Guru Nanak Engineering College

Ibrahimpatnam, Ranga Reddy District – 501 506 (A. P.)

COURSE FILE (2008-2009)

NAME OF THE FACULTY : B. SRINIVAS

DESIGNATION : ASSISTANT PROFESSOR

DEPARTMENT : HUMANITIES & SCIENCES

SUBJECT CODE : CE 05219

SUBJECT NAME : ENGINEERING CHEMISTRY

YEAR : Ist YEAR ME

 1. Target:

S. No Division No. of Students

a. First Division with Distinction 16
b. First Division 34
c. Pass Disvision 16

2. Course plan:
a. Teaching the students in the class
b. Explain the lesson using examples
c. Explain the practical applications.
d. Presentations through OHP, LCD projector
e. Guest lecture s on industrial related topics

3. Method of evaluation:

a. Internal examinations (Objective type)

b. Weekly Assignments (from previous question papers)
c. Final examination (Theory/Descriptive type)
4. Course Objective:
On completion of this course the student shall be able to:

a. Understand the role of chemistry in the field of engineering.

b. Develop analytical capabilities

c. Understand the various water treatment processes

d. Characterize, transfer and use of materials in engineering and apply

knowledge in solving engineering problems.

e. Understand the quality of lubricants.

f. Understand the different polymers and their uses..

g. Understand the hich material is corrosion resistant.

h. Understand the purity of coal.

 SYLLABUS
(CM 05219) ENGINEERING CHEMISTRY(JNTU) 2007-08
UNIT I
Water Technology-I : Introduction, Effect of Water on Rocks and Minerals, Types of impurities in Water,
Hardness of Water – Temporary and Permanent hardness. Units and Inter conversions of Units. Estimation of
hardness by EDTA Methods. Problems on Temporary and Permanent hardnesses. Analysis of Water -
Alkalinity; Chlorides and Dissolved Oxygen. Disadvantages of Hard Water. Methods of Treatment of Water for
Domestic Purposes-Sedimentation, Coagulation, Filtration, Disinfection - Sterilization, Chlorination, Break –
point Chlorination, Ozonization.
UNIT II
Water Technology-II : Water for Industrial purposes - Water for Steam Making - Boiler Troubles – Carry Over -
Priming and Foaming, Boiler Corrosion, Scales and Sludges, Caustic Embrittlement. Water Treatment: -
Internal Treatment – Colloidal, Phosphate, Calgon, Carbonate, Sodium aluminate Conditioning of Water.
External Treatment - Lime-Soda Process, Zeolite Process, Ion-Exchange Process; - Numerical Problems.
UNIT III
Science of Corrosion : Definition, Examples - Types of Corrosion: Theories of Corrosion and Mechanism –
Dry Corrosion, (Direct Chemical attack), Wet Corrosion, (Electro Chemical Theory) Principles of Corrosion,
Galvanic Series, Galvanic Corrosion, Concentration Cell Corrosion, Mechanism of Wet Corrosion – Hydrogen
evolution type, Oxygen absorption type. Factors Influencing Corrosion. Control of Corrosion – Proper Design,
Use of pure metal and metal alloys, Passivity, Cathodic Protection – Sacrificial anode and Impressed Current.
Modifying the Environment, use of Inhibitors.
UNIT IV
Protective Coatings and their applications :
Surface Preparation: (1) Solvent Cleaning (2) Alkali Cleaning (3) Pickling and Etching (4) Sand Blasting (5)
Mechanical Cleaning. Types Of Protective Coatings: Metallic Coatings – Anodic Coatings, Galvanization,
Cathodic Coatings – Tinning, Metal Cladding, Electroplating Ex: Chromium Plating, Metal Spraying,
Cementation–Sheradizing, Colourizing, Chromizing, Chemical Conversion Coatings: (1) Phosphate (2)
Chromate (3) Anodized Coatings.
Organic Coatings: Paints – Constituents and their functions
UNIT V
Polymer Science and Technology : Polymerization Reactions – Basic concepts. Types of Polymerization –
Addition and Condensation Polymerizations. Plastics –Thermosetting and Thermoplastics – Differences.
Compounding and Moulding of Plastics – Compression, Injection, Transfer, and Extrusion moulding
methods.Preparation, Properties and Engineering Uses of the Following: Polyethylene, PVC, Teflon, Bakelite,
Nylon, Polyester, Polyurethanes and Silicone Resins.Rubber – Processing of Natural Rubber, Vulcanization
and Compounding. Elastomers – Buna S, Buna N, Thiokol.
UNIT VI
Refractories and Insulators : Refractories – Definition, Classification With Examples; Criteria of a Good
Refractory Material; Causes for the failure of a Refractory Material; Insulators – Definition and Classification
with Examples; Characteristics of Insulating Materials; Thermal Insulators, Electrical Insulators – Their
Characteristics and Engineering Applications.
UNIT VII
LUBRICANTS :Principles and function of lubricants - Types of Lubrication and Mechanism – Thick Film or
Hydrodynamic Lubrication, Thin Film or Boundary Lubrication, Extreme Pressure Lubrication. Classification
and properties of lubricants – Viscosity, flash and fire points, cloud and pour points, aniline point, Neutralisation
Number and Mechanical Strength.
UNIT VIII
Fuels and Combustion : Definition and Classification.
1. Solid Fuels – Coal – Proximate and Ultimate Analysis of Coal and Significance of the Constituents –
Metallurgical Coke – Characteristics & Manufacture.
2. Liquid Fuels – Petroleum – Refining – Knocking – Octane and Cetane
Numbers – Synthetic Petrol Cracking– Bergius Process, Fischer- Tropsch Process.
3. Gaseous Fuels Natural gas, Coal gas – Calorific Value of
Fuels – Bomb Calorimeter – Junker’s Gas Calorimeter.
4.Combustion – Analysis of Flue Gas by Orsat’s Apparatus ; Problems.
6.Guidelines to students:

