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Note: Iquitos Reduced Crude is a foreign stream which is produced by the Petroperu Iquitos
Refinery and shipped to the Talara Refinery. It is composed by reduced crude (80% vol) plus
straight run naphtha (20% vol), and the average flow rate is 3,500 BPD. It shall be analyzed then to
be used in the refinery optimized by the CONTRACTOR.
PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 25 OF 81
DATE: JULY 10, 2009
International Bidding Process NPCI-002-2008-OFP/P ETROPERU
3. DESIGN BASIS
3.1 General Philosophy and Optimization Objectives
3.1.1 Reliability and Service Factor
Equipment design and sparing should be sufficient to obtain a
minimum operating service factor of 0.95, with 3-4 years of
operations between major shutdowns or general inspections. To
achieve this high reliability, all components of the plant should be of
proven design with the necessary redundancy.
The selection of materials for the plant and critical parts of principle
equipment will be designed for a 40 year service life, taking into
consideration safety factors, climatic conditions, etc.
3.1.2 Capacity and Turndown
The refinery will be designed to produce the following product slate
from a 95,000 BPSD of Crude Feed:
Product # Product Title
Nominal
Production Pattern
1. LPG 8,831 BPD
2. Gasoline 19,352 BPD
3. Kerosene/Jet Fuel 8,200 BPD
4. Diesel Fuel 39,819 BPD
5. Heavy Fuel Oil & Asphalt 10,837 BPD
Total Liquid Product (1-5) 87,039 BPD
6. Sulphuric Acid 460 T MD
7. Petroleum Coke 488 T MD
EMPLOYER has defined a service factor (refinery utilization factor) of
95% as a minimum. During the FEED effort the CONTRACTOR must
follow this instruction, taking in account the complexity of each
process unit. Any change shall be approved by the EMPLOYER.
Solvent streams shown in Figure 2-2 are intended to be transferred to
other EMPLOYER refineries for processing, while Naphtha stream
shown in Figure 2-2 will be used in the TRM Gasoline pool. But the
refinery will keep the operating flexibility to maintain the production
and dispatch of these streams.
PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 26 OF 81
DATE: JULY 10, 2009
International Bidding Process NPCI-002-2008-OFP/P ETROPERU
Capacities of individual units are listed in Sections 1 and 2 of this
MJS Part B Basis of Design document. The refinery must be able to
operate efficiently at a minimum 50-60% of the design capacity.
3.1.3 Design Philosophy
The FEED-EPC CONTRACTOR, in consultation with the
EMPLOYER or EMPLOYER Representative, will develop design
philosophies which will serve as a basis and dictate the design for:
Complying of the project objectives
Energy recovery
Piping hydraulics
Waste and Effluent generation and management
Process controls
Electrical consumption
3.1.4 Unit System of Measurement
The International unit system of measurements will be used,
nevertheless for the measurements of volume or flow rate they will be
indicated also in barrels and barrels per day and the measurements
of pressure expressed in kilogram/ square centimeters and in
pounds/square inch.
3.2 Feed and Product Specifications
The following Subsections of Section 3.2 of this MJS Volume 2 Basis of
Design document provide the Feed and Product Specifications for the Talara
Modernization Project.
PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 27 OF 81
DATE: JULY 10, 2009
International Bidding Process NPCI-002-2008-OFP/P ETROPERU
Feed
3.2.1 Crude Oil
3.2.1.1 Napo Crude Oil
Property Specification Units Method
API Gravity 18.8 @ 60 F ASTM D-287
Specific Gravity 0.9414 60/60 F ASTM D-1298
SaltContent 23.1 Lbs/1000 bbls ASTM D-3230
Pour Point +5 F ASTM D-97
Sulphur 2.18 wt. % ASTM D-4294
3.2.1.2 Talara Blend Crude Oil
Property Specification Units Method
API Gravity 34.2 @ 60 F ASTM D-287
Specific Gravity 0.8542 60/60 F ASTM D-1298
Salt Content 85.0 Lbs/1000 bbls ASTM D-3230
Pour Point 20 F ASTM D-97
Sulphur 0.071 wt. % ASTM D-4294
3.2.1.3 Talara Petrobras Crude Oil
Property Specification Units Method
API Gravity 33.2 @ 60 F ASTM D-287
Specific Gravity 0.8593 60/60 F ASTM D-1298
Salt Content 100 Lbs/1000 bbls ASTM D-3230
Pour Point -30 F ASTM D-97
Sulfur 0.094 wt. % ASTM D-4294
PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 28 OF 81
DATE: JULY 10, 2009
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3.2.1.4 Talara Petrotech Crude Oil
Property Specification Units Method
API Gravity 37.2 @ 60 F ASTM D-287
Specific Gravity 0.8389 60/60 F ASTM D-1298
Salt Content 18.0 Lbs/1000 bbls ASTM D-3230
Pour Point -60 F ASTM D-97
Sulfur 0.065 wt. % ASTM D-4294
3.2.1.5 Crude Oil Slate
The design basis for crude oil slate expressed in
nominal BPD is:
Napo 57,500 BPD
Talara Blend 7,150 BPD
Talara Petrobras 3,000 BPD
Talara Petrotech 12,350 BPD
TOTAL 90,000 BPD
With an average refinery utilization of the refimery of
95% for the TRM Project the nominal 90,000 BPD
increases to a 95,000 BDP per stream day rate (BPSD)
3.2.1.6 Reduced Crude - Iquitos
It is a raw material. Its use must be evaluated by the
Contractor as part of the project basic engineering
services. The typical characteristics are:
25
Property Specification Units Method
API Gravity 18.5 @ 60 F ASTM D-5002
Specific Gravity 0.943 60/60 F ASTM D-4052
Sulfur 0.5 % weight ASTM D-4294
kinematic
viscosity
40 cSt @ 120 F -
25
Question 54 Round 1
PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 29 OF 81
DATE: JULY 10, 2009
International Bidding Process NPCI-002-2008-OFP/P ETROPERU
Flash Point 125
o
F ASTM D-56
3.2.2 Crude Oil Assays:
3.2.2.1 Napo Crude Oil
PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
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DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 31 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 32 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 33 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 34 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 35 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 36 OF 81
DATE: JULY 10, 2009
International Bidding Process NPCI-002-2008-OFP/P ETROPERU
PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 37 OF 81
DATE: JULY 10, 2009
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3.2.2.2 Talara Crude Oil
PETROPERU S.A. VOLUME 2
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PAGE 38 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 39 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 40 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 41 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 42 OF 81
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 43 OF 81
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 44 OF 81
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 45 OF 81
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 46 OF 81
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 47 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 48 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 49 OF 81
DATE: JULY 10, 2009
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 50 OF 81
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 52 OF 81
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PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
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3.2.3 Product/By Product Specifications
3.2.3.1 Gasoline
PETRLEOS DEL PER PETROPER S.A.
MAIN OIL FUTURE SPECIFICATIONS
PETROPERU S.A. VOLUME 2
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3.2.3.2 LPG
PETRLEOS DEL PER PETROPER S.A.
MAIN OIL FUTURE SPECIFICATIONS
3.2.3.3 Kerosene/Jet Fuel
PETRLEOS DEL PER PETROPER S.A.
MAIN OIL FUTURE SPECIFICATIONS
PETROPERU S.A. VOLUME 2
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3.2.3.4 Diesel/Fuel Oil
PETRLEOS DEL PER PETROPER S.A.
MAIN OIL FUTURE SPECIFICATIONS
3.2.3.5 Solvents
PETRLEOS DEL PER PETROPER S.A.
MAIN OIL FUTURE SPECIFICATIONS
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3.2.3.6 Asphalt
PETRLEOS DEL PER PETROPER S.A.
MAIN OIL FUTURE SPECIFICATIONS
3.2.3.7 Sulphuric Acid
The minimum concentration will be 98% (in weight).
3.2.3.8 Petroleum Coke
The coke produced will be sold as fuel coke (petcoke).
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3.3 Licensor Basic Design Packages (L-BDP)
The following chart shows a general description of the licensed packages
(L-BDP):
Unit New or Expanded
Coking of vacuum residue
New
Naphtha Hydrotreatment
New
Light Naphtha Splitter and Reformer
New
FCCU (Fluid Cat Cracker Unit)
and GRU (Gas Recovery Unit)
Expanded
LPG Treatment Plant
New
Diesel Hydrotreatment
New
Fluid Cat Cracker Naphtha Hydrotreatment
New
Hydrogen Production
New
Sulphuric Acid Production
New
3.3.1. BASES AND CRITERIA FOR THE LICENSED BASIC DESIGN.
a) Basic Design Philosophy
The licensor, for the elaboration of the BDP, shall be
follow the practices and standards generally accepted in
the international industry and the particular knowledge
that had developed in the commercial unit design of
proven success, accomplishing with the objetives, goals,
specifications and other indications given to the
EMPLOYER and specifying the equipment and systems
in armony with the security and the environment.
The Licensor shall establish a summary of the Design
Bases that are going to serve as bases for the
development of the Basic Design. The plant shall be
designed considering the adequate securities and factor
designs, weather conditions, winds, seismicity, etc.
b) Measurement System
The International System of Measurement will be used;
however, for the volume measures it should be indicated
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the barrels per day and the pressure measures should be
indicated in kilograms/ square centimeters and pounds
and square inches.
c) Characterization of charges and products
The BDP cocking process of vacuum residue starts
and completes with the characterization of the charge
to be executed by the same Licensor.
The BDP process of Expansion and Modernization of
the FCC unit starts and finishes woth the
characterization of the charge to be executed by the
Licensors itself.
d) Minimal charge steady factor
Although it's quite clear that it is foreseen to operate the
plants to maximum design charge, the EMPLOYER
wishes to put it into consideration for operating to a
minimal steady secure charge sufficiently low.
e) Shutdown and Maintenance Times:
Scheduled general shutdowns are desirable at first every
4 years for process units exceptionally every 3 years.
f) Operative Flexibility
The basic design of the Unit shall be elaborated
considering the following conditions:
Normals, according to cases of design considered, for
example 50 ppm or 10 ppm S, high or low severity,
etc.
Start-up and shutdown of the plant
Emergency Shutdown
g) Design Limits
They are going to beindicated for the BDP, the maximum
conditions of design (contaminant in charges,
temperatures, pressures, etc), Limits of hydraulic design,
termic, etc.
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h) Selection of materials and metallurgy
The materials of the plant for critical parts of the main
equipment (structures, supports, housings and other parts
that are not frequently renewable) shall be designed at
first to for at least 40 years of service, considering
adequate securites and design factors, weather
conditions, winds, seismicity, etc.
The norms and codes shall be identified: NACE, ASME,
TENA, API, ANSI, NEC, etc, those will be used as
minimal requirement that are attached with the BDP
equipment specification sheets. In addition, the Licensor
shall complement the previous codes with general
specifications for design and construction developed by
itself and generally provided in the BDP packages. For
example in the case of piping, it shall be prepared
specifications by proper classes for fluids and conditions
of each process.
i) Special performance requirement
Consider specific requirements to optimize the operation
of the main process equipment, indicating conditions as:
maximum mechanical efficiency catalyst activity, mass
and energy transference efficiency, lineal speeds, mass
speeds, special speeds, residence times, etc.
j) Catalysts and chemical Products
To develop the Basic Design consider the guarantees
performance offered and determined margins that allow
the accomplishment of the maximum or minimum offered
limits without overpass them, specially those related to
the type and volume of the catalyst. If it is completely
necessary it shall be specified the employment of
additives and chemical products to fouling control, coke
deposition on pipes, foaming, corrosion, oxidation,
polymerization, rubber forming, etc.
k) Catalyst life cycle
For fixed beds of hydrodesulphurizators is desirable at
first 4 years. For other processes that economically are
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convenient have less, it will be accepted or defined
between the Licensor and the EMPLOYER.
l) Industrial Services
The licensor shall establish the miminum conditions
requeried of industrial services provided from outside of
the battery limits for its process. In case the industrial
services designed by the FEED-EPC Contractor, for
standardization reasons differ from the required in the
process unit, the the ways of control adequacy, must be
specified in the BDP Package.
m) Emissions, Effluents, Solid Residual and Noises
The licensor shall consider the accomplishment of the
maximum limits established in the World Bank guides
2007 for oil refineries.
n) List of qualified suppliers
Provide these lists only in those cases where the Licensor
consider essential to guarantee the performance of its
process for critical equipment.
o) HAZOP risk studies
HAZOP risk studies shall be executed by the FEED-EPC
Contractor. The Licensor shall elaborate a preliminar
P&ID which will be perfected by the FEED-EPC
CONTRACTOR. A Licensor specialist will participate at
the Pre HAZOP and HAZOP discussions.
p) Control Instrumentation
The Licensor shall take into account in the BDP
preparation that the EMPLOYER wishes that the FEED-
EPC considers the detailed design, implementation and
post start-up service of the instrumentation and
automation to an integrator that shall be a MAC Sub-
Contractor of the FEED-EPC Contractor, that
standardizes the systems and provide maintenance and
upgrade to themselves.
q) Drawings
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The Licensor shall take into account in the BDP
preparation that the EMPLOYER wishes that in the
FEED-EPC stage osiders the detailed design drawings
and As-Built under a unique platform integrated by data
and graphics, PDMS type (Project Design Management
System) or equivalent, it is desirable that the P&ID of the
Licensor are developed under the same concept.
3.3.2. SPECIFICATIONS FOR THE LICENSED BASIC DESIGN
The specifications for the basic design shall be prepared in a
book package, conteining the bases and design criteria, the
volumetric balances of matter and enthalpy, the sheets of
equipment specifications, instruments, diagrams, general
specifications and others, in such a way the FEED-EPC
Contractor may complete with no inconvenient the
development of the FEED and subsequently the EPC.
Each package must contain the following:
a. Process description:
Provide a brief description of the productive process,
making reference to the PDF's (Process Flow Diagrams)
and indicating a summary of mass balance of feed and
products.
b. Charges, principal products and by-products:
Indicate the yields and qualities of the principal products
and by- products of the process, indicating its final
disposition.
c. Mass and Energy Balance:
Submit in tabular form or as print out of the simulation
design software, the mass and energy balances,
identifying mass and volumetric flow patterns and
thermodynamic properties of the principal streams for
each design case of process or type of operation.
PETROPERU S.A. VOLUME 2
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d. Equipment List:
Provide a list of the equipment and process systems;
indicating a tag item for each of them, including principal
dimensions and design conditions.
e. Piping and Instruments List:
Provide a list of pipes indicating its tag for each item,
diameter, design class and other characteristics.
Instrument list (valves, controllers, indicators, analyzers,
etc.) indicating a tag for each item and the main
characteristics..
f. Drawings and Diagrams:
Provide a set of drawings and diagrams for the process
installations and equipment that correspond to the design
of the Unit, according to the following list:
f.1. Process Flow Diagrams (PFD's):
Indicating the general scheme of flows, process
equipment symbols and location of process controls
f.2. Process Flow Flagged Diagrams:
PFD Diagrams foreach case of design and operation
showing the data of the variable of main process as:
flow rates, temperatures, pressure and transferred
caloric charges.
f.3. Piping and Instrumentation Diagrams (P&ID):
Showing all main process equipment, process
piping, instruments, valves and basic control
schemes with points of control and monitoring
together with lines and facilities for start up, shut
down and other main operations.
The symbols of the instruments and tag numbers
(tag for each item) shown will be codified to indicate
the type of control, the type of primary element and
the locations of the instruments.
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In addition, they will show:
Identification of piping and identification of
process lines and utility service lines within
Battery Limit.
Specification of the process piping and
accessories, according to the class.
Shutdown instrumentation for emergency (for
example, initiators, alarms, final elements with
logic inputs and outputs).
Locations of the blockage valves of emergency.
Vent and Drainage.
Requirements of thermal isolation
Position of failure of the valves of sampling of the
analyzers and the handling systems of sampling.
Special requirements of piping and details
(Blending point liquid/ steam)
Preliminary dimensioning of the main lines based
in pression falls and typical speeds and paths
assumed by the pipes.
MAC Sub-CONTRACTOR shall integrate all the
P&IDs looking for defining the appropriate
information technology and establishing the
engineering and construction specifications.
The existing units count with their respective pipeline
and instrumentation diagrams (P&ID). The
CONTRACTOR shall prepare the P&ID of the
modernized units, as part of its functions in the
FEED activities.
26
Also, the existing units count with the specifications
sheets of the control instruments. The
CONTRACTOR shall prepare the specifications
sheets of the new instruments as part of its functions
26
Question 176.a Round 2.
PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 64 OF 81
DATE: JULY 10, 2009
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in the FEED activities
27
. They also count with the
control narrative and logical diagrams. The
CONTRACTOR shall prepare the new control
narrative and logical diagrams, as part of its
functions in the FEED activities
28
.
It is confirmed that documents related to
instrumentation and control logic is available printed
in paper, and that the Companys Instrumentation
Engineers and Maintenance People shall be
available since the beginning of the works to assist
the CONTRACTOR's specialist personnel in
surveying the existing units and collecting the
information about the current status of the
instrumentation.
29
f.4. Plot Plan Diagram:
Preliminary Plot Plan equipment based in
engineering standard practices, considering the
operating factors, maintenance, handling of
catalysts, safety and flexibility. PETROPERU S.A.
wants the spacing between equipment to abide with
the spacing guides of the former IRI (Industrial Risk
Insurances).
f.5. Drawings with details of main equipment:
Provide sketches of reactors, vessels and main
equipment of the Unit, that conform the standard
supply of the Licensor.
f.6. Define, tables of motor power and other electronic
equipment of the process area providing a list of
electric information of all type: permanent, temporary
and emergency, necessary for the development of
the detail engineering and preliminary classification
of electric areas within the process battery limit.
f.7. The drawings and diagrams will be elabvorated and
delivered of preference using an integrated sysmte
of data base and graphic platform, similar to the
Plant Design Management System.
27
Question176.b Round 2
28
Question 176.c Round 2
29
Question 176.d and e Round 2
PETROPERU S.A. VOLUME 2
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DATE: JULY 10, 2009
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3.3.3. MAIN EQUIPMENT SHEETS:
Licensors will provide as a minimum the following:
EQUIPMENT DESCRIPTION
Includes:
Code and dimensions defined by the basic design.
Determination of heat duties transferred and overall heat transfer
coefficient (thermal rating clean and fouled) and process specifications,
which includes, among other aspects, inlet/outlet temperatures, phase
change enthalpies, materials and conditions for the mechanical design.
Basic heat integration with other heat exchangers within the battery limit.
Others that supplement choices allowed by codes.
Heat
exchangers, air
coolers
Does not include: The mechanical design of the equipment, mechanical
specification and vibration analysis sheets, and rigorous heat integration with
equipment of other process units.
Includes:
Code and dimensions defined by the basic design.
Process specification and basic hydraulic design, including, among other
aspects, project performance requirements, fluid conditions and
properties, estimate of the NPSHD, materials and conditions for
mechanical design.
Definition of performance flexibility, turndown, , maximum head, power
required, selection of equipment type and driver element.
Preliminary selection of the type of mechanical seals, and seal plan
according to the corresponding API standard.
Others that supplement choices allowed by codes.
Pumps and
compressors
Does not include: Mechanical specification sheets.
Includes:
Code and dimensions defined by the basic design.
Process specification and basic hydraulic design, including, among other
aspects, project performance requirements, fluid conditions and
properties, materials and conditions for mechanical design.
Definition of performance flexibility, maximum RPM, power required (HP),
selection of equipment type and driver element.
Preliminary selection of control type (electronic governors, vibration
meters, anti-surge system, etc.).
Others that supplement choices allowed by codes.
Turbines
Does not include:
Mechanical specification sheets.
PETROPERU S.A. VOLUME 2
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Includes:
Code and dimensions defined by the basic design.
Process specifications and diagrams of general layouts, including height
and inside diameters, nozzles, vents, accesses, location of thermocouples,
liquid level, thermal isolation requirements, materials, linings, corrosion
margins and mechanical design conditions.
List of nozzles and description of internal parts sold separately, such as
entry distributors, exit collectors, anti-vortex devices, mist or foam
eliminators, with the critical dimensions of specified processes.
Others that supplement choices allowed by codes.
Vessels,
Accumulators
Does not include:
Mechanical specifications as welding details or plate distribution another
detailed blueprints.
In addition to the above specification for vessels, includes:
Code and dimensions defined by the basic design.
Number, type and spacing of the trays and/or packing filling, distributors
and collectors with the hydraulic load information for the final verification by
the internal parts supplier.
Others that supplement choices allowed by codes.
Columns
Does not include:
Mechanical specifications or detailed blueprints.
In addition to the specifications for vessels, it includes:
Code and dimensions defined by the basic design.
Process specifications and diagrams of general layouts, including height
and inside diameters, nozzles, vents, accesses, location of thermocouples,
height of catalyst bed, layout for catalyst and inert loads, thermal isolation
requirements, materials and mechanical design conditions.
Process details for internal parts, such as entry distributors, distributor
trays, cooling devices, exit collectors, etc.
Mechanical specifications, detailed detail drawings for issuing of quote
requisition, including the specification of processes, pressure and
temperature of design, metallurgy and main geometrical dimensions.
Others that supplement choices allowed by codes.
Reactors
Does not include:
Mechanical blueprints for the cutting and welding of sheets and similar
items that are normally provided by the manufacturer.
PETROPERU S.A. VOLUME 2
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DATE: JULY 10, 2009
International Bidding Process NPCI-002-2008-OFP/P ETROPERU
Includes:
Code and dimensions defined by the basic design.
Definition of type of furnace.
API 560 form for furnaces, containing the specification of the heat duty and
process data sheet, including performance requirements, conditions and
properties of the currents, heat absorbed, allowable pressure drop,
materials of the tubes and supports, mass velocities, film temperatures or
heat flow limits.
Process details for the furnace elements, such as tube coils, distribution of
burners, stacks or chimneys, convective, radiant and crossover area, etc.
Others that supplement choices allowed by codes.
Process
furnaces
Does not include:
Mechanical specifications, detailed blueprints for issuing of quote
requirements, including the specification of processes.
Includes:
Code and dimensions defined by the basic design.
Summary list of instruments, control loops, interlock and permission
systems, process monitoring instruments identified by number of
processes and services.
Identification of critical alarms related to the process.
Properties of the currents for flow instruments and control valves.
Process specification of on-line analyzers.
Summary description of emergency shutdown systems, safe operation
systems, listing start-up and response conditions.
Others that supplement choices allowed by codes.
Instrumentation
and process
control
Does not include:
Manufacturer specification sheets for instruments and control valves.
Mechanical/electrical/logic design of process control and emergency
shutdown systems.
Safety facilities
Includes:
Code and dimensions defined by the basic design.
Identification of pressure relief devices controlled by instrumentation,
defining the loads to be relieved, conditions and properties of the currents,
and location of the devices.
Others that supplement choices allowed by codes.
PETROPERU S.A. VOLUME 2
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FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
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Does not include:
The selection of relief device catalogs.
Calculation of small relief valves, that correspond normally to the FEED or
detailed design.
Dimensions of the torch systems, including the blow-down headers,
entries and blow-down vessels.
Includes:
Code and dimensions defined by the basic design.
Process specification and mass loads, performance requirements (filters,
ejectors, separators, etc.).
Others that supplement choices allowed by codes.
Miscellaneous
equipment
Does not include:
Mechanical specifications or detailed blueprints
Includes:
Code and dimensions defined by the basic design.
Define the main characteristics of the piping according to type in the flow
diagrams, indicating type and rating of the flanges, construction materials,
thickening due to corrosion and necessity for thermal isolation
(conservation of energy, personal protection or heating tracing veins or
tapes due to process needs).
Others that supplement choices allowed by codes.
Piping
Does not include:
Development of detailed mechanical specifications.
Note: The licensors will provide a list with a minimum of 03 recommended qualified suppliers for
each type of critical equipment and shall be provided with the licensed basic design packages.
For the other equipments and systems, the FEED-EPC Contractor shall present a proposal for
the approval of the EMPLOYER.
30
3.3.4. REVISION AND CONFORMITY OF DRAWINGS AND
DOCUMENTS FOR CONSTRUCTION
Review and give conformity to the technical documentation and the
detail drawings of the equipment and main vessels issued by the
Licensors, FEED-EPC Contractor or equipment manufacturer of
processes, before initiating the construction, to verify the
accomplishment of the process specifications and the philosophy of
design.
30
Question 205 - Round 1.
PETROPERU S.A. VOLUME 2
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FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 69 OF 81
DATE: JULY 10, 2009
International Bidding Process NPCI-002-2008-OFP/P ETROPERU
The Licensor shall submit this service since their offices receiving
by electronic mail or another way, the documentation to be
reviewed.
The list of documents to be reviewed shall be proportionated
previously by the Lincesors to PETROPERU.
3.3.5. INSPECTION OF THE EQUIPMENT MANUFACTURING
Participating in the inspection in workshops about the main
characteristics of the process of the principal equipment, during the
construction and before the delivery of port of shipment.
The equipment list that require said inspection will be defined
previously by the Licensor to the EMPLOYER.
3.3.6. TRAINING
Development of technical courses about the process, operation,
security and control of quality of the product addressed to technical
and operative personal of the EMPLOYER. These courses will be
given in Talara city for approximately 25 people and a minimum
duration of 40 hours before the start-up plant.
The chance of these courses shall be coordinated by the Licensor
with the EMPLOYER in a date the closest possible to the unit start-
up.
Likewise, the licensor is engaged to insert its professionalism and
maximum effort, to facilitate the operative training to facilitate the
operative training of the EMPLOYERs Personal in other countries,
where the application of the processes of the present licensing.
3.3.7. DELIVERABLES
Basic Design Packages (BDP or PB) of the process, which will be
delivered:
For the EMPLOYER 5 sets of pressed copies and 5 sets of
electronic copies in DVD or equivalent. The previous copies are
additional to those that are distributed for revision or conformity
during the design development.
For FEED-EPC Contractor the EMPLOYER 2 set of pressed
copies and 2 sets of electronic copies in DVD or equivalent.
The EMPLOYER will communicate to the Licensor the chance
of this deliver.
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3.3.8. COORDINATION
With the purpose of integrate and harmonize the development of
the Licensed Basic Design and Open Art, the Licensor and the
FEED-EPC Contractor will coordinate adequately the execution of
the activities that allow that the set of project works as well.
3.4 Additional Information
3.4.1. Location
The Talara Refinery is located on the northwest coast of Peru in
the city of Talara, in the province of Talara, Department of Piura,
approximately 1100 km by highway from the city of Lima. The
Refinery is bordered to the north by the Bay of Talara and the port
area; to the south by the Punta Arenas residential area; to the east
by the urban areas of the city of Talara; and to the west by the
Pacific Ocean and public beaches.
3.4.2. Plot Plan of Existing Facilities
A Preliminary (FED-2 Stage) Plot Plan for the Talara Refining
Modernization Project is included as Exhibit No. 5-1 in this MJS
Part B Basis of Design document for Information Only. The
FEED-EPC Contractor is expected to develop its own Plot Plan
during the FEED-EPC effort, reflecting the optimized and integrated
facilities.
3.4.3. Local Conditions
a) Seismic Conditions
Talara area is located in the coast of Peru which is considered
zone 3 for seismic design. The classification of zone 3
corresponds to seismic zoning used in Seismic Resistance
Standard E-030 of the National Building Regulations
31
.
31
Question35 Round 1.
PETROPERU S.A. VOLUME 2
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FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
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b) Meteorological Data
A summary of the meteorological conditions for the city of
Talara by periods is given below
Period Period Period Period Period
Condition
1973-1982 1983 * 1984-1997 1998 * 1999-2007
Average temperature ( C) 22.1 24.9 22.4 23.4 24.3
High Average temperature ( C) 27.1 29.8 28.3 29.3 28 .1
Low Average temperature ( C) 18.9 21.8 19.2 20.1 20. 8
Atmospheric pressure at sea
level (mb) 1011.9 1010.8 1011.9 1011.6 1012.5
Average relative humidity (%) 77.1 78.5 74 79.3 66.4
Total rainfall (mm) 3.7 124.5 8.9 96.9 0.7
Average visibility (km) 12.4 12.1 12.8 12.9 14.7
(*) El Nio-Southern Oscillation Phenomenon
Reference: Tu Tiempo web page, www.tutiempo.net
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3.4.4. Expanded/Modernized Utility Specifications
a) Steam
Low Pressure
Operating pressure 150 psig (10.35
Bar) 10.55
kg/cm2
Vapor Type Saturated
Design pressure 200 psig
Design temperature 500 F
Intermediate Pressure
Operating pressure 450 psig (31.03
Bar) 31.64
kg/cm2
Vapor Type Saturated
Design pressure 580 psig
Design temperature 500 F
High Pressure
Operating pressure 600 psig (41.4
Bar) 42.2 kg/cm2
Operating temperature Saturated
Design pressure 900 psig
Design temperature 550 F
Very High Pressure
Operating pressure 1200 psig (83
Bar) 84.4 kg/cm2
Vapor Type Saturated
Design pressure 1500 psig
Design temperature 600 F
b) Electric Power
4001 HP and above 13.2 kV, 3PH
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201 HP to 4000 HP 4.16 kV, 3PH
0.5 HP to 200 HP 480 V, 3PH
More than 0.5 HP 120 V, 1PH
c) Nitrogen
Normal pressure 125 psig
Maximum pressure 150 psig
Minimum pressure 85 psig
d) Plant Air / Air for Instruments
Normal pressure 115 psig
Maximum pressure 150 psig
Minimum pressure 85 psig
Temperature (maximum) 115 F
Dew point (instrument air) -20 F
e) Water
1) Boiler Feed Water
Temperature 268 F
Pressure As required for the boiler
to overcome the relief
valve settings
General appearance Clear and colourless
pH at 25 C > 9.0
Silica as SiO2 <0.02 mg/kg
Oxygen as O2 <0.02 mg/kg
Total copper as Cu <0.01 mg/kg
Potassium permanganate
consumption
<10 mg/kg
Oil <1.0 mg/kg
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Boiler feedwater is treated in a reverse osmosis plant that
is owned and operated by PRIDESA. Untreated water is
delivered from the seawater cooling system, and filtered
RO water is provided as boiler feedwater.
Since the operating reliability of the public water system is
quite low, it is supposed the sea water RO system is the
best alternative as the process water source.
The FEED-EPC Contractor shall define the processes
water requirements for the modernized Refinery.
The Contractor shall evaluate the available alternatives and
recommend the best. If the proposal is to extend the
capacity of the PRIDESA Plant, such activity shall be out of
the Contractors Services. If the alternative is not to extend
the capacity of the PRIDESA Plant, in such case such
activity shall be within the FEED-EPC Contractors
Scope
32
.
2) Raw Water (Ocean Water)
Sea water will be the main source to obtain process,
cooling and fire water for the refinery necessities. FEED-
EPC CONTRACTOR shall design the new system
considering a very high reliability factor to minimize the
failures and upsets.
The intake system shall be designed considering the
minimum content of sand and temperature. A chlorine or
equivalent system shall be provided to minimize the fouling
and corrosion conditions.
3) Cooling Water
The cooling water shall be supplied from the Pacific Ocean,
which at a maximum temperature to approximately 62 F. A
flow rate of 65,000 gpm is required (to be confirmed during
the FEED).
4) Fire Water
Sea water shall be used for the firefighting system. Jockey
pumps shall be installed to maintain the pressured
condition anytime. Diesel engine pumps are required to get
the water flow during electricity failures.
32
Question 131 Round 1.
PETROPERU S.A. VOLUME 2
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5) Potable Water
EMPLOYER will buy a small quantity of potable water from
the Talara public system to be used for domestic purposes.
6) Refining Process Water Effluent
The Project Environmental Assessment provides
information in relation to the Peruvian regulations and the
approved plan to mitigate the project impacts caused by
these streams.
f) Natural Gas (Typical Quality)
The typical quality of the natural gas, purchased from the local
producers, follows:
COMPOSITION % VOL
Methane 92.44
Ethane 4.45
Propane 1.80
l-Butane 0.23
n-Butane 0.27
l-Pentane 0.03
n-Pentane 0.01
n- Hexane 0.00
Oxygen 0.13
Nitrogen 0.36
Carbon Dioxide 0.28
Total 100.00
Specific Gravity 0.6058
CALORIC CAPACITY
SCF/Net Foot
3
970.9
SCF/GrossFoot
3
1075.6
g) Hydrogen
High purity hydrogen from the hydrogen plant shall meet
the following specification:
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Component Units Specification
H
2
Mol % >99.9
Nitrogen Ppmv <100
CO+ CO
2
Ppmv <10
Pressure Psig 360
Temperature F As available
Normal flow 800,000 scfh
Design flow 900,000 scfh
h) Stack Emissions
Regulations for this matter are provided in the Project
Environmental Assessment.
i) Noise Abatement
Following the Project Environmental Assessment, the noise
equipment like burners, compressors, control valves and motor
engines shall be designed using special devices for noise
abatement. As a preliminary value 80 decibels is the maximum
noise level allowed, into the process areas.
This value is not mandatory and shall be defined according to
the existing regulations and to the Environmental Impact
Assessment of the Project
33
.
33
Questions 47 and 102 Round 1
PETROPERU S.A. VOLUME 2
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4. STANDARDS
4.1 Codes and Specifications
The FEED-EPC Contractor shall develop the Basic Design taking into
account the codes and regulations for design manufacture and
construction as indicated in Part C - Project Instructions 9 from Master Job
Specifications.
The relevant GES will be identified by EMPLOYER during FEED-EPC
CONTRACTOR bid preparation or early in the FEED preparation work
period. Those GES shall be provided by FEED-EPC CONTRACTOR, to
be used during the Project activities, a whole set (printed and electronic
files) of these GES shall be given to the EMPLOYER Project Manager.
4.2 Regulations
The FEED-EPC CONTRACTOR shall develop the Basic Design taking
into account the following regulations for design, manufacturing and
construction of the Talara Refinery Modernization Project facilities:
PERUVIAN REGULATIONS
The Hydrocarbons Act, Law 26221, and its Regulations. D.S. 051-93-EM,
052-93-EM, 015-2007-EM.
For designing the building structures, the Bidder shall present its proposal
about regulations, engineering and building standards, for the
EMPLOYERs approval, but the compliance with the national structural
standards in force of the National Building Regulations must necessarily
be taken into consideration
34
.
Standard E-050; Soils and Foundations.
Standard E-030; Seismic-resistant Design.
Standard E-060; Reinforced Concrete, these shall be complemented with
the regulations for structural concrete, regulations and standards of the
ACI; the most demanding requirements shall be taken into consideration.
Standard E-070; Brickwork.
Standard E-090; Metallic Structures, must be complemented with the
AISC-LRFD structural steel standards for high-seismic areas.
4.3 Design Practices
34
Question 57 - Round 1.
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The Contractor will utilize industry accepted design practices that insure
that the required levels of quality, deliverables, definition and technical
integrity are achieved for the documentation developed and services
provided for the Basic Design Package and Detailed Engineering.
To achieve technical quality integrity, the Contractor is required to use
their own internal design review procedures, such as intra-department and
inter-department checks, squad checks, Peer Reviews, design audits,
etc. These design quality control procedures should be submitted to
Employer for review and approval prior to the start of design work.
Requirements for technical document review/approval should be listed in
a Design Document Review/Approval Distribution Matrix to be prepared
by the Contractor and approved by the Employer, or Employers
representative (PMC), acting on behalf of Employer.
Formal design review meetings will be conducted during the course of the
project with multi-discipline and multi-organization personnel attending. A
list of formal review meetings and their participants will be prepared jointly
by the FEED-EPC Contractor and Employer (or Employers
Representative - PMC) prior to start of design work.
The review/approval of technical documentation by Employer (or
Employers Representative) does not relieve the FEED-EPC Contractor of
its responsibility for the accuracy and integrity of the design.
4.4 Value Engineering Practices (VIP)
It is expected that the FEED-EPC Contractor shall integrate engineering
and design Best Practices such as Value Improving Practices (VIPs)
into its Open Art BDP, services, activities and deliverables of the Basic
Design Packages and Detailed Engineering
Value Practices to improve (VIPs) are defined as specific applications of
the science of Value Engineering that are used to improve the capital cost,
execution schedule and/or operability/reliability of a capital construction
project. The FEED-EPC Contractor is expected to provide Employer (or
Employers Representatives) with its recommendations for application of
such VIPs as may be applicable to the TRM Project, based on industry
recognized and accepted Best Practices. Employer shall give
consideration to of such recommendations for the application of
recognized and accepted VIPs such as:
Class of Facility Quality
Customized Standards and Specifications
Design to Capacity
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Process Simplification
Waste Minimization
Energy Optimization
Process Reliability Modeling
Predictive Maintenance
Constructability Reviews
Value Engineering
Design Tools
FEED-EPC Contractor shall submit in its P-PEP as stated in Part A
Project Perspective, Section 9, its proposal for application of such Best
Practices and VIPs, which (in the Contractors opinion) will, if adopted:
(a) accelerate completion
(b) reduce the cost to Employer of executing, maintaining or operating the
Facilities
(c) improve the efficiency or value to Employer of the completed Facilities,
or
(d) otherwise be of benefit to Employer (without increasing the costs
referred to in paragraph (b) or reducing the efficiency or value to
Employer of the completed Facilities.
4.5 Work Breakdown Structure (WBS)
A Work Breakdown Structure (WBS) for the Talara Modernization Project
is included in this MJS Part B Bases of Design as Appendix N 5-2. as a
work breakdown structure for the TRM Project.
4.6 Equipment and Line Numbering
Regarding the numbering system per units, equipment, instruments and
simbology for P& IDs and online diagrams, the FEED-EPC
CONTRACTOR shall submit at the beginning of the works its proposal for
a new numbering system, that shall be used for the integral scope of the
Project Engineering, including the licensed basic design packages
35
. Said
proposal shall be approved by the EMPLOYER, having into account the
norms and procedures in force of the Refinery.
35
Questions 244 and 245 Round 1.
PETROPERU S.A. VOLUME 2
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4.7 Drawing Management System
The drawings and the diagrams for the works of engineering and
construction shall be elaborated and delivered using an integrated system
of database and graphic platform using PDMS
TM
(Plant Design
Management System) or similar.
