Scribd Logo
Importer

Bienvenue sur Scribd !

  • N2 Solubility in Water

    Transféré par

    Qiuping Lv
    24 vues39 pages

    Copyright

    © Attribution Non-Commercial (BY-NC)

    Formats disponibles

    PDF ou lisez en ligne sur Scribd

    Avez-vous trouvé ce document utile ?

    Ce contenu est-il inapproprié ?

    Signaler ce document

    Droits d'auteur :

    Attribution Non-Commercial (BY-NC)
    Téléchargez comme PDF ou lisez en ligne sur Scribd
    Signaler comme contenu inapproprié
    24 vues39 pages

    N2 Solubility in Water

    Transféré par

    Qiuping Lv

    Droits d'auteur :

    Attribution Non-Commercial (BY-NC)
    Téléchargez comme PDF ou lisez en ligne sur Scribd
    Signaler comme contenu inapproprié
    sur 39
    The Solubility of Nitrogen and Air in Liquids Aubin Battino, Timothy R. Retticn,”” and Toshiniro Tominaga" Department of Chemistry, Wright State Univers, Dayton, Ohio 45435 ‘This review covers the solubility of wilsogen and at in liguids asa function of tempera ture and pressure. Solubility data for individual systems were critically evaluated. Recom- ‘mended or tentative values are presented as smoothing equations and/or in tabular form. ‘Trendsin homologous series or related solvents are discussed. Data forthe n-alkanes were smoothed with respect to temperature, pressure, and carbon number. Liquids include: water; heavy water; seawater; aqueous salt solutions; mixed solvents; hydrocarbons; or= ganic compounds containing oxygen, halogen, sulfur, nitrogen, or silicon; olive oi; va fous biological tuids; H,S; SO;; NH; CO,; nitrogen oxides; and several halogen snd boron containing inorganic solvents, Key words ar: aaneous solutions: biological fuids: ens solubility: drocarbons: nore sol vents mixed solvents nitrogen; organic solvents; seawater, Water Contents 1 Ansan son pun Waer asd 2-Propnel/ 2 Matha fest. i Wine Mie a Se Ba aug, MNES Tas 3.1, Solubility Units 567 panetriol (Glycerol}/Water Mix- 32) Relat Etats ser on 23, Fang Eat sa tae Negi bain "33a 34. Therapie Fcons se Fa steattehond 4. Ntopn Sai eA trim) Mare an Sut seen in Wa Saas ops sss ropa Seapets apt 30 ow neoace Mes pond “6 tae Sivope Sts n ey 1x, Repo ane ih promo A/a Mista Hic me han, Sara a tie Roig Bcuricon Wace side ter Mies 42, Sibi MipennSeavaersceces S10. AS, Nope Mie on (01055 4.3. Solubility of Nitrogen in Aqueous Salt So- MPa), sven te 7 UE sis af anal fee Added Danone ad Eel Pos 22. GES Gopi sae mn Fmt 35. omtsun Bs triacs Ean 44, ‘Ssbitey of Nog in Gru Sohens Ete Ont Diy Pon ine = Ether is El nd Bese Te Sisco Heenan Wate res on sae Mnuree Ppl 44m Niropn St Tinanpete and Ce Peas a eee tae. Riropn Seba ie Be. sa, Mins af hye Fw Dimethylhydrazine 7 46. Niro i Met Sve oa tf Fn Nr Se une ern ot «= HEE_‘Mit of Ae Ad ad Cy ‘Science, -1 Rida-ch, Okayama-200, Japan. kezanone tan Minuet Se © 1984 by the US. Secretary of Comme behalf of the United States. re toes SOSA mma «se Mine of Mattie ‘Repos ealabl frome ACS; ee Reprint Lit at back of se 4.6, Mixtures of Oxygen and Nitrogen 0047-2080 8¢/020865-38/807.00, 563 4 314 sm sv 375 515 375 315 ss 516 316 316 576 sm Phys. Chem Ret Data, Vol 13, No.2, 1884 41. 48. 