a. They should attend all the class to understand and learn basics of this
Course.

b. They should go through different reference books, internet browsing,

Journals, news papers to acquire the best and latest knowledge of the
Subject.

c. They should learn the things in the practical approach besides theory.

d. They should gain knowledge by using internet, news papers and journals.
7. BOOKS/REFERENCES/MATERIALS

TEXT BOOKS :
1. Text Book of Engineering Chemistry by Jain & Jain. Dhanpat Rai Publishing
Company, New Delhi
(2004).
2. Text Book of Engineering Chemistry by C.P. Murthy, C.V. Agarwal, and Andra
Naidu & B.S. Publications, Hyd (2005).

REFERENCES :
1. A Text Book of Engineering Chemistry by S.S. Dara. S.Chand & Co, New Delhi
(2006) ( 15th Edition).
2. Engineering Chemistry by J C Kuriacose and J. Rajaram, Tata McGraw-Hill Co,
New Delhi (2004)
3. A Text Book of Engineering Chemistry by Balaram Pani, Galgotia Publications,
New Delhi (2004).
4. A Text Book of Engineering Chemistry by Shashi Chawla, Dhanpat Rai
Publishing Company, New
Delhi (2004).
5. Industrial Chemistry by O.P.Veeramani and A.K.Narula, Galgotia Publications,
New Delhi (2004).
6. Advanced Engineering Chemistry by Senapati and Mohanty, Laxmi Publications,
New Delhi (2002).
7. Engineering Chemistry by R. Gopalan, D. Venkappaya and S.Nagarajan, Vikas
Publishing House,
New Delhi (2004).
8. Engineering Chemistry by R.V. Gadag A.N. Tyanand Shortly IK. International
Publishing house Pvt. Ltd.
New Delhi.

SUGGESTED WEB SITES:

WWW.GURUNANAK-CHEMISTRY.BLOGSPOT.COM
WWW.CHEMISTRYMASTER.BLOGSPOT.COM
WWW.ENGINEERINGCHEMISTRY.BLOG.CO.IN
WWW.APPLIEDCHEMISTRY.BLOG.CO.IN
WWW.CHEMISTRYABOUT.COM
WWW.MSENCARTA.COM
WWW.WIKIPEDIA.COM
WWW.CHEMISTRY.CALTECH.EDU
WWW.CHEM.VT.EDU
 COURSE SCHEDULE
Number of hours / Lectures available in this Year
Distribution of hour’s unit wise
Text Books (to be acquired by the Students)

