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w
P
a
(e
s
(T
s
) e
a
(T
a
))
r
a
0.622
a
w
P
a
(e
s
(T
s
) e
a
(T
a
))
r
a
(3)
where r
a
[s m
1
] is the aerodynamic resistance, M
a
[kgmol
1
] is
the molecular mass of air, M
w
[kgmol
1
] is the molecular mass of
water,
a
[kgm
3
] is the density of air,
w
[kgm
3
] is the density
of liquid water and P
a
[Pa] is the atmospheric pressure. In practice,
this is more or less equivalent to Eq. (2) since r
a
is mostly driven by
the wind (Chu et al., 2010). In subsequent sections we examine the
functional formof the relation between r
a
and wind speed.
2.2. Ficks First Law of Diffusion
Ignoring complications of inhomogeneity, a one-dimensional
form of Ficks First Law of Diffusion (see Fick (1995) for a trans-
lation) can be written as
J = D
dC
dz
(4)
where J [mol m
2
s
1
] is the ux density, D [m
2
s
1
] is the diffusion
coefcient, C [mol m
3
] is the molar concentration and z [m] is the
distance. (Note: the negative sign implies that J is positive when
diffusion is toward the lower concentration.) For vapour transfer,
Eq. (4) can be expressed in a nite formassuming an ideal gas
J =
D
v
R
(e
a
(T
a
)/T
a
) (e
s
(T
s
)/T
s
)
z
=
D
v
R
(e
s
(T
s
)/T
s
) (e
a
(T
a
)/T
a
)
z
(5)
where D
v
[m
2
s
1
] is the diffusion coefcient for water vapour in
air, R [J mol
1
K
1
] is the ideal gas constant, T
s
[K] is the water sur-
face temperature, T
a
[K] is the air temperature and z [m] is the
boundary layer thickness (see details in Sections 2.3 and 2.4). For
typical environmental conditions,
e
s
(T
s
)
T
s
e
a
(T
a
)
T
a
e
s
(T
s
) e
a
(T
a
)
T
a
,
and Eq. (5) can be simplied as
J
1
R
D
v
T
a
(e
s
(T
s
) e
a
(T
a
))
z
(6)
This is Ficks First Law of Diffusion in Daltons form for vapour
transfer (see Appendix D for relation to formulations commonly
used in plant physiology). It should be noted that D
v
is not a con-
stant, but increases with T
a
(Gilliland, 1934) and varies inversely
withP
a
(e.g., MonteithandUnsworth, 2008; Rohsenowet al., 1985).
An equation to calculate D
v
as a function of T
a
and P
a
is given in
W.H. Limet al. / Agricultural and Forest Meteorology 152 (2012) 3143 33
Fig. 1. Aschematic diagramof the threshold model adopted here for the variation
in vapour pressure (e) with height (z) above the evaporating surface.
After Leighly (1937) and Machin (1964, 1970).
Appendix A. We can express Eq. (6) in units of depth per unit time
(i.e., E) by incorporating M
w
and
w
,
E =
M
w
R
w
D
v
T
a
(e
s
(T
s
) e
a
(T
a
))
z
(7)
This is the general formof Ficks First Lawof Diffusionfor vapour
transfer based on an ideal gas. By comparing Eqs. (1) and (7) we see
that the aerodynamic function (f
v
in Eq. (1)) is
f
v
=
M
w
R
w
D
v
T
a
1
z
(8)
and the conductance g
m,v
[mol m
2
s
1
] is given by
g
m,v
=
1
R
D
v
P
a
T
a
1
z
(9)
2.3. Boundary layer theory
Thickness of the boundary layer in air has been measured
directly at various times and by various methods. Its order of
magnitude is froma few millimeters down to some small frac-
tion of a millimeter. Within it, gradients of vapor concentration,
temperature, and velocity are linear. Leighly (1937)
Current conceptions of vapour transfer are for a thin (bound-
ary) layer of air above the evaporating surface with transport of
vapour across that layer by molecular diffusion (e.g., Giblett, 1921,
pp. 473474; Penman, 1948) and this is conrmed by observa-
tion (Doe, 1967). Further, the boundary layer thickness is known
to decrease as the wind speed increases (Machin, 1964, 1970). The
treatment consistent with those experimental results holds that
the vapour pressure at the top of the boundary layer is the same as
the vapour pressure at a reference height (e.g., 2m above ground
level) (Leighly, 1937). The simplied threshold model is depicted
in Fig. 1.
