.Metrohm METROHM AG — CH-9101 Herisau (Switzerland) KF Titrino 701 Series 01 ... Instructions for Use 8.701.1003 89.12 Ti©.Metrohm Short Operating Guide 701 KF Titrino KFT TITER with H20 or std. TITER with Me2Tart-2420 BLANK determination Display drift core: drift value Mode Selection Pross key until the desired mode is displayed: Karl Fischer titration Titer determination with water or with a standard Titer determination with sodium tartrate Blank determination Calculations for Mode KFT Go to next inguiry with and ‘Sample size ‘Sample identification Titer Factor Divisor, e.g. for density Blank Drift correction of KFR volume Input of drift value for manual drift correction load desired mode with Initial values are printed in bold face. Input range Up to 6 digits: + X0000K (1 9) up to 8 ASCII characters 0.0000...5..09.9991 mgim! =1 000 000...1..+ 1 000 000 1.000 000..1..+1 000 000 0.0...99.9991 mi auto, man., OFF 0.0..99.9 pilin delete a Statistics with n single results Result table for statistics calculation Delete single result number n Formula and units for Mode KFT water (KER volume = blank) «titer |smplsize|» divisor factor ‘Adapt factor and divisor to the selected units of result output and sample size unit % % ppm mgimi mgimi mg mt ma'pe ‘smpl size in... 9 m9 9 a 1 1 pe factor on 100 1000 donsity [g/ml] 1 1 1 divisor 1000-density H,0 {gmt} ~ 1000 1 2..20, OFF original, delete n, delete all 1.20 Solect unit of result output with key Possible units: %, ppm, mg/m, g, mg, ml, mgipe, no unitTimit RF reag DKF davies settings ‘actual KF reag. fi11iag rate Configuration Go to next inquiry with “configuration > end center>. Meaning Counter for KF reagent (butter capacity, reagent supply) Actual value of counter Soloction of polarisation type Polarization current (voltametric indication) Endpoint Polarization voltage (amperometric indication) Endpoint Filling rate after the titration Initial values are printed in bold face. Input r 0...999 ml, OFF 0.999 mt (pol), Lipo!) -127..50..127 WA, OFF |~100...20...1500 mV -1270...600...1270 mV -150..25..150 pA 0.01..150 miimin, max. | oasesaisuttinas ‘Selection of record type to be outputted at the analog output Baud rate '300,600, 1200, 2400, 4800, 9600 Data bit 7.8 Stop bit 2 Parity leven, odd, none handshake: Handshake IHWs, HWI, SWiine, SWchar, Inone RS control: Receiving of commands via RS; “OFF” means no ION, OFF reception | >perinhece) units) ‘send to: ‘Selection of character set, depends on printer Epson, Seiko, IBM batance: ‘Selection of balance Sartorius, Mattior, AND, Procis IV vs. t, dVidt vs. t, Uvs. t, -u vs. dial date time electrode test: display KFR vol device label program Display | eetitietieg | ettration paramotors ‘Selection of dialog language (Current run number for result output Titration sequence with or without electrode test Result display with or without display of final volume Device label to identity instrument for remote control Program version Parameters Go to next inquiry with and . Meaning longlish, deutsch, francais, lespaiol yyyy-MM-DD_ HMM, o..999 ION, OFF ION, OFF lup to 8 ASCII characters no input Initial values are printed in bold face. Input range mer tier Extraction tim. Nogatve number: no adston of reagent | -9968..0.9900 s Gurng xracton tine step ott: Selection of typeof stop ceria ari, ime stop atte Stops tiation stop cits reached 1.:20,,999 pin teeter) Stop tivation if hee is no dosing during Wdslay) | 0.10.88 stop V Stop volume as security against titration vessel overflow | 0.00...99.99 ml, OFF start V Start volume in mode KFT. Predosing without controlling | 0.00...99.99 ml dos-rate Dosing ral or stat vlume 001.180 mimin, max sax.rete Maxum dosing rte during tration 0.01. 180 mimin, max tin-votuee incr. Minimum volume increment during tivation 01.89 pl min [Seeeseradtions coneitioning: Automatic coniioning o tration vessel ON, OFF rea ident: Requests ident ar start of tration ON OFF Requests sample size atter start of titration ‘ON, OFF Selection of rosut report atthe end a the tivation | fl short, OFFInstructions for Use of 701 KF Titrino Table of contents 1. Overview ae eee 2. Manual Operation 2.1 Getting started; a short operating course with examples 2.1.1 Entering data, setting the dialog language 2.1.2 Titer determination 2.1.3 Karl Fischer titrations 2.1.4 Drift, Drift, Drift. 