Book 1 Text Book of Engineering Chemistry By Jain &Jain Publishers:Dhanpat Rai

Text Book of Engineering Chemistry By C..P.Murthy , C.V.Agrawal,and AndhraNaidu & B.S
Book2
publication.
Text Books for references
Book 3 Text book of Engineering Chemistry By S.S.Dara Publishers:Chand
Book 4 A Text book of Engineering Chemistry by Balaram Pani, Galgotia publishers
Book 5 Text book of Engineering Chemistry By Shashi Chawla Publishers Dhanpat Rai & Co
Book 6 Industrial chemistry by O.P. Veeramani and A.K.Narula, Galgotia publishers
Book 7 Advanced Engineering Chemistry By Senapathi and Mohanty, Laxmi publishers.
Book 8 Engineering Chemistry By R.gopalan, D.Venkappaya and S.Nagarajan, Vikas publishers

Chapters No of
Unit Topic Classes
B-1 B-2 B-3 B-4 B-5 B-6 B-7 B-8
Water Technology-
I 1 2 1 17 6 1 14 18 6
I
Water Technology-
II 1 2 1 17 6 1 14 18 6
II
Science of
III Corrosion 7 8 4 16 17 - 11 6 5
Protective
IV Coatings and their 8 8,9 4 21 - - - 7 5
applications
Polymer Science
V 3 9 9 11 1 5 12 16 8
and Technology

Refractories &
VI 11 10,1 16 15 8,14 - - 11 5
Insulators

VII Lubricants 10 7 5 20 7 - - 13 5

Fuels &
VIII 2 3,4 2 12 5 3 13 14 7
Combustion
Classes for above curriculum topics 03
Descriptive tests 06
On – line tests 03
Revisions 03
Total no of classes 62

• Indicates Tutorial Class

 LESSON PLAN
Name of the Unit Name of the topic No.of Cumul.
classe classes
Unit- I 1.1. Sources, impurities in water 1 1
Water technology-I 1.2. Water quality- hardness, 1 2
units and its determination
1.3. Estimation of hardness by 1 3
soap solution and EDTA methods
1.4. Problems on Hardness 1 4
1.5. Analysis of alkalinity, 1 5
chlorides and D.O
1.6. Methods for treatment of 1 6
water for domestic purpose.
Unit –II 2.1. Water for industrial purpose, 1 7
Water Technology –II Boiler problems
2.2. Water treatment- Internal 1 8
treatment
2.3. External water treatment- 1 9
Lime soda
2.4. Zeolite process 1 10
2.5. Ion-exchange process, 1 11
2.6. Numerical problems in lime 1 12
soda process
Unit-III 3.1. Introduction , Corrosion 1 13
Science of corrosion definition, Types of corrosion,
Chemical corrosion
3.2. Electrochemical corrosion 1 14
3.3. Types of electro chemicals 1 15
corrosion (Galvanic, pitting
corrosion, Crevice, concentration
cell, waterline corrosion
3.4. Inter granular, Stress, 1 16
Underground Corrosion,
Microbiological, erosion corrosion
3.5. Factors affecting corrosion 1
Sacrificial anodic, Impressed 17
current cathodic protection
Unit-IV 4.1. (1) Solvent Cleaning (2)
Protective coatings and Alkali Cleaning (3) Pickling 1 18
their application and Etching(4) Sand Blasting
(5) Mechanical Cleaning.
4.2. Types Of Protective
Coatings: Metallic Coatings – 2 19
Anodic Coating Galvanization,