To ensure that the framework adopted here can be applied at
other evaporation pans we make the initial assumption that mea-
surements of vapour pressure, air temperature and wind speed
will be available at the reference height. Hence, the challenge is
to estimate the boundary layer thickness z using those available
measurements.
2.4. Boundary layer thickness
Vapour transfer can be conceived as due to free or forced con-
vection, or a mixture of both, often called mixed convection
(Monteith and Unsworth, 2008). It is difcult to specify precise
boundaries between these various convection regimes. Here, we
propose a convenient structure for estimating z without a pri-
ori selection of the thresholds. Following boundary layer theory
(Hisatake et al., 1993, 1995) we formulate the boundary layer thick-
ness as
z = f (Re, L) Re
q
L (10)
where Re is the Reynolds number (dimensionless) and L [m] is the
characteristic length of the evaporating surface. For a cylindrical
evaporation pan, we assume that L is the diameter (1.21m for a
US Class A pan). Here q is a dimensionless constant (range: 0 to
1.0). Conventionally, q is 0.5 for laminar owover a at surface
(Schlichting, 1960).
Traditionally, Re is calculated using the free stream velocity
of the air and adjusted using a numerical factor (e.g., Eq. 2.2
in Schlichting (1960)). Conceptually, the numerical factor is an
attempt to estimate the wind velocity immediately adjacent to
the evaporating surface. Importantly, the numerical factor of Re
will depend on the height at which wind velocity is measured. An
alternative formulation is to calculate Re using the wind velocity
immediately adjacent to the evaporating surface. To develop such
an expression for Re we note that
Re
inertial forces
viscous forces
=
a
u
s
L
a
(11)
where u
s
[ms
1
] is a three-dimensional wind velocity immedi-
ately adjacent to the evaporating surface and
a
[kgm
1
s
1
] is the
dynamic viscosity of air. (Note that
a
is a function of air tem-
perature, see Appendix B.) Here, u
s
f(u
V
, u
H
) where u
V
[ms
1
]
and u
H
[ms
1
] are the vertical (analogous to free convection) and
horizontal (analogous to forced convection) components respec-
tively. When u
V
u
H
, u
s
is dominated by the vertical component,
i.e., free convection dominates. Alternatively, when u
H
u
V
, u
s
is
dominated by the horizontal component, i.e., forced convection
dominates. When u
V
and u
H
are of similar magnitude, mixed con-
vection occurs.
In our experiment, the wind velocity components above the
evaporating surface (i.e., u
V
andu
H
) are not measureddirectly. Here
we assume that u
H
is some fraction of the horizontal wind speed at
the reference height, u
ref
as follows
u
H
= nu
ref
(12)
wherenis a dimensionless constant (range: 0to1.0) andu
ref
[ms
1
]
is the horizontal wind speed measured at the reference height, e.g.,
2mabove groundlevel. Usingthe standardtheorybasedonthe ver-
tical gradient in air density (see Appendix C for details), we derive
that u
V
can be calculated as
u
V
= ku
V,C
(13)
where k is another dimensionless constant (range: 0) and u
V,C
[ms
1
] is the characteristic speed of air movement in the vertical
direction.
One way of combining u
H
and u
V
to estimate u
s
is
u
s
=
u
V
+u
H
1/
(14)
where is a dimensionless constant (range: 1 to ). For exam-
ple, is equivalent to the assumption that u
s
is the maximum
34 W.H. Limet al. / Agricultural and Forest Meteorology 152 (2012) 3143
of the free or forced convection component (McAdams, 1954; Ball
et al., 1988). Alternatively, setting = 1 implies that u
s
is the sum
of free and forced convection components (Adams et al., 1990).
Intermediate values between these extremes change the relative
contributions of u
V
and u
H
to u
s
.
