fill candidate’s name in the space provided in this question

paper.

The question paper should be completed within the prescribed time limit.

While answering this question paper avoid referring to any text.

Before writing the answers please read the instructions carefully.

Be honest while evaluating yourself.

SELF-EVALUATION TEST

21

BASICS OF MOLE CONCEPT - Parishkrit Jain

General Instructions:

(i) The question paper comprises of two sections, A and B. You are to

attempt both the sections.

(ii) All questions are compulsory.

(iii) There is no overall choice. However, internal choice has been provided

in the last question of five marks category. Only one option in this

question is to be attempted.

(iv) All questions in Section A and all questions of Section B are to be

attempted separately.

(v) Question numbers 1 to 10 in Section A are MCQs. Of these, question

numbers 1 to 5 carry 1 mark each and question numbers 6 to 10 carry

two marks each.

(vi) Question numbers 11 and 12 in Section B are short answer type

questions of two marks each. The answer to these questions should not

exceed 30 words.

(vii) Question numbers 13 to 18 in Section B are also short answer type

questions but carry 3 marks each.

(viii) Question number 19 is a passage-based question and has 3 sub-questions

which are very short answer type and carry 1 mark each.

(ix) Question number 20 in Section B is a long answer type question and

carries five marks.

(x) There is no negative marking for the questions of Section B. However for

each wrong answer in Section A, 1 mark will be deducted.

22

BASICS OF MOLE CONCEPT - Parishkrit Jain

SECTION A

1. Which one of the following statements is true regarding Sodium?

a) 1 g Sodium has 1 mole atoms

b) 1 g Sodium has 6.022 X 1023 atoms

c) 23 g Sodium has 1 mole of atoms

d) 23 g Sodium has 6.022 X 1022 atoms

2. The molar mas of Chloroform (CHCl3) is-

a) 119.5 grams

b) 118 grams

c) 49 grams

d) 50.5 grams

3. Which of the following correctly represents 360 g of water:

(i) 2 moles of H2O (ii) 20 moles of water

23

(iii) 6.022 × 10 molecules of water (iv) 1.2044×1025 molecules of water

a) (i) only

b) (i) and (iv)

c) (ii) and (iii)

d) (ii) and (iv)

4. Mass of one atoms of Oxygen is

a) grams

b) grams

c) grams

d) 8 u

5. Avogadro constant is called so in whose honour?

a) Wilhelm Ostwald

b) Amadeo Avogadro

P.T.O 23

.

BASICS OF MOLE CONCEPT - Parishkrit Jain

c) Wilhelm Avogadro

d) Amadeo Ostwald

6. Which of the following would weigh the highest?

a) 0.2 mole of sucrose (C12 H22 O11)

b) 2 moles of CO2

c) 2 moles of CaCO3

d) 10 moles of H2O

7. Which of the following has maximum number of atoms?

a) 18 grams of H2O

b) 18 gram of O2

c) 18 gram of CO2

d) 18 grams of CH4

8. 3.42 g of sucrose are dissolved in 18 g of water in a beaker. The number of oxygen

atoms in the solution are-

a) 6.68 × 1023

b) 6.09 × 1022

c) 6.022 × 1023

d) 6.022 × 1021

9. Which of the following contains maximum number of molecules?

a) 1g CO2

b) 1g N2

c) 1g H2

d) 1g CH4

10. For the given reaction,

H2O + Cl2 + H2S H2SO4 + HCl, the correct statement is:

a) The mole ratio between Cl2 and H2S is 2:1 in balanced reaction

b) The mole ratio between H2O and H2S is 4:1 in balanced reaction

c) 1 mole of H2SO4 is produced from 2 moles of Cl2

d) 4 moles of H2O are required to produce 4 moles of HCl

P.T.O

24

.

BASICS OF MOLE CONCEPT - Parishkrit Jain

SECTION B

11. In a Science laboratory, there are two samples as follows:

SAMPLE A – 2 grams of Hydrogen gas

SAMPLE B – 2 grams of Helium gas

Find a relation between the number of moles of the given two samples.

12. Scientists use a unit called ‘mole’ to count the number of atoms or molecules. Why

don’t they use any other unit like, dozen or gross, to count the number of particles?