The process diagrams (P&ID, PFD, Plot Plan, on-line diagram, etc) shall
be elaborated using the intelligence technology 2D and following the ISO
15926 standards.
The Contractor shall submit its proposal to be approved by the
EMPLOYER which shall accomplish with the ISO 15926 standard
requirements.
The product or suite the contractor shall use for the development of the
technoly of intelligence in 2 dimensions, shall generate in an automatic
way, output file(s) that follow with the ISO 15926 standard.
The generation of the drawings in 2 dimensions shall be used as graphic
platform Autocad or Similar, the drawings may be elaborated working
locally or of remote way. The drawings shall be subject to a consistent
verification of the graphic elements.
The application used shall be able to question and visualize through the
graphic generated in Aauto Cad, specific and particular information of
each one of the represented elements in the diagram of 2 dimensions.
This information shall be stored in a Database which does not permit that
the elements with the same identification or tag number, all and each one
of the registers will be stored showing the actual status and representing
the whole life cycle of the installation.
The information content in the Data Base, shall be able to be taken out
from in form of data sheets, lists and report, using a proper interface and
exported to some software of public domain.
The versions of the electronic tool shall be the most recent, this version
shhal be used nowadays in similar industries (Oil and Gas) through the
American continent. The developer and owner of the technology, shall
recommend the more functional and optimal version for the project.
PETROPERU S.A. VOLUME 2
TALARA REFINERY MODERNIZATION PROJECT PART B BASES OF DESIGN
FEED-EPC CONTRACTOR IFP MASTER JOB SPECIFICATION
PAGE 81 OF 81
DATE: JULY 10, 2009
International Bidding Process NPCI-002-2008-OFP/P ETROPERU
The FEED-EPC Contractor shall propose the proper system which shall
be approved by the EMPLOYER.
36
Also, the FEED-EPC Contractor shall provide to the EMPLOYER, at the
beginning of the FEED works, the software packages and at least three
licenses so that this allow to the EMPLOYER review the drawings and the
diagrams developed by the CONTRACTOR. It is required, also, to have a
computer work station type.
Also, the FEED-EPC CONTRACTOR will elaborate new drawings of the
existing installations using the technology of 3D scanning surveying. This
activity refers to the development of 3D models from the data of the dotted
diagram obtained from the laser scanning surveying.
The scope of the Contractor works includes the development of the 3D
models and the extraction of the isometric drawings of the Refinery of the
new as well as of the existing installations.
5. APPENDICES
5.1 Preliminary Plot Plan (this Plot Plan included herein for Background
Information Only FEED-EPC Contractor to develop its own Plot Plan for
the Project)
5.2 Preliminary Work Breakdown Structure
5.3 A.D. Little/ENGlobal Engineering, Inc. Conceptual Engineering Report
(Document 10-371257-004, Rev. 3 Project No. 10-371257) - included
herein for Background Information Only FEED-EPC Contractor is
advised that any information used from this document is unofficial and to
be independently evaluated and confirmed by FEED Contractor before
accepting it for use. Direct use of this information will be at Contractors
sole risk.
5.4 A.D. Little/ENGlobal Engineering, Inc. Implementation Plan (Document
10-371257-007) FEED-EPC Contractor is advised that any information
used from this document is unofficial and to be independently evaluated
and confirmed by FEED Contractor before accepting it for use. Direct use
of this information will be at Contractors sole risk.
5.5 A.D. Little/ENGlobal Engineering, Inc./Petroperu Environmental Viability
Study (Document 10-371257-033, Rev. 4, April 2008) FEED-EPC
Contractor is advised that any information used from this document is
unofficial and to be independently evaluated and confirmed by FEED
Contractor before accepting it for use. Direct use of this information will
be at Contractors sole risk.
36
Question 208 Round 1.
f detail to Employer's Code of Account level
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Table of Contents
2.1 Introduction and Summary ..........................................................................................2-4
2.1.1 Conclusions ...............................................................................................................2-5
2.2 Section 1 Selected Case:.......................................................................................2-6
2.2.1 Selected Case Overview ...........................................................................................2-6
2.2.2 The Selected Case Will Consist of the Following Units .............................................2-7
2.3 Units in the Selected Case .......................................................................................2-8
2.3.1 Atmospheric Tower....................................................................................................2-8
2.3.2 Vacuum Tower.........................................................................................................2-11
2.3.3 Flexicoker ................................................................................................................2-11
2.3.4 Fluid Catalytic Cracker.............................................................................................2-14
2.3.5 Diesel Fuel Desulfurizer...........................................................................................2-16
2.3.6 FCC Gasoline Desulfurizer ......................................................................................2-18
2.3.7 Naphtha Desulfurizer ...............................................................................................2-20
2.3.8 Reformer..................................................................................................................2-22
2.3.9 Hexane-Heptane Splitter .........................................................................................2-24
2.3.10 New Gas Plant .......................................................................................................2-24
2.3.11 Amine Absorber Stripper ....................................................................................2-24
2.3.12 Sulfuric Acid Plant..................................................................................................2-26
2.3.13 Hydrogen Plant ......................................................................................................2-28
Overall Refinery................................................................................................................2-28
2.3.14 Blending.................................................................................................................2-44
2.3.14.1 Gasoline......................................................................................................2-44
2.3.14.2 Diesel ..........................................................................................................2-45
2.3.14.3 The calculations showing the blending of Gasoline and Diesel Fuel are given
in Table 2.1.and 2.2. .....................................................................................................2-45
2.4 Units Rejected for the Selected Case....................................................................2-48
2.4.1 Delayed Coker .........................................................................................................2-48
2.4.2 Residual Oil Hydrocracker .......................................................................................2-48
2.4.3 Solvent Deasphalter (ROSE Unit): ..........................................................................2-48
2.4.4 Medium Pressure Hydrocracker ..............................................................................2-49
2.4.5 Alkylation .................................................................................................................2-49
2.4.6 Benzout Unit ............................................................................................................2-50
2.4.7 Circulating Fluidized Bed Boiler...............................................................................2-50
2.4.8 Fluidized Bed Boiler.................................................................................................2-50
2.4.9 Claus Unit for Sulfur Production ..............................................................................2-50
2.4.10 Isobutane Column..................................................................................................2-51
2.5 Residue Reduction..................................................................................................2-51
2.5.1 Technologies Available............................................................................................2-51
2.5.2 Coking......................................................................................................................2-51
2.5.2.2 Residuum Hydrocraking..............................................................................2-52
2.5.2.3 Solvent Deasphalting ..................................................................................2-52
2.6 Environmental Considerations ..............................................................................2-52
2.7 Plot Plan and PFDs .................................................................................................2-53
2.7.1 Process Units...........................................................................................................2-53
2.7.2 Utilities .....................................................................................................................2-53
2.7.3 General Facilities.....................................................................................................2-54
2.7.4 A Block Flow Diagram of the refinery has been presented as Figure 2.11. ..........2-54
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2.7.5 The Flow Diagrams for the individual units have been given as Figures 2.1 2.9. 2-54
2.7.6 Material Balances ....................................................................................................2-55
2.7.6.1 The overall refinery material balance..........................................................2-55
2.7.7 Table 2- 4 Unit to Unit Material Balance.................................................................2-60
2.7.8 The gas balance within the refinery, showing sources and disposition of various gas
streams is also shown in Table 2.4. ................................................................................2-68
2.7.9 The hydrogen balance is given in Table 2.6.. ..........................................................2-68
2.7.10 The sulfur balance is given in Table 2.7. ...............................................................2-69
2.8 Catalyst and Chemical Consumption....................................................................2-69
2.9 Operating Cost ........................................................................................................2-70
2.10 Capital Estimate ......................................................................................................2-72
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Table of Figures
Figure 2- 1 Crude Unit .............................................................................................................2-10
Figure 2- 2 Flexicoker ..............................................................................................................2-13
Figure 2- 3 Fluid Catalytic Cracker ..........................................................................................2-15
Figure 2- 4 Diesel Fuel Desulfurizer ........................................................................................2-17
Figure 2- 5 FCC Gasoline Desulfurizer....................................................................................2-19
Figure 2- 6 Naphtha Desulfurizer.............................................................................................2-21
Figure 2- 7 Reformer................................................................................................................2-23
Figure 2- 8 Amine Unit .............................................................................................................2-25
Figure 2- 9 Sulfuric Acid Plant A...........................................................................................2-27
Figure 2- 10 Overall Refinery Block Flow Diagram..................................................................2-29
Figure 2- 11 Diagram of Results of Refinery Simulation..........................................................2-30
Table 2- 1 Calculations of Blending Gasoline and Diesel Fuel - Selected.............................2-46
Table 2- 2 Calculation of Blending Gasoline and Diesel Fuel - Selected...............................2-47
Table 2- 3 The Overall Refinery Material Balance - Selected................................................2-56
Table 2- 4 Unit to Unit Material Balance - Selected...............................................................2-60
Table 2- 5 Gas Specific Balance - Selected ..........................................................................2-68
Table 2- 6 Hydrogen Balance - Selected...............................................................................2-68
Table 2- 7 Sulfur Balance - Selected .....................................................................................2-69
Table 2- 8 Major Catalyst and Chemical Consumptions - Selected......................................2-70
Table 2- 9 Operating Cost Selected.......................................................................................2-71
Table 2- 10 Capital Estimate - Selected ................................................................................2-73
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PETROPERU
Talara Refinery Expansion Modernization
Selected Case
2.1 Introduction and Summary
The Selected Case chosen by PETROPERU is presented and discussed. This case
includes vacuum distillation of the atmospheric column residuum, and an FCC
desulfurizer to bring the gasoline into sulfur specification. This case produces
specification gasoline, and cetane specification for diesel fuel. This case also produces
heavy fuel oil. This case will adequate provide power to supply the refinery.
The Selected Case contains a Flexicoker, two vacuum towers (one existing), diesel,
naphtha, and FCC gasoline desulfurizers, a reformer, a new gas plant, a
hexane/heptane splitter, a hydrogen plant, and a sulfuric acid plant. It does not export
electricity. It does not produce natural gas. The capital cost for this plant, including
offsites is $1,306,000,000 including the 12% contingency and 20% location factor as
provided by PETROPREU. It produces a product slate that includes 39,800 bpdo of
diesel fuel, 10,800 bpdo of high sulfur fuel oil and 488 short tons of petroleum coke per
day.
There are three basic ways to dispose of the residuum from the crude slate coking,
hydrocracking, and solvent deasphalting. Of these three choices, Flexicoking, as a sub
case of coking, is the best one. This is because it will make the residuum go away by
converting in into liquid fuels and low BTU gas. The low BTU gas can have other uses,
such as refinery fuel gas, generation of electric power, or as a synthesis gas for the
production of other hydrocarbons or alcohols (with the addition of hydrogen).
The wastewater can be brought up to Peruvian and World Bank standards by the
segregation of the various waste water streams. The cooling water can be discharged
directly back into the Pacific Ocean without treatment. The other streams can be deoiled
with centrifugal equipment, and then treated in an aerobic biological treatment unit to
reduce COD and BOD.
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The air emissions are controlled by removing the hydrogen sulfide and converting it into
sulfuric acid to control SOx. The NOx will be controlled by using Flexigas, which will
burn at a much lower temperature than natural gas, plus using low NOx burners where
necessary.
The refinery has almost no solid wastes. Catalysts can be returned to the supplier.
Sludges can be handled in the Flexicoker. The few remaining solid wastes can be land-
filled.
2.1.1 Conclusions
The Talara Expansion and Modernization project is viable both technically and
environmentally.
x The Selected Case does not export electric power and requires minimum capital
expenditure.
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2.2 Section 1 Selected Case:
2.2.1 Selected Case Overview
After a review of Cases II VI, PETROPERU decided that the Selected Case should be based
upon the use of a Flexicoker for residue reduction and a Wet Sulfuric Acid plant for sulfur
disposal.
The constraints that were put upon this case are:
x Capital Expenditure should be minimized
x The consumption of natural gas should be minimized or eliminated.
x LPG needed to be a minimum of 70% C
3
s.
x Gasoline was to be 91 RON minimum, and contain 50 ppm Sulfur, maximum.
x Diesel Fuel was to be 47 Cetane Index, minimum, and 50 ppm Sulfur maximum, with
the ability to reduce sulfur to 10 ppm.
x No power will be exported, but the needs of the plant will be supplied.
x The refinery emissions were to meet Peruvian and World Bank standards.
x Tankage for 30 days of crude oil and 15 days of refined products is available from
existing tankage or projects under construction at Talara.
Several different technologies were evaluated. The competing technologies for the
same function were investigated when possible. Based upon these studies, the
following process units were selected:
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2.2.2 The Selected Case Will Consist of the Following Units
1. Atmospheric Tower
2. Vacuum Tower(s)
3. Flexicoker
4. Gas Plant
5. Fluid Catalytic Cracker
6. FCC Gasoline Desulfurization
7. Diesel Fuel Desulfurization
8. Naphtha Desulfurization
9. Catalytic Reformer
10. Amine Plant for H
2
S removal
11. Sulfuric Acid Plant
12. Hydrogen Plant
The following units were considered and rejected:
1. Delayed Coker
2. Residual Oil Hydrocracker
3. Solvent Deasphalting
4. Medium Pressure Hydrocracker
5. Alkylation
6. Benzout Unit
7. Circulating Fluidized Bed Boiler
8. Fluidized Bed Boiler
9. Claus Unit for Sulfur Production
10. Isobutane Column
The following units are being modified:
The Atmospheric Tower is being retrayed, and is having the bottom section replaced
with a larger diameter bottom. The heat exchangers will need to be augmented with
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additional new ones to provide the increased heat exchange needed for the higher flow
rate.
The existing vacuum tower will need to have its heater either retrofitted or replaced. A
second larger vacuum tower will need to be added to handle the increased volume of
atmospheric tower bottoms generated from the heavier crude slate.
The FCC will be revamped from 19,000 bpdo to 24,000 bpdo on a feed of coker gas oil,
supplemented by HVGO. To handle the increased feed rate, the wet gas compressor
will need to be replaced, the air blower will need to be replaced, and the riser will need to
be modified. The catalyst in the unit will be changed, and the unit will be operated at
lower severity to increase the production of diesel fuel and decrease the production of
gasoline.
2.3 Units in the Selected Case
2.3.1 Atmospheric Tower
The atmospheric tower already exists in Talara. This column can be expanded to
process 90,000 bpdo of the Talara crude blend that is 64% Napo. The column needs to
be debottlenecked by replacing the current 5 foot diameter bottom with a bottom that is
at least 10 feet in diameter. The existing bubble trays in the middle section of the tower
need to be replaced with valve trays.
The Refsys simulation (refinery process simulation by Aspen Tech by rigorous plate to
plate calculation) indicated that the current tower, modified as described above, will
handle between 100,000 & 110,000 bpdo of the considered crude slates. The limiting
factor is the vapor traffic within the column, indicating an even lighter crude slate could
limit the feed to the tower to a lower level.
The existing fired feed heater has been reviewed with Tulsa Heaters, Inc, the company
that made it. It was determined that the current heater will probably handle 100,000
bpdo, but not 110,000 bpdo. If much lighter crude is charged to the tower, the heater
may not handle the higher flow rate, since it takes more heat to boil a liquid than it takes
to heat it up.
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Increased heat exchange surface will need to be added to recover heat from the
products at the new higher feed rate.
The desalter was designed and built by Petreco. They reviewed the capability of the unit
to be operated at a higher feed rate. They determined that 100,000 bpdo of Napo crude
can be desalted by increasing the operating temperature of the unit.
A sketch of the flows in this unit is given as Figure 2.1.
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Figure 2- 1 Crude Unit
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2.3.2 Vacuum Tower
The existing vacuum tower with capacity 21 MBDO is undersized for the proposed
expansion, and also needs extensive renovation to bring it up to current standards. In
addition, the existing vacuum tower will need to be supplemented with a second tower of
about twice the size of the existing one in order to handle the larger amount of atmospheric
tower bottoms generated by the heavier crude slate. This would require a capital
expenditure, estimated at $60 MM.
2.3.3 Flexicoker
The Flexicoker was chosen over the other 3 residue disposal technologies for two reasons:
It can eliminate almost all of the resid while not generating large amounts of either fuel oil or
coke. Both fuel oil and coke will present a disposition problem for the refinery. Because of
the configuration of the Flexicoker, the heat for distilling the VGOs will come from burning
coke, not natural gas or refinery gas.
The Flexicoker converts the bulk of the petroleum coke into Flexigas, a low BTU gas that can
be used to fuel the refinery, minimizing or eliminating the need to purchase natural gas.
The capital required is comparable to that required for the other cases.
In the Flexicoker, the feed is sent to the top of the reactor section, where the lighter liquids
are boiled off. The heavier liquids are coked, with the vapors going overhead, commingled
with the lighter liquids from the feed, and sent into a fractionator, where they are distilled into
the various cuts. The coke flows into a Fluidized Bed (Heater Vessel), where it is partially
burned to supply the heat for the coking operation. The coke then goes into a gasifier, where
it is converted into low BTU gas. A small coke stream remains that consists of carbon and
the inorganic contaminants in the feed. There is a cement plant in Peru that that can take
this stream.
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If desired, it is possible to reduce the production of Flexigas and make more coke. The trade
off rate is that for each 100 MM BTU/hr. of Flexigas not produced, an additional 200 (short)
tons a day of coke is produced. It is expected that this will be over 1000 (short) tons/day of
additional coke. Based on the current balance the low Btu gas can be utilized to generate
high pressure steam that will be used in the process.
A sketch showing the flows in this unit is given in Figure 2.2.
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Figure 2- 2 Flexicoker
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2.3.4 Fluid Catalytic Cracker
The Fluid Catalytic Cracker (FCC) will have an increased feed rate (~24000 bpdo). The feed
to the FCC will be heavy vacuum gas oil and coker heavy gas oil.
The unit will need several modifications to handle the increased feed rate. These
modifications include replacing or increasing the capacity of the wet gas compressor and the
air blower. The riser will also need to be modified to handle the higher feed rate.
It will be necessary to return to the original design operation of the unit in order to control the
C4 content in the LPG product. The C4 bottoms product will be suitable for use as either a
blend component in gasoline for controlling RVP, as a feed to a steam reformer for the
production of hydrogen, or use in the refinery fuel gas system.
Because of this increased flow rate to the FCC gas plant, it will be necessary to add a
second gas plant to handle the off gases from the other units.
A sketch showing the flows in this unit is given in Figure 2.3.
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Figure 2- 3 Fluid Catalytic Cracker
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2.3.5 Diesel Fuel Desulfurizer
The diesel fuel desulfurizer will perform two tasks. It will remove the sulfur from the diesel
fuel, and it will raise the cetane by opening rings in the diesel fuel. ExxonMobil has
technology that will perform both tasks well. The Haldor Topsoe technology has not been
evaluated in detail.
The ExxonMobil technology is capable of producing low sulfur (3 ppm) diesel fuel and raising
the cetane index of the product diesel. This technology returns about 84% of the feed as low
sulfur diesel, and 11% of the feed as kerosene.
A sketch showing the flows in this unit is given in Figure 2.4.
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Figure 2- 4 Diesel Fuel Desulfurizer
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2.3.6 FCC Gasoline Desulfurizer
It will be necessary to desulfurize the FCC gasoline to meet sulfur specifications.
Conventional desulfurization technologies will also convert the olefins in the FCC gasoline
into paraffins. This saturation of the olefins will reduce the octane of the FCC gasoline
significantly. In order to avoid this, it is necessary to use different technology and different
catalysts. One commercial method available is reactive distillation, a technology developed
by CD Tech. In this technology, the trays or packing in a distillation column are replaced with
catalyst beds.
The hydrogen feed goes into the bottom of the column, while the FCC gasoline is fed into the
top of the column. They mix over the catalyst bed, and the sulfur is removed. Also, the
diolefins are converted into mono-olefins to reduce gum problems. This is a low capital cost
method for desulfurizing FCC gasoline.
This is a proven technology, with over 1,000,000 bpdo of installed capacity.
ExxonMobil and Chevron have technically equivalent technologies that use more
conventional (and more expensive) configurations.
A sketch showing the flows in this unit is given in Figure 2.5.
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Figure 2- 5 FCC Gasoline Desulfurizer
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2.3.7 Naphtha Desulfurizer
The naphtha desulfurization unit removes the sulfur from the reformer feed. Feed naphtha to
desulfurizer is a blend of LSRG and coker naphtha. Reforming catalyst is based upon noble
metals (primarily platinum), and is very expensive. Sulfur poisons these catalysts.
ExxonMobil technology is being used for this unit, since they do have technology in this area,
and because they are working on several other units for the project. UOP, Haldor Topsoe,
and Chevron Lummus have equivalent technologies that can be considered.
A sketch showing the flows in this unit are given in Figure 2.6.
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Figure 2- 6 Naphtha Desulfurizer
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2.3.8 Reformer
Reformers dramatically increase the octane of naphtha by dehydrogenating the naphthenes
in the naphtha to aromatics, by dehydrocyclizing some of the paraffins in the naphtha to
aromatics, and isomerizing normal paraffins to isoparaffins. The resulting product is high
octane blend stock. This blend stock will have zero sulfur. It will be high in aromatics, which
could be a problem, since the aromatic specification for gasoline is 35%. If the naphtha is
not prefractionated to remove benzene precursors, it will also be high in benzene. There is a
1% max specification in gasoline. The reformer will return about 85% of the naphtha feed as
reformate. The reformer also generates hydrogen at a rate of about 1200 scfb, depending
upon the severity of operation. Higher severity produces higher octane and more hydrogen
at the expense of product yield and length of time between regenerations.
ExxonMobil also has technology in this area. This technology utilizes semi-continuous
regeneration. In a semi-continuous reformer, the reformer is taken out of operation on a
periodic basis (usually six months to one year) for the catalyst to be regenerated by burning
the coke off the catalyst. A fresh charge of catalyst can be expected to last about 10
regenerations. This differs from a continuous catalyst regeneration reformer, where catalyst
is continually removed from a reactor, regenerated, and recycled into either the same, or a
different reactor. The Talara refinery will not have enough naphtha to justify the increased
capital for installing a continuous catalyst regeneration type of reformer.
UOP also has reforming technology that is widely respected within the industry. The
ExxonMobil was selected for this case because we are working with them on several
different technologies. Reforming technology is almost open art technology.
A sketch showing the flows in this unit are given in Figure 2.7.
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Figure 2- 7 Reformer
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2.3.9 Hexane-Heptane Splitter
This unit will be used on the desulfurized naphtha stream to keep the benzene precursors
out of the reformer. This approach increases the production of gasoline by about 200 bpdo,
and decreases the size of the reformer from 12,000 bpdo to 9,000 bpdo, with the
corresponding reduction in capital.
This approach also avoids the need for a benzene reducing unit, such, as a Benzout, to
remove benzene from the gasoline pool. The net effect is to reduce the capital requirements,
including reduction in capital for a much smaller reformer, by about $27,000,000.
2.3.10 New Gas Plant
Because the expansion of the FCC exceeded the capacity of the existing gas plant, it was
necessary to add a new gas plant to accommodate the off gases from the desulfurization and
reforming units. This unit will recover the C
3
s and C
4
s and any heavier materials for
inclusion into either the LPG or gasoline streams. A gas plant to handle the Flexicoker off
gases is included in the Flexicoker design.
2.3.11 Amine Absorber Stripper
This plant will remove the Hydrogen Sulfide (H
2
S) from the combined gas streams and then
recover it as a pure H
2
S stream for feed to the sulfuric acid plant. This is open art
technology. The Crosstex unit was also selected for consideration because it is a skid
mounted low cost unit. Other suppliers could also provide similar equipment. ExxonMobil
has included a hydrogen sulfide absorber in their unit.
The gases from the sour water strippers cannot be sent to this unit, because of the ammonia
contained in the gases. The ammonia will dissolve in the dilution water for the amine,
causing problems within the absorber. These gases will be taken directly to the sulfuric acid
plant that can handle them.
Sketch showing the flows in this unit are given in Figures 2.8.
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Figure 2- 8 Amine Unit
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2.3.12 Sulfuric Acid Plant
The Haldor Topsoe Wet Sulfuric Acid (WSA) technology was selected for use in the study.
This technology is capable of converting hydrogen sulfide directly into sulfuric acid, without
going through the sulfur intermediate. This technology can handle the ammonia in the gases
from the sour water strippers, converting it into nitrogen. The sour water stripper gases will
be fed directly to this unit, bypassing the amine unit.
This technology has two advantages for the project it reduces the capital requirement
significantly, as compared to a Claus unit, and it provides a product, sulfuric acid that has a
market in the Peruvien market area, and avoids a product, sulfur, that is already oversupplied
in South America.
There is no known comparable technology available. There are several plants in operation
around the world, so the technology is proven.
A sketch showing the flow in this unit is given in Figure 2.9.
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Figure 2- 9 Sulfuric Acid Plant A
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2.3.13 Hydrogen Plant
The hydrogen plant is part of the utilities and is covered in Section 3.2.7 of the utilities
section.
The Licenses of processes and the Basic Design Packages of the licensed processes shall be
provided by the EMPLOYER during the FEED phase.
Overall Refinery
An overall refinery Block Flow Diagram is given in Figure 2.10.
The results of the Refinery Simulation are given in Figure 2.11. The flows for this simulation
are similar to, but not identical to those used in the unit by unit material balance. This is
expected, because the unit by unit material balance uses technology supplier estimates,
while the simulation used generalized estimates. The closeness of the numbers confirms the
information given to us by the technology suppliers.
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Figure 2- 10 Overall Refinery Block Flow Diagram
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2.3.14 Blending
2.3.14.1 Gasoline
The gasoline produced at Talara will be a blend of four different components. These are
FCC gasoline octane 93.5 based on current FCC operations (no additional data was
available from the catalyst supplier for the future case), Reformate, ethanol, and Butane.
The desulfurized FCC gasoline will be low in benzene and sulfur. Reformate will be very low
in sulfur, and have little or no benzene. The gasoline blend meets all of the specifications,
and has an octane of 93.5, as compared to a specification of 91 minimum.
ADL received from PETROPERU instructions to maximize the production and yields of diesel
of which FCC Light Cycle Oil (LCO) is an important component. FCC low severity catalyst
operation is known to increase the yield of LCO from 15%-18% to 30-33% vol.
Notwithstanding the foregoing, ADL could not obtain a reply from commercial FCC catalyst
suppliers for such low severity yields, and as a result opted to produce a Conceptual Design
Volumetric Balance using the less attractive diesel yields of high severity FCC yields of the
current Talara FCC operation.
If Petroperu can revise the Basic Design of the FCC revamp to be based on a low severity
operation and design, the profitability of the project may be increased.
Removal of the C
5
and C
6
from reformate will increase the octane making the overall
gasoline blend higher than required.
The reformate will be very low in sulfur. It will be necessary to distill the reformer feed to
remove the benzene precursors. The blend of these materials is given in Table 2.1. The
octane of the heavy reformate is also calculated in this table.
Butane (or butylene) is added to the gasoline to set the RVP. For the purpose of this study,
a target RVP of 10 was selected. Since butane has an octane of 100, any butane added to
the blend will further increase the octane of the blend. Any excess butane will go into either
the hydrogen plant or the refinery fuel system.
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2.3.14.2 Diesel
The diesel fuel from the Talara refinery will be blended from two different blend stocks.
These blend stocks will be the desulfurized diesel stream, a heavy naphtha from the diesel
desulfurizer. The blend of these materials is given in Table 2.2. Excess jet fuel was
desulfurized, and blended into the diesel fuel pool.
The diesel desulfurizer will desulfurize a mixture of straight run diesel, LCO from the FCC,
and the Flexicoker diesel cut.
The blended diesel will have a cetane index of 47.1, compared to a 47.0 minimum
specification, and a sulfur content of <2 ppm.
It is clarified that the scope of the services includes in-line blending systems for residual
gasoline and fuel oils. Some blending tanks shall be used for the export products.
2.3.14.3 The calculations showing the blending of Gasoline and Diesel Fuel are given in Table
2.1.and 2.2.
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Table 2- 1 Calculations of Blending Gasoline and Diesel Fuel - Selected
Table 2.1
Gasoline and Diesel Blending
Selected Case
Product Qualities
Product:
Gasoline BBLS RON RON-bbls Sulfur ppm S - bbls Benzene,
%
BZ-
bbls
Aromatics,
%
FCC
Naphtha 8916 93.4 832754.4 3.0 26748.0 0.5 4279.7 29.6
Lt Naphtha 4196 58.8 246934.0 0.0 0.0 1.3 5454.8 1.3
Reformate 6195 110.9 686801.6 0.0 0.0 0.0 0.0 44.7
Ethanol* 1498 120.0 179760.0 0.0 0.0 0.0 0.0 0.0
Blend 20805 93.5 1946250.0 1.3 26748.0 0.5 9734.5 26.3
Specification
91,
min 50. max 1.0, max 35, max
Diesel Fuel BBLS Cetane
Cetane -
bbls Sulfur ppm S - bbls
0.0
Desulfurized
Diesel 28075 47.2 1325140.0 0.1 2807.5
Desulfurized
Heavy
Naphtha 973 30.4 29579.2 0 0.0
Blend 29048 46.6 1354719.2 0.1 2807.5
Specification
47,
min 50, max
* Dictated by
Peruvian
Law
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Table 2- 2 Calculation of Blending Gasoline and Diesel Fuel - Selected
Table 2.2
Octane Calculation*
Selected Case
Lt Naphtha Lt Naphtha from Reformer
Component Fraction RON Component Fraction RON
n-Pentane 0.0518 62 3.2 n-Pentane 5.15 62
i-Pentane 0.0131 92 1.2 i-Pentane 7.17 92
Cyclopentane 0.0033 83 0.3 Cyclopentane 0.43 83
n-Hexane 0.1037 25 2.6 n-Hexane 5.17 25
2m-Pentane 0.1008 75 7.6 2m-Pentane 13.51 75
m-Cyclopentane 0.0215 103 2.2 m-cyclopentane 0.25 103
Cyclohexane 0.0215 97 2.1 Cyclohexane 0.02 97
Benzene 0.005 101 0.5 Benzene 4.56 101
n-Heptane 0.01317 0 0.0 n-Heptane 1.34 0
2m-Hexane 0 44 0.0 2m-Hexane 0 44
Blend 0.33387 58.8 19.6 Blend 37.6 0.0
Heavy Reformate
Component Fraction RON
Lt Naphtha 0.253 58.8 14.9
Calculated
above
Hvy Reformate 0.4636 111 51.4
Reformate 0.7166 92.5 66.3 From Exxon
* Assumes linear blending
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2.4 Units Rejected for the Selected Case
2.4.1 Delayed Coker
The delayed coker was based upon Foster Wheeler technology. This technology has two major
drawbacks that led to its being discarded. The first is that the capital required is higher than the
capital required for the Flexicoker. This seems to be counter-intuitive. Upon rechecking with
both Foster Wheeler and with ExxonMobil, they both confirmed that their original estimates were
correct. The difference between the two processes is the huge amount of coke generated by
the delayed coker from the heavy crude. This leads to bigger coke drums, and more and/or
bigger coke handling equipment. Hence, the higher capital estimate.
The second drawback is the large amount of coke made by the delayed coker. There is no
reasonable way of disposing of it. The coke market is currently oversupplied, so it will be very
difficult to sell it. The Talara refinery is not situated to handle the large amount of coke. It does
not have the dock or solids handling equipment necessary to ship the coke. It does not have
the land available to store the coke. One possible solution is to convert the coke into electricity
and put the power on the Peruvian grid. The revenues generated by this approach do not
produce an acceptable return on the capital required to generate and export the power.
2.4.2 Residual Oil Hydrocracker
The residual oil hydrocracker does not convert enough residual oil, leaving large amounts of the
residual oil to be blended into fuel oil. There is no particular capital expenditure advantage to
going this route. The large amount of bottoms is analogous to the large quantity of coke
generated by the delayed coker.
One of the objectives of the project is to minimize or eliminate the quantity of fuel oil that is sold
by the refinery. This option does not meet this objective. Therefore, this option was dropped.
2.4.3 Solvent Deasphalter (ROSE Unit):
This technology is the lowest capital cost approach to the modernization project. This
technology has two fatal flaws. It generates a large quantity of residuum, and for the maximum
quantity of deasphalted oil (DAO), the con carbon content of the DAO is too high for further
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processing in a MPHC. The large quantity of residuum results in high sales of fuel oil, which is
contrary to the project objective of minimizing the production of fuel oil. This option was
dropped.
2.4.4 Medium Pressure Hydrocracker
The ExxonMobil technology is very good, but expensive. The kerosene plus diesel fuel
production is about 60% of the feed to the unit. Haldor Topsoe, and Chevron Lummus have
similar technologies that can be considered. All of these technologies could be evaluated in
depth at the FEED stage of the project. The comparisons of ExxonMobil and Chevron -
Lummus technologies are given as an example in the technology selection report the RFP for
the Chosen Technologies.
The ExxonMobil process is a two stage process that desulfurizes, opens rings, cracks, and
isodewaxes the feed to the unit. It does this in a way that maximizes the production of diesel
fuel and kerosene. The kerosene plus diesel yield from Napo crude is 65+%. The unit also
produces naphtha, LPG, refinery gas, and H
2
S. The nitrogen in the feed comes out as
ammonia. The bottoms product is a highly paraffinic low pour product that is an excellent feed
for an FCC, except for its lack of con carbon.
In spite of the advantages of this technology for the Talara Refinery, the capital required for this
unit is too high, and it was dropped from further consideration.
2.4.5 Alkylation
Although the FCC generates isobutene and olefins, the quantity of this material is not adequate
to fully supply a minimum economically sized alkylation plant. There is no need for additional
high octane gasoline feedstock, because reformate and FCC gasoline provide more than
enough octane to satisfy the demands of the gasoline market.
With no economic justification for this unit, this option was dropped.
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2.4.6 Benzout Unit
This unit is designed to remove benzene from gasoline by reacting it with either ethylene or
propylene to form either ethyl benzene or cumene. This has the additional advantage of
converting the olefins in the refinery gas stream into gasoline.
For a refinery as small as Talara, the cost of the unit is not economically justified. This unit
would cost $15,000,000. In addition, the reforming of the light naphtha would increase the size
of the reformer by about 50%. This will increase the cost of the reformer by an additional
$17,000,000. The expenditure of $32,000,000 to avoid the purchase of high octane blend
stocks is not economically justifiable.
2.4.7 Circulating Fluidized Bed Boiler
With the Flexicoker, there will be insufficent coke to burn in a boiler. This is the highest capital
cost boiler which will require up three times the stoichiometric amount of limestone to operate
and control sulfur emissions. The closest limestone to Talara is over 60 miles away and would
require an excessive number of truck loads a day. There is no need or economic justification for
this unit.
2.4.8 Fluidized Bed Boiler
With the Flexicoker, there will be little coke to burn in a boiler. This is the second highest capital
cost boiler but it only requires the stoichiometric amount of limestone to control emissions.
There is no justification for this unit.
2.4.9 Claus Unit for Sulfur Production
The H
2
S stream can either be converted into sulfur in a Claus unit or into sulfuric acid in a WSA
unit. There is three times as much sulfuric acid produced as sulfur. Sulfuric acid sells at about
twice the price as sulfur, to increase the income from the H
2
S stream by a factor of 6. At the
same time, the capital required for a WSA unit is one third to one half the capital required for a
Claus unit.
For these economic reasons, this option was dropped.
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2.4.10 Isobutane Column
This column was considered in conjunction with the alkylation unit. There is no need to
separate the butane streams to isolate isobutane as an alkylation unit feed. The other
requirement would be to adjust the proportion of C4s in the LPG stream. This can be done by
operating the depropanizer within the existing FCC gas plant hotter to take some C4s out
overhead with the C3s.
With the reasons for the isobutane column eliminated by either taking away the use for the
isobutane, or finding another way to put butanes into LPG, the need for the column was
eliminated, along with the capital cost for installing the column.
2.5 Residue Reduction
2.5.1 Technologies Available
2.5.2 Coking
Coking is the slow cracking of residuum into lighter products and coke. In the process, almost
all of the hydrogen in the residuum goes into the lighter products, while the coke contains the
remaining carbon, and any ash, metals or other solids contained in the crude oil.
2.5.2.1.1 Delayed Coking
One of the coking methods is delayed coking. In this process, the coking process is done in a
coke drum. The light products leave the coke drum as a vapor, and the coke collects in the
drum. Periodically (every twelve hours or so), the coke is cut out of the drum with high pressure
water or steam and collected in a coke pit. This technology is open art, and can be generally
used by anyone. Some licensors, such as Foster Wheeler, have improved on portions of the
process and charge a royalty for the use of their improvements.
2.5.2.1.2 Flexicoking
A second method is Flexicoking. In this technology, the coking operation takes place in a
reactor, rather than the coke drum. The coke generated in the coking operation goes into a
heater, where it is heat exchanged with coke from a downstream gasifier. This hot coke
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provides the heat for the coking operation. The coke finally finds its way into the gasifier, where
it is gasified into a low BTU fuel gas. This technology is only available from Exxon.
The advantages of this operation are that relatively little coke is generated, and that a low BTU
gas suitable as a fuel to a fired heater or a CO boiler is produced.
2.5.2.2 Residuum Hydrocraking
In this process, the residuum is contacted with hydrogen in the presence of a catalyst. This
converts the asphaltenes in the residuum into hydrogenated products that can be further
processed and converted into light products. This approach would take large quantities of
hydrogen to convert most of the asphaltenes into hydrogenated products. The catalyst usage is
high, because the metals that are normally presence in crude oil residuum poison the catalysts
that are required for the hydrocracking process.
2.5.2.3 Solvent Deasphalting
Deasphalting dissolves all of the hydrocarbons except the asphaltenes in the residuum in a light
paraffinic solvent, such as propane or pentane. The two liquid phases are separated, and the
solvent is distilled off for recycle. This is old technology that was originally developed by lube oil
refiners. It has been adapted for the processing of heavy crudes, such as Napo.
This is the lowest cost method of reducing the volume of residuum, because it does not require
large amounts of equipment, and does not operate at high temperatures and pressures.