Combining Eqs. (10)(14) the boundary layer thickness is given
by
z =
a
[(ku
V,C
)
+(nu
ref
)
]
1/
L
q
L (15)
Substituting Eq. (15) into Eq. (7), the nal formof the evapora-
tion equation is
E =
M
w
R
w
D
v
T
a
(e
s
(T
s
) e
a
(T
a
))
[(
a
[(ku
V,C
)
+(nu
ref
)
]
1/
L)/
a
]
q
L
(16)
3. Materials and methods
3.1. Field installation
The experimental US Class A Pan (with bird guard) was located
at the BoM eld station at Canberra Airport (Australia, Latitude:
35.3
S, Longitude: 149.2
(0.20u
V,C
)
2
+(0.10u
2
)
2
L
/
a
0.64
L
(17)
Note that the numerical value of L is 1.21m, i.e., the diameter of
a US Class A pan.
We subsequently used Eq. (17) to estimate E
pan
for the remain-
ing (4800) half-hourly totals. (The resulting half-hourly totals are
compared with measurements over eight typical days in Fig. 4.)
The half-hourly totals were then summed into 100 daily totals and
compared with measurements (Fig. 5a). The model explained 98%
of the observed variance in the daily E
pan
with an overall RMSE of
0.51mmd
1
giving us condence in the parameterisation.
4.2. Water surface temperature and evaporative cooling
The model parameters and results to date were derived using
our (infrared) measurement of the water surface temperature T
s
.
W.H. Limet al. / Agricultural and Forest Meteorology 152 (2012) 3143 39
Fig. 7. Half-hourlyboundarylayer thickness z (per Eq. (15); =2, k =0.20, n=0.10,
q =0.64) versus u
2
(wind speed at 2m above ground level) for the experimental
pan (7680 data points).
Fig. 8. Half-hourly aerodynamic function fv (per Eq. (17)) versus u
2
(wind speed at
2 mabove ground level) for the experimental pan (7680 data points).
In practical applications, and especially for evaluating the histori-
cal records, T
s
is unknown. Further, inspection of Fig. 4 shows that
temperature of the water surface T
s
can be quite different fromthat
of the air T
a
, as would be expected for a freely evaporating surface.
The following questionarises: canE
pan
be estimated accurately with-
out measurements of T
s
in the absence of radiation measurements? To
answer this, we assumed that the water surface was at the air tem-
perature (i.e., T
s
=T
a
) and accordingly recalculated the saturated
vapour pressure at the surface. The results, using totals from the
100 elite-days, show that this is a bad assumption for a purely
aerodynamic formulation of evaporation (Fig. 5b). In general, the
estimateof dailyE
pan
basedontheassumptionthat T
s
=T
a
was much
larger than the observations at high rates of E
pan
. That result means
that the water surface is cooler than the air when E
pan
is high and
implies evaporative cooling. The same phenomenon is visible in
Fig. 4, where T
s
is substantially lower than T
a
in the mid-afternoon
when E
pan
tends to be highest.
To investigate further, we examined the relationships between
T
s
, T
a
and the bulk water temperature T
w
(taken as the average of
measurements at 25, 100 and 175mm below the water surface).
The bulk water was found to be well mixed (results not shown) but
the evaporating surface was often up to 3K warmer or 5K cooler
than the bulk water, with an overall average of around 2K cooler
than the bulk water (Fig. 6b). We also found that the evaporating
surface could be up to 5K warmer or 11K cooler than the air, and
was on average, 1K cooler than the air over the 160 days (Fig. 6a).
In general, the temperature of the water surface was much lower
than the air when E
pan
was high (Fig. 6c), conrming our earlier
deductions about evaporative cooling. In summary, the magnitude
of the surface cooling due to evaporation was substantial.
4.3. Estimates of boundary layer thickness and aerodynamic
function
Estimates of boundary layer thickness z using the estimated
parameter values are plotted as a function of wind speed at 2m
above ground level (u
2
) in Fig. 7. For u
2
>1ms
1
, the results are
dominated by forced convection with z in the range 14mm.
For u
2
<1ms
1
, z is highly variable within an envelope constraint
imposed by the free convection regime.
The resulting aerodynamic function has been computed using
all available half-hourly data (Fig. 8). The overall features of the
aerodynamic function are consistent with the ideas put forward by
Thomet al. (1981, Figs. 2 and 5). In particular, at low wind speeds
(u
2
<1ms
1
) we see the variation in the aerodynamic function due
to a mixture between free and forced convection. At higher wind
speeds when forced convection dominates, the relation collapses
to be u
2
0.64
, which is nearly a straight line.
