EMEBU SAMUEL

ENG0701685
CHEMICAL
ENGINEERING
UNIBEN
RESISTORS IN PARALLEL

QUARACTIC EQUATION

RESISTORS

COEFFICIENTS(A TO C)

1/R

5
10
15
20
25
30
35
40
45
50
55
60
EQUIVALENT RESISTOR

0.2
0.1
0.07
0.05
0.04
0.03
0.03
0.03
0.02
0.02
0.02
0.02
1.61

ROOTS
1
10
16

-2
-8

PLOT OF Y AGAINST X WHERE Y=X^2+9X+20

X

Y
-5
-4
-3
-2
-1
0
1
2
3
4
5

0
0
2
6
12
20
30
42
56
72
90

12
10
8
6
4
2
2

10

12

10

12

2
3
4
5
6
7
8
9
10
11
12

1
2
3
4
5
6
7
8
9
10
11
12

2
4
6
8
10
12
14
16
18
20
22
24

3
6
9
12
15
18
21
24
27
30
33
36

4
8
12
16
20
24
28
32
36
40
44
48

5
10
15
20
25
30
35
40
45
50
55
60

6
12
18
24
30
36
42
48
54
60
66
72

7
14
21
28
35
42
49
56
63
70
77
84

8
16
24
32
40
48
56
64
72
80
88
96

9
18
27
36
45
54
63
72
81
90
99
108

10
20
30
40
50
60
70
80
90
100
110
120

VOL.(m^3)
2
4
8
5
3
14
9
10
11
25

IDEAL GAS LAW FOR SET OF VOLUMES AND TEMPERATURES(P=RT/V),R=8.314

TEMPERATURE(K)
273
275
294
277
303
312
299
313
1134.86
1143.18
1222.16
1151.49
1259.57
1296.98
1242.94
1301.14
567.43
571.59
611.08
575.74
629.79
648.49
621.47
650.57
283.72
285.79
305.54
287.87
314.89
324.25
310.74
325.29
453.94
457.27
488.86
460.6
503.83
518.79
497.18
520.46
756.57
762.12
814.77
767.66
839.71
864.66
828.63
867.43
162.12
163.31
174.59
164.5
179.94
185.28
177.56
185.88
252.19
254.04
271.59
255.89
279.9
288.22
276.21
289.14
226.97
228.64
244.43
230.3
251.91
259.4
248.59
260.23
206.34
207.85
222.21
209.36
229.01
235.82
225.99
236.57
90.79
91.45
97.77
92.12
100.77
103.76
99.44
104.09

IRREVERSIBLE REACTION IN SERIE

ABC, CBo=Cco=0
K1=0.4,K2=0.1,CAO=1kmolm3
TIME(S)
0
5
10
15
20
25
30
35
40
45
50
55
60

CAkmols/m3
1
0.14
0.14
0.02
0
0
0
0
0
0
0
0
0

CBkmols/m3
0
0.63
0.47
0.29
0.18
0.11
0.07
0.04
0.02
0.01
0.01
0.01
0

CCkmols/m3 Cbmax(kmol/m3
0
0.63
0.24
0.63
0.4
0.63
0.69
0.63
0.82
0.63
0.89
0.63
0.93
0.63
0.96
0.63
0.98
0.63
0.99
0.63
0.99
0.63
0.99
0.63
1
0.63

N IN SERIES

IRREVERSIBLE REACTION IN SERIES

ABC where;Cao=1.0(kmol/m^3),Cbo=0(kmole/m^3) and Cco=0(kmol/m^3)
Rate contants are;k1=0.4 and k2=0.1

TIME(sec)
0
5
10
15
20
25
30
35
40
45
50
55
60
65
70
75
80
85
90
95
100
105
110
115
120

Cb(kmol/m^3) Ca(kmol/m^3
0
0.63
0.47
0.29
0.18
0.11
0.07
0.04
0.02
0.01
0.01
0.01
0
0
0
0
0
0
0
0
0
0
0
0
0

1
0.14
0.02
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

Cc(kmol/m^3)
0
0.24
0.52
0.7
0.82
0.89
0.93
0.96
0.98
0.99
0.99
0.99
1
1
1
1
1
1
1
1
1
1
1
1
1

SERIES

kmol/m^3)

Cbmax=(kmol/m^3)
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63
0.63

a
TEMPERATU
PRESSURE VOLUME RE
atm
Litres
kelvin
3.3
7
300
1.99
10
245
1.06
15
200