This process, however, only concentrates the asphaltenes in the residuum. It does nothing to
convert the asphaltenes into usable products. For this reason, there are large quantities of fuel
oil that are generated by this process.
2.6 Environmental Considerations
Details of the environmental viablity are provided in the Environmental Viability Report.
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2.7 Plot Plan and PFDs
x The plot plan provided by PETROPERU has been updated to show the location of the
proposed new units, utilities, environmental controls, and general facilities. This plot plan is
given in Appendix A-1.
x All new units were marked with a blue honeycomb fill on the plot plan.
x All of the items on the plot plant will be reviewed during the preparation of the FEED. It is
expected that the final locations will be updated somewhat with the more detailed
information that will be developed during the FEED.
2.7.1 Process Units
x The existing units were not moved. The jet fuel caustic treater upgrade was not included,
since it will be completed as a refinery project prior to the Talara expansion and
modernization.
x The new units were placed in the same corridor as the existing units, in order to make the
modernized refinery as compact as possible and to keep the operating units well within the
refinery and away from the view of the public. The new units were also located to minimize
the length of runs for the connecting piping, cables and wiring.
x Spacing in the units and between the units conforms to NFPA and good refinery design
practices. The spacing takes into account accessibility for safety, operations and
maintenance. Plus adequate spacing is provided for all fired heaters to keep them a safe
distance from hydrocarbons.
2.7.2 Utilities
x The refinery is almost internally balanced on utilities. It will require only the purchase of 10
MM BTU/hr of natural gas to operate the gas turbine power generators. Much larger
quantities of natural gas will be required during start up before the refinery starts generating
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its own fuel and waste heat. The start up quantities of natural gas could be as high as 850
MM BTU/hr.
x The sea water cooling inlet and discharge were relocated on the Pacific Ocean side of the
refinery. The inlet was located south of the discharge to take advantage of the Humboldt
Current that flows from south to north. This location will help avoid the short circuiting of
warm water into the cooling water inlet.
x New offsite facilities, such as instrument air compressors, and the PSA nitrogen unit will be
located within the existing Industrial Services area and the new Industrial services area.
2.7.3 General Facilities
See General Facilities for detailed discussion.
2.7.4 A Block Flow Diagram of the refinery has been presented as Figure 2.11.
This diagram shows the unit sizes, and the flows between the process units within the
modernized refinery.
2.7.5 The Flow Diagrams for the individual units have been given as Figures 2.1 2.9. The units that
have flow diagrams are:
x Flexicoker
x Diesel Desulfurizer
x FCC Gasoline Desulfurizer
x Naphtha Desulfurizer
x Reformer
x New Gas Plant
x Amine Unit
x Sulfuric Acid Unit
x Hydrogen Plant
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2.7.6 Material Balances
2.7.6.1 The overall refinery material balance shows that the revamped refinery will produce:
x 8831 BPDO of LPG
x 19352 BPDO of Gasoline
x 8200 BPDO of Jet Fuel
x 39819 BPDO of Diesel Fuel
x 10837 BPDO of Heavy Fuel Oil and Asphalt
x For a total of 87039 BPDO total liquid products
x 344 short tons a day of sulfuric acid
x 488 short tons a day of petroleum coke
From:
x 57500 BPDO of Napo Crude
x 12350 BPDO of Petrotech crude
x 13000 BPDO of Petrobras crude
x 7150 BPDO of Talara Varios crude
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The overall material balance was given in Table 2.3.
Table 2- 3 The Overall Refinery Material Balance - Selected
Table 2.3A
Selected Case Refinery Products
Fuel
Gas
LPG Gasoline
Jet
Fuel
Diesel
Fuel
Sulfuric
Acid
Heavy
Fuel
Oil
Feeds
Napo Crude bpdo
Iquitos Reduced Crude bpdo
Products:
Atmospheric Tower
Refinery Gas kscfd
Light Naphtha bpdo
Heavy Naphtha bpdo
Kerosene bpdo 8200
Diesel Fuel bpdo
Reduced Crude bpdo 1160
Flexicoker
Hydrogen Sulfide kscfd
Hydrogen kscfd
Methane kscfd
Ethane kscfd
Propane bpdo
Butane bpdo
Naphtha bpdo
Diesel bpdo
Residue bpdo
Coke
short
tons/day
Gasified Coke, MMBTU/day
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Table 2.3B
Selected Case Refinery Products
Fuel
Gas
LPG Gasoline
Jet
Fuel
Diesel
Fuel
Sulfuric
Acid
Heavy
Fuel Oil
Fluid Catalytic Cracker
Hydrogen Sulfide kscfd
Ammonia kscfd
Methane kscfd
Ethane kscfd
Propane bpdo
i - Butane bpdo
n - Butane bpdo
Naphtha bpdo
Kerosene bpdo
Diesel bpdo
Residue bpdo 1677
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Table 2.3C
Selected Case Refinery Products
Fuel
Gas
LPG Gasoline
Jet
Fuel
Diesel
Fuel
Sulfuric
Acid
Heavy
Fuel Oil
Diesel Desulfurizer
Hydrogen Sulfide kscfd
Ammonia kscfd
Hydrogen kscfd
Methane kscfd
Ethane kscfd
Propane bpdo
i-Butane bpdo
n-Butane bpdo
i-Pentane bpdo
n-Pentane bpdo
Naphtha bpdo
Heavy Naphtha bpdo 1168
Kerosene bpdo 4943
Diesel bpdo 33708
Naphtha Desulfurizer
Hydrogen Sulfide kscfd
Ammonia kscfd
Hydrogen kscfd
Methane kscfd
Ethane kscfd
Propane bpdo
i-Butane bpdo
n-Butane bpdo
i-Pentane bpdo
n-Pentane bpdo
Lt. Naphtha bpdo 8893
Naphtha bpdo
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Table 2.3D
Selected Case Refinery Products
Fuel
Gas
LPG Gasoline
Jet
Fuel
Diesel
Fuel
Sulfuric
Acid
Heavy
Fuel
Oil
Reformer
Hydrogen kscfd
Methane kscfd
Ethane kscfd
Propane bpdo
i-Butane bpdo
n-Butane bpdo
i-pentane bpdo
n-Pentane bpdo
Lt Naphtha bpdo 4224
Reformate bpdo 6235
Gas Plant
Hydrogen Sulfide kscfd
Ammonia kscfd
Hydrogen kscfd
Methane kscfd
Ethane kscfd
Propane bpdo 7048
i-Butane bpdo 655
n-Butane bpdo 1129
i-Pentane bpdo 139
n-Pentane bpdo 196
Amine Plant
Hydrogen Sulfide kscfd
Ammonia kscfd
Hydrogen kscfd 6123
Methane kscfd 7564
Ethane kscfd 4680
Sulfuric Acid
Sulfuric Acid st/day 344
Total Refinery Production 8831 19352 8200 39819 344 10837
The unit to unit material balance is given in Table 2.4.
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2.7.7 Table 2- 4 Unit to Unit Material Balance
Table 2- 4 Unit to Unit Material Balance - Selected
Table 2.4A
Selected Case Refinery Unit Material Balances
Atmospheric
Tower
Vacuum
Tower
Flexicoker FCC
Naphtha
Desulfurization
FCC Gasoline
Desulfurization
Reformer
Diesel
Desulfurization
Feeds
Talara Blend bpdo 90,000
Napo bpdo
Products:
Atmospheric Tower
Refinery Gas kscfd 0
Light Naphtha bpdo -7996 7996
Heavy Naphtha bpdo -1150 1150
Kerosene bpdo -12700 4500
Diesel Fuel bpdo -14880 14880
Reduced Crude bpdo -53300 51300 840
Vacuum Tower
LVGO -6396 6396
HVGO -24580 24580
Vac. Resid -20300 20300
Flexicoker
Hydrogen Sulfide kscfd -2033
Hydrogen kscfd -1279
Methane kscfd -2880
Ethane kscfd -1450
Propane bpdo -591
Butane bpdo -421
Naphtha bpdo -4243 4243
Diesel bpdo -1888 1888
Residue bpdo -6882 6882
Coke
short
tons/day -488
Gasified Coke,
MMBTU/hr -1099
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Table 2.4B
Selected Case Refinery Unit Material Balances
Atmospheric
Tower
Vacuum
Tower
Flexicoker FCC
Naphtha
Desulfurization
FCC Gasoline
Desulfurization
Reformer
Diesel
Desulfurization
Fluid Catalytic Cracker 24302
Hydrogen Sulfide kscfd -209
Ammonia kscfd
Methane kscfd -1657
Ethane kscfd -573
Propane bpdo -5526
i - Butane bpdo -5
n - Butane bpdo -6
Naphtha bpdo -8992 8992
Kerosene bpdo
Diesel bpdo
-
10110 10110
Residue bpdo -1677
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Table 2.4C
Selected Case Refinery Unit Material Balances
Atmospheric
Tower
Vacuum
Tower
Flexicoker FCC
Naphtha
Desulfurization
FCC Gasoline
Desulfurization
Reformer
Diesel
Desulfurization
Diesel Desulfurizer 38923
Hydrogen Sulfide kscfd -271
Ammonia kscfd -15
Hydrogen kscfd -3344
Methane kscfd -1527
Ethane kscfd -1266
Propane bpdo -240
i-Butane bpdo -185
n-Butane bpdo -178
i-Pentane bpdo -21
n-Pentane bpdo -20
Naphtha bpdo 467 -467
Heavy Naphtha bpdo -1168
Kerosene bpdo -4943
Diesel bpdo -33708
Naphtha Desulfurizer 12239 0
Hydrogen Sulfide kscfd -31 -23
Ammonia kscfd
Hydrogen kscfd
Methane kscfd
Ethane kscfd -30 -11
Propane bpdo
i-Butane bpdo
n-Butane bpdo
i-Pentane bpdo
n-Pentane bpdo
Lt Naphtha bpdo
Naphtha bpdo -12104 -8893 12104
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Table 2.4D
Selected Case Refinery Unit Material Balances
Atmospheric
Tower
Vacuum
Tower
Flexicoker FCC
Naphtha
Desulfurization
FCC Gasoline
Desulfurization
Reformer
Diesel
Desulfurization
Reformer 12571
Hydrogen kscfd -10822
Methane kscfd -1500
Ethane kscfd -1346
Propane bpdo -690
i-Butane bpdo -465
n-Butane bpdo -523
i-pentane bpdo -119
n-Pentane bpdo -175
Lt Naphtha bpdo -4224
Reformate bpdo -6235
Gas Plant
Hydrogen Sulfide kscfd
Ammonia kscfd
Hydrogen kscfd
Methane kscfd
Ethane kscfd
Propane bpdo
i-Butane bpdo
n-Butane bpdo
i-Pentane bpdo
n-Pentane bpdo
Amine Plant
Hydrogen Sulfide kscfd
Ammonia kscfd
Hydrogen kscfd
Methane kscfd
Ethane kscfd
Sulfuric Acid
Sulfuric Acid st/day
Total Refinery
Production
Fuel Gas MMBTU/hr
Low BTU Gas MMBTU/hr 1099
Total Fuel Gas Available MMBTU/hr
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Table 2.4E
Minimum Capital Case Refinery Unit Material Balances
Gas Plant
Amine
Unit
Sulfuric
Acid
Caustic
Treating
Feeds
Napo Crude bpdo
Iquitos Reduced Crude bpdo
Products:
Atmospheric Tower
Refinery Gas kscfd 5
Light Naphtha bpdo
Heavy Naphtha bpdo
Kerosene bpdo 12700
Diesel Fuel bpdo
Reduced Crude bpdo
Flexicoker
Hydrogen Sulfide kscfd 2033
Hydrogen kscfd 1279
Methane kscfd 2880
Ethane kscfd 1450
Propane bpdo 591
Butane bpdo 421
Naphtha bpdo
Diesel bpdo
Residue bpdo
Coke
short
tons/day
Gasified Coke,
MMBTU/day
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Table 2.4F
Minimum Capital Case Refinery Unit Material Balances
Gas Plant
Amine
Unit
Sulfuric
Acid
Caustic
Treating
Hydrogen Sulfide kscfd
Ammonia kscfd
Methane kscfd
Ethane kscfd
Propane bpdo
i - Butane bpdo
n - Butane bpdo
Naphtha bpdo
Kerosene bpdo
Diesel bpdo
Residue bpdo
Fluid Catalytic Cracker
Hydrogen Sulfide kscfd 209
Ammonia kscfd
Methane kscfd 1657
Ethane kscfd 573
Propane bpdo 5526
i - Butane bpdo 5
n - Butane bpdo 6
Naphtha bpdo
Kerosene bpdo
Diesel bpdo
Residue bpdo
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Table 2.4G
Minimum Capital Case Refinery Unit Material Balances
Gas Plant
Amine
Unit
Sulfuric
Acid
Caustic
Treating
Diesel Desulfurizer
Hydrogen Sulfide 271
Ammonia 15
Hydrogen 3344
Methane 1527
Ethane 1266
Propane 240
i-Butane 185
n-Butane 178
i-Pentane 21
n-Pentane 20
Naphtha
Heavy Naphtha
Kerosene
Diesel
Naphtha Desulfurizer
Hydrogen Sulfide 54
Ammonia
Hydrogen
Methane
Ethane 41
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Lt Naphtha
Naphtha
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Table 2.4H
Minimum Capital Case Refinery Unit Material Balances
Gas Plant
Amine
Unit
Sulfuric
Acid
Caustic
Treating
Reformer
Hydrogen
Methane 1500
Ethane 1346
Propane 690
i-Butane 465
n-Butane 523
i-pentane 119
n-Pentane 175
Lt Naphtha bpdo
Reformate
Gas Plant
Hydrogen Sulfide -2567 2567
Ammonia -15 15
Hydrogen -6123 6123
Methane -7564 7564
Ethane -4680 4680
Propane -7048
i-Butane -655
n-Butane -1129
i-Pentane -139
n-Pentane -196
Amine Plant
Hydrogen Sulfide -2567 2567
Ammonia -15 15
Hydrogen -6123
Methane -7564
Ethane -4680
Sulfuric Acid
Sulfuric Acid -344
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2.7.8 The gas balance within the refinery, showing sources and disposition of various gas
streams is also shown in Table 2.4. A gas specific balance is given in Table 2.5. This gas
balance shows that the refinery can expect 377 MM BTU/hr of refinery gas.
Table 2- 5 Gas Specific Balance - Selected
Table 2.5
Selected Case Fuel Gas from Refinery
Fuel Gas MMBTU/hr 811 1216 BTU/scf
Low BTU Gas MMBTU/hr 1099 130 BTU/scf
Total Fuel Gas Available MMBTU/hr 1910
2.7.9 The hydrogen balance is given in Table 2.6. This table shows that the refinery needs to
produce 20 MM scfd of hydrogen in addition to the reformer hydrogen that is produced.
Table 2- 6 Hydrogen Balance - Selected
Table 2.6
Hydrogen Balance
Sources: Size
Unit
Consumption
Total
Consumption
BPDO scfb MMscfd
Hydrogen Plant 20
Reformer 8300 1350 11
Total Produced 31
Uses:
FCC Gasoline Desulfurization 9000 -350 -3
Diesel Desulfurization 25099 -760 -19
Naphtha Desulfurization 13793 -350 -5
Total Consumed -27
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2.7.10 The sulfur balance is given in Table 2.7. The sulfur balance accounts for 96% of the
sulfur.
Table 2- 7 Sulfur Balance - Selected
Table 2.7
Sulfur Balance
Sulfur In: Feed
Specific
Gravity Weight % Sulfur
Weight
Sulfur
BPDO lbs/day lbs/day
Napo Crude 57500 0.9414 18945675 2.18 413016
Petrotech 12350 0.8389 3626145 0.065 2357
Petrobras 13000 0.8593 3909815 0.094 3675
Varios 7150 0.8542 2137636 0.071 1518
Total Sulfur 420566
Sulfur Out:
Sulfuric Acid tpd 344 688000 0.326531 224653.1
Fuel Oil 11681 1.014 4145587 3.25 134732
Coke 230000 1.5 3450
Jet Fuel 16817 0.85 230000 0.3 690
Gasoline 19307 0.75 5068088 0.0003 15
Total Sulfur
363540
Sulfur Accounted for,
% 86
2.8 Catalyst and Chemical Consumption
The major catalyst and chemical consumptions are given in Table 2.8. This balance
shows that the annual chemical cost is $430,000, and the annual catalyst cost is
$9,458,000. There are probably other small consumptions of chemicals that will add to
the chemical total.
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Table 2- 8 Major Catalyst and Chemical Consumptions - Selected
Table 2.8
Catalyst and Chemical Consumption
Preferred Case
Unit Chemicals Catalysts
(K $) (K $)
Flexisorb SE 175
Proprietary
Amine
FCC 4460
Diesel Desulfurizer 3900
Naphtha Desulfurizer 360
FCC Gasoline
Desulfurization 260
Reformer 478
Amine 5 Amine
WSA 250
Hydrogen
Peroxide
Total Annual Cost 430 9458
2.9 Operating Cost
The operating cost items are summarized in Table 2.9. This table summarizes the labor,
supervision, maintenance, and other factors, shown as number of people, a factor of the
number of people, catalyst and chemical cost, or as a factor based upon capital
expenditure.
These data are typical United States Gulf Coast (USGC) numbers, and are presented in
this fashion to enable PETROPERU to adapt them to their particular operating style and
philosophy. ADL made its operating cost estimates based on industry experience, similar
operations, benchmark analysis, and other sources.
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Table 2- 9 Operating Cost Selected
Table 2.9
Operating Cost Basis
Selected Case
Unit
Men/
Shift
Total
Men Men/Shift
Total
Men
Atmospheric
Column 2 Technical:
Vacuum Column I 2
Vacuum Tower II 2
Flexicoker 6
FCC Gasoline
Desulfurizer 2 Process Engineers 7
Diesel Desulfurizer 2 Maintenance Engineers 7
Naphtha
Desulfurizer 1
Reformer 1 Utilities:
FCC 2
New Gas Plant 2 Supervisors 4
Hydrogen 2
Amine Plant 2 Engineers 1
WSA 2
Blending 2 Environmental:
Swing Operators 3
Utility Operators 4 Supervisors
Share with
Utilities
Environmental Operators 2 Engineers
Share with
Utilities
Total
Operators/Shift 39
Supervisors 25
Total Operators on Staff 156
Laboratory Technicians 20
Labor: Laboratory Supervision 4
Coke Handling 25
Shipping &
Receiving 24
General 20
Total Laborers 69
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Table 2. 9 Con't
Operating Cost Basis
Selected Case
Total Personnel
Laborers 69
Operators 156
Technicians 20
Supervisors 33
Engineers 15
Operating Supplies 10% of Operators plus Laborers
Utilities See Utility Summary
Catalyst & Chemicals See Table
Maintenance
3% of Capital (Includes Maintenance
Mechanics)
Taxes & Insurance
5% of Capital (Will vary by Peruvian Regulations and
Tax Rates)
2.10 Capital Estimate
The capital is shown in Table 2.10. This estimate shows that the total capital
required is $954,000,000, USGC basis. The contingency factor is included
in table 2.10 as provided by Petroperu policy.
Description of power generation is included as a utility in section 3.2.5. The
estimate includes a remote control room, programmer, testing, controls and
installation of the control system. This estimate includes an Emergency
Shutdown System (ESO) as listed in Chapter 4.
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Table 2- 10 Capital Estimate - Selected
Table 2.10
Talara Refinery Selected Case
Capital Estimate
ISBL OSBL
Size
Cost,
$MM Units Size
Cost,
$MM
Cost,
$MM
Utilities General Facilities Environmental
Atmospheric
Tower BPDO 90000 10
Power
Generator MW 44 60 Dock 45 Waste Water 6
Vacuum
Tower BPDO 53000 61
Substation
& Power
Lines 10 Tankage 20
Smokeless
Flare 3
Flexicoker BPDO 20000 193
Cooling
Water
MM
gpm 65 25 Fire Water 7
Chemical
Sewer 1
FCC BPDO 24000 40
CW
Pumps
MM
gpm 65 6 Nitrogen 2
Sanitary
Sewer 1
Diesel
Desulfurizer BPDO 39000 50 CO Boiler M#/hr 421 6 Office Building 5
FCC
Gasoline
Desulfurizer BPDO 9000 14 Laboratory 5
Naphtha
Desulfurizer BPDO 12600 24 Deaerator gpm 3500 1
Instrumentation &
Control Systems 64
Total
Environmental 11
Reformer BPDO 9000 40
BFW
Pumps gpm 3500 7
Coke Shipping
Equipment 21
Naphtha
Splitter BPDO 13000 5 RO Plant 0 Total OSBL 301
New Gas
Plant 30
Instrument
Air scfm 6
Total General
Facilities 169
Amine gpm 600 8 Connections 71
Sulfuric Acid ST/day 344 28
Total
Utilities 121
Hydrogen MMscfd 20 79 Total, USGC 954
Total ISBL 582
Location 20% 191
Contingency 12% 140
Owner Cost 21
Total Cost 1,306
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Table of Contents
TABLE OF CONTENTS..........................................................................................1
TABLES..................................................................................................................2
FIGURES ................................................................................................................3
3 TALARA REFINERY UTILITIES.....................................................................4
3.1 Descriptive of Conceptual Systems...................................................................................................... 4
3.1.1 Document of Calculations Made .................................................................................................. 4
3.2 Sea Water Cooling............................................................................................................................... 11
3.2.1 Cooling Water .......................................................................................................................... 11
3.2.1.1 Seawater/Waste Water Discharge: ...................................................................................... 13
3.2.1.2 Seawater Cooling Pump...................................................................................................... 14
3.2.1.3 Desalinated Water ............................................................................................................... 15
3.2.1.4 Deionized Water for Boiler Feed ........................................................................................ 16
3.2.1.5 Desalter Wash Water........................................................................................................... 16
3.2.1.6 Boiler Feed Water ............................................................................................................... 16
3.2.1.7 Boiler Feed Water Pump ..................................................................................................... 17
3.2.2 Steam.......................................................................................................................................... 17
3.2.3 Deaerator .................................................................................................................................... 18
3.2.4 Electric Power ............................................................................................................................ 19
3.2.5 Gas Turbine Generator ............................................................................................................... 19
3.2.6 Fuel Gas...................................................................................................................................... 20
3.2.7 Hydrogen Plant........................................................................................................................... 21
3.2.8 Instrument Air ............................................................................................................................ 24
3.2.9 Nitrogen Plant............................................................................................................................. 24
3.2.10 Calculations................................................................................................................................ 24
3.3 Conceptual Process Flow.................................................................................................................... 25
3.4 Diagrams and Descriptions of Conceptual Processes ...................................................................... 30
3.5 Diagrams and Descriptions of Conceptual Processes ...................................................................... 31
3.6 Unit Chemical Consumptions ............................................................................................................ 31
3.7 Liquid Effluent and Gas Emissions ................................................................................................... 31
3.8 Technical Reasons for Discarding Options ....................................................................................... 31
3.9 Investment............................................................................................................................................ 31
3.10 Labor Requirements ........................................................................................................................... 32
3.11 Implementation Plan....................................................................................................................... 32
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Tables
TABLE 3- 1 UTILITY SUMMARY SELECTED CASE............................................................................................. 5
TABLE 3- 2 UTILITY USAGE SELECTED CASE................................................................................................... 9
TABLE 3- 3 NET REFINERY CONSUMPTIONS ..................................................................................................... 10
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Figures
FIGURE 3 A....................................................................................................................................................... 22
FIGURE 3 B....................................................................................................................................................... 23
FIGURE 3- 1 COOLING WATER SYSTEM............................................................................................................ 26
FIGURE 3- 2 FUEL GAS SYSTEM....................................................................................................................... 27
FIGURE 3- 3 STEAM SYSTEM............................................................................................................................. 28
FIGURE 3- 4 ELECTRICAL SYSTEM.................................................................................................................... 29
FIGURE 3- 5 FLOW OF FUEL GAS, STEAM AND POWER TO AND FROM PLANT.................................................... 30
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3 Talara Refinery Utilities
3.1 Descriptive of Conceptual Systems
3.1.1 Document of Calculations Made
Overall utility balances for the Selected Case have been prepared, and are given
in the attached Tables 3.1 - 3.3. The tables show both generation and consumption
for all utilities.
The Selected Case will buy 10 MM BTU/hr of natural gas.
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Table 3- 1 Utility Summary Selected Case
Table 3.1
Expanded and Modernized Talara Refinery
Selected Case
Utility Summary
Unit
Atmospheric
Tower
Flexicoker
FCC
Gasoline
Desulfurizer
Utility
Feed
Rate
Consumption
per barrel
Total
Consumption
Feed
Rate
Consumption
per barrel
Total
Consumption
Feed
Rate
Consumption
per barrel
Total
Consumption
Power KW 90000 0.029 2610 51300 0.5684 29158.92 9015 0.00239 21.54585
Fuel
Gas
MM
BTU/hr
90000 0.002122 191 51300 0 9015 0.00123 11.08845
Low
BTU
Gas
MM
BTU/hr
90000 0 51300 -0.0401 -2057.13 9015 0 0
Cooling
Water
gpm 90000 0.075 6750 51300 0.3336 17113.68 9015 0.063 567.945
Boiler
Feed
Water
gpm 90000 0 51300 0.01262 647.406 9015 0
LP
Steam
M
lbs/hr
90000 0.0002 18 51300 -0.0123 -630.99 9015 0
MP
Steam
M
lbs/hr
90000 0 51300 0 0 9015 0.00331 29.83965
HP
Steam
M
lbs/hr
90000 0.0000173 1.557 51300 0.0105 538.65 9015 0
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Table 3.1 Cont
Expanded and Modernized Talara Refinery
Selected Case
Utility Summary
Unit FCC
Diesel
Desulfurizer
Naphtha
Desulfurizer
Utility
Feed
Rate
Consumption
per barrel
Total
Consumption
Feed
Rate
Consumption
per barrel
Total
Consumption
Feed
Rate
Consumption
per barrel
Total
Consumption
Power KW 10950 0.066 722.7 25099 0.1552 3895.3648 13793 0.00239 32.96527
Fuel
Gas
MM
BTU/hr 10950 0 0 25099 0.0014 35.1386 13793 0.00123 16.96539
Low
BTU
Gas
MM
BTU/hr 10950 0 25099 0 0 13793 0 0
Cooling
Water gpm 10950 0.442 4839.9 25099 0.15 3764.85 13793 0.063 868.959
Boiler
Feed
Water gpm 10950 0 25099 0 13793 0
LP
Steam
M
lbs/hr 10950 0.00104 11.388 25099 0.00584 146.57816 13793 0
MP
Steam
M
lbs/hr 10950 0 25099 0 13793 0.00331 45.65483
HP
Steam
M
lbs/hr 10950 0.00525 57.4875 25099 0 13793 0
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Table 3.1 (cont)
Expanded and Modernized Talara Refinery
Selected Case
Utility Summary, Continued
Unit Reformer Hydrogen*
Utility
Feed
Rate
Consumption
per barrel
Total
Consumption
Feed
Rate
Consumption
per MMscf/hr
Total
Consumption
Feed
Rate
Consumption
per gpm
Total
Consumption
MM
scfd gpm
Power KW
1309
9 0.125 1637 20 16.03 321 600 0.833 499.8
Fuel
Gas
MM
BTU/hr
1309
9 0.0126 165 20 15.52 310 600 0.069416667 41.65
Low
BTU
Gas
MM
BTU/hr
1309
9 0 0 20 0.70 14 600 0
Coolin
g
Water gpm
1309
9 0.278 3642 20 8.57 171 600 0
Boiler
Feed
Water gpm
1309
9 0 20 5.10 102 600 0
LP
Steam
M
lbs/hr
1309
9 0.00131 17 20 0 600 0
MP
Steam
M
lbs/hr
1309
9 0 20 0 600 0
HP
Steam
M
lbs/hr
1309
9 0 20 -1.50 -30 600 0
* Based
upon
Refinery
gas as
the
feedstock
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Table 3.1 (cont)
Expanded and Modernized Talara Refinery
Selected Case
Utility Summary, Continued
Unit
Vacuum
Tower Sulfuric Acid
Utility
Feed
Rate
Consumption
per barrel
Total
Consumption
Feed
Rate
Consumption per
ton
Total
Consumption
tpd
Power KW 51000 0.029 1479 344 2.1 722
Fuel Gas
MM
BTU/hr 51000 0.002122 108 344 0
Low BTU
Gas
MM
BTU/hr 51000 0 344 0
Cooling
Water gpm 51000 0.075 3825 344 3.14 1080
Boiler
Feed
Water gpm 51000 0 344 262
LP Steam
M
lbs/hr 51000 0.0002 10.2 344 0
MP
Steam
M
lbs/hr 51000 0 344 0
HP Steam
M
lbs/hr 51000 0.0000173 0.8823 344 -0.2 -69
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Table 3- 2 Utility Usage Selected Case
Table 3.2
Expanded and Modernized Talara Refinery
Utility Usage
Refinery
Total
Consumption
Refinery
Requirement
From
Steam
From
Low
BTU
Gas
From
Refinery
Gas
Amount
Produced
Net Required
MM BTU/hr KW
MM
BTU/hr
MM
BTU/hr MM BTU/hr
Power KW 41101 0 315 95
Fuel Gas
MM
BTU/hr 880 377 -484 -396 773 0
Natural Gas 23 23
Low BTU Gas MMBTU/hr 484 1228 169
Cooling Water gpm 42623 42623
Boiler Feed
Water gpm 1011 1011
LP Steam M#/hr -428 400 -28
MP Steam M#/hr 75 -75 0
HP Steam M#/hr 500 -500 0
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Table 3- 3 Net Refinery Consumptions
Table 3.3
Expanded and Modernized Talara Refinery
Net Refinery Consumptions
Power 0 KW
Fuel Gas 23 MM BTU/hr
Low BTU Gas 0 MM BTU/hr
Cooling Water 42623 GPM
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3.2 Sea Water Cooling
3.2.1 Cooling Water
The total amount of cooling water required for the expanded refinery is nominally
50,000 gpm
The cooling water system currently utilizes water from Talara Bay. The suction is
on the south side of the product loading dock. In Talara Bay, the water
temperature can reach 82
o
F during the summer. This is a relatively high
temperature, compared to the Pacific Ocean temperature, which is typically 62
o
F
in the summer. The seawater cooling pumps discharge into a common header that
feeds five 20 inch seawater lines to the plant. Four pumps are normally in
operation, with one on standby. During the summer, cooling water pumps have a
problem with taking in sand. This is caused by seasonal changes in currents within
Talara Bay.
The Bay is only 10 to 11 meters deep at the seawater intake. The pumps are
located within the natural channel in Talara Bay. The intake suction screens have
openings in excess of 50mm. They are currently encrusted with barnacles. As the
screens age, they are becoming more corroded. The pumps current location is
too close to the shore and bottom of the bay to accommodate the necessary
physically larger size, finer mesh screens. As an interim solution, it is
recommended that the pumps be moved to the existing mooring dolphin located
northeast of the existing loading dock. However, this will not provide cooler water
and will not solve the problem of the shallow bottom which will not provide
adequate area to reduce the inlet velocity for the new units to 0.5 ft/sec with
smaller 5 mm, screen openings. A seasonal problem in the Talara Bay and Pacific
Ocean are the Medusa (adult jelly fish) that will plug up seawater intakes. To
overcome this seasonal problem a Medusa guard shall be installed around the
seawater intake.
The best solution is to provide a deep sea intake system installed deep on the
Pacific Ocean floor. This will provide cooler water, year round, as well as provide
the increased flow rate and cooling duty requirements of the new units. Additional
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distribution lines will be required to get the increased flow of water to the
consuming locations. PETROPERU has operated a similar system in the past with
no operating problems.
A Pacific Ocean cooling water design will provide an intake approximately 18
meters deep in the ocean. This water will travel through a concrete weighted line
to a sump, where 3 or more cooling water pumps and 2 diesel powered fire water
pumps will be located. This cooling water system will be sized to provide all of the
cooling water needed by the refinery. The seawater will need to be chlorinated to
a low residual chlorine in order to control marine growth in the cooling water
system.
The use of the Pacific Ocean as a source for seawater cooling will provide lower
summer time water temperatures.
Additionally, with the low velocity intake design (0.5 ft/sec max velocity, with 5 mm
screen openings), problems with mobile marine life will be minimized. This problem
is currently being experienced at the refinery, with the existing system.
The warm seawater currently is commingled with other waste water streams, and
treated before it is discharged into the Pacific Ocean. It currently flows through a
CPI Separator and an API separator to remove any oil that is accumulated from
the tank farm, process units, and leaks. This system is not working well at the
present time and the additional loading from the expansion would make it
impossible to discharge water that meets the requirements all the time.
An improved system would segregate the various water streams. If deemed
desirable, some of the warm seawater used as cooling water could be exchanged
within a secondary closed cooling loop to eliminate any possibility of hydrocarbon
contamination. Some of the warm discharge from these coolers can be routed to
the desalination unit to improve desalination efficiency.
Oil residue from the desalter wash water will be a source of oil contamination in the
outfall caused by the increased capacity. Oil/water separation should be designed
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to remove most of the oil from the desalter using the existing CPI separator
followed by a centrifugal separator that will remove oil down to about 10 ppm or
less. This will be followed by a DAF (Dissolved Air Flotation) unit or oil absorbing
clay bed to assure that the wastewater stream is below 10 ppm oil & grease at all
times.
The exact methods to be used and ocean sensitivities will be assessed during the
preparation of the Environmental Impact Assessment.
At this time, no bathymetric study is available at the Talara site detailing
subsurface topography. Also, unavailable is information on Talara Pacific Ocean
tides, currents, water temperature and seasonal variations. This information will
assist in determining the length and location of the seawater intake line. For the
purpose of this estimate, it is assumed that the line will extend about 300 meters to
the seawater intake structure and the intake sump will be located on land,
approximately 100 meters from the shore line.
3.2.1.1 Seawater/Waste Water Discharge:
The seawater discharge is currently using three outfalls. The outfalls are at an
elevation between high and low tides. According to environmental regulations, a
discharge line must be buried and the discharge must extend far enough beyond
the beach to eliminate beach impact.
Currently, the wastewater discharge is a combined flow between the API and CPI
Separators. The API and CPI Separators emit a hydrocarbon odor indicating
excessive hydrocarbon discharge to the atmosphere. The existing oil/water
separators are not covered which is considered unacceptable by normal good
environmental design practices. The open discharge on the beach has left
remnants of dark oil stains on the sand. Additionally, the main outfall emits a
hydrocarbon odor as it discharges. This smell suggests that the free oil and grease
in the discharge is over the regulatory limit.
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The most stringent applicable wastewater effluent regulation is from the World
Bank. It requires that the wastewater system must produce discharge water does
not exceed a maximum 10 ppm free oil and grease.
The seawater discharge needs to be located to not mix with the intake water and to
discharge the water using a disperser to maintain a temperature not to exceed
2.5C at the edge of the mixing zone which will be 100 meters or less from the
discharge pipe. If seawater from the Pacific Ocean is used this should not be a
problem with a reasonable temperature rise of 10 to 15C for the cooling water. If
the source of cooling water is from Talara Bay it will start out up to 20C warmer
than the Pacific Ocean and would be expensive to build a dispersion device that
would handle the expected temperature rise up to 35C.
3.2.1.2 Seawater Cooling Pump
The source of cooling water will come from the Pacific Ocean. The Pacific Ocean
cooling water will come from an intake system approximately 18 meters deep in
the ocean. This water will travel through a concrete weighted line to a sump,
where there will be at least 3 cooling water pumps, including a spare. The cooling
water will be pumped to the refinery to handle all cooling water needs.
The RO plant needs to be fed with the warmest, oil free saltwater feed stream
possible. Some of the seawater used as cooling water could be either heated using
plate exchangers in a secondary closed cooling loop or by using all titanium tubes
in the shell and tube heat exchangers, eliminating the possibility of any
hydrocarbon contamination. As an alternative, warm sea water return could be
routed to the desalination unit. In the desalination unit, desalinated water will be
sent to process water system, while the discharged brine will be routed back to the
clean seawater discharge line.
The use of the Pacific Ocean instead of Talara Bay as the source for seawater
cooling will provide water with a lower summer time temperature and less marine
life than is currently being used in the refinery. The seawater will still need to be
treated with chlorine using either conventional chlorination methods or advanced
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methods that use low level chlorination to only control marine growth in the cooling
water system.
The seawater circulation pumps will be specified in the detailed design phase. The
wet end parts must be made of a material resistant to seawater corrosion, such as
nickel aluminum bronze. Motors and electrical supply must be capable of
withstanding a marine environment including the effects of any storm surge.
3.2.1.3 Desalinated Water
The desalinated water for the plant is provided from a Reverse Osmosis plant
operated by Pridesa, S.A., a Spanish company. This plant will need to be at least
doubled in capacity to provide sufficient desalinated water for the expanded and
modernized refinery. A supply of about 1800 gpm will be necessary to supply the
boiler feed water and the water to the desalter. Additional uses, such as potable
water will be in addition to this basic requirement.
In the current system, the feedwater to the desalination unit comes from the
refinery seawater cooling system. It is filtered through four stages of filtration prior
to going to the RO membranes. The plant operates at 64 bars (~900psig) using
FRP housings, SS inlet piping and PVC discharge piping. The plant currently
produces 2,200 m
3
/day (403gpm) of desalinated water, 1,500 m
3
/day (275 gpm) of
industrial water at 5ppm Total Dissolved Solids (TDS), and 700 m
3
/day (128 gpm)
of raw water at 200 300 ppm TDS.
The expanded RO plant will receive warmed sea water from the sea water cooling
system. This is desirable, because the higher temperature water can be more
effectively desalinated.
The current RO building was designed to be doubled in capacity within the same
building. The facility has power recovery turbines for improving the internal power
efficiency of the plant.
The reject brine from the RO plant will be mixed with the warmed sea water, and
will be returned to the Pacific Ocean.
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3.2.1.4 Deionized Water for Boiler Feed
The desalinated water from the RO plant requires deionization prior to using as
boiler feed water. Generally, boilers operating above 600 psi require deionized
water. Since the expanded boiler will operate at pressures up to 1200 psi,
deionization is required.