4.3.Cathodic Coating – Tinning,

Metal Cladding, Electroplating 2 20
Ex: Chromium
Plating, Metal Spraying,
Cementation–Sheradizing,
Colourizing, Chromizing
4.4. Chemical Conversion
Coatings: (1) Phosphate (2) 2 21
Chromate (3) Anodized Coatings.
4.5. Organic Coatings: (1) Paints 22
– Constituents and their functions 1
Unit-V 5.1. Polymerization, Types of 1 23
Polymer Science and polymerization- additional
Technology polymerization
5.2. Step growth polymerization, 1 24
Chain growth polymerizatioN
5.3. Plastics- Definition, 1 25
classification, Thermo and
Thermosetting plastics,
Compounding plastics
5.4. Composition, properties, 1 26
engineering uses of Poly-
ethylene
5.5. P V C, Teflon, Bekalite, 1 27
Nylon,
5.6. poly ester , polyurethane, 1 28
Silicon resins,
5.7.Processing of natural rubber 1 29
Vulcanization of rubber,
Compounding of rubber
5.8. Elastomers- Buna-S, Buna- 1 30
N , Thiokol,
Unit-VI 6.1. Refractories- Definition, 1 31
Refractories and Classification
Insulators 6.2. Criteria for a good 1 32
refractory material
6.3. Causes for the failure of a 1 33
refractory material
6.4. Insulators- Thermal insulator 1 34
6.5. Electrical Insulators 1 35
Unit- VII 7.1.Pinciples and factions of 1 36
Lubricants lubricants - Types of Lubrication
and Classification
7.2. Lubricants Mechanism – 1 37
Thick Film or Hydrodynamic
Lubrication,
7.3. Lubricants Thin Film or 1 38
Boundary Lubrication, Extreme
Pressure Lubrication.
7.4. properties of Lubricants – 1 39
Viscosity – Flash and Fire points
– Cloud and Pour points
7.5. Aniline-Point-, Neutralization 1 40
number and Mechanical strength.
Unit-VIII 8.1. Fuels-Definition, 1 41
Fuels and combustion classification
8.2. Solid fuels- coal formation
8.3. Analysis of coal- Proximate 1 42
analysis, 8.4. Ultimate analysis
8.5. Metallurgical coke, 1 43
8.6. liquid fuels- petroleum origin,
8.7. Refining of petroleum 1 44
8.8. Cracking of petroleum
8.9. Knocking, Octane, Cetane
numbers
8.10. Synthetic gasoline- Fischer- 1 45
Tropsch process
8.11. Bergious process, gaseous
fuels
8.12. Analysis of the gas by 1 46
Orsats Apparatus
8.13. Calorific value of fuels- 1 47
Bomb calorimeter
8.14. Junker’s calorimeter,
Combustion- problems
TOPIC WISE COVARAGE:
UNIT – I

Hour Date Topic Reference

No. s
1 1.1. Sources, impurities in water 1,2,3,4,5
2 1.2. Water quality- hardness, units and its
determination
3 1.3. Estimation of hardness by soap solution and
EDTA methods
4 1.4. Problems on Hardness
5 1.5. Analysis of alkalinity, chlorides and D.O
6 1.6. Methods for treatment of water for domestic
purpose.
REVISION

UNIT – II

Hour Date Topic Reference

No. s
7 2.1. Water for industrial purpose, Boiler problems 1,2,3,4,5
8 2.2. Water treatment- Internal treatment
9 2.3. External water treatment- Lime soda
10 2.4. Zeolite process
11 2.5. Ion-exchange process,
12 2.6. Numerical problems in lime soda process
REVISION
UNIT – III

Hour Date Topic Reference

No. s
13 3.1. Introduction , Corrosion definition, Types of 1,2,3,4,5
corrosion, Chemical corrosion
14 3.2. Electrochemical corrosion
15 3.3. Types of electro chemicals corrosion (Galvanic,
pitting corrosion, Crevice, concentration cell,
waterline corrosion
16 3.4. Inter granular, Stress, Underground Corrosion,
Microbiological, erosion corrosion
17 3.5. Factors affecting corrosion
Sacrificial anodic, Impressed current cathodic
protection
REVISION

UNIT – IV

Hour Date Topic Reference

No. s
18 4.1. (1) Solvent Cleaning (2) Alkali Cleaning (3) 1,2,3,4,
Pickling and Etching(4) Sand Blasting (5)
Mechanical Cleaning.
19 4.2. Types Of Protective Coatings: Metallic Coatings
– Anodic Coating Galvanization,

20 4.3.Cathodic Coating – Tinning, Metal Cladding,

Electroplating Ex: Chromium
Plating, Metal Spraying, Cementation–Sheradizing,
Colourizing, Chromizing
21 4.4. Chemical Conversion Coatings: (1) Phosphate
(2) Chromate (3) Anodized Coatings.
22 4.5. Organic Coatings: (1) Paints – Constituents and
their functions
REVISION