4.4. Estimates of pan evaporation without a bird guard
Our experimental pan used the same bird guard as used by the
Australian BoM (Fig. 2). The effect is to reduce the mass transfer
by 7% in comparison to a similar pan without a bird guard (van
Dijk, 1985). For comparative purposes, it is useful to estimate the
impact of the bird guard. On the boundary layer formulation used
here (Fig. 1), the bird guard would affect the evaporation rate by
reducing the wind speed near the evaporating surface and thereby
increasingtheboundarylayer thickness z. Hence, wecanincorpo-
rate that effect by adjusting the numerical value of the n parameter.
Assuming all else is held constant, we nd a decrease in n of close
to 10% will reduce E
pan
by around 7%. In summary, in the absence
of a bird guard, the parameter estimates are k =0.20, n=0.11,
q=0.64.
To compare our adjusted formulation for a pan without a bird
guard with previous research, we plotted the aerodynamic func-
tion f
v
as a function of wind speed (2m above ground level) u
2
for various differences between the water surface temperature T
s
and the air temperature T
a
under typical conditions (P
a
=101.3kPa,
e
a
(T
a
) =1kPa, T
a
=293.15K (20
C)). (a) Our model without a bird guard (per Eq. (16); =2, k =0.20, n=0.11, q=0.64) for various differences between water surface and air temperature; (b) fv from
previous studies.
is well established in laboratory studies (Doe, 1967; Machin, 1964,
1970) and the resulting formulation (Eq. (7) has a direct physical
interpretation. Hence, the utility of this approach rests on whether
the conceptual framework (Fig. 1) is useful.
The assumptionthat =2is basedonthe idea of vector average
of the uxes associated with the two physical processes (Adams
et al., 1990). In contrast, the idea of taking a maximum value of
free or forced convection (McAdams, 1954; Ball et al., 1988) means
having , which might be useful over very short time inter-
vals (e.g., minutes); yet could be less appropriate over longer time
intervals (e.g., half hours) since a mixture of both free and forced
convection is most likely to be the case under outdoor conditions.
Typical wind function approaches of the formf(u) =a +bu implic-
itly assume the free convection component (a) to be a constant
(Adams et al., 1990). This is similar to setting =1 and q=1 in
Eq. (16).
Once was set =2, the remaining parameters were estimated
using the measurement database consisting of half-hourly data for
60days. Theresultingparameters (k =0.20, n=0.10, q=0.64) were
closetobroadexpectations. Theestimatedku
V,C
range(00.6ms
1
)
is within our expected range (<1ms
1
), suggesting that our result
(k =0.20) is reasonable. Based on the logarithmic wind prole
assumption (von Karman constant of 0.41; zero plane displace-
ment of 0; roughness length for open water surface ranging from
0.0020.006m, per MonteithandUnsworth(2008, Table 16.1)), the
wind speed at 5cm above the evaporating surface (and at same
level as the rim of the pan) would range from 0.36u
2
to 0.47u
2
(i.e., n0.4). Our result (n=0.10) implies that the horizontal com-
ponent of wind velocity u
H
(see Section 2.4) probably locates at
311mm above the evaporating surface. For laminar ow over a
at surface we expect q to be 0.5 (Schlichting, 1960) and up to
0.8 for turbulent ow (Schlichting, 1960; Grace, 1977; Brenner
and Jarvis, 1995). Our result (q=0.64) implies that E
pan
u
s
0.64
and is close to E
pan
u
2
0.54
obtained by Penman (1948) using a
sunken pan, and also within the general range u
ref
0.30.8
found
for heat transfer of leaves (Brenner and Jarvis, 1995; Stokes et al.,
2006). When free convection dominates, Eq. (17) (associated with
Eq. (C.3) in Appendix C) becomes E
pan
(/)
0.32
and is con-
sistent with the ndings fromfree convection experiments, which
suggest E
pan
(/)
1/3
(Bower and Saylor, 2009, Eq. 30).
With the parameter estimates (k =0.20, n=0.10, q=0.64) we
were able to calculate the boundary layer thickness z. When the
wind speed is high (u
2
>1ms
1
), forced convection dominates, and
the air above the pan is quickly replaced by the surrounding air.