Electrodeionization (EDI) technology should be considered for treatment of RO
effluent prior to introduction to the boilers. This is particularly promising for the
purest desalinated water stream from the RO plant. Bed regeneration is by electric
field. No chemicals are involved, but it is limited to less contaminated feeds.
An alternative to EDI technology is the older mixed bed deionization technology.
This technology will work, but has the disadvantage of requiring alternate
regeneration with caustic solution and sulfuric acid. These liquids have to be
disposed of and will require neutralization prior to discharge.
3.2.1.5 Desalter Wash Water
Desalter Effluent Oil residue from the desalter wash water is a source of oil
contamination in the outfall. Consider installation of centrifuges and corrugated
plate interceptors, (CPI) separators, to remove this residual oil prior to returning to
the warm seawater return line. Also either a DAF unit or oil absorbing clay should
be used to assure that the discharge is less than 10 ppm oil & grease
3.2.1.6 Boiler Feed Water
The modernized refinery will require much larger flows of boiler feed water, due to
the increased steam generation. This water will be required for the boilers fired
with Flexigas to produce the steam used for refinery operation. In addition, the
refinery will have a great deal of waste heat recovered as steam in economizers.
This boiler feed water will need to be treated, deaerated, and pumped up to the
boiler pressure.
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3.2.1.7 Boiler Feed Water Pump
The boiler feedwater pumps provide the flow of boiler feedwater from the deaerator
storage tank to the inlet of the economizer. The pumps supply the pressure
necessary to overcome the friction losses in high pressure feedwater heaters,
piping, and the required pressure for the inlet of the boiler @ boiler relief valve
settings. The pumps will be able to supply 133% of the boiler flow, including
blowdown at relief valve setting in order to accommodate a relief situation on the
boiler. A spare pump will be provided.
The boilers will be equipped with three 66% pumps, including one installed spare.
Normally, at full steaming rates, two pumps will be operating at all times. At
steaming rates of 50% capacity or less, only one boiler feed pump will operate.
3.2.2 Steam
Currently, the refinery produces steam in a CO boiler, package boilers, and
economizers in the stacks of fired heaters.
In a CO boiler, a low BTU heating value gas, such as FCC off-gas or Flexigas, is
admitted into a fire box along with combustion air. The fire box is maintained at
about 985C. The temperature in the fire box is controlled by the fuel and air flow.
The boiler is started up using natural gas as fuel to get the fire box up to operating
temperature. Once the fire box is up to temperature the low heat value fuel is
introduced into the fire box. An advantage of a CO Boiler is that it has a large
turndown ratio, and will operate at less than 100% of design without problems.
CO Boilers are normally package boilers limited to about 300,000 lb/hr of steam
each. This can be overcome by using multiple units. Additionally, the low heat
value fuel gas can be blended with refinery off gas and used in existing process
heaters. Since this fuel is low sulfur fuel, SOx control is not required for
combustion. Since low BTU gases burn with a lower flame temperature, low NOx
burners will probably not be necessary.
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The steam that is generated by this boiler is at 600 psi and super heated. This
steam can be let down to plant steam pressures in one or more extraction turbines
to generate electric power. .
The refinery convention for steam pressure is as follows:
x 600 psi steam is designated high pressure.
x 450 psi steam is designated medium pressure
x 150 psi steam is designated low pressure
x The expanded and modernized refinery will both generate and consume steam.
In the Selected Case,
The refinery will consume medium pressure steam and of high pressure steam. This
steam will be produced from low BTU gas in a CO boiler. Boilers will be required for start
up.
3.2.3 Deaerator
The purpose of the deaerator is to remove dissolved gases (N
2
, O
2
, NH
3
, CO
2
, etc.)
from boiler feedwater and to provide adequate net positive suction head for the
boiler feedwater pumps. Incoming water flows through hydraulically-balanced,
self-adjusting spray valves and enters the condensing chamber that is filled with
steam. The steam strips the non-condensable gases from the feed
water/condensate feed. The noncondensable gases exit the system through the
deaerator vent(s). Then the water cascades through counter flowing steam and is
heated to the saturation temperature of the steam. The deaerated water gravity
flows to the deaerator storage tank as boiler feedwater.
According to industry standards, the deaerator operating pressure is based on the
required head needed for the suction of the boiler feedwater pumps, which also
dictates the deaerator operating temperature. The typical industry practice is a
residence time of 5 10 minutes in the deaerator storage tank. This residence
time determines the size of the storage tank. In a typical deaerator the O
2
content
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will be reduced to less than 0.005 cc/L and the CO
2
to zero, both of which are
industry standards.
3.2.4 Electric Power
The refinery currently uses about 8 MW of power. With the expansion, the
demand for power will increase. The current electrical substation cannot handle
additional power. Neither can the electrical system within the plant.
Energy failures occur twice per year from EEPSA and once per month from the
Talara internal distribution system. These outages are very disruptive to refinery
operations and will be addressed with the modernization.
Electric Power is currently being supplied by EEPSA from Malacca. There are two
33 kV circuits running 6 km from Malacca to the Talara substation. The 33 kV is
transformed to 2.4 kV for power distribution to the refinery, where the power
consumption is 7,300 kW.
Electric power for the refinery will be supplied by gas turbines fired with refinery
fuel gas and natural gas and will be independent of the local power grid.
3.2.5 Gas Turbine Generator
A gas turbine generator spins a turbine by burning a gas, like refinery gas or
natural gas. This turbine, in turn, drives a generator, generating electricity. The
waste heat from the gas turbine is recovered as steam. The steam is used to drive
supply process steam, as described in the previous section. These units are called
Heat Recovery Steam Generators (HRSGs).
The major advantage of HRSGs is that they recover additional energy from the fuel
used to run the gas turbine, and therefore are more thermally efficient. The major
disadvantage is that they require semi annual regular maintenance. Routine
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maintenance is probably available in Talara, but major repairs and overhauls will
need to be shipped to a repair shop which is probably available in Lima.
Operationally, without a grid back up, they are subject to going off line at any time.
If spare capacity is not operating and capable of handling 100% of the load at that
time, all operating units will go off line. This requires operating the gas turbines at
less than 66% of full load. 100% of full load is the most efficient operating point for
a gas turbine with efficiency reductions as the load decreases. The efficiency and
power availability from a gas turbine is dependent on the ambient temperature,
which will make balancing the load to the gas turbines a little more complicated.
3.2.6 Fuel Gas
For the Selected Case, the modernized and expanded refinery will require 1920
MM BTU/hr in fuel, including the fuel gas used to generate hydrogen and electric
power. The refinery gas will provide 850 MM BTU/hr in refinery gas, including
excess butane that is included in the fuel gas. The Flexicoker will provide and
additional 1099 MM BTU/hr of low BTU gas. An additional 10 MM BTU/hr of
natural gas will need to be purchased.
Natural Gas: The refinery is currently buying natural gas to fire the heaters and
boilers within the refinery. This is a large expense for them, and they want to
minimize this expense.
The reconfigured refinery will produce both refinery gas from the Flexicoker, the
FCC, and the various new hydroprocessing units.
The Flexicoker will also produce a large quantity of low BTU gas that can be
utilized within the refinery as a source of fuel.
Refinery Gas: This gas is produced by the FCC, the Flexicoker, and the
hydrodesulfurizers. It also includes the excess butane that cannot be blended into
the LPG product. If any butane is necessary to adjust the RVP of the gasoline
product, it will be taken from this stream.
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Low BTU Gas: This gas only has a heat content of 130 BTU/scf this gas produced
from the Flexicoker, and is in the FCC off-gas. This gas can be burned in fired
heaters using special burners. It can also be burned in a CO boiler.
3.2.7 Hydrogen Plant
The technology selected for hydrogen production is steam methane reforming.
Haldor Topsoe has extensive experience in this technology, which can also be
extended to produce methanol. Their technology is capable of using natural gas,
refinery gas, butane, or light naphtha as a feedstock, giving the refinery flexibility in
their operation. For these reasons, the Haldor Topsoe technology was used for
the optimum case. The unit will consume refinery fuel gas or naphtha as a
hydrocarbon feed.
Flexigas is unsuitable as a source of hydrocarbon feedstock for hydrogen
production. The Flexigas used from the Flexicoker will be used as a source of fuel
gas, not process feed gas, in the hydrogen plant. The unit will consume flexigas
mixed with refinery fuel gas as fuel gas.
Other steam methane reforming technologies are in use. None have the
widespread use of Haldor Topsoe technology.
Sketches showing the flows in this unit are given in Figures 3A & 3B.
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Figure 3 A
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Figure 3 B
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3.2.8 Instrument Air
The instrument air system is inadequate to handle the new units added during the
modernization. For the expanded refinery, the system pressure should be
increased to 125 150 psig. The current system operates at 50 psig.
The oiled compressors currently in operation should be replaced with oil free
compressors. The current air dryers are Pressure Swing Adsorption (PSA) dryers.
The existing surge drums have an unknown pressure rating, which means they
may or may not be capable of holding the higher pressure. It is recommended that
the existing surge drums be replaced with new ones. The new surge drums will be
placed both before and after the air dryers. This ensures that when a compressor
goes down, the refinery will still have a supply of instrument air until another
compressor is brought online.
3.2.9 Nitrogen Plant
A Pressure Swing Adsorption nitrogen plant (PSA) is recommended for purging
equipment of air prior to putting any hydrocarbons in it. The nitrogen gas is
produced from atmospheric air by molecular sieve adsorption. This process uses
a carbon based molecular sieve that preferentially removes oxygen from air.
Nitrogen is needed to inert vessels prior to introducing hydrocarbons, back up the
instrument air system, and provide tank blanketing to keep the products dry.
3.2.10 Calculations
The utility balance was given in the attached Table 3.1, as presented in Section
3.1.
The BTU availability was given in Table 3.2 was multiplied by .00029 for
conversion into KW. The KW was multiplied by .35 to account for the inefficiencies
in the steam system, and then divided by 1000 to convert to MW.
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3.3 Conceptual Process Flow
x Figure 3.2 shows the cooling water system and the flow from it to and from the
Water Desalination Plant.
x Figure 3.3 shows the Fuel Gas System, including the refinery gas, natural gas,
FCC vent gas, and the Flexigas.
x Figure 3.4 shows the Steam system.
x Figure 3.5 shows the electrical system
x Figure 3.6 shows the flow of fuel gas, steam, and power to and from the
expanded and modernized refinery, and how they are inter-related.
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Figure 3- 1 Cooling Water System
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Figure 3- 2 Fuel Gas System
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Figure 3- 3 Steam System
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Figure 3- 4 Electrical System
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Figure 3- 5 Flow of Fuel Gas, Steam and Power to and from Plant Needs updated
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3.4 Diagrams and Descriptions of Conceptual Processes
See the diagrams 3A through 3.6 in Section 3.2.
3.5 Unit Chemical Consumptions
See Table 2.8.
3.6 Liquid Effluent and Gas Emissions
These emissions are covered in the environmental section of the report
3.7 Technical Reasons for Discarding Options
The Circulating Fluidized Bed Boiler (CFB) was included as an option to burn
petroleum coke to make steam and power this unit is designed to burn coal which
is higher ash and it requires the addition of sand to replace the coal ash. Further
to partially replace coal ash and mainly control the SOx emissions limestone is
added along with the coke to the fire box. The CFB boiler requires about three
times the stoichiometric amount of limestone to operate properly when using
petroleum coke. This option was discarded since all the limestone would have to
be shipped into the site for distant sources. The CFB boiler was also higher capital
cost than the Fluidized Bed Boiler (FBB).
The Fluidized Bed Boiler (FBB) was a better lower cost option than the CFB and
only requires the stoichiometric amount of limestone to operate properly with a little
sand. This option was discarded when the decision was made to use a flexicoker
and ship the resulting coke to a cement plant for fuel.
3.8 Investment
The total investment for the utilities in the selected case was given in Table 3.3.
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3.9 Labor Requirements
It is estimated that the utility system will require three inside and two outside
operators. The system will require one supervisor and one engineer, although
these people may be shared with other refinery functions, such as truck loading.
3.10 Implementation Plan
The plan will be implemented by constructing and starting up a new system, and
then shutting down the old system.
The sea water cooling system will be started up before the old one is shut down.
In this start up, the flow to and from the desalination plant will be established. The
warm sea water will be segregated from other effluents, and the brine from the RO
plant will be mixed with the warm sea water effluent before the existing unit is shut
down.
The start up of the Desalination plant will be done by Pridesa.
The Boiler Feed Water will be treated, as necessary, and deaerated prior to start
up. This system will need to be started up and functioning before the boiler start
up is attempted. The existing treatment system may or may not be adequate for
the expanded refinery.
The new refinery will have new boilers for the generation of high pressure steam.
These boilers will be used in conjunction with the existing CO boiler. The existing
package boilers in the refinery will be shut down and possibly removed when the
new boilers are brought on line.
The expanded refinery will require a new substation and power lines. Upgrades
should be designed to handle both the increased startup power requirements. The
existing electrical system is limited by both voltage and capacity. The electrical
upgrades must be installed prior to the startup of the expanded refinery.
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Fuel gas will be needed to start up the plant. After start up, the refinery will
generate large amounts of both refinery gas and Flexigas that will be used to fuel
the refinery and to make hydrogen. The refinery will need to purchase some
natural gas. Any Flexigas that is not consumed will be converted to coke by not
generating as much flexigas.
The hydrogen plant will need to be on line and running prior to starting up any of
the hydrogen consuming units, such as a hydrocracker, if included, or
hydrodesulfurizers. The hydrogen plant will be started up on natural gas, and then
converted to refinery gas (as a raw material) and Flexigas (as a burner fuel). The
hydrogen plant will only produce hydrogen as needed to run the refinery, and will
supplement the reformer hydrogen.
The nitrogen plant must be online before any of the hydrocarbon processing units
are started up. This is because the vessels in the refinery will need to be purged
with nitrogen, and oxygen-free prior to start up.
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Table of Contents
4 Control and Instrumentation....................................................................................... 2
4.1 Introduction........................................................................................................ 2
4.2 Standards and Codes........................................................................................ 3
4.3 Existing Systems ............................................................................................... 3
4.3.1 Crude Distillation ........................................................................................... 3
4.3.2 FCC............................................................................................................... 3
4.3.3 Utilities........................................................................................................... 4
4.3.4 Product Storage and Transfer ....................................................................... 4
4.3.5 Fire Water System......................................................................................... 4
4.3.6 Product Loading Terminal ............................................................................. 5
4.3.7 Ballast Water Treatment................................................................................ 5
4.3.8 Electrical Substations .................................................................................... 5
4.3.9 Oil Separators................................................................................................ 5
4.4 Proposed Integrated Control System................................................................ 5
4.4.1 Overview........................................................................................................ 6
4.4.2 Distributed Control Systems.......................................................................... 8
4.4.3 SIS System.................................................................................................... 9
4.4.4 Oil Movements & Storage............................................................................ 11
4.4.5 Asset Management...................................................................................... 12
4.4.6 Advanced Process Controls ........................................................................ 12
4.4.7 Closed Circuit Television System................................................................ 12
4.4.8 Paging System............................................................................................ 13
4.4.9 Fire and Gas Detection System................................................................... 14
4.4.10 Instrumentation........................................................................................ 15
4.4.11 Remote Instrument Enclosures ............................................................... 15
4.4.12 Analyzer Systems.................................................................................... 16
4.4.13 Continuous Emissions Monitoring ........................................................... 16
4.4.14 Custody Transfer Meeting ....................................................................... 17
4.4.15 Communications Infrastructure................................................................ 17
4.5 Project Execution & Project Schedule............................................................. 18
4.5.1 Main Automation Contractor........................................................................ 18
4.5.2 Modernization Front End Engineering & Design ......................................... 19
4.5.3 Detail Engineering....................................................................................... 20
4.5.4 Testing......................................................................................................... 21
4.5.5 Factory Acceptance Test............................................................................. 22
4.5.6 Integrated Factory Acceptance Test............................................................ 22
4.5.7 Site Acceptance Test................................................................................... 22
4.5.8 Loop Check ................................................................................................. 23
4.6 Installation ....................................................................................................... 23
4.7 Options & Recommendations.......................................................................... 23
4.7.1 Engineering Productivity Tools.................................................................... 23
4.7.2 Vendor Pre-Selection .................................................................................. 24
4.7.3 Analyzer Networks/Remote Access ............................................................ 24
4.7.4 Continuous Emission Monitoring Systems .................................................. 24
4.7.5 Product Tank Gauging................................................................................. 24
4.7.6 Central Control Room.................................................................................. 25
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4 Control and Instrumentation
4.1 Introduction
The intent of this chapter is to describe at a high level the scope of work and the
functionality that is expected from the new control systems that are part of the
overall modernization and expansion of the Talara Refinery Complex.
At a conceptual level the scope of work includes the instrumentation and controls
associated with the new process units and the modernization of the retained and
the modified process units.
The overall philosophy for the execution of the control systems is to have as
many of the systems as possible installed into pre-fabricated
enclosures/buildings to allow for a fully integrated test of the largest part of the
systems prior to shipment to site. This will provide a significant reduction in the
duration and resources required on site for the equipment installation and site
acceptance testing.
Because none of the technology suppliers have been selected and contracted
with by PETROPERU detailed information as to the equipment required any
more than a general I/O count and number of analyzers is not available at this
time. However, the I/O count and number of analyzers will provide adequate
information to estimate the cost of the instrumentation. The details on what
instrumentation is required and what analyzers are required will be available
during the FEED and detailed engineering phase of the project.
An equipment list during the feasibility phase of the project would be only an
estimate to what is required since selected technology vendors al have a
different listing of what equipment is required to make their technology work
properly. The detailed information needed to generate an equipment list is not
available during the feasibility study and will only be partially available during the
FEED study. A detailed equipment list will be generated during detailed design
when all the technology suppliers are contracted to supply all the details of their
technologies to the detailed design contractor.
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4.2 Standards and Codes
x IEC 61508 Part 1 - 7: Functional safety of E/E/PES safety-related
system
x ISA 5.1 1984 Instrumentation Symbols and Identification
x ISA 5.3 1983 Graphic Symbols for Distributed Control/Shared Display
x Instrumentation, Logic, and Computer Systems
x ISA 5.4 1991 Instrument Loop Diagrams
x NEC 2008 National Electrical Code
x NFPA 72 National Fire Protection Association
4.3 Existing Systems
Control system details on the retained and modified units are provided below.
4.3.1 Crude Distillation
The Crude Unit currently has Siemens DCS and APACS SIS and uses HART
field instruments although the instruments are operating as conventional 4-20mA
devices. Modification will be associated with the changes to the process; the
incorporation of the DCS/SIS into the refinery wide architecture and the
integration of the HART data.
4.3.2 FCC
The FCC unit is currently 80% pneumatic with stand alone controllers. Some
electronic sub-systems are present and these include controls for the
hydraulically actuated valves, electronic governors on the blowers, and multipoint
temperature indicators. The Waste Water Treatment plant associated with this
unit has hybrid PLC system. All the instrumentation and controls will be replaced
with new HART instrumentation integrated into a new DCS and SIS System. This
will also be integrated into the refinery wide system.
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4.3.3 Utilities
The Utility Plant has a separate control room and is currently 95% pneumatic
with panel controllers.
x The two boilers both have pneumatic controls with a stand alone
electronic burner management system.
x The Instrument/Plant Air controls are completely pneumatic.
x The de-mineralization is currently operated though an obsolete electronic
sequence controller.
All the instrumentation and controls will be replaced with new HART
instrumentation integrated into a new DCS and SIS System. This will also be
integrated into the refinery wide system.
4.3.4 Product Storage and Transfer
PLC systems are currently installed for both the hydrocarbon and LPG custody
transfer. These systems are obsolete and will require replacement and
integration into the refinery wide system.
4.3.5 Fire Water System
The complex has two fire water pumping stations, the salt water system has
some data being passed to the Jetty Loading Control SCADA system while the
fresh water system has a stand alone PLC that communicates to the Fire Station.
There is no coordination between the two systems. These systems are obsolete
and will require replacement. The integration will include coordination of the
control of the two systems; the ability to monitor and control from the main
Control Building and the Fire Station; and integration into the refinery wide
system. It is envisioned that the seawater fire water pumps will be relocated from
the dock to the seawater intake sump to prevent sanding up and will be upgraded
to all vertical lift diesel driven pumps. The fresh water system will be replaced
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with an on site fresh firewater tank and new electric and diesel driven pumps. All
the fire water pumps will be controlled from the main control room.
4.3.6 Product Loading Terminal
The Product Loading Terminal is controlled by an Allen Bradley PLC 1990s
vintage. This system is obsolete and will require replacement and integration into
the refinery wide system.
4.3.7 Ballast Water Treatment
The Ballast Water Treatment is controlled by an Allen Bradley PLC 1990s
vintage which communicates to the Product Loading Terminal PLC via DH+. This
system is obsolete and will be retired when the ballast water treatment system is
retired since ballast water will not be present when the refinery expansion is
started.
4.3.8 Electrical Substations
The main sub-station has a PC based monitoring system that utilizes relays
connected via Modbus. This system is obsolete as is the main sub-station which
will be replaced to a higher voltage and larger capacity system. The controls
from the new main sub-station will be integrated into the refinery wide system
and will be controlled from the main control room.
4.3.9 Oil Separators
The Oil Separators are in part on/off control and in part manual. This system is
obsolete and will be demolished and modified along with the demolition and
upgrading of the oil/water treatment system. The new segregated wastewater
treatment system will all be controlled not only locally but will interface back to
the main control room with all monitoring and on line quality control available and
alarmed at the central control room.
4.4 Proposed Integrated Control System
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4.4.1 Overview
The control systems shall comprise of the following major systems:
x Distributed Control System (DCS)
x Safety Instrumented System (SIS)
The primary operator interface shall be through the DCS Graphics. These
graphics shall be Abnormal Situation Management (ASM) compliant.
The DCS and SIS systems will be tightly integrated with the SIS system(s) being
time synchronized to maintain data event time stamping integrity in the data
historian. This integration shall include standard SIS status details being
displayed graphically on the DCS Consoles.
In addition the following sub-systems shall be provided and these will
communicate to, and be integrated with the DCS:
x Fire and Gas Detection (F&G)
x Continuous Emissions Monitoring (CEMS)
x Custody Transfer Metering
x Analyzers
The preferred method for communication between the sub-systems and the DCS
will be through OPC. Should an OPC interface be unavailable then Modbus will
be an acceptable alternative.
For interfacing to the existing equipment sub-systems (i.e. turbine controls, Jetty
SCADA system, etc) the preferred method will be via OPC if this option is
available, with Modbus being an acceptable alternative. If these sub-systems do
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not support communication protocols then consideration should be given to their
replacement.
Within the DCS the following applications shall be provided:
x Advanced Regulatory Control
x Process Unit Optimization
x Asset Management
x Mass/Material Balance
x Oil Movements and Storage
x Pipeline Leak Detection (if applicable)
x Recording and alarm on environmental parameters
x Historization (PI)
x Alarm Management
To support the operations of the facility each unit will be provided with:
x Paging System
x Closed Circuit Television
All field instrumentation shall support HART protocol. HART data shall be
supported within the DCS system for device supervisory functions, or if this is not
supported then in a PC/Host Application shall be provided. This data shall also
be made available for future use in Asset Management and/or Maintenance
Management Systems.
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4.4.2 Distributed Control Systems
The DCS shall be the state-of-the art latest technology based on an open
architecture. That is, the system shall have inherent capability to integrate and
exchange information with other sub/systems and equipment from other vendors.
The DCS system hardware and software shall be of latest version, tested
successfully and proven in similar applications and has the capability to configure
Advanced Control Functions without modifications of the supplied hardware.
The Contractor shall be responsible to prepare the detailed specification meeting
all functional requirements of the system. The Contractor shall be responsible for
total system engineering, including cabinet / console layouts, equipment
compatibility, power loading and distribution, circuit protection, wire sizing,
system grounding, and the DCS and sub-system hardware and software
requirements.
Contractor shall provide hardware, marshalling cabinets, documentation,
interconnecting cables and all project services including supply of DCS with
console mounted hardware and all other equipment and services. Contractors
supply shall include but not be limited to redundant system hardware, redundant
gateways hardware required to interface to SIS systems / Flow computers/ Asset
Management System / Alarm Management System and other foreign devices,
workstations, Hardwired console with annunciator, pushbuttons, selector
switches, indication lamps, and printers with printer pedestals, etc.
DCS hardware shall be segregated by process unit. Contractor scope shall also
include software supply and software configuration for the entire DCS system
including software for integration of the DCS & SIS systems, alarm and report
management system, primary domain controller, plant control network and color
printers, etc. The integration that is now being used as mentioned above is
more advanced and more desirable than a RTIS integration since it is time
stamped and seamless.
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Contractor shall also provide all hardware and software necessary for fiber optic
communication between the central control location and the various satellite
installations which will include the remote DCS and SIS equipment in the local
RIE buildings; Analyzer houses; CEMS systems; Metering Systems; CCTV
Systems; Third Party Package sub-systems and to the plant wide networks. This
scope of supply shall include all firewalls; routers; fiber optic cables, patch
panels, etc.
As part of the C-HAZOP study, the entire control system (DCS & SIS) and
associated systems like Tank Gauging System, Flow computing, interfaces etc.
shall be Hazoped.
The Contractor shall also be responsible for providing the following services:
x System assembly
x System staging and testing
x System operation, engineering and maintenance training
x Installed system check-out
x Loop Transfer / Hot cutover and start-up services
The Contractor shall provide a protocol for performing and shall perform a fully
integrated Factory Acceptance Test. This test shall include the interfaces to all of
the third party sub/systems.
The Contractor shall provide a recommended spare parts list and list of any
special test equipment required for the proper maintenance of the proposed
system as well as list of any special programs / options required for the above.
4.4.3 SIS System
Triple Modular Redundant (TMR) and Quadruple Modular Redundant (QMR) are
the only SIS System architectures which are acceptable. The Contractor
proposed SIS systems shall provide safeguarding functionality for various units
and associated equipment. These systems shall be TV-approved and the
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implementation shall be in accordance with IEC 61508. A SIL Study shall be
performed to determine the AK class and corresponding SIL level.
The Contractor shall perform all system hardware engineering and design;
configuration of I/O; configuration of the SIS - DCS communications;
configuration of the associated DCS applications, alarms and graphics. Key
switches shall be provided for on-line testing of the SIS system and for
maintenance by-pass functions.
Where these SIS systems are to replace existing PLC and relay systems, the
Contractor shall provide proposed execution approach for the implementation of
the required modifications with the minimum of disruption to the process plants.
The proposed execution plan shall include the operational implications; it shall be
clearly stated how the intended modifications can be implemented and tested on-
line, with minimum operator disturbance. The SIS Systems shall be configured to
perform the functions as detailed in the existing SIS System Cause & Effect
and/or Sequence Logic diagrams and/or ladder logic and/or wiring diagrams
where the process units are not being modified. The Contractor shall verify the
drawings against the actual programming/wiring, from the existing Safety
Systems. For new process units or where modifications to the existing unit
impact the SIS systems, cause and effect diagrams and associated
documentation shall be provided to the Contractor.
Each of the SIS systems shall be fully tested at the SIS System Contractor works
during the SIS System FAT. The interface and integration with the DCS shall be
fully tested during the Integrated Factory Acceptance test. Factory Acceptance
Testing (FAT) of the Systems shall include the provision of all required test
facilities, test panels, where all input- and output signals can be simulated by
switches and lamps with the corresponding I/O category characteristics,
temporary workstation to enable a complete FAT of the new hardware and
applications. During the Integrated FAT a sub-set of the I/O shall be tested to
validate and confirm the SIS integration with the DCS.
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The Contractor shall provide a recommended spare parts list and list of any
special test equipment required for the proper maintenance of the proposed
system as well as list of any special programs / options required for the above.
4.4.4 Oil Movements & Storage
The Oil Movements and Storage (OM&S) Application shall run on the selected
DCS platform. This application will optimize the planning and execution of all
aspects of the product inventories, product blending and shipment. The
application shall have functionality that will:
x Provide inventory management and reporting
x Optimize the use of tank farm storage
x Plan and schedule blending and product transfer tasks
x Manage batch production, blends and shipments
x Minimize the potential for cross contamination of products
x Provide automated path selection, isolation, line up and execution for product
movements
x Enforcement of rules to ensure compliance with operational policies and
procedures to prevent the misuse or damage to plant equipment
x Provide material balances and reconciliations
x Provide reports and receipts to enterprise systems and data historian
As part of the Inventory Management, custody transfer accuracy (+1 mm) tank
gauges (radar or servo gauges) shall ideally be installed on all product storage
tanks.
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4.4.5 Asset Management
The Asset Management system (AMS) shall be a standard product offering that
resides within the architecture of the DCS control system. The Asset
Management System receives data from field devices and transforms this data
into a format that is usable by Plant Operations and Maintenance to make
informed decisions that will allow for greater plant availability and productivity.
4.4.6 Advanced Process Controls
Advance Process Controls (APC) shall be applied to the process units to
maximize process yields; reduce production costs; ensure product quality while
automatically adjust to changing process conditions. The APC shall use Mutli-
Variable controllers and Real Time Optimization to achieve these goals.
4.4.7 Closed Circuit Television System
The CCTV system shall be a networked system of IP based cameras located at
security points and critical process areas throughout the refinery. The cameras
shall be out-door rated with dual lens allowing day and night continuous
monitoring.
Cameras shall be networked using the plant fiber optic network and Ethernet
cabling. For remote plant locations where the fiber/copper network is not
accessible digital Ethernet radios shall be considered. For hazardous locations,
cameras shall be mounted in an explosion proof enclosure with a glass window.
Dedicated computer(s) shall be located in CCR for monitoring and recording
camera activity. All video management software and recording functionality shall
be integrated in the camera. Multiple cameras shall be viewable from one
computer using a web browser.
The Contractor shall be responsible for preparing the specification to meet the
functional requirements of the CCTV system during detail engineering. Actual
camera quantities and locations shall be determined at that time.
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4.4.8 Paging System
The Paging or Multi Party communication system shall be a microprocessor
controlled freely programmable exchange. Programming shall be by means of
user-friendly menu driven software.
The Paging or Multi Party communication system shall have a processor module
for the control of the central exchange. The speech diagram and other features,
such as all call, group call, alarm call, priority call, conferencing etc., shall be
resident in the processor module as a software program which shall be re-
programmable at site using laptop PCs with user friendly menu structure. Distinct
Push buttons shall be provided for various tones and their re-setting. The central
communication system shall have built-in fault diagnostic unit using test and
monitoring modules.
Paging system shall comprise of but not limited to following:
x Microprocessor based Page/Multi party communication system
x Explosion proof / weatherproof handset station / call station suitable for
hazardous area classification
x Explosion proof / weatherproof external loud speakers suitable for
hazardous area classification
x Hand set station / call station suitable for non - classified areas for indoor
/ out door use.
x All the outdoor stations shall be housed in standard Industrial Acoustic
Booths.
x Master call station(s), interface facility with other exchanges, all call
communication facility, individual page / part / conference facility, initiate
voice page & alarms, route the voice pages & alarms, acknowledge
system status & other facilities etc.
x All ancillary mounting brackets and cabling.
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The number of central control units (central exchanges) shall be equal to the
number of Process Units, quantities of peripheral devices; handsets, loud
speakers, etc shall be determined during detail engineering.
4.4.9 Fire and Gas Detection System
The F&G system shall be certified compliant to NFPA 72 (2002). The system
shall include independent stand alone panels to support fire and gas
requirements in the various process areas. The F&G panels shall be located in
the RIE buildings or existing electrical buildings. Each panel shall include the
following:
x controller and I/O modules
x local display panel for monitoring
x power supply and battery backup per NFPA 72
x Modbus or OPC interface for DCS integration
Each panel shall have I/O capabilities to support the following field devices:
x combustible gas detectors
x H2S detectors
x fire detectors
x horns
x beacon/strobe lights
x push buttons
x fire suppression systems
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Each F&G panel shall include a factory acceptance test witnessed by the
contractor and owner at the vendors manufacturing facility.
Each F&G panel shall be available during the integrated Factory Acceptance
Test for testing with the DCS and SIS systems.
The contractor shall be responsible for specification of the F&G system during
detail engineering including:
x quantity of field devices
x location of field devices
x location of panels
x installation details
4.4.10 Instrumentation
All field transmitters and valve positioners shall support HART digital protocol.
4.4.11 Remote Instrument Enclosures
Three RIE Buildings have been included in the scope of this feasibility study to
permit the installation of the control equipment in close proximity to the process
units while having the control performed from a safe location outside of the
process areas. The current DCS control room can be used as one of the RIE
buildings.
The RIE will contain DCS equipment cabinets; SIS equipment cabinets; Third
Party Sub-system equipment and cabinets; and the associated communications
infrastructure. The RIEs shall also contain an Uninterruptible Power System,
sized to be able support the equipment within the building for a period of 20
minutes in the event of a power failure. The building shall be pressurized and
have redundant HVAC and include fire detection and suppression. Current
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estimate is for each building to be 14 wide by 40 long and 13 heigh; these
dimensions are to be confirmed during detail engineering.
Each of the RIE buildings will contain the control equipment for multiple process
units; with the equipment for each process unit being physically segregated. All
the system cabling and marshalling wiring within the building will have been
completed and tested with the Central Control Room equipment and other sub-
systems prior to release for shipment to site. When details are available a
specific proposal can be requested from ENGlobal Systems group.
4.4.12 Analyzer Systems
Analyzers shall be provided as packaged systems that include the analyzers
installed in pre-fabricated shelters that are complete with all sample; drain; vent;
carrier gas and purge systems necessary for the operation of the individual
analyzers. In addition all sample probes and/or sample systems shall also be part
of the scope of supply. For the basis of this estimate we have assumed that there
will be five analyzer shelters, each with six analyzers.
4.4.13 Continuous Emissions Monitoring
The CEMs analyzers shall be provided to monitor SO2, NOx, O2, CO, CO2 and
Opacity. These shall be provided as packaged systems that include the CEMs
controller and analyzers installed in pre-fabricated shelters that are complete with
all sample; drain; vent; carrier gas and purge systems necessary for the
operation of the individual analyzers. In addition all sample probes and/or sample
systems shall also be part of the scope of supply. For the basis of this estimate
we have assumed that there will be ten analyzer shelters, each with three
analyzers.
The CEMs controller shall communicate and pass data to the DCS through an
OPC interface.
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4.4.14 Custody Transfer Meeting
It has been assumed for the purpose of this feasibility study that custody transfer
metering will be required for the following produce streams;
x Crude
x LPG
x Gasoline Low Octane
x Gasoline - Medium Octane
x Gasoline - High octane
x Jet Fuel
x Diesel
x Fuel Oil
x Sulfuric Acid
x Water
Two meters will be provided for each product stream; these shall be non-intrusive
Coriolis multivariable flow and density transmitters.
4.4.15 Communications Infrastructure
The existing fiber optic cable network shall be used or expanded to support the
new process areas and central control building. The new process areas shall be
linked back to the central control room via redundant fiber optic cable runs. The
fiber optic cable shall be outdoor armored rated cable. The number of strands per
cable shall be specified to support the new control system topology. Separate
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cable routes for the redundant fiber runs are preferred to provide system
integrity.
For remote plant locations where the fiber/copper network is not accessible
digital radios shall be considered. The preference is to hardwire all plant control
and system interfaces where possible.
The contractor shall be responsible for specification of the plants fiber optic and
communication requirements during detail engineering.
For estimating purposes fiber routing through the new process areas and existing
process areas was estimated at 10km installed.
4.5 Project Execution & Project Schedule
4.5.1 Main Automation Contractor
In essence from a control systems perspective there are two projects being
enacted at the Talara site?
i. Replacement of the existing obsolete control equipment with a modern
control system.
ii. A green field refinery expansion where new process units are being
constructed, most likely by different process licensors/EPCs in different
locations.
This adds complexity to the project execution and requires a high degree of
coordination between the project teams to ensure that the implementation of the
control systems is consistent; providing plant operators with the same look and
feel and a consistency in the engineering approaches to facilitate future
maintenance and modifications in the long term and simplifying the
implementation; pre-commissioning and commissioning activities in the short
term.
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To achieve this goal a Main Automation Contractor (MAC) should be assigned at
the inception of the project. The role of the MAC will be to establish the standards
for the design and implementation of the controls; in part these will be standards
documents and will also include the development of preferred vendors lists for
the application of specific equipment; selection and administration/management
of engineering tools; development of graphics sub-pictures and libraries;
development of standard logic blocks for standard functions; etc.
During the execution the MAC may either be directly responsible for the
implementation of the control solutions (the preferred approach) or shall be in a
position to have monitoring and oversight responsibility to ensure that all systems
are implemented to the same set of standards.
The MAC would also have responsibility for the over-arching systems that do not
fall within the process areas; this would include the plant wide networking; plant
wide applications; historization; etc.
4.5.2 Modernization Front End Engineering & Design
For the modernization of the existing units the first step will be to understand the
current controls strategies and requirements and changes/improvements that are
required. The first step in this process will be to review and fully update the
process units P&IDs to the current As Installed status; this will require full and
detailed site surveys. The next step will be to modify these P&IDs to show the
changes that are being requested and provide the new instrumentation and
controls. These modified P&IDs will have two layers, the new controls and the
equipment to be demolished in order to arrive at the final state. This will start to
form the basis for the definition of the scope.
The next step will be a review of the current site documentation in order to more
fully understand what is available; whether this has been kept up-to-date and is
in accordance with the installed state; and what will need to be reverse
engineered in order to start adding the detail to the control systems design. Give
sufficient time a comparison between the documentation and the installation
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should be performed to ensure that past modifications to the installation have
been captured in the plant documentation.
On the basis that the controls will be a replacement in kind; then surveys will be
required to collect the instrumentation data, much of this will be obtained from
existing instrument datasheets and specification documents but some will need
to be obtained by physical inspection of the control components which will
include controller tuning parameters; alarm set points; reverse engineering of
auxiliary device functions; instrument hook-ups; etc. As these details are
collected they should captured in electronic format as the basis of the Instrument
Database.
With this degree of detail having been assembled and compiled for the current
process units and their modification detailed engineering can commence.
