) (

(I Br2
) . ( Al 3+ + 3Br
(1 /
(2 .
(3 .
(4 2ml .
d = 3,1
: :
M ( Al ) = 27 g / mol :
5 27
M ( Br2 ) = 160 g / mol :
***************************************************
: :
* 1 ml = 1 cm 3
2ml = 2cm 3
:
*
) ( x
) (eau

= ) d ( x ( x) = d (eau ) = d 1g / cm 3 :
(eau ) = 1g / cm 3

:
: :

= 3,1g / cm

Al 3+ / Al (1
----------------------------------------------------------Al Al 3+ + 3e
(2
Br2 / Br

Br2 + 2e 2 Br

-----------------------------------------------------------------(3 .
---------------------------------------------------------------(4 ? ) m( Al
:
3+

Al Al + 3e
X 2

Br2 + 2e 2 Br
X 3
2 Al + 3Br2 2 Al 3+ + 6 Br
:
) n( Al) n( Br2
=
2
3
) m( x
:
:
= )n( x
)M ( x
) m( Br2
) m( Al
=
) 2 M ( Al ) 3M ( Br2
) ( Br2 ) V ( Br2
) m( Al
:
=
) 2 M ( Al
) 3M ( Br2
) 2M ( Al ) ( Br2 ) V ( Br2
= ) m( Al
:
) 3M ( Br2

 :
2 27 g / mol 3,1g / cm 3 2cm 3
= ) m( Al
0,7 g
3 160 g / mol

//////////////////////////////////////////////////////////////////////////////////////////////////////
( II .
1m 3
50ml 100cm 3 . S
S
V0 = 25cm 3 S1
. c1 = 10 4 mol / l

2
(1    
 
SO4 / SO2 : MnO4 / Mn 2+
) ( aq

) ( aq

) ( aq

) ( aq

& (2  "#$ # , -. /*) (

 (3 (1:  9 "#$1(
 V1 = 8,8ml -=> ?  12 &565 12.13.
@52& C 0 . S
3
(4( 1m .
3
( &  $ 5B 9:CD LG KH&3$* = FGH I) 250mg .m : 1
 1Q L 1 I

H&. 9-C28$ L2
 U

+
)( 1
( MnO4 + 8 H + 5e
Mn 2+ +
4 H 2 O ) x2
) ( aq

)(l

)x 5

) ( aq

SO4 + 4 H + 2e
) ( aq

2
) (l

) ( aq

) ( aq

+ 2 H

( SO

2
) ( aq

2 Mn 2+ + 5 SO4 + 4 H +
) ( aq

) ( aq

2 MnO4 + 5 SO2 + 2 H 2 O

) ( aq

) (l

) ( aq

) ( aq

-------------------------------------------------------------------------------------------------------) (2 :

)(1

) n( MnO4 ) n( SO2
=
2
5

.
----------------------------------------------------------------n
(3 :
V
C1 .V1 C 0 .VO
=
) (1 :
2
5
5C1V1 5 10 4 mol / l 8,8 10 3 l
= CO
=
= 8,8 10 5 mol / l :
3
2VO
2 25 10 l
=C

--------------------------------------------------------- (4( VO .
n o = C O VO

K. 1m 3 V = 4VO = 100cm 3 # Q12 &HY -

(Y  W* (=.-
:

n( SO2 ) = 4C O VO = 4 8,8 10 5 mol / l 25 10 3 mol / l = 8,8 10 6 mol

:
n=

m
n
: C =
M
V
C=

m
:
M V

m( SO2 ) = C O M ( SO2 ) V = 8,8 10 mol / l 64 g / mol 100 10 l = 563 10 g = 563g

5

250mg / m 3

: 1 =) FGH I *KH&3$ LG 5B 9:CD $( &

.1 L 1Q\ #

Abdelkrim SBIRO
(Pour toutes observations contactez mon mail)
sbiabdou@yahoo.fr