620s cece eee eee cnet eee 2.2 Detailed description 2.2.1 Keypad 2.2.2 Entry keys with rolling inquiries 2.2.3 Mode selection, key 2.2.4 Configuration, key 2.2.8 Parameters, key... 0.0.02. ec 0c eee 2.2.6 Titration sequence 2.2.7 What titration parameters are best? 2.2.8 Calculations . 2.2.9 Drift display, key 2.2.10 Data output on a printer 3. Operation via RS232 interface (green leaves) 8.1 General rules 3.1.1 Call up of objects. 3.1.2 Triggers 3.1.3 Status conditions, error messages 3.2 Remote control commands 3.2.1 Overview coset eet eee et ee ees 3.2.2 Description of the remote control commands 3.3. Characteristics of the AS232 intorface 8.3.1 Data transmission protocol 3.3.2 Handshake 3.3.3 Pin assignment 3.4 What can you do if the data transmission does not work? 4, Error messages, troubleshooting 4.1 Error and special messages 4.2 Diagnosis 31 31 32 33 33 36 36 40 48 48. 49 53 85 57 57 585. Preparations 6. Appendix 55.1. Selup and interconnection of instruments 6.1.1 KF Titrino with 703 Ti Stand or 649 Stirrer 5.1.2 Connecting a printer... 5.1.3 Connecting a balance 5.1.4 Setting up the instruments for work with the KF oven 5.1.5 Connecting a recorder cece 5.1.6 Connecting a computer 5.2 Titration vessel 5.2.1 Equipping the titration vessel upper half 5.2.2 Sample addition . 5.2.3 Connecting the electrode: 5.3. Preparing the Exchange Unit : 5.3.1 Setting up 6.3011.XXX and 6.3012.XXx Exchange Units 5.3.2 Assembly and setting up 6.3006.XXX and 6.9007.XXX Exchange Units 5.3.3 Exchanging Unit. . 5.3.4 Maintenance 5.3.5 Thermostat jacket of 6.3011 0X and 6.3012.00 Exchange Units 6.1 Technical specifications 6.2 Standard parameters . 6.3 Translations of dialog texts 6.4 Pin assignment of the "Remote" socket 6.4.1 Lines of the "Remote" socket during the titration 6.5 Bibliography for KF titration 6.6 Warranty 6.7 Scope of delivery and ordering designations 6.7.1 701 KF Titrino 6.7.2 Exchange Units Index .. 68 68 68 69 70 70 a nm 72 72 73. 73. 74 74 75 75 76 76 7 77 78 80 82 84 85 85 86 86 88 11. Overview Front view of instrument: OOOO OOO Exchange Unit Display Conditioning lamp Lamp is on and lights continuously when the titration cell is dry during conditioning. Lamp flashes when conditioning is being performed but the titration cell is wet. Control keys on KF Titrino Dos: Dispensing is performed as long as is pressed. Used to pre- pare the Exchange Unit STOPIFILL: ~ Stops operations, e.g. titration, conditioning = Fill command after to prepare the Exchange Unit Identical with the key of the separate keypad. START: Starts operations, e.g. titration, conditioning, Identical with the key of the separate keypad. Setting of the display contrast Control of the dispensing rate in dispensing with and in subsequent filling Separate keypadRear view of instrument: © ® ® © © © @ S232 interface for the connection of a printer and balance or a computer, Remote lines (inputioutput) for the connection of a sample changer, robot, etc. Connection for the KF electrode Connection for the separate keypad Analog output for the connection of a recorder. Mains connection In the case of power supplies where severe HF disturbances are superimposed on the mains voltage, the KF Titrino should be operated via an additional mains filter, e.9 Metrohm 615 model. 1s switch Earthing socket The KF Titrino must be properly and effectively earthed, if necessary by means of the earthing socket. Connection for 703 Ti Stand or 649 Stirrer Supply voltage: +9 V DC (1<200 mA) Display of the set mains voltage Before switching on for the first time, check that the set mains voltage matches the voltage of your power supply. If this is not the case, disconnect mains cable and change voltage. Rating plate with fabrication, series and instrument number