Under those conditions, z is predominantly a function of wind
speed. However, under low wind speeds (u
2
<1ms
1
), free con-
vection dominates, and other factors also play important roles in
determiningz. Inparticular, thespatial gradient of temperaturein
the vertical direction (a surrogate for density difference) becomes
important at lowwind speeds.
Our theory (Eq. (17)) and subsequent results (Fig. 8) show that
a unique wind function does not exist. It also suggests a depen-
dence on atmospheric pressure. Thus it would be interesting to test
whether the formulation presented here (Fig. 9a) could be applica-
ble under a wider set of conditions, such as at high altitude sites
(Blaney, 1960; Giambelluca and Nullet, 1992) where the atmo-
spheric pressure is substantially reduced. Our formulationassumes
that the water surface is always close to the top of the pan and
thereby avoids the shelter effect (Chu et al., 2010). This is most
easily achieved in operational settings by relling the pan each
day.
Measuring the water surface temperature T
s
(in absence of
radiation measurements) proved to be important for accurately
estimating E
pan
using the aerodynamic approach when the evapo-
ration rate was high and the associated evaporative cooling of the
surface was at a maximum (Figs. 5 and 6). On average, the evap-
orating water surface was cooler than both the air and the bulk
water (Fig. 6a andb), as foundpreviously inlaboratory experiments
(Hisatake et al., 1995, Fig. 5). This implies that the very thin layer of
surface water, is, on average, a net absorber of sensible heat from
both the air above it and from the bulk water below it. We were
surprised by the magnitude of this cooling effect.
Acknowledgements
We thank the BoMstaff; Tony McCarthy, Ross Heareld, Kirsty
Rhind, Nigel Smedley, David Pottage, Neil McArthur and Kenn Batt
for their help in maintaining our experimental pan at the Canberra
Airport and Liang Li for his contribution in setting up the exper-
imental pan database. We acknowledge the Australian Research
Council (ARC) for the nancial support of this study through the
grant DP0879763. We are grateful to two anonymous reviewers
for helpful comments.
W.H. Limet al. / Agricultural and Forest Meteorology 152 (2012) 3143 41
Fig. A.1. Diffusion coefcient Dv versus air temperature Ta at different values of
atmospheric pressure Pa.
Appendix A. Diffusion coefcient of water vapour
The diffusion coefcient of water vapour D
v
is calculated based
on Pruppacher and Klett (1997):
D
v
= 2.11
T
a
273.15
1.94
P
o
P
a
10
5
[m
2
s
1
] (A.1)
where T
a
[K] is the air temperature, P
a
[Pa] is the atmospheric pres-
sure, P
o
[Pa] is the atmospheric pressure at the mean sea level
(101.325kPa). Fig. A.1 shows the change of D
v
with T
a
and P
a
using
Eq. (A.1).
Appendix B. Dynamic viscosity of air
The dynamic viscosity of air
a
(assumed dry air for simplicity)
is calculated based on Jacobson (2005):
a
= 1.8325
416.16
T
a
+120
T
a
296.16
1.5
10
5
[kgm
1
s
1
] (B.1)
Although
a
is based on dry air instead of moist air, the differ-
ence is small (Maxwell, 1866; Kestin and Whitelaw, 1964). Fig. B.1
illustrates the change of
a
with T
a
using Eq. (B.1).
Appendix C. Derivation of the speed of air in the vertical
direction above evaporating surface
The vertical circulation of air above the evaporating sur-
face is determined by the air density difference (Schlichting,
1960; Incropera and DeWitt, 1990; Holman, 2002; Monteith
and Unsworth, 2008), which results from temperature gradients,
vapour concentrationgradients, or acombinationof both(Monteith
and Unsworth, 2008).
In principle, the speed of air in the vertical direction can be
derived from Reynolds and Grashof numbers using dimensional
analysis. An equivalent Reynolds number in the vertical direction
(Re
V
) is the ratio of inertial forces (in the vertical direction) to vis-
cous forces, i.e.,
Re
V
=
a
u
V
L
a
(C.1)
where
a
[kgm
3
] is the density of air, u
V
[ms
1
] is the speed of
air in the vertical direction, L [m] is the characteristic length of the
Fig. B.1. Dynamic viscosity of air a versus air temperature Ta.
evaporating surface and
a
[kgm
1
s
1
] is the dynamic viscosity of
air (calculation of
a
is given in Appendix B).
