Answer For Paper One

Question
1
2
3
4
5
6
7
8
9

Answer
B
B
B
B
C
A
C
D
D

Remarks

[OH-] =

Kb .C

= 5.48 X 10-4
pOH = 3.26
pH = 14 3.26
10.74

10
11
12

C
B
D

Mole reacting ratio between X and NaOH = 1:3

Concentration of X in aqueous layer is given by:
M X 25.0
1
0.10 X 15.55 = 3
M = 0.020 moldm-3
Mass of X in 1 dm3 aqueous solution = 0.020 X 176g
= 3.52g

50
1000

mass of X in 50cm3 of water = 3.52 X

= 0.176g
hence, mass of X that dissolved in 100cm3 of ether = 2.34 0.176
= 2.164g
partition coeffeicient of X between ether and water =

2.164
0.176
/
100
50

= 6.15

13

14

15
16
17

A
C
D

1.50 X 0.1
No of moles of Cr2O72- used =
= 0.0015 mol
1000
45 .0 X 0.2
No moles of M2+ reacted =
= 0.009 mol
1000
0.009
No of moles of M2+ oxidized by 1 mol of Cr2O72- =
=6
0.0015
However, 1 mol Cr2O72- 6e
6M2+ 2Mn+ + 6e
n=3
Based on Hesss Law:
(+107) + (+496) + (+79) + (a) + (-928) = -574
a = -328 kJmol-1

120 X

60
100

= 72

18
19

B
C

start
reacted
equilibrium

N2O4 (g)
1
0.4
0.6

2NO

(g)

0
0.6
0.8

Kp = (NO2)2 / N2O4

0.8
0.6
P )2 / (
P)
1.4
1.4
16
P
=
21
=(

20
21

C
C

Q = It
= 5 X 3860
= 19300
mole of electron involved =

19300
96500

= 0.2
Al3+ + 3e Al
Mole of Al = 0.2 / 3
= 6.67 X 10-2
mass of Al = 6.67 X 10-2 X 27
= 1.8 g

22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45

B
C
D
D
D
A
A
D
D
C
B
C
C
B
B
D
D
D
D
D
C
C
C
B

46
47
48
49
50

D
B
C
C
A