Code No.

34

Total No. of Questions : 39 ]

[ Total No. of Printed Pages : 15

March, 2008

CHEMISTRY
( Kannada and English Versions )
Time : 3 Hours 15 Minutes ]

[ Max. Marks : 90
( Kannada Version )

i)

XR XxY @ .

ii)

- A,
O.

iii)

- A XR x@ 10 , - B
XR x@ 2 20 , - C XR
x@ 5 40 - D Y D 1 10

D 2
Y XR x@ 5 10

B, C

Y XRR W

O.
iv)

WY XR O R .

- A
:

1.

i)

ii)

XR Y WY OR
. X XR O.
10 1 = 10

10

XRR O.

Y U X} X Y
XR .
[ Turn over

Code No. 34

2.

|Y| XK OOR
.

3.

xJ O Y y x\X SO ?

4.

05 M

5.

xY X O Yx X@ EO.
x ?

6.

W xY O | xY Y L R
SJ X yO ?

7.

xYY T { ?

8.

( CH3) 3 N IUPAC R .

9.

R OR .

10.

Y | W

O
?

yY

pH

( Compound )

- B
:

i)

O XRR O .

ii)

X XR R O.
10 2 = 20

11.

NY x] @ O yO.
R YW x\ .

3
12.

Code No. 34

\ z R . y R
.

13.

x y ?

14. 5

WOR

56

D(+)

WJy Y R .

.. 3 R

STP

y R .
15.

| Xx] R

xX|

} ?
16.

17.

"L # ? L x O ?

18. BCC

( Non-reducing sugar )

R .

T X{W WO ( Radius ratio ) ? Z zW O

{WR

( Geometry )

19.

X x O R xO ?

20.

X :
i)

YxY OH O.

ii)

YO.

21. 3

X. R

SOR
22.

X.

( Relative lowering of vapour pressure )

x Y
C2 H6

A, B, C

CH3 CH2 Cl

R :
B

CH3 CH2 OH
CH3 COOH

C
D

CH4

[ Turn over

Code No. 34

- C
I.

xY XR O :
23. a)

y Y _R

2 5 = 10

( Desilverisation of lead )

R .
b)

24. a)

x IUPAC R :
i)

Cu NH H O Cl

(
3 ) 2 (
2
) 2
2

ii)

Na3 [ Fe(Ox)3] .

3+2

Y yd WR . XR
order )

( Bond

. Y O Y E

P O x ?
b)

W ?

( Polydentate )

} x.
25. a)

3+2

xX| QM | xXR S
?

b)
II.

WW }R R .

xY XR O :
26. a)
b)

4+1
3 5 = 15

T XXR .
|LR
O ?

Xx]

5
27. a)

Code No. 34

x X R :
i)

yW] || O yW] {R @ J
.

b)

ii)

y YR |xY { .

iii)

R Xy Y {

X}V X O y X

( Mesomeric effect )

W WWR .
28. a)
b)

SN 1

3+2

XXR .

Y Z O Z
@Y Z x\
.

29. a)

3+2

X Xx] {L O ?
XY XXR .

b)
III.

( Drying oils )

? x@ y ?

xY XR O :
30. a)

X X

SR ;

X 9 mol/dm3 O.
mol/dm3

3+2

3 5 = 15

XY

30

O. QY X

80

45

x_ R .
b)

X P
X X ( Order ) ?

mol/dm3 /s.

QY
3+2
[ Turn over

Code No. 34
31. a)

b)

y\ X }R .
H2 O ( l )
So

H2 O ( g )

= 1188 103

XX

kJ K1

Ho = 44 kJ

O. O

PYQ NR @ .

32. a)

NY

002

PR O

33. a)

b)

3+2

JL XR .
25C

b)

001 M

y Y

XR @ .

[ H+ ]

L R X] @ ?

3+2

x O yXR .
Z{ XX ?

L x -

NQ x Z{ XX ?

34. a)

3+2

X N O PR R
. XR .

b)

| -] R . XR
.

c)

W X Xx@ } x.