The Grashof number (Gr) is equal to buoyancy forces times iner-
tia forces divided by the square of viscous forces. Since the origin
of Gr is in heat transfer studies (Karwe and Deo, 2003), it is com-
monly calculated based on a spatial temperature difference. Here,
we calculate Gr by using the spatial density difference. The purpose
is to take into account both temperature and concentration (water
vapour and dry air) differences between the evaporating surface
and the reference height, i.e.,
Gr =
2
a
g(
a
/
a
)L
3
2
a
(C.2)
where g [ms
2
] is the gravitational acceleration,
a
[kgm
3
] is the
average air density between the evaporating surface and the refer-
ence height and
a
[kgm
3
] is the spatial difference inthe density
of air between the evaporating surface and the reference height.
Assuming constant atmospheric pressure between the evapo-
rating surface and the reference height, u
V
[ms
1
] can be derived
fromEqs. (C.1) and (C.2) as follows,
Re
2
V
Gr, Re
V
Gr,
a
u
V
L
2
a
g(
a
/
a
)L
3
2
a
,
u
V
a
L, u
V
= k
a
L, u
V
= ku
V,C
(C.3)
where k is a dimensionless constant (range: 0) and u
V,C
[ms
1
]
g(
a
/
a
)L
a
=
1
R
(P
a
e
a
(T
a
))M
a
+e
a
(T
a
)M
w
T
a
(P
a
e
s
(T
s
))M
a
+e
s
(T
s
)M
w
T
s
(C.4)
42 W.H. Limet al. / Agricultural and Forest Meteorology 152 (2012) 3143
and
a
=
1
2R
(P
a
e
a
(T
a
))M
a
+e
a
(T
a
)M
w
T
a
+
(P
a
e
s
(T
s
))M
a
+e
s
(T
s
)M
w
T
s
(C.5)
respectively, where R [J mol
1
K
1
] is the ideal gas constant, T
s
[K]
is the water surface temperature, T
a
[K] is the air temperature, P
a
[Pa] is the atmospheric pressure, e
a
(T
a
) [Pa] is the air vapour pres-
sure, e
s
(T
s
) [Pa] is the vapour pressure at the evaporating surface,
M
a
[kgmol
1
] is the molecular mass of air and M
w
[kgmol
1
] is the
molecular mass of water. We set
a
=0 for conditions when the
air density at the evaporating surface is greater than that at the ref-
erence height, i.e., minimal buoyancy forces; subsequently u
V,C
=0
and thus u
V
=0 in Eq. (C.3).
Appendix D. Equivalent scheme in plant physiology
Here, we showthe relation between our theoretical framework
and the scheme widely used in plant physiology.
For vapour transfer from inside a leaf to the atmosphere, z is
the combinationof the equivalent thickness of the parallel stomatal
pores z
l
[m] and the aerodynamic boundary layer thickness z
a
[m]. Therefore, Eq. (6) becomes
J =
1
R
D
v
T
a
(e
s
(T
s
) e
a
(T
a
))
z
l
+z
a
(D.1)
Based on the ideal gas law,
RT
a
= P
a
V
m
(D.2)
where V
m
[m
3
mol
1
] is the molar volume of moist air. Substituting
Eq. (D.2) into Eq. ((D.1), we have
J =
(e
s
(T
s
)/P
a
) (e
a
(T
a
)/P
a
)
(V
m
z
l
/D
v
) +(V
m
z
a
/D
v
)
(D.3)
By replacing e
s
(T
s
)/P
a
, e
a
(T
a
)/P
a
, V
m
z
l
/D
v
and V
m
z
a
/D
v
with
w
s
, w
a
, r
m,l
and r
m,a
respectively, we obtain
J =
w
s
w
a
r
m,l
+r
m,a
(D.4)
where w
s
is the mole fraction of water vapour inside the leaf, w
a
is
themolefractionof water vapour intheair (at thereferenceheight),
r
m,l
[m
2
s mol
1
] is the leaf resistance, and r
m,a
[m
2
s mol
1
] is the
aerodynamic resistance. Eq. (D.4) is identical to Cowan (1977, Eq.
95).
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