1) A very dilute solution is prepared by dissolving 'x1' mole of solute in 'x2' mole of a solvent.

The mole fraction of solute is approximately equal to A.x1/x2 B. x2/x1 C. 1 - (x1/x2) D.1/x2 2) CaCO3 contains __________ percent of Ca by weight. A.40 C. 96 B. 48 D.12

3) The evaporation of aqueous solution of sugar causes its molarity to A.decrease. (B) increase C. remain unchanged. D.either (a) or (b); depends on the concentration of the solution. 4) S.T.P. corresponds to A.1 atm. absolute pressure & 15.5C. B. 760 mm Hg gauge pressure & 15.5C. C. 760 torr & 0C. D.101.325 kPa gauge pressure & 15.5C. 5) The weight fraction of methanol in an aqueous solution is 0.64. The mole fraction of methanol XM satisfies A.XM < 0.5 B. XM = 0.5 C. 0.5 < XM < 0.64 D.XM 0.64 6) Volume percent for gases is equal to the A.weight percent. B. mole percent. C. weight percent only for ideal gases. D.mole percent only for ideal gases.

7) Pick out the wrong statement. A.The evaporation of aqueous solution of glucose causes its molarity to increase. Both the freezing point as well as boiling point of sea water is more than that of B. distilled water. C) C)The solution containing equal masses of two liquids 'X' and 'Y' has the same mole fraction of' 'X' and 'Y'. D.both (b) and (c) 8) N.T.P. corresponds to A.1 atm.absolute pressure& 0C. B. 760 mm Hg gauge pressure & 0C. C. 760 torr & 15C. D.101.325 KPa gauge pressure & 0C. 9) Number of gram equivalent of solute dissolved in one litre of solution is called its A.normality C. molality B. molarity D.formality

10) Simultaneous doubling of the absolute temperature of a gas and reduction of its pressure to half, will result in __________ in the volume of the gas. A.no change B. doubling C. l/4th reduction D.four fold increase

11) Equal masses of the methane and Hydrogen are mixed in an empty container. The partial pressure of hydrogen in this container expressed as the fraction of the total pressure is A.1/9 B)8/9 C. 1/2 D) 5/9

1212) How many phases are present at eutectic point A)1 B)2 C)3 D)4

13) Which of the following gravity scale is used for liquids heavier than water ? A) Baume scale B) Twaddel scale C) API scale

14) A mixture of gaseous is containing 25% moles of A , 25 % moles of B and rest of gas C , average molecular weight of mixture is , If MA = 20 ,MB =10 and MC=30 A. 20 C. 22.5 B. 18 D.25

15) N2 content in urea sample was found to be only 42%. What is the actual urea content of the sample? A) 80% B)90% C)95% D)98%

16) Density of carbon dioxide is .. Kg/Nm3 A)0.002 B)1.96 C)0.51 D)1

17) The rate of material __________ is zero in case of a steady state system. A.accumulation C. Input B. production D.generation

18) pick out the wrong unit conversion of temperature.. A) 0c=(F-32)*0.55 B) Temperature difference of 1K =9/5 0F C) 0F=(0C+17.778) 1.8 D) None of the above

19) In a chemical process of two reactants A (200 kg) and B (200kg) is used as reactants. If conversion is 50% and A and B reacts in equal proportion then calculate the weight of the product formed. a) 150 kg b) 200 kg c) 250 kg d) 400 kg 20) 1M3 is approximately equals to A) 28 litres B)10 litres C)35 ft3 D)10 ft3

Q21 : In a reactor reactants are fed at 1 atm and 250 c with mass flow rate is 400 kg/hr . After the reactions , products mixture are discharge at 1 atm and 470 c with total moles of mixture is 0.55 kmol/hr . find out density(kg/m3) of product mixture. Assume no losses in the reactor. Q 22: In a mixture contain 2 mol NaOH , 2 mol Na2SO4 and 10 mol H2 O , mol fraction of Na+ ion is a) 0.3 b) 0.2 c) 0.13333 d) 0.4 Q 23: In a paper mill , a wash liquor containing 5 % (by weight ) solid is concentrated in an evaporator to yield a lye containing 40 % (by weight) solids . The quantity of water evaporated per 100 kg of feed is : a) 67.5kg b) 75 kg c) 87.5 kg d ) 90 kg

Q24: The molar composition of gas is 20 % H2 , 10% O2 ,30% CO2 and balance water . If half of water condenses , the final mole percent of H2 in the dry gas will be a) 20% b) 33.33% c) 25% d) 10 % Q25: Pure O2 is mixed with air to produce an enriched air containing 50 % volume of O2 . The ratio of moles of air to O2 used is a) 1.72 b) 0.58 c) 0.5 d) 0.20

Q26: A multiple effect evaporator has a capacity to process 400 kg of solid caustic soda per day when it is concentrating from 10% to 25% solids . The water evaporated in kg per day a) 60 b) 2400 c) 6000 d) 4800

Q27: Assuming that CO2 obeys perfect gas law , calculate the density of it (in kg/m3) at 2630 C and 2 atm . a) 1 b) 2 c) 3 d) 4

*common passage for Q28-30 In a absorbing column air is introduce at the rate of 300 m3/hr , 25oC and 1 atm . When air is leaving the tower , it containing 90 % N2 and 10 % O2 at 400C and 1 atm . Assuming that only O2 can be absorb in tower , Q28 : How much has O2 been absorbed by tower a) 47.968 kg/hr b) 48.98 kg/hr c) 50.65 kg/hr kg/hr Q29: Partial pressure of nitrogen in outlet is a) 0.21 b) 0.10 c) 0.79 d) 46.75

d) 0.9

Q30 : Volumetric flow rate of exit stream is a) 10 m3/hr b) 10.77 m3/hr c) 11.25 m3/hr d) 9.76 m3/hr

Answers: 1-a , 2-a, 3-b ,4-a ,5-b, 6-d , 7-d, 8-a, 9-a , 10-d , 11-b , 12-c , 13-b , 14-c , 15-b, 16-b , 17-a , 18- d , 19- b , 20-c 21- 27.7 kg/m3 , 22-a , 23-c , 24-b , 25-a , 26-b , 27-b , 28-a , 29-d , 30-b.