49, 4 Phys. Chem. Ret. Data, Vol 13, No.2 BATTINO, RETTICH, AND TOMINAGA in Cyclohexane ‘Nitrogen in Hydrocarbons (0.101 325 MPa) 47a. nAlkanes as a Group 471. Alkanes Individually 42.41. n-Pemtane un 4782. wlexane. 473. n-Heptane.. 474, n-Octane. 47b5. 224-Trinetiipentane. 4706, wNonane, 4.7.7. n-Decane 4TB8. Cyt0Cs 47.09. nHesadecane, Cyclic Hydrocarbons 47.0.1, Cyelohexane. ce 47.62. Other Cyclic Hydrocar- bons. Aromatic Hydrocarbons 474.1. Benzene. $7412. Toluene Ate. 42a. Nitrogen in Hydrocarbons [above 0.101 325 MPa) : 48a. The n-Alkanes asa Group 48. Methane... 48. Ethene 48d. Ethane senso 48.e Propene 481 Propane 48g Butane. 4.8), 2-Methylpropane (Isobutane) B85 MP UMAR creme 2-Methylbutane nHexane setleptane Octane . 2.2,4-Trimethyipentane Desa wenn m-Dodecane n-Hexadecane Cyclohexane $00, Methiyleyee 481. Benzene 48u, Toluene Nitrogen in Ormanic Compounds ing Oxygen (0.101 325 MPa)... 492. Alcohols asa Group .... 49. 494. 492. 2-Propanol 498. 498. 49h, 495, 495, eHtepuanl 49%. 1-Octanol 491. -Decanol 49m. 1-Nonanol. EUndecanol aad Dodecanal ... sm 377 377 377 377 377 378 378 378 378 378 378 578 578 378 379 379 379 379 490. Cyclohenano! and 1,2-Ethanediol (Ethylene Giyeo!) 49.0: 2-Propanone (Acetone). 49.p. Acetic Acid, Methyl Ester [Methyl Acetate) 49.4. 1, -Onybiscthane (Diethyl Ether 49.7. Other Organic Compounds Con- taining Oxygen ‘Nitrogen in Organic Compounds Containe ing Onygen (above 0.101 325 MPa}... 4.10, Methanol 4.108. Ethanol 410s, Cyclohexanone 410d, 1,Dioxolan-2-one,medhyl, {Propylene Carbonate} 1,2,3-Propanetriol, (Glycerol Triacetate) Pentanedioic AcidDimethyl Es- ter (Dimethyl Glutarate) 2,3,6)1,14-Pentaosapentadccane (Tetcamethylene Glycol Dimethyl Ester). oes 4.10. 1,2-Epoxyethane Ethylene Oxide) "Nitrogen in Organic Compounds Contain- ing Halogen (0.101 325 MPa)... 4.ll.a. Dichlorodifuoromethane (Freon- 12) se ve ‘Tetrachloromethane sn. ‘Trichloromethane (Chloroform) 1,2Dichlore-1,1,2.2-tetrafuor- ethane (Freon-T14) sno 1M.2ichlre22-ioroeh- 4.10. 406. ‘wiacetate 4.104. 4108. 4a. aan, atte and. Ale. sane ate. tlh ani L-Chlorohexane Undecafluro(triluorometbylley- clohexane, (perfuoromethyleyclo- Iaexane) ee Hevadecatorobepiane iperfuor- pate nn 1-Bromoheptane Decafiuorobisiridluoromethy) celohexane _(perfuorodimethy] eyelohexane) ee 1412.23,3485,5,66-Trideca- fuoro-6[1,2,2,2-etrafluoro-1- (rinuoromedsyjetaony}esane (perfiuoro-I-isopropoxyhexane} 1,12,2,334,4-Octafuoro-1y¢- bist] 2.2.2-tetraivoromethyle1- (trifucromethyljethony) butane [perfuoro-| 4-diisopropxybutane) Methane, chlorotrifuT0 uenun “Teuntupiomettaie on Germanium Tetrachloride Other Organic Compounds Con- taining Halogen 4.12, Nitrogen in Organic Compounds 4M 4k. 4a. 4.1m, 4a. 4i1o. annp. Ala. ails. 387 387 57 ses 588 S38 588 a8 see 38 se8 588 588 588, 588 seo 89 589 539 se9 589 389 369 590 390 20 590 590 ‘SOLUBILITY OF NITROGEN AND AIR IN LIQUIDS {ng Halogen (above 0.101 325 MPa}. Suiza, Calorouimuuremeviane (rico 1B) 4.12b, Dichiorodituoromethane 4c. Tetrachloromethane 4.124, Tetrafuoromethane 4.126, Chlorodiivoromethane 418, zopen in Solvents Coming Niogen (0.101 325 MPs) 4.130, Nitromethane 591 4136, NMethylacetamide 591 413e. Nitie Aci, Propyl Ester 591 48 Ryo Ping and pene dine. 4.1%¢, Nitrobenzene S91 TF Renranamine Ailion) 391 41g. 112,23,3464-Nonafuoro- NN bis. (nonsfivorobuty}I-butana- mine (perfuorobut] amine) ou. 597 413m, Hydrazine, Methylydaazine, and 1, Dimethylhydrazine $92 443i, 12Dimethylbydzazine oncnone 592 4614, Nitrogen in Solvents Containing Niosen {above 0.10) 328 MPa). 