Chapter 10 1.

A hydrocarbon C5H10 does not react with chlorine in dark but gives a single Monochloro
compound C5H9Cl in bright sunlight. Identify the hydrocarbon.

2. Write the isomers of the compound having formula C4H9Br. 3. Write the equations for the preparation of 1iodobutane from (i) 1-butanol (ii) 1-chlorobutane (iii) but-1-ene.
4. Explain why (i) the dipole moment of chlorobenzene is lower than that of cyclohexyl chloride? (ii) alkyl halides, though polar, are immiscible with water? (iii) Grignard reagents should be prepared under anhydrous conditions? 5. Give the uses of freon 12, DDT, carbon tetrachloride and iodoform. 6.

7. Which of the following will have a higher boiling point and why ? CH3NH2 or CH3OH
8. Explain why phenol is acidic but ethanol is neutral. 9. In absence of kerosene oil can we store sodium metal in diethyl ether or ethyl alcohol or anhydrous hexanol ? 10. Write the IUPAC name of aspirin. 11. Give chemical test to distinguish between the following pair of compounds: Phenol and Benzoic acid 12. How will you distinguish between 1-Propanol and 2-Propanol by suitable chemical test ? 13. Of the two hydroxy organic compounds ROH and R'OH, the first one is basic and the other is acidic in behaviour. How is R different from R' ? 14. Mention an industrial product manufactured from methanal. 15. Mention two important uses of methanol. 16. Give reason for the following : Ortho-nitrophenol is more acidic than ortho-methoxyphenol. 17. Account for the following : o-nitrophenol has lower boiling point than p-nitrophenol.

Chapter 01 1. With the help of a labeled diagram show that there are four octahedral voids per unit cell in a cubic close packed structure. 2. Show that in a cubic close packed structure, eight tetrahedral voids are present per unit cell. 3. How does the doping increase the conductivity of semiconductors?

4. A sample of ferrous oxide has actual formula Fe0.93 O1.00. In this sample what fraction of
metal ions are Fe2+ ions? What type of nonstoichiometric defect is present in this sample?

5. Why are liquids and gases categorised as fluids? 6. Why are solids incompressible?

7. Inspite of long range order in the arrangement of particles why are the crystals usually
not perfect? 8. Why does table salt, NaCl, some times appear yellow in colour? 9. Why is FeO (s) not formed in stoichiometric composition? 10.Why does white ZnO (s) becomes yellow upon heating?

11. Why does the electrical conductivity of semiconductors increase with rise in
temperature?

12. Explain why does conductivity of germanium crystals increase on doping with galium. 13. In a compound, nitrogen atoms (N) make cubic close packed lattice and metal atoms
(M) occupy one-third of the tetrahedral voids present. Determine the formula of the compound formed by M and N? 14.Under which situations can an amorphous substance change to crystalline form? 15.Why are solids rigid? 16.Why do solids have a definite volume?

17. Classify the following as amorphous or crystalline solids: Polyurethane, naphthalene,

benzoic acid, teflon, potassium nitrate, cellophane, polyvinyl chloride, fibre glass, copper. 18.Why is glass considered a super cooled liquid? 19.Refractive index of a solid is observed to have the same value along all directions. 20.Comment on the nature of this solid. Would it show cleavage property? 21.Give the significance of a lattice point. 22.Name the parameters that characterise a unit cell.

23. Distinguish between

(i) Hexagonal and monoclinic unit cells (ii) Face-centred and end-centred unit cells.

24. Explain how much portion of an atom located at (i) corner and (ii) bodycentre of a cubic
unit cell is part of its neighbouring unit cell. A compound is formed by two elements X and Y. Atoms of the element Y (as anions) make ccp and those of the element X (as cations) occupy all the octahedral voids. What is the formula of the compound? 25. A compound is formed by two elements M and N. The element N forms ccp and atoms of M occupy 1/3rd of tetrahedral voids. What is the formula of the compound? 26. Which of the following lattices has the highest packing efficiency (i) simple cubic (ii) body-centred cubic and (iii) hexagonal close-packed lattice?

27.An element with molar mass 2.710-2 kg mol-1 forms a cubic unit cell with edge length 405 pm. If its density is 2.7103 kg m-3, what is the nature of the cubic unit cell? 28.Calculate the efficiency of packing in case of a metal crystal for (i) simple cubic (ii) body-centred cubic (iii) face-centred cubic (with the assumptions that atoms are touching each other).