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% + $& ,-
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http://echem.blogfa.com The Ohio State University Dept. of Chemistry BETHA Project % "# $

- 2-
2Zn(s) + Ag2O2(s) + 2H2O(l) + 4 OH (aq) 2Ag(s) + 2Zn(OH)4 (aq)
#$ !# "" !
!
- 2+ + + 3+
3MnO4 + 5Cr + 24H 3Mn2 + 5Cr + 12H2O
! $ " # # " ! $
"
2- 2- +
S2O8 (aq) + 2H2O(l) H2O2(aq)+ 2SO (aq) + 2H (aq)
! $ " # # " ! $
%& '(' ) * + , - ./0 #
6 4 7, 8 4 ,5 ) *1 + , - ./0 2 3 ,

+ 2+
H (aq) / H2 (g) (Pt) Mg (s) / Mg (aq)
+
<+ 2 > = H ! <+ '9 : ;' *
2+
<+ 2 > = Mg # <+ 2 > = H2 "
4 7, 8 4 ,5 ) *1 + , - ./0 2 3 , $
2+ 3+ 2+
Zn (s) / Zn (aq) Fe (aq) / Fe (aq) (C)
<+9' + 4 = 2 ;? @ A'= ! <+ 6 Zn
<+ C +( 2, %B 8 * B "
2+ 2+
<+ 2 > 9 Fe $ <+ 2 > = Zn #
6 4 7, 8 4 ,5 ) *1 + , - ./0 2 3 ,

2+ 4+ 2+
Sn (aq) / Sn (aq) (Pt) Fe (s) / Fe (aq)
4+
<+ 2 > 9 Fe ! <+ 2 > = Sn
2+ 2+
<+ 2 > 9 Sn # <+ 2 > = Fe "
0
+ ) E 5 4 4 )'9 3 D , C

2+ - -
Mn (aq) / (C) MnO4 (aq) (C) Br / Br2 (l)

Eo = +1.065 V 2 Br- (aq) Br2 (l) + 2 e-

Eo = +1.51 V Mn2+ + 4 H2O MnO4- (aq) + 8 H+ (aq) + 5 e-

HFE## $ HFE"I # G!E$C " H!E$C ! GFE##
 0
+ ) E 5 4 4 )'9 3 D , I

-
SbO2 (aq) / Sb (s) In (s) / In(OH)3 (s)
-
In(OH) 3 (s) + 3 e In (s) + 3 OH- Eo = -1.00 V
- -
SbO2 (aq) + 2 H2O (l) + 3 e Sb (s) + 4 OH- (aq) Eo = -0.66 V
HFE"# $ H EF! # H E I " HFEJI ! H!E"#
0
+ ) E 5 4 4 )'9 3 D , J
3+ 4+ - 2+
(C) Ce (aq) / Ce (aq) MnO4 (aq) / Mn (aq) (C)
Eo = +1.51 V MnO4- (aq) + 8 H+ (aq) + 5 e- Mn2+ (aq) + 4 H2O (l)
Eo = +1.61 V Ce4+ (aq) + e- Ce3+ (aq)
HFE F $ H E! # H!E " HFE$F ! H"E !
:' ) ) :' K 2L M* F
0 0 0
:' 4 , E ' 2L M* < , %* + G EFF , , In(OH)3 / In ) :' E <+ + HFE"# ) E
-
< SbO2 / Sb

SbO2- (aq)/ Sb (s) In (s)/ In (OH) (s)

3

HFEI $ H EC # G E$ " G EC ! H E$ (

) K 29 *
6 %* 2 4K Q ' Q''R6 1 2, S , * 4 )'9 3 % ) :' 4 N ' 2OP/*
< 2> ? 7, 8 1 T' 6 2)' ,
o 2- + -
E = +0.60 V S2O6 (aq) + 4 H (aq) + 2 e 2 H2SO3 (aq)
Fe3+ (aq) + e- Fe2+ (aq) Eo = +0.771 V
Eo = +1.00 V VO2 (aq) + 2 H+ (aq) + e-
+
VO2+ (aq) + H2O (l)
Eo = +1.77 V N2O (aq) + 2 H+ (aq) + 2 e- N2 (g) + H2O(l)
H E C $ HFE#F # H E"C " HFE C ! HFECC
6 %* 2 4K Q N', ' Q''R6 1 % ) :' 4 )'9 3 % ) :' 4 N ' 2OP/* !
< 2 > ? 4 7, 8 1 T' 6 2)' , ,
o 2- + -
E = +0.60 V S2O6 (aq) + 4 H (aq) + 2 e 2 H2SO3 (aq)
Eo = +0.771 V Fe3+ (aq) + e- Fe2+ (aq)
Eo = +1.00 V VO2+ (aq) + 2 H+ (aq) + e- VO2+ (aq) + H2O (l)
Eo = +1.77 V N2O (aq) + 2 H+ (aq) + 2 e- N2 (g) + H2O(l)
H!EFF $ H!EJF # H E"F " H ECC ! H!ECC
6 %* 2 4K Q N', ' Q''R6 1 % ) :' 4 )'9 3 % ) :' 4 N ' 2OP/* "
< 2 > ? 4 7, 8 1 T' 6 2)' , ,
o - - -
E = -0.858 V AuBr4 (aq) + 3 e Au(s) + 4 Br (aq)
Eo = -0.43 V Eu3+ (aq) + e- Eu2+ (aq)
Eo = -0.14 V Sn2+ (aq) + 2 e- Sn(s)
Eo = +0.49 V IO- (aq) + H2O(l) + 2 e- I- (aq) + 2 OH- (aq)
HFEC! $ HFE#! # H E$# " H E"$ ! H EFF
= 9 - U 29 * #
<+ 9 Q ,2 ?@ ' Q''R6 ' 29 * 1 % ) :' V'9 3 % ) :' 4 N
o 3- -
E = -1.05 V PO4 (aq) + 2 H2O (l) + 2 e HPO3 + 3 OH- (aq)
2-