4.5.3 Detail Engineering
With the scope of work for each of the process areas having been developed
either by the process licensor or through the FEL process on the existing units
detail engineering can now commence within the framework defined by the MAC.
This will entail the following activities:
x Development of the project schedules and execution plans
x Hazop and LOPA Studies
x Development of the overall System Architecture
x Specification of the Controls Systems components and layouts
x Development of the Instrument Database; Location Pans; Hook-Ups;
Datasheets; etc.
x Preparation of Functional and Detail Specifications
x DCS and SIS configuration
x Development of the HMI Graphics
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x Implementation of SIS Logic
x Implementation of DCS control strategies
x Preparation of procurement packages and material/equipment
procurement
x Preparation of construction work packages
x Preparation of test plans
x Closeout and transfer to site
4.5.4 Testing
Testing will be carried out at the various vendor locations (FAT) and at the overall
systems integrator (IFAT) to ensure that the control systems are tested to the
maximum extent possible prior to shipment to the site. This investment will
reduce the issues encountered at the site and reduce the time required for site
testing; loop checking; commissioning and start-up. Specifically this testing will
include:
x Factory Acceptance Test - Each sub-system at the vendors works
x Integrated Factory Acceptance Test All sub-systems as Systems
Integrator
x Site Acceptance Test A sub-set of the FAT/IFAT at the site
x Loop Check & Commissioning
For each of these tests there will be a documented test plan developed that will
follow a methodical and structured approach to performing the system tests.
There shall also be the opportunity for unstructured testing by the client.
The system vendors and the systems integrator shall have performed and
documented these tests to their own satisfaction and quality standards prior to
offering the systems for client testing. Copies of these internal test results shall
be made available for review.
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During each phase of testing punch lists of non-compliance or incompletion will
be generated and addressed. Each phase of testing will require resolution of
punch list items and customer acceptance to be deemed complete. Any
deficiencies or incomplete items shall be clearly identified along with plans for
their completion.
4.5.5 Factory Acceptance Test
This testing will be carried out at each sub-system at the vendors works and the
intent is to verify that the system has been implemented in accordance with the
documented and approved specifications and requirements. The system will be
inspected to ensure that all component parts are present, that all workmanship is
to the required standards and that all work has been completed. The tests will
include simulation of I/O points to check wiring and point parameters; graphical
displays; controller configuration; logic; historization; etc. In the case of the
Safety Systems this will require that all points are simulated in order to test
functionality of the system logic.
4.5.6 Integrated Factory Acceptance Test
This testing will be performed at the Systems Integrator and will test the overall
control system as it will be installed at the site with all system interconnection
cables (temporary) in place. The purpose of the testing is to ensure that the sub-
systems communicate; pass data and interact correctly. I/O will be simulated to
prove data transfer; communications and interactions between the sub-systems.
4.5.7 Site Acceptance Test
Once the system has been installed at the site and has been inspected;
powered-up and all the system software and configuration has been loaded and
communication between the sub-systems verified then the site acceptance test
can commence. This test will be a sub-set of the FAT and IFAT and is to ensure
that there has been no damage during shipment and that all systems are
performing as they were prior to shipment.
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4.5.8 Loop Check
With this project being partly a conversion of the existing units from pneumatic to
DCS control and partly new units/changes to existing units it is envisaged that
loop checking could be for hot and cold cut-overs, however for the purpose of
this document the assumption has been made that all loop checks will be on
cold process plants. The loop check will verify that the field installation has
been completed correctly; loops are energized and functioning correctly;
transmitter and valve calibrations are within specification; control action is
correct; alarm limits are correctly configured and that points are displayed
correctly on graphics. Once these tests are complete the loops are signed off and
ready for turn-over to operations for pre-start-up activities.
4.6 Installation
While it is anticipated that a Construction Contractor will be engaged to provide
the on-site resources to carry out the installation of the CCR console and
equipment; the RIE buildings; the Analyzer Shelters; the CEMs Systems,
specialist resources from the Controls Contractor shall be present to direct and
supervise this work.
Pre-deliver work shall include the running of the power cables to all of the
locations of the RIE buildings; the Analyzer Shelters; the CEMs Systems in order
that power may be provided for the HVAC systems to protect the equipment from
local environmental conditions. Installation of the home run cables; the grounding
and the system communications cables shall only be carried out by a qualified
contractor.
Field instrumentation shall have been installed in accordance with the project
specifications and instrument hook-up details.
4.7 Options & Recommendations
4.7.1 Engineering Productivity Tools
In order to facilitate the instrumentation and controls systems design process we
would recommend the selection of an engineering productivity tool such as SPI
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(INtools). The decision to such a tool needs to be made early in the project
lifecycle so that all design work is started in the tool making full use of the
efficiency and productivity savings that this will provide.
4.7.2 Vendor Pre-Selection
It would be our recommendation that a short list of qualified and acceptable
vendors be compiled prior to the commencement of detailed engineering and a
pre-selection process be performed to select one vendor in the major equipment
categories. This pre-selection will reduce the procurement cycle times during
project execution; enhance standardization; and provide a more consistent
implementation that will benefit the project during lifecycle support and
maintenance.
4.7.3 Analyzer Networks/Remote Access
To facilitate the maintenance and trouble shooting of the proposed analyzer
systems secure network tunneling technology should be implemented to allow
remote access, diagnostics and repair.
4.7.4 Continuous Emission Monitoring Systems
The scope of work calls for provision of CEMs Systems and this has been
included in the design basis it would be our recommendation that unless these
CEMs systems are required for permitting then the CEMs budget should be used
to reduce emissions. The CEMs estimate allows for 10 systems with a budget of
around $2.5 million. Based on gas that will be burned in the process heaters and
boilers the emissions from these units with low NOx burners should be low
enough as to not require the use of a CEMs unit. The use of CEMs will not
reduce emissions but will increase the maintenance and operating cost more
than it will benefit the environment in this situation.
4.7.5 Product Tank Gauging
The requirement to gauge product and crude tanks to 1 mm is a nice goal but if
the existing tank gauging system is reliable and will provide input to the DCS
system then the added accurately using radar tank gauging is not worth changing
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out the tank gauging system currently in place. However, radar tank gauging is
recommended for all new tank installations and for any gauging equipment that is
being replaced.
4.7.6 Central Control Room
The automated control room extinguishing system with the ban on using Halon is
not recommended since carbon dioxide systems are usually not effective and
safe for the operators. The modern control room designs do not generate the
heat and have adequate combustible material in a small space to sustain a fire.
The addition of smoke detectors will foresee a problem prior to a fire starting and
all cabinets will be temperature monitored.
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Table of Contents
5 Talara Refinery General Facilities.......................................................................... 2
5.1 Description of General Facilities ................................................................... 2
5.1.1 Storage Facilities....................................................................................... 2
5.1.1.1 Tank Service Change Over ................................................................... 4
5.1.1.2 Coke Storage......................................................................................... 4
5.1.2 Roads: ....................................................................................................... 4
5.1.3 Buildings.................................................................................................... 4
5.1.3.1 Laboratory Building................................................................................ 4
5.1.3.2 Office Building ....................................................................................... 5
5.1.3.3 Control Room/DCS................................................................................ 5
5.1.4 Flare System: ............................................................................................ 6
5.1.5 Other General Facilities............................................................................. 7
5.1.5.1 Fire Water.............................................................................................. 7
5.1.5.2 Dock Facility .......................................................................................... 8
5.1.5.3 Loading and Unloading Docks in Talara Bay......................................... 9
5.1.5.4 Sanitary Sewer ...................................................................................... 9
5.1.5.5 Crane................................................................................................... 10
5.1.5.6 Fork Truck ........................................................................................... 10
5.2 Calculations for General Facilities .............................................................. 11
5.2.1 Tank Requirements Calculations............................................................. 11
5.3 Description and Flow Diagrams for General Facilities .............................. 12
5.4 Unit Chemical Consumptions ...................................................................... 12
5.5 Effluents and Emissions............................................................................... 12
5.6 Discarded Options ........................................................................................ 12
5.6.1 The Talara Refinery has adequate tankage for all of the hydrocarbon
products to be produced in the optimum case. Several tanks will be needed in
other services. However, no floating roof tanks will need to be added. ................. 12
5.6.2 The exception to this is LPG storage. To have adequate storage,
additional LPG storage will need to be added......................................................... 12
5.6.3 Using the existing control room as a plant central control room was
discarded as discussed in Chapter 6 Control and Instrumentation. The primary
reason is the safety issue in the event of a disaster the control room personnel will
not be safe in the existing control room................................................................... 12
5.6.4 Relocating the lab and office building is for safety reasons to reduce the
number of personnel at risk in the event of a refinery disaster................................ 13
5.7 Capital Expenditures for the General Facilities in Chapter 2.................... 13
5.8 Labor Required See Chapter 2.................................................................. 13
5.9 Implementation Plan ..................................................................................... 13
5.10 Plot Plan......................................................................................................... 13
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5 Talara Refinery General Facilities
5.1 Description of General Facilities
5.1.1 Storage Facilities
The tank storage requirements of the new expanded refinery are based on 30
days of feed crude oil, and 15 days of finished product storage. The overall
tankage requirements were calculated, and compared to the available tankage.
In order to meet the expanded tankage requirements, an additional 81,000
barrels of LPG storage capacity need to be constructed along with new sulfuric
acid storage. Discussed below.
New 30,000 bbl fire water tank for fresh water storage.
The rest of the storage requirements can be met by changing the service of
existing tanks as follows:
x 320,000 barrels of gasoline storage tanks converted to crude oil storage.
x 30,000 barrels of jet fuel storage tanks converted to diesel fuel storage.
x 127,000 barrels of fuel oil storage tanks converted to diesel fuel storage.
x 41,000 barrels of fuel oil storage tanks converted to reduce crude storage.
This will give the refinery the following overall storage capacities:
x 2,700,000 barrels of crude oil
x 135,000 barrels of reduced crude
x 132,000 barrels of LPG
x 626,000 barrels of gasoline
x 255,000 barrels of jet fuel
x 645,000 barrels of diesel fuel
x 320,000 barrels of fuel oil
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Note: Minor products, such as solvents and asphalt, were not considered, since
they already have tanks for storage, and the production of these products will not
increase.
The Talara Refinery has two tank farms, one on the hill and one at the main
refinery elevation.
The tank farm on the hill receives local Talara crude in four tanks and
international crude in two tanks. Additionally, a third tank is being converted from
a water tank into a crude tank.
The lower tank farm has 30 tanks (20 for Products & 10 for crude). The refinery
is expanding their capacity for storing both crude oil and products. Four new
tanks will be added to this tank farm for crude storage with existing projects that
are under construction. The crude oil storage will need to be able to
accommodate a 30 day supply, and the product storage would need to be able to
accommodate a 15 day capacity of each product plus 14 day capacity for sulfuric
acid storage.
Sulfuric Acid Storage requirements:
Sulfuric acid storage requirements depend upon whether the required storage is
based on 14 days of production or the amount required to load out one full
shipload.
Based upon 750 short tons a day of acid production, 14 day capacity of sulfuric
acid storage would be two tanks with a capacity of 20,000 bbl each. The amount
of sulfuric acid stored in each tank would be 5,836 tones.
The capacity of one ship for sulfuric acid is 35,000 metric tons (tones), or 50 days
production. In order to load full shiploads, the total acid storage capacity will
need to be increased to 130,000 bbls.
Since the RFQ did not ask that storage match full shipments it will be assumed
that since the storage for a full ship load of sulfuric acid is 50 days production
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and it would not be reasonable to have a dedicated sulfuric acid ship it will be
assumed that it will be shipped with the other petroleum products. Shipping
sulfuric acid with hydrocarbons will require adequate safeguards to assure that
the acid never gets mixed with the hydrocarbons since this could promote a mild
exothermic reaction.
5.1.1.1Tank Service Change Over
Currently the Talara Refinery is making service changes with some of its product
tanks. They are changing their fuel oil storage tanks over to kerosene and diesel
service. With the expansion of the refinery throughput there will be more low
sulfur diesel and kerosene produced, which means that more tank storage will be
needed. The fuel oil tanks are being converted over because the market for fuel
oil in South America is declining. In the change over, the kerosene and diesel
tanks must meet a 40 ppm sulfur spec based on industry service changes
standards. The existing piping for fuel oil will be blinded off and taken out of
service, and new piping will be installed for the kerosene and diesel service.
5.1.1.2Coke Storage
The Flexicoker will produce powdered coke. This will be shipped in closed
reusable containers. Since the containers will be returnable, container storage
for two months of coke production should be provided. An area capable of
holding empty and full containers will be provided.
5.1.2 Roads:
The existing road system will need to be augmented with new roads for access.
A road will be provided on each side of the new units. In addition, road access to
new facilities as, such tanks, buildings, flare, dock, etc will be provided.
5.1.3 Buildings
5.1.3.1Laboratory Building
The new laboratory building will be built outside the process area of the refinery,
and must provide laboratory space for both the existing laboratory and the new
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laboratory area required for the current and new testing to accommodate the new
units. The new lab will be a replacement of the existing lab plus meet the
demands of the expanded refinery. The new lab will provide offices for chemists,
and laboratory space for existing and new test equipment. Areas of the new lab
will be electrically classified to handle light hydrocarbons safely.
This building area is estimated to be approximately 1,200 square meters. The
actual size will be determined during detailed design. The location must be out
of the area that will be impacted from a worst case explosion. This building must
be able to protect the personnel with either distance or overpressure design or a
combination of the distance and building design to survive the worst case
explosion.
5.1.3.2Office Building
The new office building will be built outside of the process area. This building will
be a replacement for the existing office building and also provide work space for
the administrative personnel required for the expanded and modernized refinery.
It will house 75 100 administrative and management employees. The building
is estimated to provide 15 square meters per employee plus a 20% allowance for
conference rooms and other non office space for a total of about 1,900 square
meters. The actual size will be determined during detailed design based on the
needs of PetroPeru.
The location must be out of the area that will be impacted from a worst case
explosion. This building must be able to protect the personnel with either
distance or overpressure design or a combination of the distance and building
design to survive the worst case explosion.
5.1.3.3Control Room/DCS
The new control room/ DCS systems will be housed in a new control room
located a safe distance from the new and existing units. Using modern DCS
control the existing control room will be utilized as described in Chapter 6 Control
and Instrumentation.
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The actual building size will be determined during detailed design based on the
needs of PetroPeru. The location must be out of the area that will be impacted
from a worst case explosion. This building must be able to protect the personnel
with either distance or overpressure design or a combination of the distance and
building design to survive the worst case explosion.
The control system and the building to house it are discussed further in Chapter
6, Control and Instrumentation.
5.1.4 Flare System:
The existing flare system may be undersized for the current operation, and it will
be undersized for the modernized and expanded refinery. This system is
continuously burning 30,000 scfd of vented gas. The refinery off gas that is
vented could be compressed and used as fuel gas. Currently, the refinery does
not have any overhead flare lines from the distillation towers. The flare system
handles all emergency relief situations from the towers. A knockout drum to
separate liquids from vapors prior to going to the flare is highly recommended.
The existing relief and flare systems need to be reevaluated based on the
increased capacity and the latest API RP-520 and 521 standards for the existing
units.
The refinery will need a new flare system to handle the new units. This system
can have a controlled compressor that will use the waste gases as refinery fuel
gas. The flare line will require a small positive pressure to exclude oxygen. This
pressure can be provided by either a nitrogen or natural gas purge. There are
several flare systems available for consideration that should be considered for
the final configuration of the refinery. The lowest cost option is used for this
estimate which is a simple pipe flare with steam assist for smokeless operation.
Based on the flare loads or requirements of Petroperu determined during detailed
design the type of flare may be more complex.
The Flare Gas Recovery System will reduce emissions from the facility. This has
value in environmental protection and public relations. This unit also reduces
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natural gas purchases, and extends the life of the flare tips. It can be integrated
into the existing flare system.
Flare sizes and types will be determined during detailed engineering.
For the purpose of this study it is assumed that the main flare has a 36 inch line.
The exact capacity and sizing will be determined during detailed design once the
relief load cases are determined and the relief valve sizing is complete.
5.1.5 Other General Facilities
5.1.5.1Fire Water
Currently the refinery is operating with fire water from the ship loading dock
facility. Fire water pumps are available on the dock, however they can sand up
when in operation. It is recommended that fire water pumps for the dock be
placed where they have a clear seawater intake. Relocate the existing diesel
pumps in Talara Bay to a deeper location and provide new diesel pumps in the
Pacific Ocean seawater intake sump to provide the necessary water capacity to
provide firewater back up for the dock and refinery.
The existing fire water system in the refinery is on a ring main, to supply fire
water to all process units if any one portion of the main is shut off. When the
refinery adds new units, there will be a need for more fire water. To address the
current and future fire water demands, a fresh water storage tank is
recommended in addition to jockey, electric, and diesel pumps being added to
the ring main. These pumps would be fed from the fresh water tank. The water
storage tank, jockey, electric, and diesel pumps will work in series. The water
tank will be the first choice of fire water supply. The jockey pump will maintain
pressure on the ring main to provide for leaks and small uses of fire water. If the
fire water needs increases, the second choice will be the electric pump(s)
supplying fresh water and the final resort will be the diesel pumps supplying
seawater.
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5.1.5.2Dock Facility
The Talara Refinery has a dock facility located in Talara Bay. The dock can only
handle one ship at a time. Ships are being loaded 20 hours a day at the existing
dock. Talara Bay can also be used for barges, however the additional liquid
products produced in the expanded refinery will require additional shipping
capability. There is another existing dock that is being used for tug boats. It will
need extensive rebuilding to make it suitable for loading ships.
Solids loading could conceivably be done on the Pacific Ocean side, but it would
require an extremely long and expensive dock, and possibly a breakwater
structure to protect against wave action. On the ocean side, there is either a cliff
or gently sloping land followed by a gentle sloping beach and ocean bottom. A
long dock would be required to reach adequate water depth. For these reasons,
the upgrade of the construction dock detailed in section 5.1.5.3, below, is
recommended.
An existing sub sea system is in place for unloading crude the system is being
upgraded from two 12 inch lines to two, 20 inch diameter lines. The upgraded
system will include a seawater reuse purge system that will reduce the amount of
seawater in the crude tanks. Currently seawater is purged trough the lines after
each load of crude and left in the lines until the next load of crude is unloaded
pushing this seawater into the crude tanks. The new seawater reuse system will
collect and store this seawater purge and reuse it to purge the sub sea lines
between crude loads.
A new dock will be built south of the existing dock in Talara bay extending the
existing tug dock. Both docks will be located in the bay in the existing natural
channel.
The new dock, will be constructed so a 35,000 ton ship can be berthed on either
side for unloading crudes and loading petroleum products and sulfuric acid. The
design unloading capacity is 21 - 30 MMbbl/month for each side. Duel loading
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arms will be provided to accommodate loading two ships at once. The dock is
expected to operate 24 hours a day.
The new dock will be 500 to 700 feet long, and about 120 feet wide. A concrete
slab and beam system is proposed for the decks, with steel pipe columns with
braces supporting the decks. Sea bed geotechnical data and wave load
conditions need to be considered in the structural design of the dock. Mooring
dolphins will be built as necessary. The dock is to be designed for
accommodating up to a 50 ton crane. The crane will be used for maintenance.
The location and size of the new dock is shown in the plot plan.
5.1.5.3Loading and Unloading Docks in Talara Bay
The ships currently load products out of the existing ship loading dock in Talara
Bay. All products and crudes at this dock are loaded or unloaded using loading
arms that are equipped with shut of valves and spill prevention systems to
reduce the risk of hydrocarbon spills into the Bay.
A new liquids loading dock will be constructed in Talara Bay that will use the
latest technology for spill prevention and capture. This dock will be constructed
in the existing natural channel and will not require disruptive dredging of the Bay.
Solids and containerized chemicals and solid products will be shipped and
received with an upgraded dock. The existing construction dock will be upgraded
and equipped with a loading/unloading crane, to load and unload containers.
This will divert shipments from trucks to ships, and reduce the amount of truck
traffic that would be required to ship the petroleum coke. This also provides a
means for receiving containerized materials and chemicals needed for refinery
operations.
5.1.5.4Sanitary Sewer
The purpose of the sanitary sewer is to carry sewage, liquid or waterborne waste
from the sewage source to a sanitary treatment facility. The flat topography at
Talara Refinery requires lift stations for pumping the sewage to a treatment
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facility. It will be treated and then reused in the irrigation system. This will
probably be an expansion of the existing wastewater treatment and reuse
system.
5.1.5.5Crane
The containers must be physically loaded onto a transportation vehicle either a
truck or a ship. One method of doing this is by a crane. A lifting crane typically
has capacity of 50.8 tons, a lifting height of 18 meters, a span of 50 meters, and
an outreach of up to 12 meters. Its hoisting speed with a load 30 is m/min, with a
trolley transverse speed up to 150 m/min, and a gantry travel speed of up to 240
m/min.
The Rail Mounted Gantry (RMG) crane will be used for the unloading of
equipment during construction, and will be used to load containers of coke for
shipment. This is a practical design for this application. The crane is based on a
sophisticated Load Control System that does not use hydraulics. Full AC
frequency controlled drives control squirrel cage motors. The RMG gantry
wheels are made of surface hardened chrome molybdenum steel, which has
exceptionally high impact strength and durability. The wheels can be realigned
for the site conditions to assure smooth gantry travel and minimum wearing of
the crane rails.
5.1.5.6Fork Truck
An alternative method of handling containers to load and unload trucks or ships
is a heavy duty fork lift. These units are capable of stacking containers three
high. This approach could save capital.
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5.2 Calculations for General Facilities
5.2.1 Tank Requirements Calculations
Tankage Requirements
Preferred Optimum Case
Required Tankage Service Changes
30 Day Crude, 15 Day Products, 2 Day Intermediate, & Blend Tanks
Current Need Add/Remove Source New Total
Raw Materials
Crude Oil 2380 2700 320 From Gasoline 2700
Reduced Crude 94 135 41 From Fuel Oil 135
Intermediate
Products
Coker Feed 0 103 103 From Fuel Oil 103
MPHC Feed 0 60 60 From Fuel Oil 60
FCC Feed 0 48 48 From Fuel Oil 48
Diesel
Desulfurizer
Feed 0 50 50 From Fuel Oil 50
Naphtha
Desulfurizer
Feed 0 40 40 From Gasoline 40
Reformer Feed 0 20 20 From Gasoline 20
Lt Naphtha 0 20 20 From Gasoline 20
Reformate 0 20 20 From Gasoline 20
Blend Tanks
Gasoline Blend
Tank 0 50 50 From Gasoline 50
Diesel Blend
Tank 0 40 40 From Fuel Oil 40
Products
LPG 51 132 81 Build 132
Gasoline 946 285 -320 To Crude Oil 626
-80 To Intermediate Storage 546
-50 To Blending 496
Jet Fuel 285 255 -30 To Diesel Fuel 255
Diesel 488 645 30 From Jet Fuel 518
127 From Fuel Oil 645
Fuel Oil 488 -41 To Reduced Crude 447
-127 To Diesel Fuel 320
-261 To Intermediate Storage 59
-40 To Blending 19
Net Actions Required:
Convert 320,000 bbls of Gasoline storage to Crude Oil
Convert 80,00 bbls of Gasoline storage to Intermediate
Convert 50,000 bbls of Gasoline storage to Blending
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Convert 30,000 bbls of Jet Fuel storage to Diesel
Convert 127,000 bbls of Fuel Oil storage to Diesel
Convert 41,000 bbls of Fuel Oil storage to Reduced Crude
Convert 261,000 bbls of Fuel Oil storage to Intermediate
Convert 40,000 bbls of Fuel Oil storage to Blending
Build 81,000 bbls of LPG storage
The LPG storage tanks selected are horizontal bullets which can be shop
fabricated and shipped to Talara. These tanks are much more cost effective
than the Horton Spheres not only because they are built in the field but
because they cost less per barrel of storage. The choice of type of tanks and
location will be determined during detailed design based on the disaster
model and client preferences. The number of tanks required can easily be
reduced to save capital cost without any impact on adding more tanks later.
5.3 Description and Flow Diagrams for General Facilities
NOT APPLICABLE
5.4 Unit Chemical Consumptions
NOT APPLICABLE
5.5 Effluents and Emissions
See Environmental Viability Report
5.6 Discarded Options
5.6.1 The Talara Refinery has adequate tankage for all of the hydrocarbon products to
be produced in the optimum case. Several tanks will be needed in other
services. However, no floating roof tanks will need to be added.
5.6.2 The exception to this is LPG storage. To have adequate storage, additional LPG
storage will need to be added.
5.6.3 Using the existing control room as a plant central control room was discarded as
an option due to the location in the center of the operating plant. The primary
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reason is the safety issue in the event of a disaster the control room personnel
will not be safe in the existing control room.
5.6.4 Relocating the lab and office building is for safety reasons to reduce the number
of personnel at risk in the event of a refinery disaster.
5.7 Capital Expenditures for the General Facilities in Chapter 2
5.8 Labor Required See Chapter 2
5.9 Implementation Plan
5.10 Plot Plan
The plot plan for the refinery showing all of the modifications in the refinery is
attached.
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Table of Contents
Table of Contents.............................................................................................................. 1
Definition of the Scope..................................................................................................... 2
A. Project Objectives.............................................................................................. 2
B. Scope Description ............................................................................................. 2
1. Utilities .............................................................................................................. 3
2. Controls and Instrumentation........................................................................... 3
3. Environmental................................................................................................... 3
4. General Facilities.............................................................................................. 4
5. Shipping............................................................................................................ 4
6. Buildings ........................................................................................................... 4
7. Other General Facilities.................................................................................... 4
8. Project Constraints ........................................................................................... 5
C. Main Deliverables............................................................................................... 5
D. Milestones and Main phases............................................................................ 6
E. Work Breakdown Structure .............................................................................. 6
F. Cost Estimate of major Items........................................................................... 8
G. Chronogram of the estimate........................................................................... 10
H. Management contingency reserves .............................................................. 12
I. Recommended Owners Organization Chart................................................. 12
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Definition of the Scope
A. Project Objectives
PETROPERU S.A. is the Peruvian state-owned petroleum company. ENGlobal
Engineering has assisted Arthur D. Little in performing a technical feasibility
study for the expansion and modernization of the PETROPERU Talara Refinery.
The technical objectives for the study are to modernize and expand the Talara
refinery, to improve the quality of the LPG, gasoline and diesel products, to
maximize the production of diesel fuel, and to minimize the production of heavy
fuel oil, and to allow processing of heavier sour crudes and residues.
The feasibility study evaluates the current status of the PETROPERU S.A. Talara
Refinery and what modifications are required to enable it to make low sulfur
motor fuels to meet the Peruvian requirements. The 2010 regulations require a
level of 50 ppm sulfur in both diesel fuel and gasoline. An additional objective is
to determine the configuration necessary for increasing the refinery capacity from
62,000 BDO to 90,000 BDO. The crude slate to be considered is 57,500 BDO
Napo crude, 7,150 BDP mixed Talara crude, 13,000 BDO Talara Petrobras
crude and 12,350 BDO Talara Petrotech crude.
B. Scope Description
The Selected Case is based upon including vacuum distillation capability and
includes the following units.
Atmospheric Tower (Existing)
Vacuum Tower(s) (New and Existing)
Flexicoker (New)
Fluid Catalytic Cracker (FCC) (Expanded existing unit)
New Gas Plant (New)
FCC Gasoline Desulfurization (New)
Diesel Fuel Desulfurization (New)
Naphtha Desulfurization (New)
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Reformer (Includes a C
6
/C
7
Splitter) (New)
Amine Plant for H
2
S removal (New)
Sulfuric Acid Plant (New)
Hydrogen Plant (New)
The expected capital expenditure for the Selected Case is $954,000,000, United
States Gulf Coast Basis (USGC), with no allowance for contingencies or location
factor. The total cost after applying these factors will be $1,306,000,000. The
project will be built using a fast-track implementation approach, with the same
contractor for FEED and EPC stages of the project.
1. Utilities
Cooling water will be taken from and returned to the Pacific Ocean.
The process water will continue to be supplied by Pridesa. A warmed
cooling water stream will be supplied to them for their reverse
osmosis (RO) units.
Steam will generated by waste heat boilers, process kettles, and
boilers that will burn either gas from the Flexicoker (Flexigas) or a CO
rich flue gas from the FCC regenerator.
The refinery gas generated and flexigas produced by the Selected
Case will supply in great part the needs of heat for furnaces and
boilers. Excess gas will be used for the generation of electricity in a
self generation cogeneration power plant.
2. Controls and Instrumentation
The control system will use a Distributed Control System (DCS).
3. Environmental
The project will be designed to meet both Peruvian and World Bank
Standards.
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4. General Facilities
Existing Hydrocarbon Fuels Storage is adequate. The service for
several Fuel Oil and Gasoline Tanks will need to changed, but no new
tanks will need to be added for liquid hydrocarbons.
There is not enough storage for LPG. Several LPG tanks will need to
be added to provide the required 15 day storage. For economic
reasons, bullets should be preferred to spheres.
Sulfuric Acid storage will need to be added, since none is currently on
site.
Coke storage was provided in shipping containers to allow for easy
loading, storage and shipping of coke.
5. Shipping
Two new docks were provided. One is a two sided dock that will
handle two ships simultaneously. The other is the existing shipping
dock. The required equipment for loading and unloading containers
was included.
6. Buildings
A new office building was included.
A new laboratory was included.
The DCS/Control room will be relocated away from the units for
personnel safety.
7. Other General Facilities
A new flare to handle the refinery is included.
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A new sanitary sewer with a treatment plant for the new facilities is
included.
8. Project Constraints
Water depth is only 10 meters at the port
Roads to the town are 2 lane roads with heavy traffic
Flooding and heavy rains, resulting from possible future El Ninos
Lime stone is 60 miles from the site; the site is all sand stone
Desert Climate
o Limited fresh water supply
Limited local supply of skilled labor
o Limited infra structure to support imported labor
Location is 600 miles from Lima
Limited number of hotel rooms
No supermarkets in the area
Limited infrastructure to support construction
o Limited amount of construction materials available
o Lack of available rental construction equipment in the area
o Lack of construction support service
C. Main Deliverables
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The following table lists the main deliverables for the Talara Refinery Expansion and
Modernization project.
Figure 1: Main Deliverables
ITEM DELIVERABLE DATE
1. Technology Design Q1-2009
2. Environmental Assessment Q3-2009
3. Front End Engineering Design Q3-2009
4. Project Finance approved Q3-2009
5. Detail Engineering Q3-2011
6. Procurement Q3-2011
7. Construction Q4-2014
8. Commissioning and Start up Q4-2014
D. Milestones and Main phases
The project schedule has four major phases as indicated on the Gantt Chart and the
milestones are shown in red color. This is an estimated schedule on a range of plus or
mines three months based on the feasibility study information. See the attached
schedule built in Microsoft Project version 2003 according to PMBOK guidelines
(Attachment 1). This schedule was developed on a fast-track basis and assumes the
same contractor is used in both the FEED and EPC phases.
E. Work Breakdown Structure
The Work Breakdown Structure will define the major phases for the Talara Refinery
Project and establish the structure for the cost, schedule and resource information
according to PMBOK guidelines. See the major Work Breakdown Structure in
Attachment 2.
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1.0 PHASE 1 PRELIMINARY ENGINEERING & TECHNOLOGY
1.1 TECHNOLOGY Technology selection and design package
1.1.1 Selection/Award Prepare and send RFP, selection of best bidder and award
1.1.2 License Contract Review contract, negotiate and sign
1.1.3 Develop Basic Design Package Selected suppliers develop design
1.1.4 Engineering Design Package from Licensors Suppliers deliver information and design package as required
1.2 ENVIRONMENTAL Environmental Assessment
1.2.1 Selection/Award Contract Prepare and send RFP, selection of best bidder and award
1.2.2 Environmental Assessments Supplier develop and deliver Environmental Assessment
1.2.3 Permits Owners summit and obtain require permits for the project
1.3 PMC Project management contract process
1.3.1 Selection/Award Prepare and send RFP, selection of best bidder and award
1.3.2 Manage the FEED Package contract Subcontractor performs control on the FEED Package process
1.3.3 Manage Construction and Startup Subcontractor performs control on the EPC execution and Startup
1.4 ENGINEERING Basic Engineering process
1.4.1 Selection/Award Prepare and send RFP, selection of best bidder and award
1.4.2 FEED PREP for units/offsite Contractor develop basic engineering for units and offsite
1.4.2.1 Phase 1 Develop and deliver phase 1 as per RFP FEED document
1.4.2.2 Phase 2 Develop and deliver phase 2 as per RFP FEED document
1.4.2.3 Phase 3 Develop and deliver phase 3 as per RFP FEED document
1.4.2.4 Phase 4 Develop and deliver phase 4 as per RFP FEED document
1.4.3 Detail Engineering and Data Sheets for long lead items Develop and deliver data sheets for long lead items
1.4.4 Estimate for Major Equipment Develop estimate for the major long lead items
1.4.5 Bids and award Long lead Items Prepare and send RFQ, selection of best bidder and award
1.4.6 Estimate -15% to +20% Develop and deliver the estimate for the scope of the EPC contract
1.4.7 Schedule Develop and deliver the schedule for the EPC contract
2.0 PHASE 2 FINANCE /CONTRACT ADMINISTRATION
2.1 PROJECT FINANCE Financing process for the project
2.1.1 Supply requirement & documents Supply necessary requirement & documental to financial institution
2.1.2 Financial Review Financial review of project documentation for project finance approval
2.1.3 Sign financial agreement Financial Institution approvals of agreement for the project execution
2.2 EPC CONTRACT ADMINISTRATION EPC contract process
2.2.1 Legal EPC Contract Creation Prepare legal and technical documents for the EPC contract
2.2.2 Legal Review/Negotiation Legal review and negotiate difference for scope and condition w/Parties
2.2.3 EPC Contract Signed Obtain final contract signed
3.0 PHASE 3 DETAILED ENGINEERING & PROCUREMENT
3.1 ENGINEERING Detail engineering processes
3.1.1 Civil Specs & Detail Engineering Develop and deliver detail structural and civil engineering
3.1.2 Mech/Piping Specs & Detail Engineering Develop and deliver detail Mechanical and piping engineering
3.1.3 Elect/IE Specs & Detail Engineering Develop and deliver Instrument and Electrical engineering
3.1.4 Process Specs & Detail Engineering Develop and deliver specs and detail process engineering
3.1.5 Automation Specs & Detail Engineering Develop and deliver specs and detail automation engineering
3.1.6 Estimate for Bulk Commodities Develop and deliver estimates for minor equipment and bulk material
3.1.7 Fabrication Needs Identified Develop constructability plan and prefabrication needs
3.2 PROCUREMENT Procurement process
3.2.1 Civil Prepare and send RFQ, selection of bidder and award for equipment & material
3.2.2 Mech/Piping Prepare and send RFQ, selection of bidder and award for equipment & material
3.2.3 Elect/IE Prepare and send RFQ, selection of bidder and award for equipment & material
3.2.4 Process Prepare and send RFQ, selection of bidder and award for equipment & material
3.2.5 Automation Prepare and send RFQ, selection of bidder and award for equipment & material
3.2.6 Bulk Commodities Prepare and send RFQ, selection of bidder and award for material
4.0 PHASE 4 CONSTRUCTION/STARTUP
4.1 CONSTRUCTION Construction process
4.1.1 QA/QC Auditing & Testing Develop plan and execute QA/QC
4..1.2 Site Prep Execute site preparation
4.1.3 Civil Construction & Installation Execute civil construction and installation
4.1.4 Large Equipment Set Up Plan and execute requirements for large equipment installation
4.1.5 Long Lead Items Installation Plan and execute requirements for long lead equipment installation
4.1.6 Mech/Piping Construction & Installation Execute mechanical and piping installation
4.1.7 Elect/IE Construction & Installation Execute instrument and electrical equipment installation
4.1.8 Automation Construction & Installation Execute automation equipment and material installation
4.1.9 Commissioning of Equipment Plan equipment commissioning for earlier startup units
Figure 2: Work Breakdown Structure Dictionary
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F. Cost Estimate of major Items
The cost estimate is summarized in the conceptual engineering document Figure 3 below and it
is also structured by WBS components on the next Chronogram with the Cost Breakdown.
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Figure 3: Cost Estimate
Talara Refinery Selected Case
Capital Estimate Per the Latest Information from PetroPeru
ISBL OSBL
Size
Cost,
$MM Units Size
Cost,
$MM
Cost,
$MM
Utilities General Facilities Environmental
Atmospheric
Tower BPD 90000 10
Power Generator
- 4 Half Sized
Units MW 44 60 Dock 45 Waste Water 6
Vacuum
Tower BPD 53000 61
Substation &
Power Lines 10 Tankage 20 Smokeless Flare 3
Flexicoker BPD 20000 193 Cooling Water MM gpm 65 25 Fire Water 7 Chemical Sewer 1
FCC BPD 24000 40 CW Pumps MM gpm 65 6 Nitrogen 2 Sanitary Sewer 1
Diesel
Desulfurizer BPD 39000 50 CO Boiler MW/hr 421 6 Office Building 5
FCC
Gasoline
Desulfurizer BPD 9000 14 Laboratory 5
Naphtha
Desulfurizer BPD 12600 24 Deaerator gpm 3500 1
Instrumentation &
Control Systems 64 Total Environmental 11
Reformer BPD 9000 40 BFW Pumps gpm 3500 7
Coke Shipping
Equipment 21
Naphtha
Splitter BPD 20000 5 RO Plant 0 Connections 71
New Gas
Plant 30 Instrument Air scfm 6
Total General
Facilities 169 Total OSBL 372
Amine gpm 600 8
Sulfuric Acid ST/day 800 28 Total Utilities 121
Hydrogen MMscfd 20 79 Total, USGC 954
Total ISBL 582
Peru Location
Adjustment (20%) 191
Owners Cost 21
Total, Peru 1166
Contingency (12%) 140
Total 1306
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G. Chronogram of the estimate
The Figure 4 shows a cost breakdown estimate chronogram for the project. This cost breakdown is in the range of +/-30%.