2+2+1

Code No. 34

- D
D 1
IV.

xY XR O :
35. a)

QMR

1 10 = 10

, x@ ||X-

( VBT )

y R O y R .
b)

QM ?
QM

12 1010

T| X
O. T|

R .
c)

R ?

d)

Z- ? Z- R .
3+3+2+2

36. a)

Mg|Mg2+ | | Ag+

OR
o

c)

( Standard free energy )

EAg = 08 V
b)

| Ag

EMg

xY

= 237 V.

x XR :
i)

xU X

ii)

R ]

X XK

?
d)

J R .

3+4+2+1

[ Turn over

Code No. 34

8
D 2

V.

xY XR O :
37. a)

2 5 = 10

|X |-|XR XY

?
b)
38.

X W x\R .

3+2

| T| O | XY N
}R XR .

39.

xJ X

250 cm3

T| R

( Standard )

| xX|

XR R . Y
X R x.

Code No. 34

( English Version )

Instructions :

i)

The question paper has four Parts.

ii)

Parts A, B, C and D are common to all the candidates.

iii) Part A carries 10 marks. Each question carries one mark.

Part B carries 20 marks. Each question carries two marks.
Part C carries 40 marks. Each question carries five marks.
In Part D D 1

carries 10 marks and D 2

carries

10marks. Each question of D2 carries five marks.

iv) Write balanced chemical equations and draw diagrams
wherever necessary.

PART A
Note :

i)

Answer all the 10 questions.

ii)

Questions have to be answered in one word or in one

sentence each. Each question carries one mark.
10 1 = 10

1.

Write the reaction which occurs in zone of combustion in the blast furnace
during extraction of iron.

2.

Name the first compound of a noble gas prepared by Bartlett.

3.

Out of cobalt and zinc salts, which is attracted in the magnetic field ?

4.

What is the pH of 05 M sulphuric acid ?

5.

Why is the osmotic pressure of sodium chloride solution higher than

glucose solution ?
[ Turn over

Code No. 34
6.

10

Between aluminium chloride and potassium chloride, which one is

required in minimum concentration to coagulate gold sol ?

7.

Name the crystal lattice in sodium chloride crystal.

8.

Write the IUPAC name of ( CH3)

N.
3

9.

Name the substance to decolourise an oil.

10. What type of linkage is present between the polypeptide chains of

Insulin?

PART B
Note :

i)

Answer any ten questions.

ii)

Each question carries two marks.

10 2 = 20

11. At low temperature carbon monoxide is a better reducing agent than

carbon. Explain with the help of Ellingham diagram.
12. Write the energy level diagram of Lithium molecule. Indicate the magnetic
property of it.
13. What is Chiral carbon atom ? Write the structure of D ( + ) Lactic acid.
14. Calculate the time required to liberate 56 cm3

of hydrogen at STP, if

5amperes of current flows.

15. What is the action of potassium hydroxide on potassium dichromate ?
16. Write the Haworth structure of a non-reducing sugar.
17. Define gold number. Why is Gelatin added to gold sol ?

11

Code No. 34

18. What is the radius ratio-range of a BCC crystal ? Mention its coordination
number and geometry.
19. Why do transition metals form complex compounds ?
20. Give a reaction to show that glucose contains
i)

five OH groups

ii)

six carbon atoms in a straight chain.

21. 3 g of urea is dissolved in 9 g of water. Calculate the relative lowering of

vapour pressure.
22. Identify the reagents A, B, C and D in the following conversions :
C2 H6

CH3 CH2 Cl

CH3 CH2 OH
CH3 COOH

CH4

PART C
I.

Answer any two of the following questions :

23. a)
b)

24. a)

2 5 = 10

Describe Parkes process of desilverisation of lead.

Write the IUPAC names of the following :
i)

Cu NH H O Cl

(
3 ) 2 (
2
) 2
2

ii)

Na3 [ Fe(Ox)3] .

3+2

Write the electronic configuration of oxygen molecule. Calculate

the bond order.

