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Chemistry1251

Exam#2KEY(75minutes)
October6,2011

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27

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Bysigning,youaffirmingthatyouhavefollowedtheUNCCharlotteStudentCodeofAcademicIntegrity.

Pleasecheckthesectioninwhichyouareenrolled:
Jew(001)MWF8:00AM_______ Rabinovich(A/B05)TR11:00AM______
Jew(A/B02)MW2:00PM_______ Rines(A/B06)MW6:30PM______
Hutchison(004)TR9:30AM_______
Pleasereadeachquestioncarefullyandansweritcompletelyandclearly.Mostofthefactualinformation
youneediscontainedinthetextoftheproblem.Answerthequestionsyoufindeasyfirst;questionswhich
appear difficult at first usually require a revision of your thought process. Always keep in mind the
intendedexaminationtopicsifaproblemappearstoohard.

Thequizshouldhave5pagesforatotalof16questions.Individualpointvaluesforfreeresponsearegiven
inthecornerofeach answerspace.Multiplechoicequestionsareworth4pointseach.Youmustshow
yourworktoreceiveanycreditforproblemsinvolvingcalculations.Allcalculatedanswersandwork
mustincludeunits,andshouldberoundedtotheappropriatenumberofsignificantfigures!

88.91

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Free Response Instructions: Solve the following problems in the boxes provided below each question.
Besuretoshowallyourworkandunits,androundyouranswerstotheappropriatesignificantfigures.

1.(a)Writeoutthebalanced,chemicalequation,includingstatesofmatter,forthereactionofa
solutionofhydrobromicacidwithasolutionofbariumhydroxide.

2HBr(aq)+Ba(OH)2(aq)BaBr2(aq)+2H2O(l)
+2correctspecies

Ifspeciesarecorrect,+1states,+1coefficients
4

(b)Ifanexcessofbariumhydroxidewasaddedtothemixture,whichofthefollowingspeciesare
stillfounddissolvedinsolution?Checkallthatapply.+0.5eachcorrectline

__X__Ba2+

_____Ba(OH)2

__X__OH
_____H+

_____HBr

_____BaBr2

_____H2O
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__X__Br

2.Considerthefollowing,unbalancedreaction:?Zn(s)+?AgNO3(aq)?Zn(NO3)2(aq)+?Ag(s)

(a)Whichatomisoxidized?Circleone:
Zn

Ag

O
2

+1
0
(b)EachatomofAggoesfromanoxidationstateof

toanoxidationstateof
.

2
(c)Writethebalanced,netionicequationforthisreaction.

+
2+
+2correctspecies
Zn(s)+2Ag (aq)Zn (aq)+2Ag(s)

Ifspeciesarecorrect,+1states,+1coefficients
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3.Breathalyzersworkthroughthereductionofdichromateaccordingtothebalancedreaction:

C2H5OH(aq)+2Cr2O72(aq)+16H+(aq)2CO2(g)+4Cr3+(aq)+11H2O(l)

A10.002grambloodsampleneeded5.04mLof0.06743MCr2O72toreachtheequivalencepoint.

(a)Determinethenumberofmolesofalcohol,C2H5OH,presentattheequivalencepoint.
5.04mL103L0.06743MCr O 2=3.3985104molCr O 2
2 7
2 7
1mL+2MV(1ifmLused)

3.3985104molCr2O721molC2H5OH=1.699104molC2H5OH1.70104molC2H5OH

2molCr2O72

+2moleratio

+1correctsigfigs

1anymissingunits
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(b)Usingyouranswerfrompart(a),determinethemasspercentofalcoholinthebloodsample.

1.70104molC2H5OH46.07gC2H5OH=0.0078319gC2H5OH

1molC2H5OH +2molg(1incorrectMM)

0.0078319gC H OH100%=0.0783%
+1sameSFaspart(a)
2 5
10.002gblood
+2masspercentsetup
+1correctanswer
1missingunits
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4. Calculatetheoxidationstates,including+/signs,ofeachindividualatomindicatedbelow.

MnO4

H3PO4

+1eachbox

+1
+5
+7
2
2

5
eacheacheach

eacheach
H
PO

MnO

5.Considerthefollowingbalancedchemicalequation(Al2(CO3)3=233.99g/mol):

3K2CO3(aq)+2Al(NO3)3(aq)6KNO3(aq)+Al2(CO3)3(s)

(a)If15.0mLof0.200MK2CO3aremixedwith15.0mLof0.150MAl(NO3)3,whatisthelimiting
reactant?Showallofyourwork.
15.0mL103L0.200MK2CO31molAl2(CO3)3=0.00100molAl2(CO3)3wouldbemadeifall

theK2CO3isusedup
1mL

3molK2CO3

+2MV(1ifmLused)

+2moleratio

15.0mL103L0.150MAl(NO3)31molAl2(CO3)3=0.001125molAl2(CO3)3wouldbemadeif
alltheAl(NO3)3isusedup
1mL

2molAl(NO3)3

+2moleratio
+2MV(1ifmLused)

SincetheK2CO3produceslessproduct,K2CO3isthelimitingreactant.

Ifsetupiscorrect,+1correctL.R.

1foranymissingunits,1incorrectcalculationwithcorrectsetup

(b)Explain,indetail,yourprocessforfindingthelimitingreactantinpart(a).Explainthelogic
andcomparisonsbehindyourcalculations,notjustwhatthecalculationsare.
Inonestep,assumingthatalltheK CO isthelimitingreactant,wefoundhowmanymolesofthe
2
3
Al2(CO3)3productcouldbemadeifalltheK2CO3isusedup.