UNIT – V
Hour Date Topic Reference
No. s
23 5.1. Polymerization, Types of polymerization- 1,2,3,4,5
additional polymerization
24 5.2. Step growth polymerization, Chain growth
polymerizatioN
25 5.3. Plastics- Definition, classification, Thermo and
Thermosetting plastics, Compounding plastics
26 5.4. Composition, properties, engineering uses of
Poly-ethylene
27 5.5. P V C, Teflon, Bekalite, Nylon,
28 5.6. poly ester , polyurethane, Silicon resins,
29 5.7.Processing of natural rubber Vulcanization of
rubber, Compounding of rubber
30 5.8. Elastomers- Buna-S, Buna-N , Thiokol,
REVISION
UNIT – VI
Hour Date Topic Reference
No. s
31 6.1. Refractories- Definition, Classification 1,2,3,4,5
32 6.2. Criteria for a good refractory material
33 6.3. Causes for the failure of a refractory material
34 6.4. Insulators- Thermal insulator
35 6.5. Electrical Insulators
REVISION
UNIT – VII
Hour Date Topic Reference
No. s
36 7.1.Pinciples and factions of lubricants - Types of 1,2,3,4,5
Lubrication and Classification
37 7.2. Lubricants Mechanism – Thick Film or
Hydrodynamic Lubrication,
38 7.3. Lubricants Thin Film or Boundary Lubrication,
Extreme Pressure Lubrication.
39 7.4. properties of Lubricants – Viscosity – Flash and
Fire points – Cloud and Pour points
40 7.5. Aniline-Point-, Neutralization number and
Mechanical strength.
REVISION

UNIT – VIII
Hour Date Topic Reference
No. s
41 8.1. Fuels-Definition, classification 1,2,3,4,5
8.2. Solid fuels- coal formation
42 8.3. Analysis of coal- Proximate analysis, 8.4.
Ultimate analysis
43 8.5. Metallurgical coke,
8.6. liquid fuels- petroleum origin,
44 8.7. Refining of petroleum
8.8. Cracking of petroleum
8.9. Knocking, Octane, Cetane numbers
45 8.10. Synthetic gasoline- Fischer- Tropsch process
8.11. Bergious process, gaseous fuels
46 8.12. Analysis of the gas by Orsats Apparatus
47 8.13. Calorific value of fuels- Bomb calorimeter
8.14. Junker’s calorimeter, Combustion- problems
REVISION
Actual Date of Unit Completion and Remarks

UNIT – I Water Technology-I

Actual Date :
Completion Date :

Remarks: Total classes held :

As per Teaching Schedule Total No. of Hours: 6

UNIT – II Water Technology-II

Actual Date :
Completion Date :

Remarks: Total classes held :

As per Teaching Schedule Total No. of Hours: 6

UNIT – III Science of Corrosion

Actual Date :
Completion Date :
Remarks: Total classes held :
As per Teaching Schedule Total No. of Hours: 5

UNIT – IV Protective Coatings and their applications

Actual Date :
Completion Date :

Remarks: Total classes held :

As per Teaching Schedule Total No. of Hours: 5

UNIT – V Polymer Science and Technology

Actual Date :
Completion Date :

Remarks: : Total classes held :

As per Teaching Schedule Total No. of Hours: 8

UNIT - VI Refractories & Insulators

Actual Date :
Completion Date :
Remarks: : Total classes held :
As per Teaching Schedule Total No. of Hours: 5

UNIT - VII Lubricants

Actual Date :
Completion Date :

Remarks: : Total classes held :

As per Teaching Schedule Total No. of Hours: 5

UNIT – VIII Fuels and Combustion

 Actual Date :

Completion Date :

Remarks: : Total classes held :

