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.

AMAP Assessment Report: Arctic Pollution Issues. Arctic Monitoring and Assessment
Programme, Oslo, 1997.
Arctic Pollution Issues: A State of the Environment Report. Arctic Monitoring and
Assessment Programme, Oslo, 1997.
Compilation of EU Dioxin Exposure and Health Data. Report produced for European
Commission DG Environment UK Department of the Environment Transport and the
Regions (DETR). Commission of the European Community, Brussels, 1999
HELCOM 1996. Third Periodic Assessment of the State of the Marine Environment of the
Baltic Sea, 1989-93. Helsinki Commission, Helsinki, 1997.
National and Regional Dioxin and Furan Inventories: National and Regional Emissions of
PCDD/PCDF. UNEP Chemicals, Geneva, Switzerland, 1999
Organochlorines Programme. Ministry of the Environment, Wellington, New Zealand, 1998.
Persistent, Bioaccumulative and Toxic Chemicals in Central and Eastern European Countries
State-of-the-Art Report. Draft 1st Version, TOCOEN Report No 150. Recetox TOCOEN
73

& Associates, Brno, Czech Republic, August 1999.

Persistent Environmental Contaminants and the Great Lakes Basin Population: An Exposure
Assessment. Ministry of Public Works and Government Services, Canada, 1998.
Persistent Organic Pollutants. Monitor 16. Swedish Environment Protection Agency,
Stockholm, 1998.
Regionally Based Assessment of Persistent Toxic Substances. Workshop Reports from a
Global Environmental Facility Project. UNEP Chemicals, Geneva. 1999.
THE INVENTORY OF SOURCES OF DIOXIN IN THE UNITED STATES, External
Review Draft, EPA/600/P-98/002Aa, 1998
UNEP/IPCS. Training module No. 3. Chemical Risk Assessment. Geneva, 1999.

WHO/IPCS, Environmental Health Criteria Document

-

Aldrin, No. 91, 1989.

Chlordane, No. 34, 1984.

DDT and its derivatives, No. 9, 1979.

DDT and its derivatives, Environmental Aspects, No. 83, 1989.

Dieldrin, No. 91, 1989.

Endrin, No. 130, 1992.

Heptachlor, No. 38, 1984.

Hexachlorobenzene, No. 195, 1998.

Mirex, No. 44, 1984.

Polychlorinated biphenyls and terphenyls, No. 140, 1993.

Polychlorinated dibenzo-p-dioxins and dibenzofurans, No. 88, 1989.

Toxaphene (Camphechlor), No. 45, 1984

UNEP Chemicals is operating a POPs Clearinghouse (http://www.chem.unep.ch) which also
has extensive links to other international and regional organizations, governments, NGOs,
conventions etc. e.g. http://www.ospar.org; (http://www.helcom.fi; http://www.ijc.org/ and
http://www.gefweb.org You may also join the PBTs (Persistent Bioaccumulating Toxic
Substances) Discussion Club No. 1 on http://recetox.chemi.muni.cz/PBTs/content.htm. Other
useful addresses include Riskline HTTP://www.kemi.se/default.cfm?page=kemdatbas.htm
the Integrated Risk Information System (IRIS) in USEPA http://www.epa.gov/eris and the
74

European Chemicals Bureau http://ecb.ei.jrc.it.

- - -o---

75