Inanotherstep,weassumedthattheAl(NO3)3isthelimitingreactantandfoundhowmanymolesof
Al2(CO3)3couldbemadeifalloftheAl(NO3)3isusedup.

Comparingthesetwoamounts,thelimitingreactantwillproducethesmalleramountofaproduct.
+0,+2,or+4

(c)Whatisthepercentyieldifyoucollect0.200gramsofsolid?(Al2(CO3)3=233.99g/mol)

0.00100molAl2(CO3)3233.99gAl2(CO3)3 =0.23399gAl2(CO3)3

1molAl2(CO3)3
+2molg

0.200gAl2(CO3)3collected100%=85.5%
0.23399gAl2(CO3)3theoretically
+2percentyieldsetup
+1for3significantfigures

1calculationerrorwithcorrectsetup;1missingunits
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6.Chloromethane,anorganicsolvent,containsonlyC,H,andCl.Ifthecombustionofexactly
1gramofthiscompoundproduces0.01981molCO2and0.02971molH2O,howmanygramsof
chlorineatomsarefoundinthissampleofchloromethane?
0.01981molCO 1molC12.01gC=0.237918gC
2

1molCO21molC

+2molCO2molC +2molCgC
0.02971molH2O2molH1.008gH=0.0598954gH

1molH2O1molH

+2molH2OmolH +2molHgH
1.000000000000000gC

xHyClz
0.237918gC
0.0598954gH
0.70220464gCl0.7022gCl

+2subtraction

1calculationerrorwithcorrectsetup
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MultipleChoiceInstructions:CLEARLYwritethebestanswerchoiceinCAPITALlettersonthe
linebesideeachproblemnumber.Circledanswerswillnotbegraded.Eachquestionisworth4
points.

____D___7.Rankthefollowingfromlowesttohighestnumberofoxygenatoms:

II.0.5molO3molecules

III.1molH2O
I.61023CO2molecules

(A)I<II<III

(B)II<I<III

(C)I<III<II
(D)III<II<I

(E)III<I<II

____D___8.Supposeyouhavethereactionofaqueousbariumhydroxideandaqueouszincsulfate.
Whichtestdefinitivelytellsyouwhichreactantisinexcess?

(A)connecttheleadsofalightbulbintotheresultingsolution
(B)addsilvernitrateandasolidprecipitates
(C)addsodiumcarbonateandasolidprecipitates
(D)addbariumnitrateandasolidprecipitates
(E)boiloffthewaterandweighthesaltleftover

____B___9.Ifacompanywantstoproduce40,800kgofViagraeachyearandthepercentyieldfor
theprocessis54.8%,whatshouldyouaimforasyourtheoreticalyieldofViagra?

(B)74,500kg
(C)63,200kg
(D)40,800kg
(E)22,400kg
(A)2.24106kg

____A___10.HowmanymolesofLiOHwillbeproducedif0.550molLireactsaccordingtothe
followingequation?
2Li(s)+2H2O(l)2LiOH(aq)+H2(g)

(A)0.550mol
(B)1.10mol
(C)0.275mol
(D)2.20mol
(E)2.00mol
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____D___11.WhichofthefollowingisTRUEaboutthereactionbelow?

N2(g)+3H2(g)2NH3(g)

(A)Forevery1gramofN2usedup,3gramsofH2willbeusedup.
(B)Forevery2gramsofN2usedup,1gramofNH3willbeproduced.
(C)Forevery1moleofN2usedup,1moleofNH3willbeproduced.
(D)Forevery1moleofN2usedup,3molesofH2willbeusedup.
(E)Forevery2molesofH2usedup,3molesofNH3willbeproduced.

____C___12.1.00Mammoniumcarbonatebreaksintowhatspeciesinsolution?

(B)2.00MNH3,1.00MH2CO3
(A)2.00MN3,8.00MH+,1.00MC4+,3.00MO2
(C)2.00MNH4+and1.00MCO32

(D)1.00MNH3,1.00MH2CO3
+
2
(E)1.00MNH4 and1.00MCO3

____C___13.Whichoftheseactionsdecreasestheconcentrationofasolution?

(A)addingmoreofthesameconcentrationsolutiontotheoriginalsolution
(B)pouringouthalfoftheoriginalsolution
(C)addingwatertotheoriginalsolution
(D)addingmoresolidsoluteintotheoriginalsolution

____E___14.ThelabelonabottlereadsMOH,andyousetouttofindtheidentityofthemetal
(M).Assumingthatthisisanalkalimetalhydroxide,youweighout6.27gramsofthesolid.It
takes0.0418Lof1.00MHCltotitratethemetalhydroxide.Whatistheidentityofthesolid?

(A)LiOH

(B)NaOH

(C)KOH

(D)RbOH

(E)CsOH

____C___15.Whatarethespectatorionsforthefollowing,balancedreaction?Notethatthestates
oftheproductshavebeenpurposelyomitted.

2KOH(aq)+MnCl2(aq)Mn(OH)2(?)+2KCl(?)

II.OH
III.Mn2+
IV.Cl
I.K+

(A)IandII
(B)IIandIII
(C)IandIV
(D)IIIandIV
(E)I,II,III,IV

____B___16.Whatvolume,inmLofa1.20MHClsolutionmustbedilutedinordertoprepare
1.00Lof0.0150MHCl?

(A)15.0mL
(B)12.5mL
(C)12.0mL
(D)85.0mL
(E)115mL
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