Figure 4: Estimate Chronogram
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H. Management contingency reserves
The contingency reserves distribution is shown in a separate line in the previous table. Assuming
contingency reserves are 12% the contingency amount is $140 MMUSD.
I. Recommended Owners Organization Chart
The proposed organization chart for PETROPERU Project Team has been broken down into Phases
following the WBS and the Gantt Chart. See Organization chart in figure 5.
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Figure 5: Recommended Owners Organization Chart
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Arthur D. Little Talara Refinery Expansion Modernization Project Project No. 10-371257
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ENVIRONMENTAL VIABILITY
APRIL 2008
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Table of Contents
EXECUTIVE SUMMARY 1 ____________________________________________________________ 4
ACRONYMS 1 _______________________________________________________________________ 9
1 Environmental Viability.................................................................................................... 14
1.1 OverviewEnvironmental Viability: ................................................................................ 14
1.2 Volumetric Balance Regarding Emissions, Effluents and Residuals .............................. 17
1.3 Estimated Volumes or Quantities of Gas Emissions, Liquid Effluents and Solid
Residuals ............................................................................................................................................ 20
1.3.1 Air Emissions ............................................................................................................................................20
1.3.2Wastewater Effluents....................................................................................................................................22
1.3.3Solid Waste Considerations .........................................................................................................................23
1.4 Estimated Concentration of Emissions, Effluents and Residuals.................................... 26
1.4.1 Air Emissions ............................................................................................................................................26
1.4.2Wastewater Effluent .....................................................................................................................................27
1.4.3Solid Waste (Residuals) ...............................................................................................................................28
1.5 Project Evaluation in Light of National and International Regulations (Standards): .. 31
1.5.1Perus National Regulations:........................................................................................................................31
1.5.1.1 General Law / Rights and Principles...........................................................................................31
1.5.1.2 Regulations Related to Hydrocarbons ........................................................................................33
1.5.1.3 Public Hydraulic Issues: ..............................................................................................................33
1.5.1.4 General Law of Waters ................................................................................................................34
1.5.1.5 Hydrocarbons ...............................................................................................................................36
1.5.1.6 Air Quality Standards ..................................................................................................................36
1.5.1.7 Law of Solid Residuals ................................................................................................................37
1.5.1.8 Noise and Vibrations....................................................................................................................39
1.5.1.9 Planning for Disasters ..................................................................................................................40
1.5.1.10 Conservation of Natural Resources.............................................................................................40
1.5.1.11 Control of Restricted Goods........................................................................................................40
1.5.2Additional Peruvian Regulations: ................................................................................................................41
1.5.2.1 Oil Spills .......................................................................................................................................41
1.5.2.2 Construction Authorization .........................................................................................................42
1.5.2.3 Storage ..........................................................................................................................................42
1.5.2.4 Fire Protection ..............................................................................................................................42
1.5.2.5 Reporting Requirements ..............................................................................................................43
1.5.2.6 Other Regulatory Environmental Issues.....................................................................................43
1.5.3World Bank Regulations ..............................................................................................................................44
1.6 Define Concepts to Control & Treat Pollutants ................................................................ 50
1.6.1Addressing Air Emissions............................................................................................................................51
1.6.2Addressing Water and Wastewater Issues: .................................................................................................52
1.6.3Solid Waste (Residuals): ..............................................................................................................................61
1.6.4Other Considerations (Noise, Radiation, Odors, etc.) ................................................................................62
1.6.5Summary of Concepts to Control and Treat Pollution ...............................................................................63
1.6.5.1 Air Emissions ...............................................................................................................................63
1.6.5.2 Water Effluents.............................................................................................................................65
1.6.5.3 Solid Waste (Residuals)...............................................................................................................66
1.7 Estimate Footprint & Investment Requirements.............................................................. 72
1.7.1 Land Footprint............................................................................................................................................72
1.7.2Investment in Environmental .......................................................................................................................73
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1.8 Provide a General Diagram of the Plant and Processes Used to Control Emissions,
Effluents and Residuals .................................................................................................................... 74
1.9 Summary and Present Conclusions Related to the Project and Identify Measures that
will Affect Construction.................................................................................................................... 75
1.10 References............................................................................................................................. 77
1.11 Appendices............................................................................................................................ 78
1.11.1Pacific Ocean Cooling Water System.......................................................................................................79
1.11.2Summary of Air Emissions ........................................................................................................................80
1.11.3 Plant Plot Plan with Emission Points (Appendix/Drawing sent separately).........................................81
1.11.4 Wastewater Treatment Plant (Process Flow Diagram) ...........................................................................84
1.11.5Talara Refinery Process Flow Diagram (Selected Case) .........................................................................85
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Executive Summary 1
EXECUTIVE SUMMARY
SUMMARY/OVERVIEW: There are nine (9) Client-Specific Requests (CSRs) included in
the clients planning document titled: TERMINOS DE REFERENCIA (TDR) 7.1-2007. This
Environmental Viability document (report) addresses each of the nine CSRs.
1. Overview of ENVIRONNMENTAL VIABILITY considerations:
There will be minimal impact on the surrounding area due to the Talara refinery expansion.
There will be changes to the seawater intake system; however, designs for lower velocity
intakes with smaller screen openings and adequately dispersed discharges along with taking
them out of Talara Bay will improve fishing and beach conditions.
Air emissions will be affected, however new equipment and unit processes will be designed to
meet Peruvian Regulations and World Bank Standards. As a result, modernization efforts that
include the production of low-sulfur fuels, the utilization of wastes and the control of emissions
can have an overall positive impact on the environment not only of Talara but of the country of
Peru as well as create positive economics. The latter includes income for the sale of coke,
sulfuric acid and higher value motor fuels. The pollution control impact will be reviewed in
detail in the Environmental Impact Assessment (EIA).
2. Volumetric balance regarding emissions, effluents and residuals:
State-of-the-art environmental technology processes are included as part of the modernization
feasibility assessment. The air emissions addressed (to comply with both Peruvian and World
Bank requirements) are volatile organic compounds, sulfur oxides, nitrogen oxides, carbon
monoxides, particulates, and noise.
Liquid leaving the plant will primarily be once-through seawater that will have only a minimal
temperature effect on receiving water. All process water, blowdowns and other liquid streams
enter a wastewater treatment plant whose effluent will meet regulations for biological and
chemical oxygen demand, oil and grease, suspended and dissolved solids, and for other
contaminants that must be removed in order to meet national or World Bank standards.
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3. Estimated volumes or quantities of gas emissions, liquid effluents and solid residuals:
High sulfur heavy crude oil can be handled by the retrofitted refinery with sulfur recovery units
tied to a new sulfuric acid plant that will meet national and international standards. This acid
unit carries the bonus of providing a saleable product tied to pollution control. Wastewater
effluents are estimated based on profiles for typical world scale refineries.
Using once-through seawater alleviates fresh water consumption tied to heat transfer, and
estimates for the amounts of process water are consistent with profile-outputs from typical
petroleum refinery processes.
Solid waste considerations are a factor during construction. Once the modernization is and
startup is completed, many sludges and process solids end up in the coking unit where the
organics and residuals become refined product, refinery fuel, or a saleable solid fuel.
4. Estimated concentrations of emissions, effluents and residuals:
Sulfur oxide emissions will be below the regulator requirements of 150 parts per million for the
sulfur recovery unit. Sulfur oxide emissions from the balance of the refinery will be negligible
nitrogen oxides over all plant average will be approximate 20 parts per million leaving the
stacks and particulate emissions will be less that 50 parts per million leaving the stacks.
Once-through seawater will be aerated to reach less than 0.1 parts per million of residual
chlorine. All potentially oily water will be treated to less than 10 ppm oil & grease and
discharged at less than the 150 parts per million limit for Chemical Oxygen Demand (COD)
set by the World Bank with the COD in specification the Biological Oxygen Demand will also
be in specification since the sanitary waste will not be discharged to the sea. The wastewater
treatment units shall be designed to meet the requirement for removal of suspended solids.
The refinery upgrade offers the potential for at source reduction of solid waste. This, coupled
to the addition of the Flexicoker, will allow the upgraded refinery to virtually eliminate refinery
sludges and tank bottoms as a source of pollution.
5. Project evaluation per National and International regulations:
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This report involved a page-by-page assessment of:
System of Environmental Management--Peruvian Standards
General Analysis of Perus Environmental Regulations
World Bank Pollution Prevention Abatement Handbook
Specifically, ENVIRONMENTAL VIABILITY assesses feasibility by reviewing (Article by Article
in the regulations) the requirements for air, wastewater and residuals. Tabular data is included
for: Handling (transport) of hydrocarbons, General Law of Waters, dangerous residuals, noise,
allowable air emissions, pollutant loads per tonne of crude oil processed and specific
requirements for minority pollutants including temperature rise.
ISO-14000 will be used for refinery operation as it is now at Talara and was considered as
part of ENVIRONMENTAL VIABILITY.
6. Define concepts to control and treat pollutants:
A unit-by-unit pollution control assessment was considered in respect to pollutants. Thus, in
considering expansion feasibility, environmental issues address treatment issues for air, water
and solid waste. Besides the normal pollutants expected and evaluated, the report also
considers the presence of ammonia, hydrogen sulfide, and other sulfur-containing
compounds. The selection of processes for wastewater treatment led to aeration units,
centrifugation, and corrugated plate separators integrated with pollution abatement
recommended by the American Petroleum Institute. The selection of sulfuric acid technology
is tied to minimizing exhausts of sulfur oxide and acid mist.
In respect to sludge, the Flexicoker becomes a desirable home for all such wastes, organic or
other. Because the ultimate use for the coke is probably in cement production, this end-use
alleviates leachate issues for heavy metals (that become part of the oxide portion of the
cement).
As part of ENVIRONMENTAL VIABILITY, the feasibility study did not uncover any specific
issue that would preclude the expansion. Specifically, this includes evaluations of issues
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discussed above, and more focused attention to: Seawater, cooling issues, all plant
wastewater streams, pollution tied to loading or unloading of ships, stormwater runoff, tank
leaks, accidental incidents, oil recovery and reuse, chemical sewer wastewater treatment, and
acid or basic nature of process streams of effluents. The report includes an outline for the
TALARA SOLID WASTE MANGAGMENT PLAN.
7. Estimate footprint and investment requirement:
While there are several new units that are included in expansion considerations, the existing
refinery plot can easily handle all of the new units or expansions. The impacted environmental
footprint of the existing refinery is about 100,000 square meters of area that is already in the
refinery area.
8. General Diagram of the plant and processes:
Plot plans and block flow diagrams are part of the Appendix of the report. ENVIRONMENTAL
VIABILITY suggests that the expansion is consistent with national and international standards
and can meet any local requirement.
9. Summary and conclusions related to the project and identify measures that will affect
construction:
In respect to construction there are issues related to housing, feeding and social
considerations of thousands of workers that will be at the construction site. These issues
include the interface with local population. Technical issues during construction are addressed
but do not create insurmountable problems.
In respect to the finished project the expanded refinery will provide the base for new hiring for
both, operations and maintenance personnel as well as supporting shops and industries for
parts, supplies and services (welders, machine shops, millwrights). These jobs are considered
well paid. Other jobs will be created to support the expanded marine and shipping industry.
RECOMMENDATIONS: The air ENVIRONMENTIAL VIABILITY is consistent with choosing
the new processes that both alleviate pollution and provide two additional income streams for
the refinery. These are positive attributes toward the modernization processes. The expansion
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also improves the potential to produce more electricity than required to operate the refinery
that could have a positive Return on Investment.
In respect to water, there are scenarios that enhance the possibility for improved fishing
conditions in areas of the bay. The changes in the intake hardware will have a positive effect
on newly-hatched species and the potential for additional aquaculture benefits. This new
equipment will also improve or eliminate entanglements of larger fish or mollusks. This speaks
to the positive value of the project from an environmental aspect.
In respect to residuals, new and existing contracts with catalyst suppliers to handle catalysts
from cradle-to-grave become a bonus for PETROPERU. Furthermore, minimal residuals are
expected that will require removal of toxic or hazardous waste from the site, nor is there a
requirement for landfarming. Instead, the Flexicoker becomes a depository for all oily sludges
and solids, so that they leave the plant as a saleable product or are consumed. Hence, this is
a positive recommendation tied to environmental issues.
CONCLUSIONS: From an ENVIRONMENTAL VIABILITY point of view, one can conclude
that the Talara modernization will positively affect the air people breath both in Talara and
Peru, and it will improve the quality of nearby receiving waters. It will not create oily solid
waste residuals that are harmful to the environment. In fact, two of the new pollution
control/processing units (The Flexicoker and the Sulfuric Acid plant) actually reduce pollution
while creating saleable byproducts.
Those byproducts (coke for fueling cement plants and sulfuric acid used in mining operations)
have two economic benefits: (1) Provide two new income steams for PETROPERU [that were
not there prior to the expansion], (2) Improve the countrys balance of payments issue
because Peru will not have to import as much sulfuric acid or fuel for the cement plants. Also,
should the refinery will use flexigas to run the plants boilers, this is an environmentally friendly
use of flexigas, and improves energy conservation that reduces formation of NOx emissions.
In addition, there is another overall community and regional benefit. That is: The refinery will
be making low-sulfur fuel for use in transportation. This will create a positive effect on ambient
air quality because trucks and cars will be using a better quality fuel. This is a benefit that is
over and above any improvements that result from better pollution-control measures at the
refinery itself.
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Acronyms and Definitions
Acronyms 1
Acronym Definition
# Pounds
$ US Dollar (unless specified otherwise)
% Percent
~ Approximate
Inches
Feet
Ag Silver
API American Petroleum Institute
B A bel (See db) Also B is the symbol for benzene
Ba Barium
BACT Best Available Control Technology
bbl Barrels, (one barrel equals 44 gallons)
BOD Biological Oxygen Demand
BTX Benzene, Toluene, Xylene
Btu British thermal unit
C Carbon
Ca Calcium
Cd Cadmium
CEMS Continuous Emission Monitoring System
centi 1/100
CGS See SI
Cl Chlorine
cm Centimeters
CN Cyanide
CO Carbon Monoxide
CO
Carbon Dioxide
COD Chemical Oxygen Demand
CONAM Perus National Council of the Environment
CPI Corrugated Plate Interceptor
CPM Critical Path Method
CSRs Client Specific Requests
d Day
DAF Dissolved Air Flotation
DAY
Perus Declaration of Environmental Import for solid waste
(residuals)
db
Decibel (measurement of noise level) A decibel is one tenth of
a bel (B). A decibel is a dimensionless unit
dB
Decibel, a measurement of noise. Noise level is usually
measured in dB for relative poweror it is a measure in
picowatts for absolute power. A suffix (for example, the A in
dBA) is added to denote a particular reference base or specific
qualities of the measurement.
dB (A) See dB
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Acronym Definition
dBA See dB
DCS Distributed Control System
deci 1/10
deka 10
DGAAE Perus Ministry of Energy and Mines
DICAPI Environmental arm of Perus Ministry of Defense
DIGEMID Perus Department of Medication and Drugs
DIGESA Perus Department of Environmental Health
DO Dissolved Oxygen
Document 19128 World Bank Pollution and Abatement Handbook
ECA
Standard of Environmental Quality, it is the measure of the
concentration or grade of elements, substances or physical,
chemical and biological parameters, in the air receiving body
that doesnt represent significant risk to health.
e.g. For Example
EIA Environmental Impact Assessment
Environmental
Management
Group of decisions, general or specific that are related to
politics and environmental legislation
EPA Environmental Protection Agency
ES Earliest Start Time
Fe Iron
FEED Front End Engineering Design
Flexicoker
A method of producing coke as licensed by EXXON
Corporation
Flexigas Gaseous products exiting the Flexicoker process
ft Feet
ft/sec Feet per Second
Fugitive Emissions Emissions that escape from flanges, valves, fittings, etc.
GAELR General Analysis of Environmental Legal Requirements
gal Gallon
gpm Gallons per minute
gm Gram (or gramme)
H
2
Hydrogen (two atoms)
H
2
S Hydrogen Sulfide
H
2
SO
4
Sulfuric Acid
Haz waste Hazardous waste
HC Hydrocarbons
hecto 100
Hr or hr Hour
Hydrocarbons
All organic, gassy compounds, liquid or solid, that consist
mainly of carbon and hydrogen
IPCC Intergovernmental Panel on Climate Change
ISO International Standards Organization
ISU See SI
Kg Kilogram (or kilogrammes )
kilo 1000
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Acronym Definition
L or l
The litre or liter is a unit of volume. There are two official
symbols: the letter L in lower (l) and upper case (L). The liter
appears in several versions of the metric system although it is
not an SI unit. It is accepted for use with the SI. The
international unit of volume is the cubic meter (m). One liter
is denoted as 1 cubic decimeter (dm).
Law Law N 26221, Organic Law of Hydrocarbons and their
modifications
LGDA Ley General del Ambiente
LMP Maximum Permissible Limit (also see MPL)
LNG Liquefied Natural Gas
Long ton 2240 pounds. In the United Kingdom the long ton is often
referred to simply as: ton (also see t)
LPG Liquefied Petroleum Gas (usually liquid propane and/or
butane)
LST Latest Start Time
m Meters or minute
MT Metric tonne (also see t and tonne, metric tonne and ton). It
is 1000 kilograms of mass.
Maximum Permissible
Limit (LMP)
They are the values or measures of the concentration or grade
of elements, substances or physical, chemical and biological
parameters present that characterize to an effluent or an
emission that, when being exceeded, can cause damages to
the health, human well-being and to the environment.
Metric ton MT a metric ton (also referred to as a metric tonne) is 1000
kilograms of mass, or roughly 2204.6 pounds.
Metric tonne See metric ton
mg Milligram
Mg (weight) Megagram (also see tonne and t) megagram is the proper SI
word for a tonne.
Mg (an element) Magnesium
mg/L Milligrams per liter (preferred over mg/l)
mg/l Milligram per liter (see mg/L)
mg/lt Incorrect nomenclature for mg/L
mic Micrometer (a measurement gauge not a unit of length)
milli 1/1000
Min Minute (Also see m)
MKS See SI
mm Millimeters
Mn Manganese
MPL Maximum Permissible Limit (some use LMP instead of MPL)
MTBC Mean Time Between Change out
MTBF Mean Time Between Failure
MTBT Mean Time Between Turn Around
mwg Meters Water Gauge
N or N
2
Nitrogen (usually expressed N
2
because two nitrogen atoms
travel together)
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Acronym Definition
NDT Non Destructive Testing
NORM Naturally Occurring Radioactive Materials
Ni Nickel
NMP Fecal Coliforms
N Number
NO
2
Dioxide of Nitrogen (Nitrogen Dioxide)
NOx Nitrogen Oxide (all types)
O or O
2
Oxygen (usually expressed as O2 because two oxygen atoms
travel together
O
2
Oxygen (two atoms of oxygen)
O
3
Ozone (three atoms of oxygen)
C Degree Centigrade
F Degree Fahrenheit
P Phosphorous
P Pressure Change or Pressure drop
PA Polynuclear Aromatics
PAMA Perus program for handling environmental waste
PEMS Predictive Emission Monitoring System
PERT
Program Evaluation and Review Technique (often referred to
as a PERT chart or a PERT diagram or PERT arc).
pH
Measure of acidity and basicity on a scale 0-14 with water
being neutral with a value of 7.0
PM Particulate Matter
PM-10 Particulate Matter 10.0 millimeter or less
PM-2.5 Particulate Matter 2.5 millimeter or less
PPB or ppb Parts per Billion
PPM or ppm Parts per Million
PPMV or ppmv Parts per Million by Volume
psi Pounds per square inch
psig Pounds per square inch gauge
PW
Produced Water (Produced water is the water that
accompanies crude oil during the production (recovery) of
crude oil from the earth.
Residual Solid waste (Usually from a process unit or tank bottoms)
RO Reverse Osmosis
s Second (also see sec)
S Sulfur
Se Selenium
sec Second (also see s)
Short ton 2000 pounds. In the USA the short ton is often referred to
simply as: ton (also see t)
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Acronym Definition
SI
International System of Units (also known as ISU) There are
two clusters of metric units in science and engineering. One
cluster, based on the centimeter, the gram and the second is
called the CGS system. The other, based on the meter, the
kilogram and the second is called the MKS system.
International System of Units is normally abbreviated SI from
the French: Le Systeme International d unites
SINANPE Perus national System of Natural Protected Area
SO
2
Sulfur Dioxide
SO
3
Sulfur Trioxide
SOP Standard Operating Procedure
SOx Sulfur Oxide (all types)
t
Tonne, also known as a metric ton (M/T) or a metric tonne.
A tonne is a measurement of mass equal to 1000 kilograms. It
is not an SI unit but is accepted for use with SI. Also see ton.
t Time, or, temperature
T Temperature, Also see t.
TDR
Terminos de Referencia (Planning document for Talara
project)
TDS Total Dissolved Solids
Ton
2000 pounds (also see t, ton, see long ton and see short ton.
The ton is a term mainly used in the USA). The letter t is the
acronym for ton or tonne.
tonne 1000 kilograms or 1 megagram, Mg or 2205 pounds
TSS Total Suspended Solids
UN United Nation
US United States (a shorter version of USA)
US EPA United States Environmental Protection Agency
USA United States of America
V Vanadium
VOCs Volatile Organic Compounds
WSA Wet Sulfuric Acid
WWT Wastewater Treatment
yr Year
Z
n
Zinc
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1 Environmental Viability
There are certain Client-Specific Requests (CSRs) to be addressed and included in
the ENVIRONMENTAL VIABILITY section of this feasibility report. These CSRs were
listed in Section Six of the planning document: TERMINOS DE REFERENCIA (TDR)
7.1-2007. The TDR listed the CSRs as follows:
Overview of ENVIRONMENTAL VIABILITY considerations (1.1)
Volumetric balance regarding emissions, effluents and residuals (1.2)
Estimated volumes or quantities of gas emissions, liquid effluents and solid
residuals (1.3)
Estimated concentration of emissions, effluents and residuals (1.4)
Project Evaluation per National and International regulations (1.5)
Define concepts to control and treat pollution (1.6)
Estimate footprint and investment requirements (1.7)
Provide a General Diagram of the plant and processes used to control
emissions, effluents and residuals (1.8)
Summarize and present conclusions related to the project and identify
measures that will affect construction (1.9)
Each of these CSRs is addressed in the following paragraphs;
1.1 OverviewEnvironmental Viability:
The impact of the refinery expansion to the Talara area will be covered in the
Environmental Impact Assessment (EIA) to be performed during the next phase of the
project. Based on the current usage of the site and no additional land requirements for
the project, it is anticipated that the environmental impact of the project will be minimal
to the Talara area. The only disturbance of areas outside of the refinery will be to
install an additional new product shipping dock and seawater intake and discharge
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lines in the Pacific Ocean. Since the new seawater intake and discharge lines will
improve the current seawater cooling system by using low velocity intakes, mobile sea
life can avoid the intake. Also, a deep sea discharge complies with the Peruvian law
that bans discharging wastewater on the beach.
A risk study using disaster modeling should be run to determine the impact on the local
schools and homes that may either require design modification to move high risk items
further away or to relocate the sensitive receptors including the office building, control
room and laboratory. The main consideration would be the location of the Horton
Spheres since they are now close to the administration building and may pose an
unacceptable risk in their proposed location. The risk study will be performed during
the FEED stage of the project on location and types of equipment that can be used to
mitigate the risks.
The proposed upgrades and new units that will be added to the refinery will all be
designed to meet or exceed World Bank Standards, National Standards and local
regulations. The net effect will be that the entire refinery will be upgraded to meet all
of the above standards.
The EIA will quantify and mitigate emissions, effluents and solid waste (residuals).
The water currently being discharged into the Pacific Ocean sometimes exceeds the
10 parts per million (ppm) free oil and grease limits set by World Bank. Air emissions
on new, modified, and existing equipment will be designed to be within Peruvian and
World Bank standards.
The overall impact of the refinery modernization to the country of Peru will be a net
environmental positive since the sulfur in the motor fuels will be reduced from up to
3000 ppm to less than 50 ppm and the amount of high sulfur residual fuel oil sold will
be reduced to only supply the small local market.
The impact of the refinery expansion to the Talara area will be reviewed in detail in the
EIA. One major advantage in the modernization is that less high-octane blending stock
will need to be imported under the new refinery configuration reducing the amount of
material that will be imported to Peru at a high cost.
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The modernization of the refinery will provide a source of low sulfur gaseous fuels that
will reduce the dependence on burning natural gas in the refinery. These low sulfur
fuels can also be used to make steam and subsequently electricity for refinery use and
for sales.
The conversion of the residual material from fuel oil to refinery products, Flexigas and
coke will reduce the amount of fuel oil currently being sold in Peru thus reducing the
amount of sulfur dioxide from burning the high sulfur fuel oil.
The seawater intake for cooling will be designed using US EPA criteria to prevent
mobile sea life from entering the seawater intakes. Wastewater treating will be
designed to meet World Bank regulations with safeguards to assure that all waters
discharged to the sea meet World Bank regulations.
The production of sulfuric acid as a by-product from the refinery will reduce Peruvian
imports of sulfuric acid.
The generation of petroleum coke will provide fuel to the cement plants operating in
Peru and thus reduce the importing of coal.
By using modern refinery unit design to include low NOx burners, and by operating the
refinery heaters at cooler temperatures, there will be a reduction in NOx emissions
once the refinery expansion is completed.
The refinery expansion will be in an area (existing acreage) that is already being used
by the refinery and is approved for industrial purposes. The project will not require the
use of any land that is not already part of the refinery except some area in and near
Talara Bay for the new docks.
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1.2 Volumetric Balance Regarding Emissions, Effluents and Residuals
The modernization project will affect the amounts of:
Gaseous Emissions
Liquid Effluent
Solid Residues (toxic, hazardous & non-toxic, non-hazardous)
Other Considerations (Noise, radiation, odors, etc.)
State-of-the art environmental technology processes and equipment can actually
improve some of the current conditions at the facility.
When considering the affects of the expansion on air, water and solid waste, gaseous
emissions (emissions into the atmosphere) are the most important for the project to
address. Gaseous emissions are the emissions that are noticed by the community first
and can impact the quality of life in the short term. This is because the volume (or
weight) of materials reaching the air is more noticeable than in the case of pollutants in
the water discharges or that of solid waste. In the case of water discharges there are
no significant problems with toxic or hazardous pollutants (for example, heavy metals).
In the case of solid waste, the most significant volume (or weight) is in spent catalysts.
Air emissions include Volatile Organic Compounds (VOCs), Sulfur Oxides (SOx),
Nitrogen Oxides (NOx). Carbon Monoxide (CO) which is allowable at higher levels
and particulates which will not be detectable in a desert climate from a plant burning
mostly gaseous fuels without sulfur. The largest amount of air emissions will be NOx
which will be generated from burning refinery fuel gas and low-Btu (British thermal
units) Flexigas. The VOC emissions are typical for a refinery of this size.
Liquids leaving the plant will primarily be seawater cooling discharge which, basically,
is clean seawater with some increase in temperature and a slight residual of chlorine.
The balance of the liquid effluents will be wastewater from boiler blow down, and
treated oily water from various sources. These wastewater streams will only be a
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small fraction of the seawater discharge stream. The wastewater treatment plant will
utilize Best Available Control Technology (BACT).
Solids will consist of mainly municipal type trash from packing and human activity
since catalyst and chemical containers will all be recycled (to suppliers of these
materials) leaving only such things as scrap metal and a small amount of hazardous
waste which will primarily be filter cartridges and solvents from maintenance
operations.
Noise will be generated by the construction of the facility but will be temporary and will
be mitigated as to reduce the impact to the community by using mufflers on
construction equipment and receiving as many supplies as practical by sea to reduce
traffic through the community. The noisy construction will be limited to daytime only if
it becomes a problem. A problem is not anticipated since the main part of the
construction effort will be in an area remote from the community shielded by the
existing plant tank farm. The only potential problem area for construction is driving of
pilings for the new product shipping dock. This can easily be mitigated if needed using
newer quieter pile driving methods.
Noise emissions after the project is completed will be minimal since equipment will be
shielded form the community by the tank farm and will be purchased to mitigate noise
since potentially noisy equipment will be specified with noise limitations. Many pieces
of new equipment, such as large motors, are now designed with lower decibel (dB)
output in mind, so, the refinery expansion will benefit by these advances in technology
Noise should not be problem from this project.
Social considerations could become a construction issue due to the influx of large
numbers of specialized skilled workers required to build the new plant. The imported
workers will be brought in to supplement local labor availability and lack of adequate
local skilled workers. First hiring preference will be to local labor if they are qualified
for the task. The impact of over a thousand men living single-status, far from a major
city, might increase the incidence of crime by both the imported men and opportunists
taking advantage of many single men who will have cash to spend or loose. The
project should address the needs of additional police, as well as a clinic to handle any
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social diseases that are common with the influx of many single status men on the
community.
Overall, the economic impact on the community will be positive for the five years
during construction, but the influx of additional people may strain the economy to
provide adequate goods and services causing potential local inflation. When
construction is complete and the imported work force leaves the area, the community
could experience a mild recession since the demand for goods and services will drop.
The resulting economy will still be larger than it is now since the added capacity will
bring more permanent jobs and opportunities for support services. Strategic planning
by PETROPERU, in concert with community government, should address during and
after-construction issues.
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1.3 Estimated Volumes or Quantities of Gas Emissions, Liquid Effluents and
Solid Residuals
The process-intensive refining industry has demanding environmental challenges to
protect air, water and soil. A first step in meeting these challenges is to consider the
various processes that are needed to make the product slate. Once the unit
operations have been determined, engineers must address the material balances and
emissions that reach air, water and land.
1.3.1 Air Emissions
The VOCs emitted are estimated are about 296 tons/yr based on what is known about
the existing and proposed refinery. This number is expected to increase about 20 to
30% during Front End Engineering Design (FEED) and detailed design when more
accurate information is available on the exact number of valves, flanges, and pumps.
Also several minor emission sources such as fugitives from wastewater treating were
not included in these numbers. The tank emissions were determined using the US
EPA program Tanks version 4.09d that does not calculate accurate emissions for
crude tanks with floating roofs below 100 foot in diameter. The less than 100 foot in
diameter crude tanks were factored off of the larger tank calculations. The VOC
emissions by source are found in the Appendix 1.11.2.
The Nitrogen Oxide (NOx) emissions will be the next largest air emission estimated for
each heater but may change during detailed design based on the actual burner used
and heater design. More accurate numbers will be obtained during FEED and refined
during detailed design. The NOx estimate for each fired sources can be found in the
Appendix 1.11.2 on the summary table and the heater and boiler calculation sheet.
In summary, the total plant NOx emissions, based on the process heaters for each
unit, is shown for point source 001 in the appendix for NOx, plus the additional
contribution from FCC, CO Boiler, flares, engines and power generation. The NOx
levels are reasonable since the low Btu gas burned to make steam will combust at a
low temperature and will not generate NOx; however, some of the process heaters and
WSA unit will be operated at a higher temperature and may generate more NOx.
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Sulfur Dioxide (SOx) emissions will be minimized since all the fuel gas and Flexigas
will have most of the sulfur removed before combustion reducing the SOx emissions
from the heaters and boilers to very low levels. SOx emissions from burning diesel
fuel for the cranes, fire water pumps and emergency generators will be lower than the
4 tonnes/yr because the diesel fuel being burned will be a low sulfur diesel fuel
produced by the refinery. The regeneration of FCC catalyst will also generate SOx
emissions as indicated in the Appendix. Some SOx emissions will be generated from
the Wet Sulfuric Acid (WSA) unit. The emission level of SOx from the WSA will be
less than 150 ppm, which is below the Peruvian, World Bank, and US EPA standards.
SOx emissions from the storage and loading of sulfuric acid will be controlled using a
wet scrubber system to capture and control these emissions.
The emissions from the WSA unit are as follows without any emissions control. The
without emissions control case is what is shown on the summary of emissions table in
the Appendix 1.11.2.
Pollutant ppm tonnes/yr
SOx 150 351
NOx 50 80
VOC 5 5
CO 5 5
With the addition of a hydrogen peroxide unit down stream, the capital cost of the unit
including the hydrogen peroxide unit will not increase but the complexity will increase
and it will require the purchase of hydrogen peroxide to operate the unit. The revised
emissions would be as follows:
Pollutant ppm tonnes/yr
SOx 15 35
NOx 5 8
VOC 0 0
CO 0 0
COS 3 7
The WSA unit without emissions control will meet World Bank standards on
concentration of pollutants. Currently no units in South America include the hydrogen-
peroxide-emissions-reduction option, which will cost more to operate. PETROPERU
and the lenders must consider if the low emissions option will be implemented at
Talara on the basis that it will increase the operating cost while producing about 344
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tonnes per year of sulfuric acid. The low emissions option is shown in the emissions
table in the Appendix 1.11.2.
Since the refinery will be burning fuel gas in all heaters and boilers, particulate
generation form fired sources will not be of concern. Talara is a desert location.
Particulate emissions from the site can be reduced by paving over the tank dikes
(which is a current project) and paving the expansion area.
1.3.2 Wastewater Effluents
The once-through seawater cooling will use about 65,000 gallons/minute of seawater.
One can compare this value with typical, rule-of-thumb, refinery wastewater usage.
TYPICAL WASTEWATER GENERATION BY REFINERY UNIT
Process
Wastewater flow (Gallons
per bbl of oil)
Crude distillation 26.0*
Fluid Catalytic Cracking 15.0*
Reforming 6.0
Desalting 2.1
Coking 1.0
Hydrotreating 1.0
Source: Energetics, 1998 Industrial Water Use and Energy Implications
* Original source is: EPA Office of Compliance Sector Notebook Project, Profile of the
Petroleum Refining Industry September 1995, Office of Compliance Office of
Enforcement and Compliance Assurance U.S. Environmental Protection Agency401 M
St., SW (MC 2221-A) Washington, DC 20460 Exhibit 15: Typical Material Outputs
from Selected Petroleum Refining Processes
Based on simulations preformed during the feasibility study it appears that the above
numbers are high by a factor of 10. Other water considerations include: water exiting
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the vacuum tower (steam jets) and the effects of water conservation tied to design
efficiencies that will be part of the expanded facility.
Except for the desalter, the resulting amount of wastewater generated by refinery
processes will be less than shown in the above table because much of the wastewater
generated is sour water, which will be stripped and reused in the desalter, in the
hydrogen unit and the hydrotreating units. At steady state operations, the real amount
of process wastewater (excluding the desalter water) will approach zero or close to
zero.
All other wastewater flows will be from wash down, maintenance and rainwater and will
be based on the design and operation of the refinery. Which based on the tour of the
refinery will be minimal to non-existent since all operating areas were free of
hydrocarbons. The predicted flows for the Groups of wastewater are listed in Section
1.6.2. The wastewater are listed as types of wastewater since the wastewater form
maintenance wash down and rainfall are based on the area of the operating plant and
is not assignable units since the operation of each unit will be different when the plant
is operating. The plant design will include the maximum predicted instantaneous flow
from each unit and the maximum flow from all units at any given time. The values
provide are average predicted flows from the refinery.
1.3.3 Solid Waste Considerations
In the refinerys planning, catalysts suppliers have agreed to pick up and recycle these
solids, so, there is no solid waste catalyst disposal requirement by PETROPERU.
Spent catalysts leave the site as the property and responsibility of the manufacturer.
Empty chemical containers will also be recycled back to the suppliers for reuse or
disposal. This is a common practice.
The construction effort will generate many tonnes of packing material, and metal scrap
that can be recycled. Since the packing material will be clean and free of chemicals, it
is possible that some of it can be recycled locally. The control of these materials will
be the responsibility of the construction contactor with reports provided to
PETROPERU to make sure all materials are recycled properly and will not cause
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environmental problems. All items disposed of during construction will be handled in a
traceable manner with oversight by PETROPERU.
During the operation of the facility, the largest solid waste stream will be normal
garbage from personnel. This will be handled the same as household garbage.
During construction, the quantity of solid waste will be dependent upon how many
workers will be at the site at a particular time. The latter will be compatible with
PETROPERU planning using a Critical Path Method (CPM) for construction that will be
tied to a Program Evaluation and Review Technique (PERT) diagram and timetable.
A very small quantity of hazardous waste (such as paint sludges containing residual
solvents) will be generated during construction. Similarly, once the expansion is
completed, during normal operations and maintenance procedures, (or as a result of
spills or events), the refinery will handle materials such as cleaning liquids, solvents,
oily rags, oil soaked materials, spent absorbents, insulation, filter cartridges,
chemically contaminated materials or other hazardous substances generated in the
Operation and Maintenance (O&M) of the facility. Standard Operating Procedures
(SOPs) will be developed that will address O&M and disposal procedures, plus policies
and regulations to handle all types of waste (normal, toxic, hazardous, other). This will
include a secured area, controlled access, policing, training and personnel-safety
issues (such as protective clothing and breathing apparatus).
Solid waste generation from the incoming crude and recovered oily sludges will be
eliminated since the sulfur will be removed from the products and converted into
sulfuric acid which will be sold and the remaining sulfur, residuals, and metals will be
reduced to petroleum coke which will be partially gasified.
Heavy metals (that end up in the coke from the Flexicoker) will not be a problem.
These materials are part of the fuel-coke that will be fed into the cement kiln where the
metals are oxidized to a non-leachable state rendering them harmless to the
environment.
The only solid waste coming from the units that is not consumed in the refinery and not
returned to the supplier is filter cartridges and maintenance wastes. It is not possible
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to separate the quantities by refinery unit or predict the total quantity of this material
that will result from the refinery operation.
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1.4 Estimated Concentration of Emissions, Effluents and Residuals
From an environmental perspective, the Talara retrofit/expansion can actually lead to
improvements in air quality and water quality around and near the refinery. This is
because there have been advances in technology used to control air emissions, water
effluents and disposal of solid waste. There are improvements in design and
equipment that allow for optimized pollution control. In addition, sensors and process
control systems allow for better and more accurate monitoring of environmental issues.
1.4.1 Air Emissions
The air emissions will consist of NOx, VOC, CO, SOx, and particulate matter. Since
this refinery will not be burning any residual fuel oils or coke, there will be no heavy
metals detectable as air emissions.
