1 SECTION A Attempt all questions

Des Foundation

ICSE Chemistry F.M=75

QI (a) Name the following: ....5 (i) A gas smells of rotten eggs. (ii) A gas whose solution in water turns neutral litmus solution to blue. (iii) A white coloured ionic compound present in mothers kitchen. (iv) A liquid which is non-eletrolyte. (v) The gas that changes acidified potassium dichromate from orange to green. (b) A hydrocarbon X contains 85.7% carbon by mass. .....3 (i) Determine the empirical formula of X (ii) If the relative molecular mass of X is 28, find the molecular formula of X. (iii) Name X (c) Give one term/ phrase for the following: ....5 (i) Formation of positively charged particles from atoms. (ii) Number of electrons present in the outermost shell of an atom. (iii) The ease with which an atom bonded by a covalent bond, attracts the electron pair towards itself. (iv) The volume of a gram-mole at STP (v) Mass of 2 ml of oxygen gas compared to the mass of 2ml of hydrogen gas. (d) In this question you are required to supply the word (or words) that will make each sentence into a correct statement which is to be written down in full example: ....5 (i) The electrolysis of water liberates hydrogen gas and oxygen gas. (ii) Sodium nitrate reacting with sulphuric acid using nitric acid. (iii) Sulphur can be converted to sulphuric acid using nitric acid (iv) Greenish yellow gas is evolved when hydrochloric acid reacts with red lead. (v) Ammonium hydroxide reacts with ferric chloride produces ferric hydroxide (e) The table given below shows the electronic configuration of six elements A to F. ..5 Element Electronic configuration A 2, 8, 8, 1 B 2, 8, 2 C 2, 8, 7 D 2, 1 E 2, 4 F 2, 8, 8 Answer the following questions: (i) The two elements present in the same group of the periodic table. (ii) An alkali earth metal (iii) The most metallic element (iv) A noble gas (v) An element having the highest electron affinity (f) For each of the following reactions, describe what would you observe and name the reaction product that is responsible for the observation: .....3 (i) Solution of sodium chloride and barium nitrate are mixed. (ii) Sodium hydroxide solution is added to ferrous sulphate solution

(g) Write the IUPAC name of the following compounds. (i) H3C C C CH3 (ii) CH3CH2OH (iv) CH3CH2CHO (v) H3C O CH3

(iii) H3C CO CH3 ....5

SECTION B Answer any 4 questions QII (a) (i) Name the process for the manufacture of nitric acid from ammonia....2 (ii) Write equation for the catalytic oxidation of ammonia (iii) Give the temperature and pressure for the reaction (II) (b) Write balanced chemical equations for the following reactions: .....4 (i) Aluminum power is treated with hot concentrated caustic soda solution (ii) Red lead is warmed with concentrated hydrochloric acid. (iii) Carbon treated with concentrated nitric acid. (iv) Excess ammonia reacts with Chlorine (c) From the chemical equations: .....3 C + 2 H2 SO4 CO2 + 2 H2O + 2 SO2 Calculate: (i) the mass of carbon required to react completely with 19.6g of sulphuric acid. (ii) the volume of sulphur dioxide measured at STP, liberated at the same time. [RA M of H=1, C=12, O=16, S=32] QIII A- Hydrogen chloride gas B- Ammonia C- Sulphur dioxide D- Hydrogen sulphide E- Chlorine From the above list choose the appropriate letters to answer the following questions: Some letters may be repeated .......6 (i) The gas that is lighter than air. (ii) The gas that is used for bleaching silk (iii) It fumes in moist air (iv) It is used as an antichlor (v) It turns lead acetate paper black (vi) When the two gases are mixed, one in oxidized and the other is reduce to the same substance QIV (a) Give reason: (i) Washing soda crystal looses its crystalline shape when exposed to air. ....4 (ii) Iron (II) chloride should be kept in air tight bottle. (iii) Quick lime is used to dry ammonia (iv) Level of concentrated sulphuric acid increases when it is exposed to ordinary air for a long time (b) Name the anion present in each of the following compounds. .....2 (i) Compound A, when heated with concentrated H2SO4, gives a gas which fumes in moist air and produces dense white fumes with NH3. (ii) When freshly prepared solution of ferrous sulphate is added to a solution of G and concentrated sulphuric acid is gently poured from side of the test tube, a brown ring is formed.

QV (a) State your observation when excess of ammonium hydroxide is added to: ....4 (i) Copper (II) sulphate solution (ii) Lead (II) nitrate solution (iii) Zinc sulphate solution

(iv) Iron (II) chloride solution QVI (a) Write the equation for the following reactions: .....4 (i) Dilute nitric acid and copper (ii) Dilute hydrochloric acid and sodium thiosulphate (iii) Dilute sulphuric acid and sodium sulphide (iv) Dilute hydrochloric acid and zinc (b) Account for the following: .....3 (i) Hydrochloric acid is a better conductor than acetic acid of equivalent molar concentration (ii) When copper (II) sulphate is electrolyzed using copper electrodes the colour of the electrolyte is not fades (iii) Hydrogen can not prepared by the reaction between dilute nitric acid and zinc. (c) Each of the three flasks A, B and C contain 4.0g of a gas at the same temperature and pressure, flask A contains carbon dioxide, flask B contains sulphur dioxide and flask C contains nitrogen dioxide. (i) Which flask contains the least number of molecules? (ii) If flask A contains N molecules, how many molecules are present in flask B and C? [R A M of C=12, N=14, S=32, O=16] QVII i. A solution X turns blue litmus red, so it must contain ________ ions, another solution Y turns red litmus blue and therefore , must contain _____ ions. When solution X and Y are mixed together, the product will be _____ and _____ If a piece of magnesium were to put into solution X , _____ gas will be evolved ( ammonia,ammonium,carbonate,carbon dioxide, hydrogen,hydronium,hydroxide, precipitate,salt,water) ....21/2 ii.You are provided with following chemicals : NaOH , Na2CO3, H2O , Zn(OH)2 , CO2, HCl, Fe, H2SO4, Cl2, Zn . Using the suitable chemicals from the given list how will you prepare (give reaction only with condition if required) . ..................5 a. Iron(III)chloride b. Sodium sulphate c. sodium zincate d. Iron(II)sulphate e. Sodium chloride iii. Out line the steps required to convert lead(II)oxide into lead chloride. ...1 iv. On heating this salt changes from green to black name the salt (copper sulphate/ copper carbonate / copper nitrate ) (write reaction)...11/2