4.14. Pyrvolidinon,t-methyl- 414. 2-Pyzrolidinone,1 5-dimethy)- Nitrogen in Organic Conmponnde Crntsin: ing Sulfur o Scone 415. Carbon Disulfide 4180. Sali isethane Dime So rosie} Sulfur Hexafuoride.. Octamethyleycloterasiloxane Methyltrichloroilane and Silicon Tetrachlerde. Biologia! Fuids 4.163 Solubility in Some Oils and Lara ANG. Solubility in Olive Oi 4.160. Nitrogen Solubilities in Various ‘Human and Animal Fuids Nitrogen Sohbilities in Benzene Solutions ot Cholesterol, Cepna- Tin, and Lecithin ann [Nitrogen Solubities in Urea/Wa- fe Mites on Nitrogen Solis in Some Mis- cellaneous Biological Solutions. Miscellaneous Fluids... : 4.17. Compounds Containing Sur 417. Nitrogen Oxides AW 2e. AmmORIA conn 4178. Carbon Dioxide nn 417e. Halogen and Boron Cont inne Solvents ‘Air Soluble. S11, Water and Aqnnove Sat Soiions 52 Hygrcurtonsand Orpen Cotining o- vents Halogen Containing Solvents. 4186. 4isd. 4182. 416, 4.164, 4.166. 4165, 4.7 33, $90 390 590 390 530 590 590) ° i & 13 14 18, 16. 1. 1. Se. Miscellaneous ‘Cuneta ‘Acknowiedgments, References List of Tables. ‘Second virial coficients fr nitrogen... Solubility of nitrogen in water for partial pres: sureof gas0.101 325 MPa calculated by Eq (10) ‘Thermodynamic functions fr the process of dis solving nitrogen at 0.101 325 MPs partial pres ‘vein water at selected temperatures Solubility of nitrogen in D.O at 0.101 325 MPa Coeficients for Eq. (13) for several solubility bility in seawater Bunsen cotficient cfr nitrogen solubility in ‘seawater at several temperatures and salinities. Sechenov sal-flect parameters for nitrogen ds ‘solved in aqueous sulfuric acid solutions Sechenoysalt-eflect parameters for nitrogen di ved in aqnente stom hydroside slutins Sechenovsalt-eflect parameters fr nitrogen dis solved in aqueous sodium chioride solutions. Sechenov sal-effect parameters fr nitrogen sal ‘Uptyin molar Liciana Rt aqueous solunons Sechenov salt-effect parameters for dissolving sitrogen in aqueous K,CO, solution. Sechenoy salt-effect parameters for disalving nitrogen at 298.15 Kin aqueous acetate solu- ‘Mole fraction solubilities of nitrogen in alabol/ water mintoree at 0.101 328 MPa partial pres- sure of nitrogen, 10%, Mole fraction solubilities of nitrogen in water rich regions of sleahol/water mintures at ‘O.101 325 Ma partial pressure of nieogen ‘Mole fraction solubilities of nitrogen in mixtures ‘of ethanol plus 2-propanone and ethanol plus 2.2dctrimethvlpentane 0.101 325 MPa partial pressure of nitrogen, 10%, Mole fraction solubilities of nitrogen in mixtures cof acetic ci, ety ester ethyl acetate] plus eth- i tum ny ts) pls wt ‘nol: and beazene plus ethanol at 0.101 325 MPa partial pressure of nitrogen, 10x, ‘Mole faction solubilities of nitrogen in mixtures ‘of I-propano! plus 2,24-trimethylpentane:c)- ‘lohexane plus 22.4rimethylpentane; and hy-

    Vous aimerez peut-être aussi