As per Teaching Schedule Total No. of Hours: 7

Assignments
UNIT-I WATER TECHNOLOGY - I
1. a) What is meant by “hardness” of water. And what are the disadvantages of hard water.? b)
Week -1 Distinguish between temporary and permanent hardness of water. C) What are its units? D) How
do you express the hardness of water?
2. (a) What is the principle of EDTA method? Explain the estimation of hardness
of water by complex metric method.
(b) Mention the dis-advantages of using hard water for industrial purpose.
3. (a) Explain the terms temporary and permanent hardness of water. (b) How do you
estimate the temporary hardness of water by EDTA method? (c) 50 ml of a sample of
hardwater was titrated against 0.01 M EDTA, required 48 ml of EDTA for titration. 50 ml
of the same hardwater after boiling and filtering etc. required 35ml of the EDTA for
titration. Calculate the total and temporary hardness of water in degree Clark.
1. (a) Estimation of free chlorine in water samples.
(b) Discuss the impurities in water and their effects.
Week-2 c. Explain the sedimentation process for the treatment of municipal water
2. Write a short notes on the following: (a) Break - point chlorination (b)
Dissolved oxygen (c) Hardness of water (d) Sedimentation and coagulation.
1. What is meant by disinfection? What is its significance? Explain the different methods used for
disinfection of surface water.
2. (a) Why is sterilization of water necessary? Discuss any two methods of
sterilisation. (b) 0.5 g of CaCO3 was dissolved in dil.HCl and diluted to 1000 mL.
50 mL of this solution required 48 mL of EDTA solution for titration. 50 mL of
hard water sample required 15 mL of EDTA solution for titration. 50 mL of same
water sample on boiling, filtering etc, required 10 mL of EDTA solution.
Week-3
Calculate
the different kinds of hardness in ppm.

Date of submission
Date of valuation of Assignment
UNIT-II WATER TECHNOLOGY - II
1. Write short notes on the following:
a) Carry over b) Phosphate conditioning (c) Caustic embrittlement
Week-4
2. a) Write short notes on Internal treatment methods
b) State the disadvantages of scale formation in boilers.
Week-5 1. (a) Describe the demineralisation of water by ion - exchange method.
(b) Mention the disadvantages of using hard water for any two industries
2. Explain the Ion-exchange method for the removal of dissolved impurities and its
 advantages over lime soda process
3. (a) Explain the cold lime soda process and hot lime soda process. What are the
advantages of lime soda process? (b) 100 ml of a water sample contains hardness
equivalent to 25 ml of 0.08 N MgSO4. [8+8]
i. What is the hardness of water sample in ppm? ii. What is the amount of lime and soda
required for the treatment of the water sample?
3. Explain the Ion-exchange method for the removal of dissolved impurities and its
Advantages over lime soda process. [16]
1) a) What is the chemical composition of Zeolite? How are they classified? Explain the mechanism of the
treatment of hard water by Zeolites.
b) A Zeolite softener was exhausted and regenerated by passing 100 liters of NaCl solution containing 585
gms per liter. Calculate the total hardness of the water sample in ppm, if the Zeolite softener can soften 1000
liters of water before regeneration.
2) Write a comparative statement on lime soda & Zeolite process.
3) Calculate the lime and soda needed for softening 50,000 litres of water containing the following salts:
CaSO4 = 136 mg/lit; MgCl2 = 95 mg/lit; Mg(HCO3)2 = 73 mg/lit; Ca(HCO3)2= 162 mg/lit. Given that the molar
mass of Ca(HCO3)2 is 162 and that of MgCl2 is 95
Week-6 4) Determine the amount of soda and lime required in Kg’s to soften 5000 lit of water containing the following
salts MgCl2 = 15.5 ppm, Ca(Hco3)2 = 32.5 ppm, Ca(No3)2 = 22.4 ppm, NaCl = 50 ppm, KCl = 22.5 ppm.

Date of submission

Date of valuation of Assignment

UNIT-III SCIENCE OF CORROSION
1) Explain the process of wet corrosion by evolution of hydrogen and absorption of oxygen
(or) Describe the electrochemical theory of corrosion.
2) Differentiate the following with suitable examples. a) Galvanic series and electrochemical series. b) Pitting
corrosion ad stress corrosion.
Week-7
3)(a) What is meant by differential aeration corrosion? Illustrate with suitable
examples. (b) How is rate of corrosion influenced by i. Nature of corrosion
product ii. Relative anodic to cathodic areas iii. Temperature and moisture.

