(21 G ) (99

 









20132012

.
(22 MeV

"!
 
 


 






3

Mo

@@a@na

(3 g  P

@aa@n@ra@z@a@H1

P 99P

 ) (1

)i(t

Y

) uC(t (t)=u(t).i(t) : 

P )

C = 400E
R =2000F
G

(
8

(13 5,55.10 BqP 08h00


8

(23 G  3,46.10 Bq
) t1/2 =6h (
@ @ ba
(1 Ca =10 mol.L
-2

-1

K =10m-1 G =5,4.10-3 S

(11
P i(t) : ) uC(t .
) u (t ) u (t . t = 1s
YZ )(V

(11 .

)(mA

(12 YZ

(21 YZ ) (A t = 1s

gh

(31 gh ) UC(t A B

(13 .

(2  V =200mL Y )HNO2(aq

RC@ka@br@@ba@aa(2

) ) (HCOO-(aq) +Na+(aq P

(12
YZ ) (t E R C t tm

G n1 = 40mmol Y 80mmol

gh R C

(4  D C

(21 / 

. = 100 C
F

E = 4V

(22  .

: bra@na Y 

(23 Y Qr,q

gh  P
. Y
Y Y

(1

-2

(24 xe = 3,3.10 mol

 P Qr , q
(25 pH .

Y Y

 YZ

. pK A1 = 3,3

HCOO-aq
pKe =14
@ @

G Tc X
(2

HNO2

Y Y

H3O35,5mS.m 2.mol -1 ; A - 5,46mS.m 2.mol -1

@ @

pKA2 =3,6