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CLASS TEST - 2 (INORGANIC)
IIT-JEE
CHEMISTRY

P. JOY

Dear student following is an Easy level [ ] test paper. A score of 25 marks in 15 minutes would be a satisfactory performance: Q.No. 1 to 14 (+3, 1). (M.M. 42) Single option correct Q.1 HBH bond angle in BH4 is : (A) 180 (C) 109 Q.2
0 0

Q.8

(B) 120 (D) 900

Which of the following compound have ionic, covalent and coordinate bonding. (A) KCN (C) H3O
+

(B) NH4Cl (D) BF4

The percentage of p-character in the hybridisation state of carbon in CH4, CH3+ and CH3 respectively will be (A) 75, 50, 50 (C) 75, 66.7, 75 (B) 75, 66.7, 50 (D) 50, 50, 75.

Q.9

In formation of SO42 sulfur uses its (A) Ground state (B) First excited state (C) Second excited state (D) Third excited state

Q.3

The molecule in which the central atom is surrounded by five electron pairs of which two are lone pairs is : (A) PCl5 (C) ClF3 (B) PCl3 (D) IF5.

Q.10

How many pure p-orbitals are present in nitrogen molecule. (A) 4 (C) 0 (B) 2 (D) 1

Q.4

What is the steric number for the central phosphorus atom in phosphoryl chloride, POCl3 ? (A) 1 (C) 3 (B) 2 (D) 4

Q.11

Which of the following pairs of compounds do not exist ? (A) PCl5, SF4 (C) OF2, SF6 (B) NCl5, OF6 (D) POCl3, NO2

Q.12

Q.5

Which of the following ions cannot be formed ? (A) [SiF6]2 (C) [BF6]3 (B) [AlF6]3 (D) [BF4] Q.13

Expansion of octet around central atom does not take place in (A) SF4 (C) XeF4 (B) BrF3 (D) CF4

Q.6

Choose the molecule in which hydridisation occur in the ground state (A) BCl3 (C) PCl3 (B) PCl5 (D) BeF2 Q.14

NH 2 , NH 3 and NH 4+ do not show similarity in the following : (A) Hybridisation state of Nitrogen (B) Number of lone pair of electrons (C) Atomic number of nitrogen (D) Type of orbital overlapping in NH How many electrons are present in ammonium ion NH4+ (A) 10 (C) 9 (B) 8 (D) 7

Q.7

The maximum number of bonds between two atoms is (A) 3 (C) 1 (B) 2 (D) 4

&
CHEMISTRY IIT JEE (CLASS TEST - 2) (INORGANIC) ANSWER KEY
Name : .......................................................................................................... A 1. 2. 3. 4. B C D 5. 6. 7. 8. 9. A B C D 10. 11. 12. 13. 14.

&
M.M. 42
Roll No. : .................................. A B C D

CLASS TEST - 2 (INORGANIC)

Que. Ans. 1 C 2 C 3 C 4 D 5 C 6 C 7 C

IIT-JEE
CHEMISTRY

P. JOY
10 A 11 B 12 D 13 B 14 A

8 B

9 C

Sol.1 (C) BH4 has sp3 hybridisation & tetrahedral geometry.

H H B H
109

While Si, Al has vacant d-orbitals so they can expand their octet. Sol.6 (C) In BCl3, B has sp3 hybridisation occurs in its Ist excitation state. In PCl5, P has sp3d hybridisation occurs in its Ist excitation state. In BeF2, Be has sp hybridisation occurs in its Ist excitation state. But in PCl3, P has sp3 hybridisation occurs in ground state. Sol.7 (C) In single, double & triple bond between 2 atoms, maximum number of -bond is 1. Sol.8 (B) K C N
H + H Cl

So H B H bond. Angle in it is 109. Sol.2 (C) In CH4 & CH3 molecule, C is in sp3 hybridisation state in which % of scharacter is 25% and of p-character is 75%. In CH3+ molecule, C is in sp2-hybridisation state in which % of s-character is 33.3% & of p-character is 66.7%. Sol.3 (C)
Cl Cl Cl

H H O H

N H

B F

(A)

Cl

P Cl

P has 5 bond pairs. Sol.9 (C)

..

(B) Cl

Cl Cl
O

O S O O

P has 3 bond pairs & 1 lone pair

.. F F

S - 3s2 3p4 3d0 Ist excited state :

(C) F

Cl ..

Cl has 3 bond pairs & 2 lone pairs

F .. F F

II excited state :

(D) F I

I has 5 bond pairs & one long pair. Sol.4 (D)

O Cl P Cl Cl

sp3

O O O O

Sol.10 (A) In N2 molecule, each N atom is in sp hybridisation state & has 2 pure p-orbitals. So total 4 pure p-orbitals are present in N2.

In POCl3, P forms 1 -bond & 4 -bonds. So steric number for P atom is 4. Sol.5 (C) In [BF6]3, Boron has 12 valence electrons which is invalid because B can not expand its octet.

CLASS TEST - 2 (INORGANIC)

Sol.11 (B) In NCl5 & OF6, central atoms N & O having 10 & 12 electrons respectively which is invalid because they cannot expand their octet due to the absence of vacant dorbitals. While P & S has vacant d-orbitals. So they can expand their octet. Sol.12 (D) In SF4, BrF3 & XeF4, central atom S, Br, Xe has 10, 10 & 12 electrons respectively. (Expanded octet) while in CF4, C has 8 electrons (octet).

IIT-JEE
CHEMISTRY

P. JOY
: : : 2 l.p. 1 l.p. 0 l.p.

Sol.13 (B) NH2 NH3 NH4+ Sol.14 (A)

7N

1s2, 2s2 2p3

sp .

H H H H

2 + 8 = 10 electrons.