Between

oxygen molecule and hydrogen

molecule which is more stable and why ?

b)

What is a ligand ? Give an example of polydentate ligand.

3+2

[ Turn over

Code No. 34
25. a)

12
How is pure potassium dichromate manufactured from chromite
ore ?

b)
II.

Name a metal which shows photoelectric effect.

Answer any three of the following questions :

26. a)
b)

4+1
3 5 = 15

Explain the mechanism of sulphonation of Benzene.

What happens when acetaldehyde is treated with dil. NaOH
solution? Write the equation.

27. a)

b)

Write the equations for the following reactions :

i)

Dry distillation of calcium acetate and calcium benzoate.

ii)

Acetic acid is treated with phosphorus pentachloride.

iii)

Phenol is treated with dil. Nitric acid.

Mention any two differences between mesomeric effect and

inductive effect.

28. a)
b)

3+2

3+2

Explain the mechanism of SN 1 reaction.

Give a reaction to show that benzene contains three double
bonds. Mention a test to indicate that these double bonds are
different from those of alkenes.

29. a)

3+2

What happens when Benzaldehyde is treated with strong

solution of sodium hydroxide ? Explain the mechanism involved
in the reaction.

b)

What are drying oils ? What are the causes of it ?

3+2

13

Code No. 34

III. Answer any three of the following questions :

30. a)

For the first

order

reaction

3 5 = 15

products,

the

initial

concentration of A was found to be 9 mol/dm3 . After

30minutes, the concentration was reduced to 45 mol/dm3 .
Calculate the time required for 80% completion of the reaction.
b)

The unit of velocity constant of a reaction is mol/dm3 /s. What

is the order of the reaction ?

31. a)
b)

3+2

Explain the buffer action of a basic buffer solution.

For a process H2 O ( l )

H2 O ( g ), Ho = 44 kJ and

So = 1188 103 kJ K1 . Calculate the temperature at

which water vapour and water are at equilibrium.
32. a)

3+2

Write the mathematical form of Ostwalds dilution law. Calculate

the dissociation constant of 001 M acetic acid if the degree of
dissociation at 25C is 002. Also calculate [ H+ ] concentration.

b)
33. a)
b)

Describe Bredigs arc method for preparation of gold sol.

Explain the construction and working of Daniel Cell.

What is spontaneous process ? Why is melting of ice a

spontaneous process though it is endothermic ?

34. a)

3+2

Write

an equation which

relates

the

rate

3+2
constant

and

temperature of a reaction. Name the reaction.

b)

State vant Hoff-Charles law and write its mathematical form.

c)

Give an example for Psuedo first order reaction.

2+2+1
[ Turn over

Code No. 34

14
PART D
D 1

IV. Answer any one of the following :

35. a)

1 10 = 10

With the help of VBT explain the hybridisation in tetracarbonyl

nickel. Indicate the magnetic property of it.

b)

Define solubility product. The solubility product of barium

sulphate is 12 1010 . Calculate the solubility of barium
sulphate in water.

c)

How do you convert methyl amine to methyl isocyanide ?

d)

What is Zwitterion ? Write the structure of Zwitterion of alanine.

3+3+2+2

36. a)

Calculate the change in standard free energy for the cell

Mg|Mg2+ | | Ag+ | Ag.
o

EAg = 08 V and EMg = 237 V.

b)

c)

Explain the following reaction with equations :

i)

Kolbes reaction

ii)

Perkins reaction.

How is helium separated from the mixture of noble gases by

Dewars method ?

d)

Write Nernst equation.

3+4+2+1

15

Code No. 34

D 2
V.

Answer any two of the following :

37. a)

2 5 = 10

How is m-dinitrobenzene prepared in the laboratory from

nitrobenzene ?

b)

Explain the general test for proteins.

3+2

38. Describe an experiment to show the effect of temperature on the rate

of the reaction of potassium persulphate and potassium iodide.

39. Describe the estimation of the amount of ferrous ammonium sulphate

present in 250 cm3 of the Mohrs solution using standard potassium
dichromate solution. Give the equation.

[ Turn over