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Salt Analysis 2012-2013

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Salt Analysis
Salt Analysis of Cations and Anions
CATIONS : Pb2+ ,Hg2+ ,Cu2+ ,Cd2+ , Ag+ , Fe2+ , Fe3+ , Al3+ , Zn2+ , Mn2+, Co2+ , Sr2+ , Ba2+ , Mg2+ , NH4+ ANIONS : CO32- , S2- , SO32- , SO42- , NO2- , NO3- , Cl- , Br2- , PO43- , CH3COO-

Below we are providing a download link for Salt Analysis Chart which can be useful for Class 12 Chemistry students.The file is in PDF format and contains procedure for all tests.
Download Salt Analysis Chart

Cations Group Zero Group Group Reagent O.S. + NaOH + Heat Radicals NH4+
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Salt Analysis 2012-2013

I Group

O.S. + HCl

Pb2+

II Group III Group IV Group V Group VI Group

O.S. + HCI + H2S O.S. +NH4Cl + NH4OH O.S. + NH4CI + NH4OH +H2S O.S. + NH4CI + NH4OH +(NH4)2CO3 O.S + NH4CI + NH4OH + NaH2PO4

Cu2+ AI2+ ,Fe3+ Ni2+ ,Mn2+ , Zn2+ ,Co2+ Ba2+, Ca3+, Sr2+ Mg2+

Anions Preliminary Tests Group I Group II Group Group Reagent Salt + dil. H2SO4 Salt + conc. H2SO4 Add Cu piece and heat Radicals CO32-, SO32-, S2-, NO2Cl-, Br-, I-, CH3COONO-

Add KMnO4 soln.

c2o42-

III Group

O.S. + BaC!2

so42-

IV Group

O.S + Conc.HNO3 + Heat + (NH4)24 MoO PO43-

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Salt Analysis 2012-2013

Test Physical Appearance Colour White

Observation

Inference

NH4+, Pb2+, Al3+ , Zn2+, Ba2+, Ca2+ , Sr2+ and Mg2+ Cu2+ Ni2+ Fe3+ Co2+ Mn2+ NH4+ CH3COOS2CO32- , SO32-, S2- and ClBr-, NO3IPb(NO3)2 and Ba(NO3)2 Cu2+ Cu2+
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Blue Green Brown Red Light pink Odour Smell of NH3 Smell of vinegar Smell of rotten eggs Dry Heating Colourless gas evolved

Blown gas evolved

Violet gas evolved Crackling sound Brown residue Flame Test


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Greenish blue

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Salt Analysis 2012-2013

Light green Brick red Crimson red

Ba2+ Ca2+ Sr2+

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Salt Analysis 2012-2013

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