Eo= +0.28 V PbO2 (s) + H2O (l) + 2 e- PbO (s) + 2 OH- (aq)
Eo= +0.56 V IO3- (aq) + 2 H2O (l) + 4 e- IO- (aq) + 4 OH- (aq)
- 3- -
1) IO 2) PO4 3) PbO 4) IO3 5) PbO2
 <+ = Q ,2 ?@ ' Q''R6 ' 29 * 1 % ) :' V'9 3 % ) :' 4 N $
o - - -
E = -0.858 V AuBr4 (aq) + 3 e Au (s) + 4 Br (aq)
Eo= -0.43 V Eu3+ (aq) + e- Eu2+ (aq)
Eo= -0.14 V Sn2+ (aq) + 2 e- Sn (s)
Eo= +0.49 V IO- (aq) + H2O (l) + 2 e- I- (aq) + 2 OH- (aq)
- 2+ -
1) I 2) Eu 3) IO 4) Au
<+ = Q ,2 ?@ ' Q''R6 ' 29 * 1 % ) :' V'9 3 % ) :' 4 N
o
E = +0.60 V S2O62- (aq) + 4 H+ (aq) + 2 e- 2 H2SO3 (aq)
Eo= +0.771 V Fe3+ (aq) + e- Fe2+ (aq)
Eo= +1.00 V VO2+ (aq) + 2 H+ (aq) + e- VO2+ (aq) + H2O(l)
Eo= +1.77 V N2O (aq) + 2 H+ (aq) + 2 e- N2 (g) + H2O (l)
+ 2+ +
1) VO2 2) Fe 3) N2 4) H2SO3 5) VO2
- ;)> %L9 4 W3 C
' T6 * %? = - U ;> T'6 6 2, D C , B , A ;)> # - ./0 4 L* ,
< ' 6 H2 ? 6 = %* HCl Y * )M* , C X >
< %( V' N6 C B - ;)> * %* V' N6 D ;)> 5 Z 4;)> 4 % )M* 2, %* 2> [ A % U !
1) A < D < C < B 2) A < D < B < C 3) D < A < B < C
4) D < A < C < B 5) B < D < A < C
' T6 * %? = - U ;> T'6 6 2, D C , B , A ;)> # - ./0 4 L* , I
< ' 6 K '= ? 6 = %* HCl Y * )M* , C B , A X >
< %* V' N6 D B - ;)> 5 Z - ;)> )M* 2, %* 2> [ C % U !
n+
1) C > A > D > B 2) B > D > A > C < = = A 6 %( C ;)> "
3) C > A > B > D 4) A > C > D > B 5) A > C > B > D
' T6 * %? = - U ;> T'6 6 2, D C , B , A ;)> # - ./0 4 L* , J
< ' 6 H2 ? 6 = %* HCl Y * )M* , C A X >
< %* ' 6 D B, A 4 =;)> 5 %* 2> [ Z - ;)> )M* 2, C % U !
+ +
< %* ' 6 Dn B ;)> 2, Bn = %* = D ;)> "
1) C > A > D > B 2) B > D > A > C 3) A > C > B > D
4) C > A > B > D 5) A > C > D > B
4 V'9 3 * %* (. 4 \* !F
< , %* ;' ) 1 - D] ', 4 = 2 ;? '*
0 1 @ B + Q (* " < > %* _ D6 = 1 2 + %& B ! < '? %* :' ^ 0
<+ + = 2 ;? N', $ < %* `WB %D * 4 # < , ;> ;' V(.
%& ) 6 - D] = %* N 4 = 2 ;? '* !
< %* +> )M* ^ 0 " < > %* _ D6 9 V(. 1 ! < = 2 ;? N',
%* + P 1 +( 2, %B 8 * $ < , ;> - * 1 @ B + Q (* #
+ + 4 M'[ 6 '* !!
<+9= K '= ? 4 , D9(6 N> )M* 4 , EF M+O)a %& '(' ) 4 , + P <I
< 2L M* +9 2 R* X 6 6 %* = 9 4 , R6 +, b <II
< = %* ''c6 ) V'9 3 = ? N> ''c6 <III
III $ III , I # II " II , I ! I