3.59
1.6
2.9

0.04
0.02
0.02

0.08
CO2
O2
NH2

2
1
1

VAN-DAR WAALS EQUATION OF STATE (P=(RT/(V-nb)-(a^2/V^2)

Where R=Gas Constant ,a & b Constant Which Depend On The Gas And n=Number Of Moles Of Gas

R at different units
(j/mol.k)
=
8.31
(cal/mol.k)
=
1.99
(m^3.atm/mol.k) = 8.21E-05
(cm^3.atm/gmol.k) =
82.06
(btu/lbmol.R)
=
1.99
(ft.lb/ lbmol.R) =
1545.3
(hp.h/lbmol.R )
= 7.81E-04
(kwh/lbmol.R)
= 5.82E-04

List Of values of a & b for gases

Gases
CO2
O2
NH3
NH4
NO2
NO
SO2
CH4

b
3.59
1.6
2.1
2.5
3
2.8
4.2
2.65

Conversion

n
0.04
0.02
0.03
0.03
0.04
0.03
0.05
0.04

1
2 T(R)
3 1atm
4 1ft ^3
5 1cm^3
6
7
8
9
10

=
=
=
=

TEMPERATURE
VOLUMES(^3)
5
10
15
20
25
30
35
40
45
50
55
60

273
465.36
229.79
152.56
114.19
91.24
75.97
65.08
56.92
50.58
45.51
41.36
37.91

278
473.9
234
155.36
116.28
92.91
77.36
66.27
57.96
51.5
46.34
42.12
38.6

283
482.43
238.21
158.15
118.37
94.58
78.75
67.46
59
52.43
47.17
42.87
39.29

288
490.96
242.42
160.95
120.46
96.25
80.14
68.65
60.05
53.36
48.01
43.63
39.99

293
499.5
246.63
163.74
122.55
97.92
81.53
69.85
61.09
54.28
48.84
44.39
40.68

298
508.03
250.84
166.54
124.64
99.59
82.93
71.04
62.13
55.21
49.67
45.15
41.38

303
516.56
255.05
169.33
126.74
101.26
84.32
72.23
63.17
56.13
50.51
45.91
42.07

nb)-(a^2/V^2)

Of Gas

Conversion

Conversion factors
k=k
1
1.8T(k)
k=R
0.56
101.3(kN/m^2 m=m
1
0.0283m^3
m=ft
35.31
1E-06m^3
m^3=cm^3 1.00E+06

308
525.09
259.27
172.13
128.83
102.94
85.71
73.42
64.22
57.06
51.34
46.66
42.77

313
533.63
263.48
174.92
130.92
104.61
87.1
74.61
65.26
57.99
52.17
47.42
43.46

318
542.16
267.69
177.72
133.01
106.28
88.49
75.81
66.3
58.91
53.01
48.18
44.15

NAME
MAT NO
DEPT
FACULTY
SCHOOL

EMEBU SAMUEL
ENG0701685
CHEMICAL
ENGINEERING
UNIBEN

123

ABBOT ENGINEERING TEST REQUIREMENT OF PRODUCTS

SPECIFIED PRODUCT REQUIREMENT

Q
1.24
1.21
1.25
1.26
1.1
1.2
1.49
1.14
1.22
1.25
1.3
1.36

P
0.1
0.2
0.5
0.6
0.4
0.3
0.25
0.29
0.7
0.9
0.15
0.8
PASS

Qmax
Pmin
Q TEST
0
0
1
1
0
0
1
0
0
1
1
1
50%

=
=
P TEST
1
1
1
0
1
1
1
1
0
0
1
0
67%

1.25
0.5
P AND Q TEST
0
0
1
0
0
0
1
0
0
0
1
0
25%

COLOUR NATUER
BLUE
BLUE
RED
RED
BLUE
BLUE
RED
BLUE
BLUE
RED
RED
RED

0
0
0
0.01
0.21
0.01
0
0
0.75
0.56

0
0
0
0.1
0.03
0
0
0
0.71
0.5

0
1
1
0
1
1
0
0
1
1

0
0
0
0.1
0.03
0
0
0
0.71
0.5

RESULT OF VARIOUS COURSES FOR THE STUDENT DESCRIPTION BELOW FOR FIRST AND SECOND SEME
NAME
OGHOJOR OPIA
MAT NO ENGO134455
DEPT
CHEMICAL
FACULTY ENGINEERING
COURSES
CHE311
CHE321
CHE331
CHE341
CHE351
CHE361
CHE312
CHE322
CHE332
CHE352
CHE362
CHE372
CHE301
CHE302