The NOx levels leaving the heater stacks will vary from a high of 200 ppm from the old
modified 2,000 bbl/day vacuum tower heater and atmospheric tower heater which are
existing heaters will be limited in the ability to reduce NOx emissions. For practical
reasons the NOx levels may not be able to be reduced down to 48 ppm and may
remain at a couple of hundred ppm especially for the small vacuum tower heater. The
other new process heaters NOx levels will be easily controlled to a maximum of 20
ppm NOx using low NOx burner technology and heater design.
The steam boilers designed to burn low Btu gasses from the Flexicoker will be able to
operate with less than 5 ppm NOx since they can be designed to operate below
1400 F flame temperature without increasing the NOx above the levels in the fuel gas
[1400 F is the NOx formation temperature].
The overall average NOx will be about 20 ppm as it leaves the stacks. The SOx
emissions will be a couple of ppm in the flue gas because all the gas being burned will
be low in sulfur compounds. CO emissions will be about 50 ppm out of the stacks but
may exceed this number during an upset or start up condition. Particulate emissions
will be less than 50 ppm and will exceed this number during abnormal operating
conditions.
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Based on the location and strong prevailing winds from the Southeast or Southwest,
dispersion modeling using a screening model will show that the projected worst-case
emissions increase will be negligible on the community.
1.4.2 Wastewater Effluent
The once-through seawater will be returned to the sea after aeration that will partially
de-chlorinate the seawater down to less than 0.1 ppm residual chlorine. The
temperature increase in the Pacific Ocean after the initial mixing of the cooling water
will be less than the 2.5 C. This meets allowable t emperature increase by Peruvian
regulations and the 3 C limit by the World Bank. Ac cording to the Revised World bank
April 2007 Guidelines the 2.5 C is at the edge of t he mixing zone At the edge of a
scientifically established mixing zone which takes into account ambient water quality,
receiving water use, potential receptors and assimilative capacity. This was more
simply stated in the previous World bank Guidelines ..at the edge of the zone where
initial mixing and dilution take place. Were the zone is not defined use 100 meters
from the point of discharge.
All the potentially oily water streams will be segregated and individually treated to less
than 10 ppm free oil and grease prior to discharge into the warm seawater discharge
stream.
In some cases, the chemical sewer, tank drainage, and desalter water may contain
more than the allowable 150 ppm Chemical Oxygen Demand (COD) limit set by the
World Bank. If this is the case, these streams will be biologically treated (after the oil
and grease is removed) down to less than 150 ppm COD to reduce both the Biological
Oxygen Demand (BOD) and COD to acceptable limits.
The desalter, tank water draws, and treated chemical sewer liquids will be the only
significant wastewater streams that will contain dissolved organics. These streams will
be salty from their origins and may have to be treated biologically to reduce the
dissolved organics to acceptable levels. As long as the salt levels remain reasonably
constant, biological treating will be successful and inexpensive due to the low flow rate
of these streams.
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1.4.3 Solid Waste (Residuals)
As part of the modernization project at Talara and anticipation of the project the
refinery is adopting substantial changes to its solid was management system. A
number of new initiatives are being introduced into the solid waste management
program and these changes will be integrated into the total environmental
management program. Specifically, the refinery expansion will also offer the
opportunity for at source solid waste reduction and recycling. The program should
result in considerable waste reduction and reduce waste generation resulting in
substantial saving in waste handling and disposal costs. In respect to residuals, the
new Flexicoking unit offers the opportunity to move organic sludge and bottom-of-the
barrel materials into the coker where disposal costs can be turned into product profits.
[Note: Integrated waste management practices must involve both waste minimization
and recycling].
As part of the EIA, the solid waste section of that document should address technical
advances that have occurred. In addition, the SOP for solid waste must address
changes due to a variety of reasons including economic conditions, regulatory and
licensing requirements, health and safety issues and changing public attitudes.
Reducing pollution involves both pollution prevention options and process modification
options. This includes training in good housekeeping practices, segregating waste
streams, avoiding dilution, control of solids entering sewers and minimizing solids
entering the crude tower. (Solids entering the crude distillation unit are likely to attract
more oil and can produce emulsions and sludge).
Cleaner production initiatives involve a unit-by-unit process evaluation that considers
both the Source of solid waste and its Material Characteristics. For Talara this
includes:
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SOURCE MATERIAL CHARACTERISTIC
FCC UNIT CATALYST FINES
STORAGE TANKS OIL CONTAMINATED SOLIDS
SEWER OILY SLUDGE
VARIOUS SOURCES CONTAMINATED SOIL
PROCESS UNITS SPILL CLEAN-UP DRUMS
NEW PROCESS UNITS SPENT CATALYST
WASTEWATER TREATING RECOVERED OIL & BIOSOLIDS
FLEXICOKER CONTAMINATED OR SPILLED
COKE FINES
In addition, a typical refinery compared to the expanded Talara Refinery generates a
variety of uncontaminated solid wastes (some recyclable) that can have a considerable
impact on overall waste management costs. These wastes, and an estimated
generation rate in tonnes per year, are:
MATERIAL MATERIAL CHARACTERISTIC
CLEAN DRUMS 20
SCRAP METAL 450
WASTE PAPER 6
CARDBOARD 10
ALUMINUM 2
GREEN WASTE 1
Source: Caltex Refinery, Lytton, QLD, Australia
Note: Solid waste reduction is enhanced by site environmental audits conducted by
external contractors that can provide objective overviews of processes and
procedures].
Most of the solid waste listed as generated by a typical refinery will be recycled or
shipped back to the supplier such as drums and catalysts. Recycling will take place
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for scrap metal, cardboard, aluminum, paper, recovered oil, and oily sludge. This will
only leave oil contaminated rags, household garbage,
The basis for Talaras waste management program will be to introduce cleaner
production elements to the manufacturing process. These elements include:
Continuing waste management awareness training especially in respect to
toxic and hazardous wastes
Inventorying solid waste streams and identifying where they are generated
Identify process-unit waste recycling technologies and opportunities
Developing additional on-site waste reduction and recycling options
Creating or modifying SOPs for solids waste handling to cover the new units
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1.5 Project Evaluation in Light of National and International Regulations
(Standards):
In order to address the ENVIRONMENTAL VIABILITY of PROYECTO:
MODERNIZACION DE REFINERIA TALARA, Petro Peru S.A. requested an analysis
of both National and International regulations that pertain to the project. In that light,
the technical screening includes an evaluation of:
National: Perus Environmental General Law No. (N) 28611(15.10.2005)
English Ref. Environmental General Law No. 28611
Spanish Ref. Ley General del Ambiente Ley N28611(15.10.2005)
International: World BankPollution and Abatement Handbook April 2007
(Document 19128)
1.5.1 Perus National Regulations:
To provide the following regulation assessment, engineers thoroughly reviewed
approximately 7000 pages of:
System of Environmental Management ISO 14001 (SEM-ISO)
General Analysis of Environmental Legal Requirements (GAELR)
The SEM-ISO / GAELR provide a National perspective, for the following list of
regulations that are considered important to the project. Each item listed below was
evaluated as part of the ENVIRONMENTAL VIABILITY of this feasibility document.
Each of the following headings is in sequential order as the data appeared in SEM-ISO
/ GAELR.
1.5.1.1 General Law / Rights and Principles
English Ref. Environmental General Law No. 28611
Spanish Ref. Ley General del Ambiente Ley N28611(15.10.2005)
Article 25 Environmental Impact Assessment (EIA) (Artculo 25 .- De los Estudios de
Impacto Ambiental): Each of the proposed expansion activities and each process
considered in the modernization are considered in respect to the pollution impact and
its affect on the social environment.
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Article 32 Maximum Permissible Limit (MPL or LMP)( Artculo 32.- Del Lmite Mximo
Permisible): In every environmental evaluation of the project the LMP is characterized
as the concentration of elements or physical and biological parameters that
characterize an emission or effluent as exceeding the limit that can cause danger to
human well-being or to the environment.
Article 56 Public Authorities (Artculo 56.- De la Autoridad Ambiental Nacional): For
the project, the final authority for environmental questions is: Environmental national
Authority The National Council of the Environment (CONAM) to include all regulations
and functions.
Articles 74 & 75 Responsibilities & Risk Prevention: The project will clearly identify
operator responsibilities in respect to emissions effluents, discharges and negative
impact on the environment, Furthermore, the operators shall adopt risk prevention
measures that conform to Peruvian law.
Article 101 Marine & Coastal Ecosystems (Artculo 101.- De los ecosistemas marinos y
costeros): The project will prevent or control the negative impact that the refinery will
generate that could result in discharges that negatively affect the sea and/or coastal
adjacent wetlands.
Article 107 National System of Natural Protected Area (SINANPE) (Artculo 107.- Del
Sistema Nacional de reas Naturales Protegidas por el Estado): The project must assure
the continuity of the ecological and evolutionary process as well s the history and
culture of the country
Article 115- -Noises & Vibrations (Artculo 115.- De los ruidos y vibraciones): Project
managers are responsible to the sectoral (local) authorities in respect to noises and
vibrations that may ensue from construction and operation of the project. See Noise
and Vibrations below.
Article 116 - Radiation (Artculo 116.- De las radiaciones): While radiation should not be
a factor in either constructions or operation of the modernized refinery, management
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must be aware of the need to address radiation if there is a health concern. This is a
possibility
1.5.1.2 Regulations Related to Hydrocarbons
English Ref. - Regulations for Environmental Protection of Hydrocarbon Activity
D.S. No. 015-2006-EM
Spanish Ref. Reglamento de Proteccion Ambiental en las Actividades de
Hidrocarburos D.S. N 015-2006-EM(05.03.2006)
Article 1 Applicable Laws & Regulations: It is the objective of the project o meet all
laws governing the environments starting with the General Law (28611), but, in respect
to hydrocarbons to consider 28245 (Environmental Management), 27446 (Evaluation
and Environmental Impact) and Ordinance Supreme 04202005-EM (pertains directly to
hydrocarbons and volatile organic compounds [VOCs] ).
Article 28 (and previous) Environmental Impact Studies: The project must address
certain timetable requirements and provisions for source identification of hydrocarbons
and their control. This will be done through the appropriate government agencies (e.g.
DGAAE [Ministry of Energy & Mines]) as required by Peruvian Law. Hydrocarbon
issues are extremely important because inappropriate action can lead to prosecution
(Article 82).
1.5.1.3 Public Hydraulic Issues:
Both underground water and surface water are important issues that are the domain of
the state under: Waters Law 29 dated August 2, 1985
English Ref. Waters Law 29 dated August 2, 1985
Spanish Ref. Ley 29-1985, del 2 de agosto, de Aguas(Ley General de Aguas
Decreto Ley N 17752(25.07.1979))
Article 57 7 58 Water Concessions: All concessions and hydrological plans are
granted for 75 years and must be adopted in ways that serve the public. The project
must consider hydrological criteria in its planning. This includes water needs of the
public, irrigation, industrial and marine uses.
Article 91 Saltwater Incursion: The refinery modernization must assure that there is
no degradation of groundwater through leaching from the surface into the aquifer, or
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by intrusion of saline waters. Spills of hazardous or toxic materials cannot reach the
aquifer. Surface containment is required. (Stormwater runoff ponds will be sized to
accommodate rainfall).
1.5.1.4 General Law of Waters
English Ref. Regulation of Titles I, II, and III of D.L.N. No. 17752 of General Law
of Waters - Supreme Decree - No. 261-69-AP
Spanish Ref. Reglamento de Los Titulos I, II, Y III Del D.L.N. N 17752 Sobre Ley
General De Aguas Decreto Supremo N 261-69-AP
Article 7, 8 & 9 International Waters: The project must consider international waters
out to a distance of 200 adjacent miles and address fishery rights plus regulations that
pertains to lakes, lagoons and tidelands.
Article 56 ff Preservation: Project approvals in respect to vertimento (spillage) (both
domestic and industrial) must be addressed in concert with local sanitation authorities,
commissions and ministries that have authority over drainage, and water quality in
fresh water area or marine or terrestrial waters.
Article 81 Pollutants: Since we will be discharging to the Pacific Ocean this will be a
Class IV discharge requirement pollutants that will be addressed in the expansion
(modernization project) for discharge include: Color, suspended solids, dissolved
materials, oil & grease, BOD, fluorine, cyanides, and heavy metals (from arsenic to
zinc).
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PERUVIAN CLASS IV WATER REGULATIONS
(Applicable to coastal regions)
Contaminant Peruvian Requirement Talala Refinery
Color 30 units Applies
Substances that cause
scent or flavor
Absent Applies
Floating solids Absent Applies
Suspend solids 100 mg/l Applies
Oil and grease Absent Address in EIA
Phenols Less than 0.01 mg/L Applies
Lead 0.1 mg/L Applies
Arsenic 0.2 mg/L Applies
Fluorine 1.0 mg/L Applies
Selenium 0.05 mg/L Applies
Hexavalent chromium 0.05 mg/L Applies
Cyanide 0.01 mg/l Applies
Barium 0.01 mg/L Applies
Cadmium 0.01 mg/L Applies
Silver 0.05 mg/L Applies
Iron 0.03 mg/L Applies
Zinc 5.0 mg/L Applies
NMP 20,000 C/100 ml Applies
BOD (five day) Less than 50 mg/L @
20 C
Applies
DO 3 mg/L minimum Applies
pH 6 -8.5 Applies
Temperature Less than 2.5 C Applies
Cobalt 1.0 mg/l Applies
NOTE: Comparing Peruvian regulations for effluents with World Bank regulations shows that
several Peruvian requirements are more stringent that the World Banks. In addition, The
World Bank did not address the issue of fecal coliforms (NMPs). This value is tied to the
presence of pollutant bacteria and/or virus. In that light, the refinery would normally have to
address the issue of sanitary sewage discharge and any processing conditions that would
lead to presence or growth of harmful organisms. Since the sanitary sewage is being treated
for reuse as irrigation water for non-contact irrigation and not being discharged.
PETROPERU will have to label the green areas that are irrigated with reclaimed water that
this area is irrigated with non-potable water.
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The oil and Grease standard of absent is not reasonable for a large refinery but the
level of 10 ppm as specified by the World Bank is reasonable. It is possible that this
may be interrupted as no visible oil and grease which 10 ppm will satisfy since it will
not be detected except by a laboratory test. The EIA will address this issue in more
detail and determine if this means no visible oil and grease on non-detectable.
1.5.1.5 Hydrocarbons
Under the direction of Resolution Number 030-96-EM / DGAAE (1) pertaining to
Hydrocarbons, there are supreme decrees and directives (as many as fifty each) that
will be addressed by the project to include requirements as detailed as identifying
sampling points, monitoring of pollutants and control points and control equipment to
reduce or eliminate fugitive emissions and hydrocarbons reaching cooling water or
wastewater.
English Ref. Maximum Levels of Permissible Effluents of Active Liquid Products,
Exploitation and Commercialization of Hydrocarbon Activity - Directorial Resolution
No. 030-96-EM/DGAA(1)
Spanish Ref. Niveles Maximos Permisibles Para Efluentes Liquidos Producto De
Actividades Explotacion Y Comercializacion De Hidrocarburos Resolucion Directoral
N 030-96-EM/DGAA (1)
Peruvian Environmental Agencies utilize GNATT Charts for timetables and
scheduling. Gantt Charts identify significant milestones of a project and provide a time
line for completing each task. Each milestone is to have a measurable result of
whether tasks are completed and that completion is verified. This project monitoring
techniques can be important to construction and operations objectives.
1.5.1.6 Air Quality Standards
English Ref. Regulation of National Standards of Environmental Air Quality -
Supreme Decree No. 074-2001-PCM
Spanish Ref. Reglamento De Estandares Nacionales De Calidad Ambiental del Aire,
Decreto Supremeo N 074-2001-PCM
Articles 2 & 4 Standards 7 measurements: Consistent with the Decree Supreme
Number 044-98-PCM for Air Pollution Control, the project will address seven major air
pollutants to include monitoring instruments and timing of monitoring, these are: sulfur
dioxide, carbon monoxide, nitrogen oxides, ozone, hydrogen sulfide, lead and
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particulates. Particulate monitoring and control will address particulates as small at 2.5
millimeters. This latter is referred to as PM-2.5. Less stringent (PM-10 standards)
apply in certain cases. This will be addressed further in the EIA considering the
location of this project in the desert. Also monitoring will be addressed since this could
mean periodic samples taken and analyzed compared to Continuous Emission
Monitoring System (CEMS). Since continuous emission monitoring is expensive and
it does not improve the environment when other options are available like taking
periodic manual samples for analysis and programming in Predictive Emission
Modeling System (PEMS) data to allow the DCS to do the modeling based on process
parameters and conditions from heaters and furnaces.
Article 10 Air Quality Improvement: The project will emphasize Best Available
Control Technology (BACT) with a focus on improving the quality of fuels, especially
low sulfur diesel. The EIA should address how the refinery can minimize driving miles
associated with refinery operations
Article 28 - : Dispositions: Both COMPLEMENTARY DISPOSITIONS and
TRANSITORY DISPOSITIONS are addressed by national and sectoral (local)
authorities. Peruvian air control recommendations consider guidelines tied to the US
EPA and the State of California Air Resources Board.
1.5.1.7 Law of Solid Residuals
English Ref. Approve the Regulation of Supreme Law No. 27314, General Law of
Solid Residuals, Supreme Decree No. 057-2004-PCM
Spanish Ref. Aprueban el Reglamento de la Ley N 27314, Ley General De Residuos
Slidos, Decreto Supremo N 057-2004-PCM
Article 26 Environmental Issues related to Solid Waste: Three important issues (in
respect to solid waste) should be noted as part of this feasibility document:
1. Management of solid generated residuals must be addressed in the
Declaration of Environmental Impact (DAY)
2. DAY information must be integrated into the EIA. [The Peruvian government
often refers to this integration as: Studies of Environmental Impact].
Article 39 & 40 Storage: Storage regulations exist for dangerous materials and their
handling to include a timetable for handling and removal. Key issues must be
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addressed in the EIA (as per these paragraphs 39 & 40) to include risk of fire,
emissions, hygiene and security.
Article 73 Handling and Infrastructure: in addressing issues related to solid waste,
there must be a program for handing this waste (under PAMA). Also, all residual
programs must be approved by the Department of Environmental Health (DIGESA).
DICAPI of the Ministry of Defense addresses residual issues in marine waters and
ports. Contact DICAPI.
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LIST OF DANGEROUS RESIDUALS
The residuals of this table are defined as dangerous in conformity with the Peruvian
Legislative Resolution Number 26234, Agreement of Basle
CHEMICALS AND HEAVY
METALS
OTHER RESIDUALS
Antimony Heavy metal muds or sludges
Arsenic Galvanic muds
Beryllium Paint wastes
Cadmium Solids from dust collectors
Chromium Sludge from WWT operations
Lead Contaminated soils
Mercury Catalyst fines
Selenium Filter aids and filter media
Tellurium Certain electronic components
Thallium Ashes
Tank bottoms
While some of the above materials are not common to refinery construction or
operations and maintenance, the EIA must address the possible existence or creations
of some of these solid wastes and provide for appropriate treatment or disposal. In
cases of toxic or hazardous material fixation, technology can be considered to make the
residual neutral and harmless (by oxidizing it to a non-leachable state).
1.5.1.8 Noise and Vibrations
Noise and Vibrations Supreme Decree No. 085-2003-PCM lists the noise limits as
follows:
Allowable noise levels
Area Daytime limit Night time
limit
Area of Special
Protection
50 dBA 40 dBA
Residential Area 60 dBA 50 dBA
Business District 70 dBA 60 dBA
Industrial Area 80 dBA 70 dBA
These limits will have to be met at the refinery fence line using the design and location
of the noisy units that will be included in the refinery expansion.
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World Bank noise regulations are not as strict as Supreme Decree No. 085-2003-
PCM.
English Ref. Approve the Regulation of National Standards of Environmental Quality
for Noise - Supreme Decree No. 085-2003-PCM
Spanish Ref. Aprueban el Reglamento de standares Nacionales de Calidad
Ambiental para Ruido, Decreto Pupremo N085-2003-P CM
1.5.1.9 Planning for Disasters
Under guidelines set by The Department of Energy & Mines (supreme Resolution
Number 047-2004-EM, the EIA and the project itself must address issues related to
hydrocarbons and their transport, storage and dikes, emissions, and the potential for
gaseous or spontaneous combustion.
English Ref. Approve the Disaster Plan of Prevention and Attention of the Sector of
Energy and Mines - Supreme Resolution No. 047-2004-EM
Spanish Ref. aprueban el Plan De Prevention y Attencion de Desastres del Sector
Energia y Mines, Resolucion Suprema N 047-2004-EM
1.5.1.10 Conservation of Natural Resources
Peruvian natural resources are protected by the Constitution (Article 68). Project
modifications / modernizations at the refinery are near natural Protected Area declared
as such. The EIA will address issues of biological diversity, cultural and historical
interests as will as the countrys goals of sustainable development.
1.5.1.11 Control of Restricted Goods
While the refining industry does not normally produce chemicals that are a security risk
or usable for illegal purposes, the EIA and the project must address a display of
organic compounds (sometimes used as solvents) that fall into the category of
forbidden goods. Such materials would be covered under Supreme Ordnance Number
037-91-AG published 16.09.91 .and.Law Number 26744 published 18.01.1997.
Control of forbidden goods is addressed the Department of Medications, and Drugs
(DIGEMID). DIGEMID also is responsible for any radioactive activity. Radioactivity
does not appear to be a factor in the modernization project unless the crudes contain
(NORM) Naturally Occurring Radioactive Materials. As explained in Section 1.5.2.7.
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1.5.2 Additional Peruvian Regulations:
The previous section of this report addressed key (National Government) regulations
for air, water and solid waste (residuals). These were contained in the first 2200 pages
of Ley General del AmbienteLey No. 28611 (15.10.2005). This section deals with the
regulations contain in the final 4800 pages of the regulations.
English Ref. Environmental General Law No. 28611
Spanish Ref. Ley General del Ambiente Ley N28611(15.10.2005)
1.5.2.1 Oil Spills
Peruvian regulations in respect to oil spills address three spill possibilities:
Plant spills, marine transportation spills and land transportation spills. In all three
cases, the regulations suggest that spill possibilities, especially at sea, are not remote.
In that light, the EIA must carefully address the detailed requirements of the law and
even more so PETROPERU probably already has SOPs in place that deal with spills
of all types from the standpoint of both immediate response and strategic response.
Reaction training is essential, a risk assessment document should deal with what on-
site spill absorbents, and other materials must be on-hand at all times to address both
mini-spills (less than ten barrels) potential catastrophic spills. Leak protection and tank
inspections are part of a spill program (in order to identify problems before they
happen). Double hull ships are a requirement to assure bay and ocean spills are
minimized. Training should include contingency planning (as recommended by law).
Spill laws particularly address on-land loading and unloading equipment and strategies
(to include VOC control). In the case of marine spills, planning must address SOPs for
the terminal and its interface with the sea, rivers, jetties, navigable lakes and from an
equipment viewpoint: floating faucets, moorings, snub service, naval devices,
manifolds, headers, connections and there must be an active an interface with marine
authorities.
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1.5.2.2 Construction Authorization
There are environmental considerations that must be addressed in terms of
construction and contractors used for the modernization, particularly if the companies
are not Peruvian-based. Licenses and permits are involved, and each of these must be
addressed by the EIA. Assure compliance at both the national level and at the
Provincial Municipality level.
Contractors should be aware of the potential impacts of El Nino on construction
activities and the possibility of heavy rainfall events that are possible during and after
construction. The design should include provisions to accommodate these rainfall
events without causing an environmental excursion.
1.5.2.3 Storage
The project must address Perus laws in respect to storage, storage tanks, storage
tank design and containment. This extends into special requirement for storage of
liquid propane and/or liquefied butane.
1.5.2.4 Fire Protection
Addressing fire issues may seem obtuse in respect to environmental concerns, but
Peruvian regulations do cover certain aspects of flammable liquids. Not only are the
liquids VOCs, but environmental regulators can be concerned about the health effects
of the combustion products of materials that burn. In some cases after a fire, engineers
and chemists may be required to proved a complete combustion/oxidation analysis of
everything that burned in a fire (from solvents to forklift tires). The government can use
this information to determine fines and health issues.
The plot plan spacing both within the individual units and between the units is based
on NFPA standards for safe distance from fired heaters to hydrocarbon sources both
within the units and between the units. The FEED package design and the detailed
design will determine the details of spacing within the units and arrange them to
maximize the safe spacing between hydrocarbons and potential ignition sources. The
detailed design contractor will have to run studies to assure that adequate escape
routes of adequate size are provided for personnel to avoid injury while fleeing from a
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possible fire or explosion. The new administration building and lab are located remote
from the plant to maintain a safe distance from the processing units in case of a fire or
explosion. The exact distance required and the building design to handle the potential
over pressure will be determined during detailed design when it is possible to calculate
the amount of material that will be involved in a worst-case explosion.
1.5.2.5 Reporting Requirements
There are two types of reports that must be addressed in the EIA.
Required environmental reports that are tied to a timetable
Reports that must be submitted if there is an episode
Special conditions apply to eachandsubmission of the reports can be critical
because late reports can lead to fines or other legal action by the government.
There is also a concern (and legal requirements) tied to any solvent that can be
construed as necessary raw materials to make drugs.
1.5.2.6 Other Regulatory Environmental Issues
Electricity generation can become a part of the pollution assessment of the refinery.
One important consideration is NOx formation. The EIA should address any equipment
that operates at temperatures above 1400 F (the NOx formations temperature).
Radiation: Radiation is generally not a problem for refineries, however plant
management should be aware that uranium falls into the same valence line as calcium
and other minerals that area found in certain produced water (PW) and/or crude oil
assays. Often these metals are crusted onto the side of the tubing of the oil well but to
avoid this deposition, chemicals can be added (at the well) to keep the salts from
scaling onto the pipe/tubing. With this treatment, the salts are carried out as part of the
crude oil production. Thus, a crude oil can contain uranium salts (some which are
radioactive) that can end up as part of the refinery feedstock (rather than remaining in
the producing zone or fouled onto the production tubing). Consequently, there should
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be periodic quantitative analysis of all crudes entering the refinery to make sure they
do not contain NORM.
1.5.3 World Bank Regulations
In respect to petroleum refining, the World Bank reference document for environmental
issues is: POLLUTION PREVENTION AND ABATEMENT HANDBOOK Toward
Cleaner Production 1998 (revised April 1999) pages 377-381 plus the April 2007
update of the Pollution Prevention Handbook.
In reviewing appropriate air pollution practices, the World Bank does not publish an
emission requirement for carbon dioxide. However, in the Banks discussion of
emission gases carbon dioxide is specifically mentioned as a pollutant that must be
addressed in the selection of boilers, process heaters and other operations that
generate carbon dioxide. In that light, the summary section of this report suggests that
the EIA address how and if the topic of carbon dioxide credits need to be addressed
for the project. If, for example, biodiesel fuel can become part of the final diesel blend,
this will not only reduce the sulfur level in the fuel, but may also lead to credit
payments.
As part of the EIA, that document must address the specific levels of pollution control
required by The World Bank for air, water and solids waste (residuals).
For air, this includes; Particulate matter, sulfur oxides, nitrogen oxides, aromatics
(BTX), VOCs, as well as hydrogen sulfide and nickel + vanadium. The latter carries a
combined value (emission total) that must be less than 2 milligrams per normal cubic
meter.
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WORLD BANK
Allowable Air Emissions
Per tonne of Crude oil Processed
Pollutant Allowable limit per
tonne of crude
processed
Estimated Talara
Emission Level
(after expansion)
Particulate matter 0.1-3.0 kg Applies
Sulfur Oxides 0.2-0.6 kg Applies
Nitrogen Oxides 0.06-0.5 kg Applies
BTX
(Benzene, Toluene,
Xylene)
0.75-6.0 g Applies
VOC Emissions 0.5-6.0 kg Applies
NOTE: BTX values: Tabular value is approximately 0.14 grams (gr) Benzene, 0.55 gr
toluene, 1.8 gr xylene. Gram values are per tonne of crude processed. Values are tied
to Claus sulfur recovery. BACT is acceptable if better than Claus. WSA is better than
Claus and much better than Claus with a tail gas-treating unit with the H
2
O
2
unit for
additional pollution control.
Talara will meet these standards and reduce air emissions by:
Minimizing losses from storage tanks and product - transfer area by methods such as
vapor recovery systems, double seal floating roofs, double mechanical seals on pumps
and flanges and valves that have reduced leakage and by positive or negative
pressure conditions that move emissions into pollution control equipment instead of to
the atmosphere.
Minimizing SOx emissions by using state-of-the art processing and pollution control
hardware that meets Peruvian (and World Bank) standards.
Recovering and recycling catalysts back to the supplier and controlling dust emissions
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Monitoring and limiting fugitive emissions
Keeping fuel usage to a minimum and firing below the NOx formation temperature of
1400 F. (Fuel will be low sulfur).
Utilizing stack gas monitoring (Maximum opacity level of 10%)
Create SOPS for Corrective action as well as response to emergencies
For water, the World Banks effluent guidelines for refineries are generally consistent
with Peruvian regulations. The EIA can address a side-by-side comparison (World
Bank vs. Peru) for: pH, BOD, COD, TSS, oil and grease, and nitrogen levels. In
respect to nitrogen, there are specific (more lenient) World Bank notations related to
unit operations and unit process that are not considered to add nitrogen to the water
(such as hydrogenation and amine processing).
The World Bank also addresses effluent control requirements for chromium, lead,
phenol, benzene, benzo(a) pyrene, sulfides and nitrogen. Talara will meet World Bank
standards for these pollutants as well as for temperature increases. Temperature
increases of the receiving bodies are addressed in other sections of this document,
and the conclusion is that temperature increase in the receiving waters is not a
problem. This is because of dispersion design and location of the outfall and depth and
flow of water in the sea.
Refinery wastewaters will utilize a combination of treatment equipment (Separators,
DAF units etc.) to meet World Bank regulations. Where required, separation of
different streams, such as storm water, cooling water, process water, sanitary,
sewage, etc. will compliment and be synergistic with WWT. Effluents will meet
Peruvian and/or World Bank Standards (whichever is more stringent).
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WORLD BANK REQUIREMENTS
FOR WASTEWATER
(Achievable pollutant loads per tonne
Of crude oil processed)
Contaminant World Bank Talara
BOD 6 g Applies
COD 50 g Applies
TSS 10 g Applies
Oil and grease 2 g Applies
For solid waste, World Bank recommends that generation of sludges be kept below
0.3 kg per tonne of crude processed with a maximum limit of 0.5 kg per ton of crude
processed. This should not be a problem since hydrocarbon-based sludges and some
organic sludges can be processed to extinction in the Flexicoker. In respect to solid
waste, disposal techniques or fixation techniques must address the issue that leachate
must be at acceptable levels. Overall, the challenge of residuals (solid waste) issues at
the local or Peruvian level may be more stringent than Bank guidelines, particularly in
respect to the affect on groundwater or runoff into the sea.
It is important that project engineers understand the monitoring and reporting
requirements of The World Bankespecially if such reporting is tied to financing the
project. Address such issues in the EIA. [Also, be aware that The World Bank does not
normally finance the purchase of used environmental or process equipment].
In summary, the project will consider ISO-14000 as part of ENVIRONMENTAL
VIABILITY. In addition, the project will address World Bank emission levels and
effluent levels using the following parameters:
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WORLD BANK AIR EMMISSION
LEVELS FOR REFINERIES
(Milligrams per normal cubic meter)
Parameter Maximum value Talara
Particulate Matter
(PM)
50 Applies
NOx 460 Applies
SOx 150 for sulfur
recovery units; 500
for other
Applies
Nickel & Vanadium
(combines)
2 Applies
Hydrogen Sulfide
(H
2
S)
152 Applies
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WORLD BANK EFFLUENT REQUIREMENTS
(Milligrams per liter)
Parameter Maximum Value Talara
pH 6 - 9 Applies
BOD 30 Applies
COD 150 Applies
TSS 30 Applies
Oil and grease 10 Applies
Chromium
Hexavalent
Total
0.1
0.5
Applies
Lead 0.1 Applies
Phenol 0.5 Applies
Benzene 0.05 Applies
Benzo(a) pyrene 0.05 Applies
Sulfide 1 Applies
Nitrogen (total) 10 Applies
Temperature
Increase
Equal or less than
3C
Applies
NOTE: Peruvian regulations for temperature increase is equal or less than 2.5 C
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1.6 Define Concepts to Control & Treat Pollutants
In considering expansion feasibility, environmental issues are addressed in this report
using root cause analysis, or, more specifically, unit-by-unit pollution potential for air,
for water and for solid waste. In the case of air, fugitive emissions (non-point-source)
are part of the analysis.
Air pollution associated with the Talara Refinery includes: VOCs, SOx, NOx, COS and
particulates. The report also considered the presence of carbon monoxide (CO),
ammonia (NH
3
), hydrogen sulfide (H
2
S), and other organic and inorganic emissions to
include all toxic and hazardous gases.
Wastewaters from the refinery include an analysis of once-through ocean -cooling
water and effluents from process units, cooling systems, stormwater and sanitary
sewage water. Sanitary sewage water is treated and reused as irrigation water.
Controlling contaminated water containing BOD, COD, TSS, TDS, NH
3
are specifically
addressed as WWT issues. The study considers affects of pollutants on biological
treatment.
Solid waste residuals include: tank bottoms and sludges (to include heavy metals),
emulsions, dissolved oil and greases, heavy hydrocarbon residues and hazardous
waste, contaminated soils, used oils and lubricants, paint and solvent wastes sludges,
and waste chemicals. Solid waste also includes non-hazardous solids such as trash
and scrap materials from operation and maintenance.
In addition to standard pollution control procedures, the environmental assessment
includes the potential of accidental discharges of large quantities of pollutants that may
occur because of abnormal operations, equipment failure or human error that
potentially poses a major local environmental hazard.
All environmental issues are addressed in respect to local laws, Peruvian standards
and World Bank regulations.
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1.6.1 Addressing Air Emissions
The expected air emissions are listed and summarized for all pollutant sources in the
Appendix section 1.11.2.
All furnaces and boilers installed as part of this project will utilize low NOx burners to
reduce, if necessary, the NOx to about 48 ppm or less in the flue gas. The use of
Flexigas in the heaters will reduce the flame temperatures in the heaters, and thereby
reduce the NOx generated.
The SOx emissions will be controlled on heaters by removing the sulfur in the fuel prior
to combustion. The removed sulfur will be converted to sulfuric acid for sales.
Vapor recovery will be provided on the ship loading and unloading to minimize VOC
pollution. The oil/water separators will all be covered to reduce VOC emissions.
Volatile products, such as gasoline, and crude oil will be stored in double seal floating
roof tanks to reduce emissions. High vapor pressure liquid products, such as LPG will
be stored in pressurized tanks.
The less volatile products and recovered oil will be in cone roof tanks with
conservation vents to reduce VOC emissions. The process pumps will be equipped
with mechanical seals and flanges and valves will be inspected and maintained on a
regular schedule to reduce VOC emissions.
Sulfuric acid tankage and ship loading vents will be routed to scrubber(s) that will
remove most of the acid fumes and the resulting acidic water will be routed to
wastewater treatment where it will be neutralized prior to disposal.
In summary, in respect to gaseous emissions there are three major considerations.
The first is Volatile Organic Compounds (VOCs). The second is Sulfur Oxides (SOx),
and the third is Nitrogen Oxides (NOx). VOCs will be controlled for gasoline and crude
oil by the floating roofs on the volatile products within the refinery tank farm, which are
all being currently upgraded to double seal floating roofs. VOCs will be further
controlled by adding double mechanical seals to all hydrocarbon pumps, which is
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currently taking place and will be included on all new pumps. SOx will be controlled by
the removal of most of the sulfur compounds from the fuel gas streams in the refinery.
These sulfur compounds will be converted into sulfuric acid. NOx will be minimized by
the extensive use of Flexigas within the refinery. The Flexigas will burn with a lower
flame temperature, lowering the NOx production within the facility. If it is necessary,
the existing burners within the refinery can be converted into low NOx burners to meet
the emission requirements. All new burners will be low NOx burners.
In respect to air pollution control, in all cases, the project will consider:
Fugitive emissions (From tanks, valves, flanges, pumps etc.)
Stack emissions
Flare Operations and emissions
Other air pollution control techniques applicable to the refinery process units (e.g.
collection of catalyst fines from those units that require catalysts)
1.6.2 Addressing Water and Wastewater Issues:
SEAWATER: An important consideration for the project is seawater both intake
seawater and seawater discharge.
The seawater intake is currently located in Talara Bay and is capable of taking in sea
life since it is only protected by a screen with 5 cm openings. The current system is
proposed to be replaced with a deeper sub sea system located in the Pacific Ocean
using the recommended maximum 0.15 meters/sec (0.5 ft/sec) velocity required by the
US EPA and will use heavy duty intake screens that have slot openings of less than 5
mm and possibly velocity caps as defined by the US EPA.
The low velocity will provide a mechanism for mobile sea life to swim away from the
intake screens since they will naturally avoid an artificial current such as seawater
intake screens. The sub surface intake(s) will also be protected with Medusa (large
jellyfish) fences to keep the Medusa from plugging the intake structures. This will
reduce potential damage and impact on the sea life in both Talara Bay and the Pacific
Ocean. The seawater will be used for cooling the process either directly using titanium
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tube heat exchangers or using titanium plate heat exchangers to cool an intermediate
cooling fluid where no process contact is possible.
The warm seawater will be discharged into the Pacific Ocean to avoid impacting the
sensitivity of Talara Bay. It will be at a location that will not short circuit to the intake
structure (probably north of the inlet to take advantage of the Humboldt Current). The
only other material mixed in with the effluent that has not been treated and sampled is
the reject brine from the desalination plant. The desalination plant takes the warm
seawater as a feedstock, to produce desalinated water. The rejected water is higher
salinity brine that is mixed with the other warm seawater for discharge into the ocean.
