Q.1.

Write the cell symbol for the following galvanic cell reaction: Cu + 2AgNO3 Cu (NO3)2 + 2Ag [1]

Q.2. It is preferable to determine the change in enthalpy than change in internal energy. Why? [1]

Q.3. Why are lithium salts commonly hydrated and those of the other alkali metal salts are usually anhydrous? Q.4. Draw the structure of BeCl2 in solid state. [1] [1]

Q.5. What is the effect of increasing temperature on G for an exothermic reaction for which S is negative. Q.6. (a) Give an example of electrolyte used in salt bridge. [2] [1]

(b) Write two functions of salt bridge.

Q.7. A swimmer coming out from a pool is covered with a film of water weighing above 18g. How much heat must be supplied to evaporate this water at 298K? Calculate the internal energy of vaporization at 100oC. vapK for water at 100oC is 40.66 kJ / mol. Q.8. Kc for the reaction H2(g) + I2(g) same temperature. Q.9. For the equilibrium reaction N2(g) + 3H2(g)
[1]

[2]

2HI(g) at given temperature is 49. H2 (g) + I2(g) at the

Calculate Kc for the reaction HI(g)

2NH3(g) the partial

pressure of N2(g) and NH3(g) at equilibrium are 0.80 and 1.6

atmospheres respectively at constant temperature. If total pressure of the system at equilibrium is 2.8 atm. Calculate Kp for the reaction. Q.10. [2]

List any two chemical properties in which lithium and magnesium resembles? [2]

Q.11.

Eo for Cl2/Cl-, I2 / I-, Ag+ / Ag, Na+ / Na and Li+ / Li are +1.36V, + 0.53V, +0.79V, -2.71V and -3.0 V respectively. Arrange these ionic species in decreasing order of their reducing agent. [2] [13=3]

Q.12. (a) (c) Q.13. Q.14. (a) (c) Q.15. (a) (c) Q.16.

Define and illustrate: Hesss law of constant heat summation. Adiabatic process.

(b) Extensive properties

Derive the relationship between Cp and Cv for an ideal gas. What happens when (give balanced chemical equations only) Potassium superoxide is treated with water. Chlorine gas is passed through slaked lime. Give reason for: Be2+ resembles Al3+ diagonally. Magnesium do not impart colour to the flame. (a) Explain why pure solid and liquids can be ignored while
[2]

[3]

(b) Lithium carbonate is heated. [13=3] [13=3]

(b) Potassium carbonate cannot be prepared by solvay process.

writing expression for equilibrium constant.

(b)

Derive relationship between Kp and Kc.

[1+2=3]

Q.17.

0.068 moles of PCl5 are allowed to dissociate in a 2 litre closed vessel at 510 K. At equilibrium 0.2 moles of PCl5 are dissociated. Calculate Kc for the reaction. PCl5(g) PCl3(g) + Cl2(g) [3]

Q.18.

Balance the following redox reaction by using any method. Also show appropriate steps of the method used: PH3 + H2PO2- (in basic medium) OR MnO4- + IMnO2 + I2 (in basic medium) [5]

P4 + OH-

Q.19.

(a)
(b)

Draw a neat diagram of bomb calorimeter used to measure q/v of substance. Give any six labellings. The equilibiurm constant for the reaction is 10. What will be value of Go? R = 8.314 JK- mol-1, T = 300K. [3+2=5] OR Calculate the enthalpy of formation of acetic acid if its enthalpy of combustion is -867 kJ / mol. Enthalpy of formation of CO2 and H2O are -393.5 and -285.9 kJ/mol.

(a)

(b)

Calculate the enthalpy of formation of SO3 from S8 and O2. S8 + 8O2 8SO2 H = -2775 kJ 2SO2 + O2 2SO3 H = -198 kJ Define Le Chateliers principle. [1+2+2=5]

Q.20.

(a)

(b) Apply Le-Chateliers principle to Habers process for obtaining maximum yield of ammonia.

[3]

(c)

N2(g) + 3H2(g)

2NH3(g), Kp = 4.310-3. If PN2, PH2

and PNH3 at any time is 0.5, 3.0 and 0.5 atm. Predict the direction in which reaction will proceed. Justify your answer. OR
(a)

What is the relation between Kp and Kc for the reaction: NH4HS (s) NH3(g) + H2S(g)

(b)

Apply Le-Chatelier principle to the given equation so as to obtain maximum yield of SO3. 2SO2(g) + O2(g) 2SO3(g) + 193.2 kJ

(c)

A sample of HI(g) is placed in flask at a pressure of 0.2 atm. At equilibrium, the partial pressure of HI is 0.04 atm. What is Kp for the given equilibrium 2HI(g) H2 + I2(g)

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[4]