1) What mass of silver chloride will be obtained adding 51g of silver nitrate to excess sodium chloride? (Na CL =58.5.

AgNO3=170, Ag CL=143.5) 2) calculate the mass of lead(II) oxide formed heating 64g of lead(II) nitrate strongly (Pb = 207, N = 14, O =16) 3) a metal X with relative atomic mass 56 forms an oxide with formula X2o3. how many grams of the metal will combine with 10 grams of oxygen? ( O = 16) 4) calculate the mass of sodium nitrate NaNO3 formed when 31.8g of anhydrous sodium carbonate, Na2CO3, are added to excess nitric acid, HNO3. (Na =23, N = 14, C=12, O=16, H=1) 5) 12.5g of zinc carbonate, ZnCO3 were heated very strongly to a constant mass and the residue treated with excess hydrochloric acid, HCL. Calculate the mass of zinc chloride, ZnCL, that will be obtained. (Zn=65, C=12, O=16, H=1, CL=35.5) 6) In a certain reaction, 0.20g of hydrogen combines with 3.20g of oxygen. If the relative molecular mass of the comoubd is 34.0, calculate the molecular formula ( H=1, O=16) 7) How many grams of hydrogen sulfide would be necessary to precipitate 5g of copper (II) sulfide from a copper (II) sulfate solution? 8) How much magnesium much be burned in oxygen to make 4.0g of magnesium oxide? 2Mg(s) + O2(g)____2MgO(s) 9) What mass of ammonia would be evolved by heating together 100g of ammonium chloride and 70g of calcium hydroxide? Which of the reagents is in excess and by what mass? 10) What mass of calcium oxide is formed when 25g of calcium carbonate is decomposed by heat? CaCO3(s)_______CaO(s)+CO2(g) 11) 4.6g of sodium are added slowly to 10g of water in a small dish. What is the total mass of the solution left when the action is complete? 12) In the blast furnace iron(III) oxide is reduced to iron by carbon monoxide FeO3(s)+3CO(g)______2Fe(s)+3CO2(g)

a) what mass of carbon monoxide is needed to reduce16 tonnes of iron (III) oxide? b) What mass of iron is obtained from the reduction of 16 tonnes of the oxide?

13) 5.2g of lead were converted into dilead (II) lead(IV) oxide and this was added to excess of dilute nitric acid. What mass of lead(IV) oxide was obtained in this way? 14) What mass of coke is consumed in a blast furnace in the production of 2.8 tonnes of carbon monoxide? 2C(s)+O2(g)_____2CO(g) 15) What mass of water would be required to react with the calcium oxide which could be obtained strongly heating 100g of calcium carbonate? 16) What is the loss in mass when 1.25g of blue copper(II) sulfate crystals, CuSO4.5H2O, is heated and decomposed to anhydrous copper(II) sulfate, CuSO4? 17) What mass of copper would be required to react with 100g nitric acid, and what mass of copper nitrate would be formed, use the equation: 3Cu+8HNO3______3Cu(NO3)2+4H2O+2NO 18) what mass of ammonia, NH3 is formed when 12g of hydrogen, H2, combines with nitrogen, N2? 19) Which would be the greater mass and by how much, the mass of black copper oxide which could be obtained by heating 100g of copper(II) nitrate crystals, Cu(NO3)2.3H2O, or by heating 100g of malachite Cu(OH)2.CuCO3? 20) Lead(II) oxide, PbO, reacts with hydrogen to form lead and steam, H2O. calculate the mass of lead formed when 446g of lead(II) oxide is reduced in this way.

21) 0.920g of a mixture of metallic copper and copper(II) oxide was heated in a stream of hydrogen until reduction was complete. The residue weighed 0.752g. what was the percentage of metallic copper in the original mixture? 22) What mass of sulfur is needed to react with 8.0g copper to form copper(I) sulfide, Cu2S? 23) 1.12g of a mixture of sodium chloride and ammonium chloride was dissolved in water and an excess of silver nitrate solution was added to precipitate the silver chloride. This precipitate was found to weigh 2.87g. what were the masses of sodium chloride and ammonium chloride in the original mixture? 24) What mass of copper is formed when 4.0g of copper(II) oxide is reduced by carbon? 25) 15g of copper were dissolved in nitric acid and the product heated carefully. The copper (II) oxide obtained was dissolved in dilute sulfuric acid and crystals of copper (II) sulfate were obtained by evaporation. What was the maximum yield of copper (II) sulfate crystals which could have been obtained? 26) What mass of sodium chloride can be crystallized from a solution formed by dissolving 5.0g of sodium hydroxide in water and then neutralizing the alkali which dilute hydrochloric acid? 27) What mass of lead is displaced when 1.3g of zinc is added to excess lead(II) nitrate? 28) What mass of aluminium is required to react with dry chlorine gas to make 4g of anhydrous Aluminium chloride? 29) What mass of sodium carbonate is formed when 8.4g of sodium hydrogen carbonate is decomposed by heat? ( the other products are water and carbon dioxide)

30) 33dm3 of oxygen were needed to convert a certain mass of zinc sulfide into zinc oxide. What was the volume of sulfur dioxide which passed off during the action? 31) What mass of 1,2 dibromoethane is formed when 5.6g of ethene combines with bromine? 32) Magnesi um sulfate can be obtained from magnesium oxide by the following reaction: MgO_H2SO4______MgSO4+H2O. a) (i) what is the relative formula mass of magnesium oxide, MgO? (ii) what is the relative formula mass of magnesium sulfate, MgSO4? b) what mass in grams of magnesium sulfate MgSO4, could be obtained from 1g og magnesium oxide,MgO? 33) carbon dioxide can be prepared commercially by roasting limestone in a kiln. The equation for the reaction is: CaCO3_______CaO+CO2 given that the relative atomic masses are Ca=40,C=12,O=16, calculate the mass of carbon dioxide and calcium oxide produced from 50 tonnes of limestone. 35) the equation for the reaction between ammonia and heated copper (II) oxide is: 3CuO+2NH3=3Cu+N2+3H2O Calculate the mass of copper which could be produced by the reaction of 10g of ammonia with an excess of copper (II) oxide. 34) (a) rewrite balanced forms of the following equations, which refer to the extraction of copper from its ore chalcopyrite (CiFeS2) CuFeS2+O2=Cu2S+FeO+SO2 Cu2S+O2=Cu2O+SO2 Cu2S+Cu2O=Cu+SO2 (b) calculate the maximum amount of copper which can be obtained from 100kg of chalcopyrite.

36) (a) calculate the maximum mass of iron which could be produced from a blast furnace charge of 80 tonnes of haematite ore, Fe2O3. (b) the mass of iron actually extracted amounted only to 45 tonnes. Give two reasons to account for this low yield. 37) (a) (i) describe how you would prepare dry crystals of sodium sulfate. (Na2SO4.10H2O), starting from dilute sulfuric acid and dilute aqueous sodium hydroxide. (ii) excess aqueous barium chloride was added to a solution of 0.025 mole of sodium sulfate dissolved in water. Write down the ionic equation for the reaction and calculate the mass of the dry product. 38) each year 200 million tones of new carbon monoxide is released into the atmosphere. It is thought that almost all of the CO is eventually oxidized to carbon dioxide. a) write down an equation to represent the oxidation reaction. b) Calculate the mass of carbon dioxide produced yearly by this transformation.