SCORES
55
43
65
61
76
34
84
55
12
66
90
38
41
88
70

GRADE
C
D
B
B
A
E
A
C
F
B
A
E
D
A
A

ST AND SECOND SEMESTER

DETERMINING ROOT OF EQUATIONS

2X2+3X-6

SAMPLE
1.14
-2.64
SAMPLE

0
0

5X3+6X2+X+8
-1.66
-1.66
-1.66

0
0
0

SOLVING SIMULTANEOUS EQUATIONS USING SOLVER

GIVEN;
2X+3Y-3=0
3X+2Y-5=0
USING ANY VALUE FOR X AND Y
X
1.8
0
0
Y
-0.2
0
0
0

GIVEN THAT;
SAME AS

A-1
0.4
-0.3

0.2
0.1

GIVEN THAT;

SOLVING SYSTEM OF LINEAR EQUATION USING MATRIX METHOD

X-2Y+1=0
3X+4Y-17=0
X-2Y=-1
3X+4Y=17
A
C
1
-2
-1
3
4
17
-1
A .C
3
2
2X+3Y-2Z-15=0
3X+9Y+2Z+2=0
4X-Y+3Z-2=0
2X+3Y-2Z=15
3X+9Y+2Z=-2
4X-Y+3Z=2

SAME AS;

23

2
3
4
0.22
-0.01
-0.29

A-1
-0.05
0.11
0.11

A-1.C
0.18
-0.08
0.07

3.74
-0.47
-4.47

A
3
9
-1

-2
2
3

C
15
-2
2

X METHOD

46

MATERIAL BALANCE CALCULATIONS

PRODUCTION OF METHANOL FROM CARBON MONOXIDE AND HYDROGEN
BY THE REVERSIBLE REACTION
CO+H2CH3OH
CHECK NOTE FOR DIAGRAM OF PROCESS
GIVEN BASIS FOR CO FEED AS 100MOL/hr
GIVEN CONVERSION FACTOR OF CO AS 0.3
ASSUMING PERFECT SEPARATION BTW METHANOL & UNREACTED REACTANT
FOR NO RECYCLE
100
0.3
STREAM
FLOWRATE(MOL/hr)
CH3OH
CO
FROM REACTOR
FROM SEPARATOR TOP
FROM SEPARATOR BOTTOM
FOR RECYCLE
100
STREAM
FROM REACTOR
FROM SEPARATOR TOP
FROM SEPARATOR BOTTOM

70
70
0

30
0
30

0.3
FLOWRATE(MOL/hr)
CH3OH
CO
245
250
0

105
0
105

YDROGEN

y
0
1
2
3
4

12
10
8
6

3
5
7
9
11

12
10
Series1

Series1
Linear R
Series1

6
4
2

4
21

42

6 3

4 8

5 10

12

Series1
Series1
Linear Regression for
Series1

5 10

12

y
0
1
2
3
4

3
5
7
9
11

12
10
Series1

8
6
4
2
1

Series1

time(seconds) temp
light
1
11
2
11
3
11
4
11
5
11
6
11
7
11
8
12
9
13
12
60
10
24
11
11.34
10
50
12
12
40
8
13
10

0
0
0
0
0
34
56
11
23
45
7
9
3

Series1
temp
Series2
light

30
6
20
4
10
2
0
0

22

44

466

88 6

1010

81212

1414
10

12

Series1
temp
Series2
light

81212

1414
10

12

2.46E-05
1.08E-04
4.75E-04
1.63E-03
5.76E-03
1.85E-02
R(J/kmole)
E(j/mole)

273
283
293
303
313
323
8.31
42216.99

-4.61
-3.97
-3.32
-2.79
-2.24
-1.73

0
0
0
0
0
0

-1
-2
-2
330
-3
320
-3
310
-4
-4
300
-5
290
-5
280
270
260
250
240
-5
0.00E+00
-5
-5

-5

-4.61
-3.97
-3.32
-2.79
-2.24
-1.73
Series1
Linear
Regression for
Series1
Series1
Linear Series1
Regression for
Series1

5.00E-03
-4 -5
-4
-4

1.00E-02
-3
-4-3 1.50E-02
-2
-4

-3

-3

-2
2.00E-02
-4
-2

-2

Series1
-3

Series1
Linear
Regression for
Series1
Series1
Linear Series1
Regression for
Series1