At this time, no bathymetric study is available at the Talara site detailing subsurface
topography. There is currently no available information on Talara Pacific Ocean tides,
currents, water temperature and seasonal variations. This information will assist in
determining the length and location of the seawater intake line. For the purposes of
this estimate, it is assumed that the line will extend about 300 meters to the seawater
intake structure, and, the intake sump will be located on land, approximately 100
meters from the shoreline.
Cooling water could potentially have hydrocarbon contamination if there are leaks in
heat exchangers or other processing equipment. All tubes of heat exchangers with
hydrocarbons using seawater cooling will be titanium to mitigate potential leaks.
[Titanium reduces corrosion that, in turn, can lead to leakage. Choosing this corrosion-
resistant metal is an environmentally sound practice].
In addition, to assure that no pollutants reach the receiving waters, oil-water sensors
will monitor the once-through cooling water to identify if and when oil is present in the
effluent. Engineers performing the EIA can address the remedial Standard Operating
Procedures (SOPs) tied to monitoring and control of cooling water effluent. Analyzers
will identify if a leak occurs. On-line quality control procedures integrated with
laboratory analysis will enable operators to determine where the leak is located so that
immediate remedial action can be taken. The monitoring system can be fitted with
alarms.
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The offending heat exchange will be isolated, and, any tainted discharge can be routed
to the area drains where the effluent can be treated in the Corrugated Plate Interceptor
(CPI) separator system prior to discharge.
The warm sea water from the cooling system will be discharged directly to the ocean,
with the warning that analyzers to detect oil will be placed in the stream to determine
whether oil has entered the stream, the location will be determined by testing the
discharge water at key locations throughout the facility to isolate the leaking heat
exchanger. Cooling water circulation will be in a closed loop that goes from the Pacific
Ocean to the heat exchangers within the refinery, and then back to the Pacific Ocean.
A slip stream of warm water will be diverted into the Reverse Osmosis plant to make
the desalinated water required within the plant. (A higher temperature improves the
operation of a reverse osmosis unit.) The Reverse Osmosis concentrate will be
discharged with the seawater cooling. The seawater for cooling will be chlorinated to
control the growth of biological material in the refinery since this will be once through
cooling the chlorination will be at a low residual level. The warm seawater will be
analyzed continuously for hydrocarbon contamination which detection of hydrocarbons
will be alarmed for remedial action. The seawater will be aerated prior to discharge to
reduce residual chlorine to acceptable levels.
OTHER WASTEWATER STREAMS: All other plant wastewater streams will be
isolated to be treated and discharged separately from the warm seawater. These
other water discharge streams will be cleaned to World Bank standards and be
analyzed prior to discharging.
PLANT WASTEWATER: The plant has several types of potential wastewater pollution
sources they are:
Other Sources of Water Pollution
Continuous oily wastewater
Potentially contaminated storm water
Spent caustic
Other chemical wastewaters
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These wastewater streams will all be treated to World Bank standards prior to being
discharged. Maximum use of waste minimization and source treatment will be used to
reduce the load on the treatment systems and increasing their effectiveness.
Each wastewater stream that will potently contain hydrocarbons will be treated as
close to the source as possible using oil/water separation technology and oil skimming
that will recover no more than 5% water and the balance oil. Using this skimming
equipment will leave only small quantities of oil in the oil/water separators. These
separators will be covered to control Volatile Organic Compounds (VOC) emissions.
Monitoring equipment will be installed down stream of all oil/water separators to detect
oil concentrations that exceed World Bank Standards. Some oil/water monitor brands
are Slick Watch by Ionics or Oil monitor from Analytical Systems International.
OTHER SOURCES OF WATER POLLUTION: The unloading crude of ships uses
offshore mooring dolphins to unload through two 12 sub sea lines. These lines are
currently being flushed with seawater after unloading each ship to mitigate the
possibility of oil leaking into the sea. The lines are left full of seawater between ship
unloading events. The seawater in the line is pushed into the crude tanks when the
next ship is unloaded. This generates more water to be drained from the crude oil
tanks prior to processing the crude in the refinery.
This situation will be corrected by PETROPERU with a separate project of replacing
the 12 sub surface lines with 20 sub surface unloading lines and a seawater capture
and reuse system. This will reduce the seawater that is added to each load of crude
unloaded and reduce the amount of water that needs to be drained from the crude
tanks.
STORM WATER RUNOFF: The Talara area (and the refinery) lies in an arid plane that
receives less than three inches of rainfall annually. It would seem that rainfall runoff
would not be a problem in an arid location. However, all runoff which can occur during
a heavy rainfall will be collected and sampled prior to discharge if it has the potential to
be contaminated. This is addressed in the individual units that will include sumps to
catch and wash down water or rainfall runoff and send it to be treated prior to
discharge. This will be an issue for consideration in the EIA. Storm water will be
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contained and tested and treated prior to discharge as required to assure that runoff
will be within the required discharge limits.
.
TANK LEAKS: The tank farm storage tanks are all adequately contained to handle a
single tank rupture in each dike and each dike is being lined with concrete to reduce
the risk of contaminating the soil and ground water under the tank. All new tankage
will be contained and the containment area will be lined with concrete or a water proof
impervious liner to meet Peruvian regulations.
WASTEWATER TREATMENT (WWT): The current refinery wastewater treatment
consists of American Petroleum Institute (API) separators and Corrugated Plate
Interceptors (CPI) separators. The separators are not covered and have large
amounts of oil floating on top. A CPI Separator is receiving spent caustic from the
caustic wash operation that contains soaps from the caustic soda and the naphthenic
acids in the oils. This causes partial emulsification of the oil and water.
The water and oil drained from the crude oil tanks is routed through a flooded sewer by
gravity to the main CPI Separator, causing the CPI Separator to be overloaded with oil.
The API Separator receives oily water from the process units including the desalter
after it passes through a CPI separator dedicated to the desalter effluent and the
seawater used for process cooling. This hydraulically overloads the separator, and is
the cause of the large amount of oil found on this unit.
Currently, split pipe skimmers are located on both the API and CPI Separators.
These skimmers skim off the oil and take large amounts of water with the oil. New oil
skimming technology using oilphilic tube shimmers will be installed to limit the amount
of water that is mixed with the recovered oil. This will not only facilitate oil recovery
(and its recycle) but will also reduce the energy input and size of the WWT system.
The current configuration for the existing API and CPI Separator will be completely
reworked. The old API Separator will be demolished and the CPI Separator will be
refurbished to include a cover to reduce VOCs and oilphilic tube skimmers. The feeds
will be segregated so that feeds containing large amounts of oil are treated separately
to remove the gross quantities of oil. The water sent to the separators should not have
more than a slight sheen of hydrocarbon. The water from the desalter and the tank
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farm will be centrifugally deoiled to a 10 ppm level. The water from deoiling the
desalter and tank farm will be sent to CPI separators and finally to a common
Dissolved Air Flotation (DAF) unit prior to discharge directly to the ocean. The
recovered oil will be suitable for recycling to the oil feed tanks.
The process water will use oil-skimming technology such as oilphilic roll or oilphilic
tube skimmers.
The water from the caustic treatment area will be acidified to break the emulsion,
separate the oil and water, and then pH adjusted to meet environmental standards.
OIL RECOVERY & REUSE: Currently oil is recovered in the API and CPI Separators.
The recovered oil is placed in a storage tank and re-used as feed stock. In the current
system, there is not enough retention time for the oil and water to separate causing the
retained oil to build up. The presence of salt water with oil and the inclusion of dust
and dirt from the open separators increase the severity of the separation problem by
causing dirt and salt stabilized emulsions. This makes the re-use of the recovered oil
possible, but difficult.
Normally heating, chemical addition, and increased retention time would improve the
performance of the oil recovery system based on past refinery operations. However,
to make the system cost effective and more effective segregation of wastes and
collecting oil without collecting large quantities of water is more effective at cleaning up
the wastewater prior to discharge. Handling the chemical waste separately to keep the
emulsifiers out of the oil recovery system will also improve its performance. It is
recommended that wastewater streams be segregated, and that a new oil skimming
system be installed on streams with lesser amounts of oil to decrease the amount of
water that is recovered with the oil to less than 5% water.
The water from both the tank farm and the desalter will be treated separately in
centrifugal separators to meet effluent specifications, and will not flow through the
existing CPI separator. Both the old and any new separators will be covered to
prevent VOCs from escaping into the air. All of the oil/water separators will be covered
to reduce VOC emissions. The covers will also keep dust out of the oil and/or water.
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A pair of small CPI separators will be provided for the process area to remove oil from
wash down and rain water. Several different oil analyzers will be installed to locate the
source of any off specification discharge water.
The exact configuration and location for each analyzer centrifuge, and separator will
be determined during the FEED package and detailed engineering.
CHEMICAL SEWER WASTEWATER TREATMENT: Chemical sewer WWT will be
determined and detailed during the FEED engineering phase of the project. There are
several options for the treatment of spent caustic. The amount of spent caustic will
increase in quantity after the refinery modernization is completed and operations begin
at the new, higher capacities. The current practice of doing a simple gravity separation
and releasing this material will not be adequate after the expansion because
environmental control measures must follow World Bank and Peruvian Standards.
The refinery is currently upgrading the kerosene caustic treating. This upgrade will
reduce the quantity of the load on the chemical sewer system, but it will also improve
the quantity of wastewater that needs to be treated.
When one considers in-line WWT there is the potential to use low-energy static mixers
to facilitate treatment. Static mixers consist of a sequence of stationary guide plates
that result in a systematic, radial mixing of fluids flowing through a pipe. The flow path
follows a geometrical pattern, precluding any random mixing. The mixing operation is
completed within a very short flow distance.
In contrast to stirred tanks or empty pipe systems, static mixers ensure that the
complete fluid stream is subjected to compulsory or enforced mixing or contacting.
The energy required mixing or for mass transfer is taken from the main stream, which
is taken by a slightly higher-pressure drop than found in a comparable empty pipe
system. This pressure drop depends on the design of the mixer, the properties of the
fluids being mixed, and the operating conditions. This pressure drop is generally 0.02
3.0 Meters of Water Gauge (mwg). The energy requirement of static mixers is at
least an order of magnitude smaller, as compared to agitator systems. The energy is
evenly dissipated throughout the entire mixer volume.
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In the Talara Refinery chemical sewer configuration, the static mixer will be placed
upstream of the CPI Separator to be used in the adjustment of pH. Downstream of the
static mixer, a pH probe will be used to control pH of the stream to 4 or less to spring
the naphthenic acids from the soaps, and break the emulsion. Oilphilic tube skimmers
in the CPI system will then finish separating the oil from the system to assure that the
oil in the discharge is within the discharge requirements. To understand the total
wastewater treatment system, refer to the process flow diagram in the Appendix
1.11.1.
In summary, the water from the refinery will be segregated into three different groups.
GROUP #1: The oily water from the desalter is normally about 5% of the crude charge
or about 45000 bbls/day of desalter water. Since the crude is high in salts, the flow will
be higher, as shown in the following table. This water will contain high levels of oil,
dissolved organics and salts after treating in the existing deoiler.
The levels expected from the existing deoiler, factoring in the capacity increase range
as follows, depending on operation of the deoiler and the crude.
Flow 190 to 270 gpm
Oil & Grease 100 to 1,000 ppm expected with additional flow
COD 350 to 4,000 ppm, based on current range
Salts 25,000 to 50,000 ppm
pH 6 to 8.5
Tank farm drainage from crude tanks this water will be generated as it is now, with
varying flows dependent on manual tank drainage practices.
The properties of this stream will range as follows, prior to treatment.
Flow 0 to 2,500 gpm
Oil & Grease 100 to 100% crude oil
COD 350 to 4,000 ppm
Salts 50,000 ppm
pH 6 to 8.5
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GROUP #2: The oil and water from the process units will be caught and processed
through the existing CPI separator. The work of this separator will be augmented by
tube skimmers to remove the last bit of oil before going into the DAF unit and then to
the outfall.
The properties of this stream will range as follows, prior to treatment.
Flow 10 to 3,100 gpm, based on 2 cm/hr rain fall (dependent
on paved area estimated at 1,400,000 sq meters)
Oil & Grease 0 to 1,000 ppm at units
COD 25 to 150 ppm
Salts 10 to 500 ppm
pH 6 to 8.5
GROUP #3: The water in the chemical sewer will be acidified to a pH of 4.0 or less to
spring the oil and break any emulsions. The acidified water will be sent to a CPI
separator. After the CPI separator, the pH will be adjusted to 6.0 to 8.5. The process
unit drains will be sent to the modified existing CPI Separator. This will reduce the oil
content of the water effluent to below the 10 ppm level. By mixing the CPI separator
with the centrifugal oil/water discharge in the DAF, the plant effluent will be below the
10 ppm oil limit.
The levels expected, prior to treatment area, depending on the unit operation.
Flow 205 to 300 gpm,
Oil & Grease 20 to 1,000 ppm
COD 500 to 5,000 ppm
Salts 0 to 10,000 ppm
pH 10.0 to 13.0
The pH of the water effluent must be between 6.0 and 8.5. The effluent from the
refinery will easily be within these limits.
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1.6.3 Solid Waste (Residuals):
The amount of solid waste generated by the refinery will consist of the following:
Oily sludge from oil/water treating, tank bottoms, and other non-leaded sources can
be disposed of in the Flexicoker.
Spent catalysts which will be returned to the suppliers for reprocessing or disposal
Empty chemical drums or containers which will be sent back to the original supplier
for reuse or disposal
Mixed oils from lab operations which will be recycled in to the crude tanks for
reprocessing
Scrap metal from maintenance operations, which will be recycled for scrap value.
Non-hazardous office, lab, food, and maintenance waste which will be disposed of
in a local municipal disposal site.
Hazardous waste from maintenance operations like used oil can be disposed of in
the crude tanks.
Hazardous waste other than used oil such a oil filters, oily rags, oil dry, solvents,
paint and other miscellaneous hazardous waste will be disposed of in a hazardous
waste incinerator or licensed hazardous waste land fill.
Radioactive waste form level detectors and other sources will be disposed of in
licensed radioactive waste facility. It is possible with Radar level gauges that
additional radioactive level detectors will not be used in this design.
All used lumber, and chemical containers will potentially be contaminated they will be
disposed of using secure disposal sites that assure that they will not be recycled in the
community with potential ill effects to the community. It will be the responsibility of the
refinery to police the disposal of all solid waste and only allow clean streams of waste
to be recycled.
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1.6.4 Other Considerations (Noise, Radiation, Odors, etc.)
Neither noise, vibration, nor radiation is currently considered a problem at the refinery
at this time. To assure that there are no significant noise increases under the
modernization program, purchases of equipment will be within work place noise
limitations as part of the purchase order. All equipment must be within the work place
noise limits of Perus National Regulations (Section 1.5.1.8 of this report) and as noted
in Ley General del AmbienteLey N28611 and Decreto Supremo N085-2003-
PCM also World Bank regulations on noise apply.
English Ref. Environmental General Law No. 28611
Spanish Ref. Ley General del Ambiente Ley N28611(15.10.2005)
The new refinery units that will contain major noise sources will be located near the
existing refinery and will be shielded by both distance and large storage tanks from the
community. The only portion of the project that will not be handled by distance and/or
shielding will be the loading of coke on the ships and moving of the containers to and
from the dock. This will be mitigated using mufflers on the truck engines and using low
emission diesel engines on the cranes loading the containers on the ships and to
remove them from the trucks.
The other area of possible noise pollution to the community would be the new
emergency flare on top of the small hill in the refinery. This will have to be addressed
during detailed design to make sure it does not exceed the nighttime noise levels for
the community or is exempt since it will only be used at full rate in an emergency.
Noise levels in the plant related to work place noise and will be limited by design,
shielding, or by designating mandatory hearing protection areas due to high noise
levels.
Construction noise may be a problem and will be the responsibility of the construction
contractor who may have to consider doing noisy operations only during the day time
and using mufflers on equipment and muffling the piling for new dock facilities.
As a protection against existing ambient noise from other sources, it is recommended
that PETROPERU take ambient noise readings in and around the plant prior to start of
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construction to make determine a noise base line. This will protect PETROPERU from
existing noise sources that may put the project over the allowable limit.
It is also recommended that a predicted noise model be run on the new facilities during
detailed design to make sure it will not exceed the allowable noise limits when the unit
is built. The noise model should take into account not only the distance but also the
impact of shielding from tanks and buildings.
Information on radiation is also covered in Section - 1.5.2.6 of this report.
Any odor emanating from the refinery is the result of a VOC or sulfur compounds.
Control of odors is therefore consistent with control of VOCs and in the particular case
of sulfur emissions; the sulfur-related technology being considered in the
modernization is well within the Best Available Control Technology (BACT) for all types
of sulfur-containing gases.
1.6.5 Summary of Concepts to Control and Treat Pollution
Previous paragraphs addressed the volume and quantity of emissions, effluents and
residuals. This section (following paragraphs) summarizes certain aspects of
technology selection, optimization and verification.
1.6.5.1 Air Emissions
There is a summary of air emission data found in the Appendix of this report. VOC
tank emissions were calculated using EPA Tank-emission software Tanks version
4.0.9d. It was discovered that the software tanks 4.09d did not handle floating roof
tanks under 100 feet in diameter. This inconsistency was corrected by factoring the
emissions from the tanks under 100 feet in diameter. The equipment covered by this
report includes: compressors, storage tanks (kerosene, crude oil, jet fuel, diesel fuel,
gasoline, and other liquid fuels, feedstocks or intermediates), turbine systems, loading
racks and other equipment that has the potential to emit VOCs.
Fugitive VOC Emissions were included as part of the air emission calculations.
Standard emission factors were used in calculating air emissions. These factors and
other basis for the air emission calculations are found in the Appendix of this report,
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SUMMARY OF AIR EMISSIONS. The basis of the calculations for air emissions
(including fugitive emissions) are found in Section 1.10.
NOx considerations were part of the analysis for modernization, and control of NOx is
addressed by selecting heating equipment (furnaces, boilers, etc. that can operated
below the NOx-formation temperature of 1400 degrees Fahrenheit or operated with
low NOx burners. In preparing the EIA, the NOx emission potential will be considered
for every piece of fuel-burning equipment.
Of particular importance in control of air emissions and plant safety is a properly
operating relief and flare system that can safely vent and flare gasses and liquids in an
upset condition. This is why the new flare is tentatively located on top of the hill away
from refinery operations and higher than the main refinery allowing the relief lines to all
to slope into a relief drum and then run up to the flare with out any liquid trapping
pockets. This design without any pockets in the lines will provide a safe relief system
that will provide an environmentally acceptable method of disposing of excess
pressure on towers and vessels during abnormal operating conditions.
The existing flare system may be undersized for the current operation, and it will be
undersized for the modernization and expanded refinery. Currently there are no
overhead flare lines tied to the distillation towers. The flare system handles all
emergency relief valves or rupture disks, these must be re-evaluated in light of refinery
changes, which will increase the throughput in existing equipment, and new methods
of calculation flare loads based on the current API 521 standard, which was revised
after the existing units, were constructed. A knockout drum to separate liquids from
vapors (prior to flaring) is required.
In the new flare system, the piping will be designed to maintain either a positive
pressure or it will be purged with either Flexigas or an inert gas to assure no oxygen
enters into the system. There are several flare systems available, but the
configuration chosen must match the requirements of the new refinery units and be
smokeless. There are several aspects of flare selection (discussed in more detail in
the General Facilities Section of the Final Report). These factors are:
Flare Gas Recovery System (to recover usable energy)
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Steam-assisted flaring (to water gas shift and mix incoming gases for
smokeless operation)- lowest cost option used in the study
Staged flaring (to utilize available pressure to provide smokeless flaring)
1.6.5.2 Water Effluents
The wastewater treatment plant will be expanded and upgraded under the refinery
modernization program. The new system will consist of a series of high efficiency
hardware and isolation of streams that will be utilized to treat:
Desalter water
Tank water draws
Unit wash water
Chemical sewer water
Sea water (used for once-through)
The system is integrated and sized to handle; Solids (particulate) removal, treatment of
dissolved organics and to treat or control minor pollutants if required by regulation.
(See Appendix 1.11.4)
While minimal pollution is expected in the combined single seawater outfall, the EIA
can address how additional (higher) flow rates and/or temperature rise will affect the
receiving bodies. The incoming seawater from the Pacific Ocean will exclude all
mobile fish and sea life which will successfully avoid the intake screen with a velocity
not to exceed 0.5 ft/sec with the screens and all currently, it is expected that the
temperature rise of the receiving bodies will be virtually unaffected. This is because of
the location of the discharge pipe and because the temperature rise due to once-
through cooling is expected to be less than 20 F. If the intake is from Talara bay the
expected temperature rise can be in excess of 40 F in the summer time and may
exceed the 2.5 C mixing zone limitation. The disch arge stream will be dispersed into
the sea to provide adequate mixing with the seawater as to not short circuit and come
back to the inlet or increase the temperature at the discharge more than a few
degrees. A slight temperature increase in the seawater will increase the fish
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population in the immediate area due to the increased food supply from algae and
other smaller sea life whose growth will be stimulated with the increased temperatures.
Most of the heavy metals in the crude will leave the process in the coke except
selenium, which is present in the crude and increases as the sulfur levels in the crude
increase. The current Peruvian regulations of 0.05 mg/l of selenium in ocean
discharge will not be reached with the wastewater if it is biologically treated since
biological treating will remove 60 to 80% of the selenium present in the wastewater.
The only potential source of this metal is from the stripped sour water, which is used
for the desalter.
For purposed of an estimate the amount of wastewater generated by refinery units,
one can consider the following information:
1.6.5.3 Solid Waste (Residuals)
The major source of solid waste generated by the modernized refinery will be spent
catalyst. However, under agreements with the catalyst manufacturers, PETROPERU
has and will negotiate a cradle-to-grave concept for spent catalyst. The suppliers will
be responsible for picking up spent catalyst and reworking it (or disposal) so that that
residual is not a consideration in terms of land disposal.
There will solids related to the periodical change-out of caustic in the sodium hydroxide
treater and there is no cooling tower blowdown or sludges related to the cooling tower
is eliminated by using once-through cooling.
Some disposal considerations may have to be given to handling spent cartridge filters.
Depending on the contaminates in these filters they may be hazardous and may have
to be disposed of in hazardous waste landfills. While some refinery waste (garbage
and miscellaneous waste) can go to a standard landfill, processing sludge and any
toxic or hazardous waste will be addressed by an updated detailed WASTE
MANAGEMENT PLAN as follows.
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TALARA SOLID WASTE MANAGEMENT PLAN
CONTEXT:
The expansion project will generate solid waste during construction and during routine
plant operations and maintenance. Some waste will originate from processing units or
from environmental processing. Both general waste and toxic and hazardous waste
are addressed as feasibility issues to include where the waste is produced (generated)
and the specific disposal requirements for each waste. Licensed landfill will be used for
wastes moving offsite. Very little process waste will be moved offsite because these
materials can be fed to the coking unit.
PURPOSE AND SCOPE:
The Talara waste management plan applies to all project construction wastes, also
operations, and maintenance wastes. For the purpose of this plan, engineers will
address both hazardous and non-hazardous waste and wastes that are toxic (due to
heavy metal content or chemical contamination). Catalyst wastes are not a
consideration because catalyst suppliers have accepted cradle-to-grave disposal
and/or recycle.
LEGISLATIVE AND POLICY REQUIREMENTS:
In respect to residuals, the principle environmental objective for waste management is
to assure that liquid and solid wastes (to include sludges) do not adversely affect
groundwater, surface water or ocean water quality nor lead to soil contamination of
any kind. All Peruvian and World Bank requirements are considered as part of the
plan.
The project will address legal requirements for solid waste (residuals) to include waste
reduction issues (particularly at the unit level), treatment of soils that may become
contaminated with hydrocarbons, collections of runoff (with attention to leaching),
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direction of both contaminated and non-contaminated water to avoid solid
contamination (that, in turn, could lead to solid waste issues).
The expansion will address all licensing and permitting requirements with a specific
goal to, as much as possible, reclaim, reuse and recycle solid waste generated on the
Talara refinery site
EXISTING SOLID WASTE COMMITMENTS:
Existing commitments include:
Continuing the philosophy of waste minimization
Promoting reused and recycling where practical and economical
Operating refinery solid waste facilities in a manner that protects the values of
surface and ground water
Investigate practical alternatives for on-site reuse
Investigate alternatives for recycling waste oil
Ongoing communication with local community leaders to assure the refinery
remains an asset to the community
Commitments after the expansion include:
Identify and quantify all project waste
Identify and quantify all process waste
Minimize the generation of waste at the unit level
Monitor waste volumes (mass) and disposal methods
Consider state-of-the art methodology to handle toxic or hazardous waste
Continually evaluate the economics solid waste alternatives
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An example of economic considerations would be to consider fixation schemes that
would neutralize toxic or hazardous wastes so that they would be suitable for standard
general disposal.
POTENTIAL IMPACTS / ENVIRONMENTAL OBJECTIVES:
Address activities or aspects of the proposed expansion so that they will have minimal
impact on:
Disposal of waste to alleviate or prevent surface water from contaminating ocean
water, ground water or reaching soils.
Assure there is no accumulation of large volumes of waste that is either unsightly
or is a potential for rodents
Assure disposal of residuals in an acceptable manner
KEY PERFORMACNE INDICATORS:
The effectiveness of waste management for Talara will be indicated (through
recordkeeping) against performance parameters that include:
Reduction in generation of waste
Landfill storage volumes
Disposal costs for each type of waste
Volume of contaminated materials from each unit operation
Volumes of solid waste from every environmental operation
Monitoring surface and groundwater quality
Performance against corporate minimization targets
Positive interface with government environmental officials
Meeting or exceeding permit levels
Creating and passing SOP for residual housekeeping
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MANAGEMENT PRIORITIES:
Specific priorities relate to management of all types of solid waste by:
Identification and quantification of types of waste (waste characterization)
Source segregation of wastes
Maximizing the re-use and recycling of waste
To the degree possible, turn waste into saleable product (this may involve novel
aspects of using the new coker)
Minimizing disposal of waste to landfill
Reduction of packaging and consumables purchased for operating and
maintenance
Expand Vendor return policies (already being considered for catalysts)
MANAGEMENT PLANNING AND CONTROL:
Establish waste minimization teams that have the responsibility for facilitating waste
minimization programs. These teams will have the objective of reducing both office
and industrial waste and increasing recycle. The waste minimization teams will accept
responsibility for the corporate targets of PETROPERU.
Storage, handling and disposal of waste will be managed to ensure that the risk
contamination of soil, source water or groundwater is both monitored and minimized
through bundling or containment. The entire refinery site will be operated to minimize
any off-site impacts.
At the refinery, all runoff from unit process area will be treated to remove oil wastes.
The WWT facility is designed to accommodate treatment of each waste that is
expected under the higher operation rates of the refinery.
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Contingency measure will be put into place that will address collection, containment
and redirection of waste should monitoring indicate a leakage or spillage has occurred.
Monitoring of the Talara waste management program includes volume surveys,
residual disposal techniques, shipping and containerization of wastes (especially
hazardous material that may leave the site). An important aspect of solid waste
disposal and handling of residual includes monitoring water quality to include
monitoring wells as required.
Talara will report waste management information in an Annual Environmental
Assessment Report to include minimization measures, waste volumes, landfill
volumes, reductions of waste (year-to-year) and, finally, annual water quality
comparisons.
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1.7 Estimate Footprint & Investment Requirements
As part of the ENVIRONMETAL VIABILITY assessment one must consider the land-
footprint requirements and its effect on the environmental aspects of the project. One
must also consider investment requirements, and, define the estimated dates for
completion of the Modernized Refinery:
1.7.1 Land Footprint
In respect to the overall land footprint and the plot plan, the following facilities must be
considered during (FEED) and in EIA planning: These include: the control room,
laboratory, administration building, the existing and new (larger) flare system, the cargo
dock, and WWT facilities to include API and CPI separators. These are discussed
below. Specific to environmental, the primary land requirements are for the WSA plant,
the WWT facilities and the amine unit.
The control room final location will have to be determined by the FEED contractor after
the results of a disaster model is run on the new and existing units. This will determine
the impact of the worst-case explosion on the control room. At that time, the control
room will either have to be located at an adequate distance or the structure will have to
be constructed to withstand any over pressure from the worst-case explosion.
The lab and administration building are located remote from the new and existing units
and their location too will have to be reviewed to assure the safety of the occupants,
which is enhanced by the existing warehouse, which will act as a shield and the
distance form the units.
The existing flare and relief valves will have to be reviewed by the FEED or detailed
engineering contractor to determine if they are adequate for current regulations (API-
521) and the increased capacity.
The new flare can be a simple pipe flare with steam for smoke control located on top of
the hill using a 100 meter radius for thermal radiation. The exact size of the radius will
be determined during detailed engineering based on flare loading and stack height.
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The fishing dock which was the original cargo dock will be used to load out containers
of coke and is shown approximately on the plot plan. Containers will be moved form
the Flexicoking area to the dock area by truck.
The existing API separator will be taken out of service and replaced with a segregated
sewer system using modern oil/water separation technology that will use less energy
and produce higher quality recovered oil while meeting international and US standards
for vapor control for oily water separators. If the refinery will meet US EPA standards a
biological treatment plant will be required in the area shown as available for additional
process units near the sea. A biological treatment facility will require at least a three
day retention pond (must consider footprint and lining in EIA and FEED) where the
wastewater can be buffered with lime or limestone if required since treating
contaminated desalinated water in a biological treatment unit will cause pH drifts form
carbon dioxide production that will kill the biological material that provides the
treatment.
The environmental-equipment footprint needed for the expansion is approximately
42,000 square meters (not contiguous). Totally, the WSA unit, the WWT unit and the
amine unit will require approximately this amount of square footage.
1.7.2 Investment in Environmental
The environmental investment projections are included in the overall capital
investment required for the modernization. The current estimate is that environmental
capital investment will be about $11 MM. It can be argued that the WSA unit should
be added to this number, which would be about $28 MM, and the amine unit should be
included along with the Flexicoker. When including units that are considered
environmental investment it is possible to argue that with the exception of increasing
the refinery through put all the units that produce low sulfur motor fuels and reduce
residuals that would otherwise end up as high sulfur fuel oil and make them into low
sulfur fuel gas and products are environmental investments. If this logic is used then
most of the investment is environmental.
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1.8 Provide a General Diagram of the Plant and Processes Used to Control
Emissions, Effluents and Residuals
In the analysis one must also Include the Plant Flow Diagram in the Appendix 1.11.3
as part of the Feasibility Study plus address issues of equipment and process
selection as well as environmental (or other) emitting of each process. One must
assure that under all regulatory guidelines that the technology will assure the
expansion meets national and international regulations.
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1.9 Summary and Present Conclusions Related to the Project and Identify
Measures that will Affect Construction
While ENVIRONMENTAL VIABILITY is a serious issue for any refinery or
petrochemical plant, there are a number of favorable factors when considering
modernization:
Processes have become more efficient in controlling pollutantsgaseous, liquid and
solid. For example, A Wet Sulfuric Acid (WSA) sulfuric acid plant can now reach sulfur
emissions down to 150 ppmv or lower. (World Bank requirement). The US EPA
standard is 250 ppmv of SO
2
for a sulfur recovery plant with an incinerator. Thus, the
WSA process is better than EPA requirements. This technology is noteworthy and it is
being used for the expansion project being considered.
Equipment is available that greatly extends on-line time: This translates into extended
MTBF (Mean Time Between Failure) or MTBC (Mean Time Between Change outs).
High-volume, large-scale, pleated cartridge filters for amine plants dramatically reduce
filter costs and on-line time.
There is one issue that may be a factor as the project unfolds and that is the question
of whether the project might somehow be tied in to the availability of carbon credits
from the United Nations (UN) Intergovernmental Panel on Climate Change (IPCC)
The refinery expansion will have a social and economic impact on the Talara area.
The construction phase will create jobs, and, with refinery startup there will be long-
term jobs for the local community and additional long-term cash flow in the community.
The expansion will provide low sulfur motor fuels not only to the local community but
also to the country of Peru reducing the amount of SOx emissions from operating
vehicles.
The truck traffic created during construction will be alleviated once construction is over.
Traffic will be a short-term impact and will be mitigated as much as possible by
receiving as much as possible through the construction dock in Talara Bay.
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One of the biggest burdens on the local economy will be an influx of construction
workers that will have to have temporary housing, sanitation and food service. The
community is not equipped to handle the large number or additional workers and is
unable to supply the majority of the workers due to lack of skills. Once the local labor
pool is exhausted, workers will be imported to the construction site on a temporary
basis.
Another short-term impact will be a marginal inconvenience and potential short-term
impact to the fishing industry due to dock construction. The disruption will be kept as
confined as possible and an attempt will be made to schedule ship arrivals later in the
day as to not interfere with the fishing activities. The long-range impact will be neutral
since more of the Bay will be used for shipping and receiving products but the
seawater intake from and discharges of wastewater to the Bay will be stopped. This
will reduce the impact on juvenile fish and small sea life, improving the fishing. The
new dock will also provide some artificial reef areas that will improve the quantity of
fish in the Bay. The warm seawater discharge into the Pacific Ocean may actually
lead to a localized increase in fish population at the discharge point, which will help
local fishermen.
Fire protection, security, routine and emergency medical services will be provided by
the construction contractors to reduce the burden on the local economy during
construction.
The footprint of all new units will be located on land that is already in industrial use and
owned by the refinery with the exception of the construction that will take place on the
two docks. The laboratory and administration building will be relocated away from
both the existing and new units, and will act as a buffer between the community and
the new refinery units. The area near the community will be landscaped, as it is now
to provide an attractive appearance for the community.
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1.10 References
1. Laboratory evaluation of NOx reduction techniques or refinery CO boilers.
Final report, March-December 1983
Creator/Author Lange, H.B. ; Arand, J.K. ; Mansour, M.N. ; Hunter, S.C.
Publication Date 1985 Apr 01
OSTI Identifier OSTI ID: 5489192
Report Number(s) PB-85-200285/XAB;KVB-72-806034-1948
Research Org KVB, Inc., Irvine, CA (USA)
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1.11 Appendices
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1.11.1 Pacific Ocean Cooling Water System
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1.11.2 Summary of Air Emissions
(Appendix sent separately)
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1.11.3 Plant Plot Plan with Emission Points (Appendix/Drawing sent separately)
Talara Refinery Expansion and Modernization Project Refinery Plot Plan (Plant
Flow Diagram)
All new units were marked with a blue honeycomb fill on the plot plan.
All of the items on the plot plant will be reviewed during the preparation of the FEED. It is
expected that the final locations will be updated somewhat with the more detailed information
that will be developed during the FEED.
Process Units:
The existing units were not moved. The jet fuel caustic treater upgrade was not included,
since it will be completed as a refinery project prior to the Talara expansion and
modernization.
The new units were placed in the same corridor as the existing units, in order to make the
modernized refinery as compact as possible and to keep the operating units well within the
refinery and away from the view of the public. The new units were also located to minimize
the length of runs for the connecting piping, cables and wiring.
The new units were spaced to take into account internally the required spacing for
maintenance and what is required by NFPA. The plot lay out in general included spacing as
required for safety by NFPA and taking into account the risk of explosion to protect the people
in the lab, control room and administration building during the worst-case disaster in the
refinery. The exact spacing and lay out may be modified as required during detailed design to
assure that it is in full compliance with good design practices, NFPA, and meets the needs of
the worst case explosion while allowing adequate escape routes from the units in case of
emergency.
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Utilities:
The new power plant was located close to the existing power plant to take advantage of as
many existing facilities as possible, and as close to the source of Flexigas as possible.
The seawater cooling inlet and discharge were relocated on the Pacific Ocean side of the
refinery. The inlet was located south of the discharge to take advantage of the Humboldt
current that flows from south to north. This location will help avoid the short-circuiting of warm
water into the cooling water inlet.
New offsite facilities, such as instrument air compressors, and the PSA nitrogen unit will be
located within the existing Industrial Services area.
As an alternative to this, the FEED should analyze the possibility of placing the sea water inlet
in the new dock as a way to potentially reduce cost.
Environmental:
The new flare is a simple pipe flare with steam for smoke control located on top of the hill
using a 100 meter radius for thermal radiation.
The wash down water and potentially contaminated storm water will be handled in the unit to
separate most of the oil from the water streams prior to sending the wastewater to the new
wastewater treatment facility.
The existing API and CPI separators will be taken out of their current service and replaced
with a segregated sewer system using modern oil & water separation technology. The
wastewater treatment area will be located near the current separators. An existing CPI
separator may be used for treatment of unit wash down water, and potentially contaminated
storm water. If the refinery will meet US EPA standards for BOD and COD, a biological
treatment plant will be required to handle the wastewater. A biological treatment facility will
require at least a three day retention pond.
General Facilities:
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A new two-sided dock for loading liquid products, including sulfuric acid was provided. It is
located within the existing channel. This new dock will provide the capability to load twice the
capacity of the existing dock, so that the modernized and expanded refinery will have three
times the loading capacity of the existing one.
The fishing dock was the original cargo dock. It will be returned to this service during
construction, and will be used to load out containers of coke after start up. Its location is
shown on the plot plan. Containers will be moved form the Container storage area to a
staging area by dock area via truck.
The lab and administration building are located remote from the new and existing units. This
location will have to be reviewed in the worst explosion case to assure the safety of the
occupants. The proposed location is enhanced by the existing warehouse, which will act as a
shield.
The control room final location will have to be determined by the FEED contractor after the
results of a disaster model is run on both the new and existing units. The worst case
explosion will determine the exact location of the control room. The structure will need to be
constructed to withstand any over pressure from the worst case explosion. For the purposes
of this study, an optimum location was selected, based upon safety considerations.
Two new sets of tanks are provided one for LPG and one for sulfuric acid. They are located
in the area proposed by PETROPERU for the storage of sulfur.
The firewater area was moved to the south side of the dock, an area that is not prone to
sanding up, like the existing area. Additional fire water facilities will be provided near the new
cooling water intake sump. There will also be a four hour fresh water tank for normal fires,
with the emergency back up of seawater from the relocated fire water pumps.
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1.11.4 Wastewater Treatment Plant (Process Flow Diagram)
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1.11.5 Talara Refinery Process Flow Diagram (Selected Case)
Eliminado: <sp>
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