13. In the formation of CO, it is found that 2.445 g of carbon combines with 3.260 g of

oxygen. What is the atomic ratio of carbon and oxygen which combine?

14. Calculate number of atoms in 120 gram of Calcium and 120 gram of Iron. Which one

has more number of atoms and how much is the difference?

(Given atomic mass of Calcium = 40 u, Iron = 56 u)

15. If one gram of Sulphur contains x atoms, what will be the number of atoms in one

gram of oxygen? (atomic mass of S = 32u)

16. Calcium chloride when dissolved in water dissociates into its ions according to the

following equation.

CaCl2 (aq) → Ca2+ (aq) + 2Cl– (aq)

Calculate the number of ions obtained from CaCl2 when 222 g of it is dissolved in

water.

17. The mass of one steel screw is 4.11 g. Find the mass of one mole of these steel

screws. Compare this value with the mass of the Earth (5.98 × 10 24 kg). Which one of

the two is heavier and by how many times?

18. A currency counting machine counts 6 lakh notes per day. A bank has as many notes

as number of Hydrogen atoms in 24.8 grams of Na2S2O3.5H2O. How many days would

be required to count these notes? Give an approximate answer in terms of power of

ten.

19. Read the following passage carefully and answer the questions that follow:

Moles measure quantity of substance. There is a subtle ambiguity about treating

“moles” – whether as “mass” or “number”. We take the position that it measures

“amount of substance”, which can be either be expressed in terms of mass or in

terms of numbers. The two approaches are equivalent and need not be a source of

ambiguity any further. We only need to interpret the meaning as appropriate in a

particular context.

P.T.O

25

.

BASICS OF MOLE CONCEPT - Parishkrit Jain

b) How is mole related to ‘number’?

c) What does mole actually measure?

20. A sample of ethane (C2H6) gas has the same mass as 1.5 × 1020 molecules of

methane (CH4). How many C2H6 molecules does the sample of gas contain?

OR

In photosynthesis, 6 molecules of carbon dioxide combine with an equal number of

water molecules through a complex series of reactions to give a molecule of glucose

having a molecular formula C6H12O6. How many grams of water would be required to

produce 18 g of glucose? Compute the volume of water so consumed assuming the

density of water to be 1 g cm–3.

*****

26

BASICS OF MOLE CONCEPT - Parishkrit Jain

SECTION A

1. c)

2. a)

3. d)

4. a)

5. b)

6. c)

7. d)

8. a)

9. c)

10. b)

SECTION B

11. Number of moles of Sample A (Hydrogen) is double that of Sample B (Helium).

12. Relative advantage of using mole is that not only number but also mass of 1 mole of

a particular substance is always fixed.

13. 1:1

14. Calcium- 1.8066 X 1024; Iron- 1.2904 X 1024 ; Calcium has 5.162 X 1023 more atoms

15. 2x atoms

16. 3.6 132 X 1024 ions

17. Mass of 1 mole of steel screws- 2.475 X 1021 kg; Earth is 2400 times heavier.

27

BASICS OF MOLE CONCEPT - Parishkrit Jain

19. a) Mass of 1 mole of a substance is fixed and equals molar mass of the substance.

b) 1 mole of a substance always contain Avogadro number of particles.

c) Amount of substance- either in terms of mass or number

20. 0.8 X 1020 molecules

OR

*****

28

BASICS OF MOLE CONCEPT - Parishkrit Jain

exactly 12 g of Carbon.

Mole is the amount of substance that contains the same number of particles

(atoms / ions / molecules/ formula units etc.).

1 mole of any species (atoms / ions / molecules/ particles) is that quantity in

number having a mass equal to its atomic mass molecular mass in grams.

Mass of 1 mole of a substance is called its molar mass.

Number of moles = n

Given mass = m

Molar mass = M

Given number of particles = N

Avogadro number = NO

Key formula-

i) =

ii) =

Other formula-

iii) Mass = Number of moles X Molar mass

iv) Number of particles = Number of moles X Avogadro number

v) Mass =

29

BASICS OF MOLE CONCEPT - Parishkrit Jain

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