4
00E-02
-2

Series1
-3

Series1
Linear Regression for Series1

-3

-2

-2

ession for Series1

-2.25
-2.58
-3.08
-3.71
-4.37
-4.77
-4.99

2.08
1.79
1.61
1.1
0.69
0

3
Series1
Linear
Regression for
Series1

2
2
1

-5

-5

-4

-4

-3

-3

-2

Series1
Linear
Regression for
Series1

1.00E-02
1.00E-01
1.00E+00
1.00E+00
7.00E+00
1.00E+01
5.00E+01
1.00E+02

10000
1000
100
10
7
1
0.7
0.5

6.97
3.98
2.33
2.33
1.56
1.47
1.14
1.05

0
0
0
0
0
0
0
0

0
20
40
60
120
180
300

10
8
6
5
3
2
1

0
0.1
0.1
0.08
0.06
0.04
0.03

1
0.9
0.78
0.7
0.48
0.3
0

Err:502
-1
-1
-1.08
-1.23
-1.35
-1.52

(-rA=
#NAME?

-1
-2
-2
1

Series1
Linear
Regression
for Series1

8.31
8314
8.21E-05
8.21E-02
7.30E-01

10
20
30
40
50
60

273
229.29
114.06
75.91
56.89
45.49
37.89

3.59
0.04

283
237.7
118.24
78.69
58.97
47.15
39.28

293
246.1
122.42
81.48
61.05
48.82
40.67

1
0.56
1
1.00E+03
35.31
1
7.15E-03
303
254.5
126.6
84.26
63.14
50.49
42.06

313
262.91
130.78
87.04
65.22
52.15
43.45

2.5

323
271.31
134.96
89.82
67.31
53.82
44.83

333
279.71
139.14
92.6
69.39
55.48
46.22

CAO

K
16
XA

EA
10

T
0.1
0.2
0.3
0.4
0.5
0.6
0.7

0
0
0.01
0.01
0.02
0.04
0.09

n
0.5

2
0
5
10
30
50
70
90
97.5

700
600
500
400
300
200

430
455
468
502
533
561
596
650

Series1
Linear
Regression for
Series1

100
20

40

60

80

100

120

Series1
Linear
Regression for
Series1

0
26
5
36
16
38
50
25
22
25

0
2.5
12.9
23.2
43.9
54.7
67
73.8
90.3
104.8

#DIV/0!
0.17
0.01
0.03
0.01
0.01
0.01
0.01
0
0

CHART OF T VS V

Series1
Linear
Regression for
Series1

20

40

60
Axis Title

80

100

120

Series1
Linear
Regression for
Series1

CA

time(S)
0
2
4
6
8
10
12
14
16
18
20
22

CB
100
90
80
75
60
55
50
45
35
25
20
10

CC
80
70
65
55
50
45
40
45
30
25
20
10

10
20
30
40
50
60
70
80
90
100
110
120

RATE OF DISAPPEARANCE A

c
140
o
n 120
c 100
e
n 80
r
60
a
40
t
i
20
o
n

10

15

Time(hrs)

20

25

SAPPEARANCE AND FORMATION

Cc
Linear
Regression for
Cc
Ca
Cb

20

25

N2 +3H2

2NH3

IMPORTANT CONVENTIONS
minus sign :means disapprearance ie for reactants

1mol:3mol 2mol
100

ASIS OF CALCULATION:N2(mol) =

0.25

REACTION CONVERSION:

FRACTION OF COMPONENTS IN PRODUCT STREAM

N2 =
0.01
H2 =
NH3 =

N2
H2
NH3
TOTAL

0.01
0.98 mixer out
Err:522
mixer in
Err:522
100
300
0
400

Err:522
Err:522

reactor reactor out prod strm recycle

Err:522
Err:522
Err:522
Err:522
Err:522
Err:522
Err:522
Err:522
Err:522
-197.04

Err:522
1383.33

Err:522
202.96

Err:522
1180.38

ONVENTIONS
prearance ie for reactants

N2
X
FOP
N2
H2
NH3

100
0.74
0.01
0.01
0.98

N2
H2
NH3
TOTAL

1
100
300
0
400

TPR
TKp

220
0.05

2
Err:522
Err:522
Err:522
543.38

3
Err:522
Err:522
Err:522
-199.65

4
Err:522
Err:522
Err:522
343.73

MOLE FAC OF 4
N2
H2
NH3
TOTAL

Err:522
Err:522
Err:522
Err:522

Kpc

Err:522

At equilibrium conv TKp-Kpc=0

Err:522

5
Err:522
Err:522
Err:522
200.35

6
Err:522
Err:522
Err:522
143.38

NAME
MAT NO

EMEBU SAMUEL
ENGO7O1685

PART 1

REACTION WITH NORMAL CONVERSION

2NH3
N2 +3H2
1mol:3mol 2mol
BASIS OF CALCULATION:N2(mol) =
REACTION CONVERSION:

