BI TP HA L ( T 1 )

TN : L c Thnh
MSSV: 61003200
BI 1:
NH3 (L)

NH3 (K)

Qu trnh ha hi thun nghch NH3 lng ti:

p=1 atm
S = 23,208 cal/mol.K
1,5 mol NH3 lng c hh = 8,355 kcal
Tsi (NH3) =?
GII
Nhit ha hi thun nghch ca 1 mol NH3 l:
hh =
Shh =

=5570 cal/mol
Tsi =

=240 0K

H2Ohi

100

Vy Tsi =240 0K
BI 2:
. 1amt

Qu trnh ngng t ng nhit thun nghch :

T =100

, Qhh =40,656 KJ/mol

A=? , Q =? , H =?, U =?
GII
Q ngng t= -Qha hi = -40,656 KJ/mol
A = PV =(PV) =(nRT ) =nRT
M n = bin thin s mol kh = -1

H2Okh

A
V l qu trnh ng p nn H = Qp = -40,656 KJ/mol
U = Q A = -40,656 (3,1)= -37,556 KJ/mol
Vy : A=-

kJ

Q=-40,656 KJ/mol
H = -40,656 KJ/mol
U =-37,556 KJ/mol
BI 3 :
CP= 20,17 + 0,3665T ( J/mol.K)
Nng nhit 1mol kh t 25

ln 200

Tnh Q, A , H, U vi iu kin ln lt l :a) P=const

b) V=const
GII
a) P=const
QP =

PdT

A = PV =(PV) = nRT =

)
(

=28,254 KJ/mol
)

KJ/mol

H = Qp = 28,254 KJ/mol
Trong qu trnh ng p, ta c :
H = U + PV

U = H PV = 28,254 -

Vy : QP =28,254 KJ/mol
A=

KJ/mol

H = 28,254 KJ/mol
U = 26,799 KJ/mol
b) V=const

= 26,799 KJ/mol

Qv = (

A = PV =0 ( do V =0 ) KJ/mol
H = U + PV = U
M Qv = U
H =

KJ/mol

Vy : Qv = 26,8 KJ/mol
A =0
H = U =26,8 KJ/mol
BI 4
H2Ohi

H2Okh

n= 1 mol , T = 2980K , p= 1atm

Cp( hi nc )= 33,47 J/mol.K
Cp( nc lng )= 75,31 J/mol.K
ha hi 3730K= 40,668KJ/mol
Tnh H, S, G v cho bit qu trnh c t xy ra khng
GII
S
H2Olng 250C

(1)

H2Olng 1000C

Theo s ta c :

H2Ohi 250C

(3)

(2)

H2Ohi 1000C

KJ/mol

H = H1 + H2 + H3=

p(l)dT

+ ha hi +

p(k)dT

+ 40668 +

=43806J/mol

Tng t nh trn ta c :
S = S1 + S2 + S3=

p(l)

=118,42J/mol.K
G = H - TS
=43806 - 298 118,42= 8516,84 J/mol.K
BI 5
Tm phng trnh ph thuc nhit ca G0T
Cp,Au(kh )= 20,9 J/mol.K
Cp,Au(rn)= 23,65 + 5,18 10-8T J/mol.K
H0298,Au(rn)

Au(kh)

= 378,29 KJ/mol

G0298,Au(rn)

Au(kh)

= 338,58 KJ/mol
GII

Phng trnh ph thuc nhit ca G0T :

G0T = H0T - TS0T
Hoc
Au(rn)

( HT1 +

Au (kh)

Theo Cp,Au(kh ) v Cp,Au(rn) ta c

a0= -2,75
a1= -5,18.10-3
Ta c phng trnh :

pdT)

p(k)

HT = H0 + a0T + a1T2
H0 = HT - a0T - a1T2
=378,29 - (-2,75) 298 - (-5,18 10-3) 2982 =379340 J/mol
Th H0 vo phng trnh :
GT = H0 - a0TlnT - a1T2 + JT
G298 = H0 - (-2,75) 298 ln(298)- - (-5,18 10-3) 2982 + 298T
J = -153
G1000 = 379340 - (-2,75) 1000 ln(1000) - ( -5,18 10-3) 10002 + 1000 (-153)
=247926 J/mol
Vy G1000 = 247926 J/mol