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27/04/2011 14:13
http://webwormcpt.blogspot.com/2009/09/estimate-mixture-flammability.html
One shall take note that these equations are used for single component. For a mixtures, the LFL/LEL and UFL/UEL at operating pressure (P) and temperature (T) will be calculated using following equation (as discussed in "Estimate Mixture Flammability & Explosivity At Reference P & T":
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Calculation Steps 2 steps in determining mixtures LFL/LEL and UFL/UEL at operating pressure (P) and temperature (T) . (i) Estimate LFL/LEL and UFL/UEL at operating pressure (P) and temperature (T) for every component in a mixture (ii) Estimate mixture LFL/LEL and UFL/UEL Example A mixture contains of Methane, Ethane and Propane with volume% of 20%, 20% and 60%. Estimate UEL at (i) 20 degC & 101.325 Pa, (ii) 70 degC & 3 MPa.
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27/04/2011 14:13
http://webwormcpt.blogspot.com/2009/09/estimate-mixture-flammability.html
Data Methane (C1) UELC1,20C,1ATM = 15.0%, EC1,combustion = 212.79 kcal/mole Ethane (C2) UELC2,20C,1ATM = 12.4%, EC2,combustion = 372.81 kcal/mole Propane (C3) UELC3,20C,1ATM = 10.1%, EC3,combustion = 526.74 kcal/mole Output (i) UELMix at 20 degC & 101.325 Pa UELMix = 1 / [ 0.2/15 + 0.2 /12.4 + 0.6 / 10.1 ] UELMix = 11.25 vol% at 20 degC & 101.325 kPaA (ii) UELMix at 70 degC & 3 MPa UELC1,7oC,3MPa = 15 x [1+0.75(70-20)/212.79] + 20.6 x [Log10(3)+1] = 48.07 vol% UELC2,7oC,3MPa = 12.4 x [1+0.75(70-20)/372.81] + 20.6 x [Log10(3)+1] = 44.08 vol% UELC3,7oC, 3MPa = 10.1 x [1+0.75(70-20)/526.74] + 20.6 x [Log10(3)+1] = 41.25 vol% UELMix,70C,3MPa = 1 / [ 0.2/48.07 + 0.2 /44.08 + 0.6 / 41.25 ] UELMix,70C,3MPa = 43.02 vol% at 70 degC & 3 MPaA
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27/04/2011 14:13
http://webwormcpt.blogspot.com/2009/09/estimate-mixture-flammability.html
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27/04/2011 14:13