100

0.25

FRACTION OF COMPONENTS IN PRODUCT STREAM

N2 =
0.01
H2 =
NH3 =
FC Valve

0.01
0.98
PROCESS FLOW DIAGRAM

Compressor

IMPORTANT CONVENTIONS
minus sign :means disapprearance or consumption
feed

reactor

reactorout prod strm

recycle

100

Err:522

Err:522

Err:522

Err:522

Err:522

H2
NH3

300

Err:522

Err:522

Err:522

Err:522

Err:522

0
400

4.02
1580.38

Err:522
-197.04

Err:522
1383.33

Err:522
202.96

Err:522
1180.38

TOTAL

PART2

mixer out

N2

REACTION WHERE CONVERSION IS LIMITED TO EQUILIBRIUM CONSTANT

BASIS OF CALCULATION:N2(mol) =
100
EQUILIBRIUM CONVERSION:

0.74

FRACTION OF COMPONENTS IN PRODUCT STREAM

N2 =
0.01
H2 =
NH3 =

0.01
0.98
feed

mixer out

reactor

reactorout prod strm

recycle

N2

100

Err:522

Err:522

Err:522

Err:522

Err:522

H2

300
0
400

Err:522
Err:522
543.38

Err:522
Err:522
-199.65

Err:522
Err:522
343.73

Err:522
Err:522
200.35

Err:522
Err:522
143.38

NH3
Total

Equilibrium Constant of Rxn(kp)

0.05
Total Pressure of Rxn(p)
:
220
Mole Fractions of reactorout
N2
Err:522
H2
Err:522
NH3
Err:522
Total
Err:522
Calculated value of Kp(Kpc) :
At Equilibrium conversion,Kp-Kpc=0

Err:522
:

Err:522

ONSTANT

NAME
MAT NO

EMEBU SAMUEL
ENGO7O1685

PART 1

REACTION WITH NORMAL CONVERSION

2NH3
N2 +3H2
1mol:3mol 2mol
BASIS OF CALCULATION:N2(mol) =
REACTION CONVERSION:

100

0.25

FRACTION OF COMPONENTS IN PRODUCT STREAM

N2 =
0.01
H2 =
NH3 =
FC Valve

0.01
0.98
PROCESS FLOW DIAGRAM

Compressor

IMPORTANT CONVENTIONS
minus sign :means disapprearance or consumption
feed

reactor

reactorout prod strm

recycle

100

Err:522

Err:522

Err:522

Err:522

Err:522

H2
NH3

300

Err:522

Err:522

Err:522

Err:522

Err:522

0
400

4.02
1580.38

Err:522
-197.04

Err:522
1383.33

Err:522
202.96

Err:522
1180.38

TOTAL

PART2

mixer out

N2

REACTION WHERE CONVERSION IS LIMITED TO EQUILIBRIUM CONSTANT

BASIS OF CALCULATION:N2(mol) =
100
EQUILIBRIUM CONVERSION:

0.74

FRACTION OF COMPONENTS IN PRODUCT STREAM

N2 =
0.01
H2 =
NH3 =

0.01
0.98
feed

mixer out

reactor

reactorout prod strm

recycle

N2

100

Err:522

Err:522

Err:522

Err:522

Err:522

H2

300
0
400

Err:522
Err:522
543.38

Err:522
Err:522
-199.65

Err:522
Err:522
343.73

Err:522
Err:522
200.35

Err:522
Err:522
143.38

NH3
Total

Equilibrium Constant of Rxn(kp)

0.05
Total Pressure of Rxn(p)
:
220
Mole Fractions of reactorout
N2
Err:522
H2
Err:522
NH3
Err:522
Total
Err:522
Calculated value of Kp(Kpc) :
At Equilibrium conversion,Kp-Kpc=0

Err:522
:

Err:522

ONSTANT