4) (a) What is oxidation corrosion and how does it take place? Describe the
mechanism of oxidation corrosion. (b) Describe the various factors influencing
Week-8
the rate of chemical corrosion.
5) Write down the equation for the hydrogen evolution in an electro chemical corrosion reaction?
1. What are the factors effecting corrosion?
2. a) Explain the following factors influencing the rate of corrosion. i. Nature of
corrosion product ii. Position in electrochemical series iii. pH. (b) Differentiate
Week-9 between dry corrosion and wet corrosion
3. Define corrosion? Explain any 4 factors that affect the rate of corrosion & explain
any 4 corrosion control methods.
 1. Explain how corrosion control can be brought about by the following methods.
a) Modifying the environment b) Cathodic protection.
2. Write a short note on Inhibitors & Cathode protection.

Week-10

Date of submission

Date of valuation of Assignment

UNIT-IV PROTECTIVE COATINGS AND THEIR APPLICATIONS
Explain the protective coatings you would choose for steel; cast iron and concrete pipe. Give reasons
Week-11
for your answer.
1.(a) Describe the mechanism of drying of conjugated oils. (b) Name any four important drying oils.
(c) Define the following:i. Acid value of an oil ii. Saponification Value iii. Iodine Value.
2. Write notes on Surface preparation.
Week-12
3. (a) Discuss how the surface of a metal is prepared prior to the application of a protective
coating.(b) Write the important applications of protective coating.
(c) Why is moderate current density employed during electroplating?
What is metallic coating? Name the metallic coating methods.
Week-13 2. (a) Describe the process of sheradizing? Mention its applications?(b)
Distinguish between anodizing and electroplating. (c) Define Anodizing
1. (a) What are organic paints? Name their important constituents and their
re-spective functions with an example? (b) Mention the functions of
pigment and vechicle in a paint
Week-14 2. write a short note on Chemical conversion Coatings
Date of submission
Date of valuation of Assignment

UNIT-V POLYMER SCIENCE & TECHNOLGY

1. Write the differences between a) compression-Injection moulding b) additional polymerization-condensation
Week-15 polymerization c) thermoset-thermoplasts.
2. Explain any one of the mechanism of additional polymerization, using suitable example. .
1. Write a note on thermo setting plastics? Write a note on properties and uses of Teflon.
2.Describe the manufacture , properties ,uses of a)polyethylene
Week-16 b) Teflon c) Thiokol d) PVC
3.(a) How is HDPE is prepared? Give its properties and uses? (b) Explain the injection moulding
process with a neat diagram? Mention its advantages.
1.What is moulding of plastics? Explain compression moulding technique in detail.
2.How is Bakelite manufactured? Discuss its important uses and properties.
Week-17
3. Identify the thermosets & thermoplasts among the following: PVC, polyethylene, silicon,
polyester fiber, bakelite. What is Bakelite? How is it manufactured and mention its uses.
1.Describe the preparation, properties and engineering uses of Polythylene.
Week-18 2. (a) Explain the preparation, properties and uses of Bakelite.
(b) Describe with a neat sketch, the process of compression moulding
 1. (a) What are elastomers? Give the preparation, properties and uses of Buna S. (b) Describe a
method for moulding of thermoplastic resin
2. Write a short note on rubber and vulcanization. Write a brief account of elastomers,
silicons.
3 Write preparation, properties and uses of nylon, polyester, and polyurethanes. (a) Why are
Silicones called inorganic polymers? Discuss the synthesis of linear chain Silicones. (b) Why Bakelite
Week-19 can’t be remoulded and write its repeating unit? (c) Describe condensation polymerization with an
example

Date of submission

Date of valuation of Assignment

UNIT-VI REFRACTORIES & INSULATORS

1. Discuss any FOUR essential properties of a good refractory in detail.
Week-20 2. What are electrical insulators? Discuss their characteristics & engineering applications.
3. What are thermal insulators? Discuss their engineering applications and characteristics
1. (a) What are refractories? How important are the properties - refractoriness under load and thermal
conductivity for industrial applications? (b) Compare acidic and basic refractories with examples
Week-21
2.What do you understand by ‘refractoriness’. Explain its measurement.Write a note on ‘refractoriness-under-
load (RUL)’.
1. What are refractories? Explain thermal spalling, strength and porosity of the refractories.
2. (a) What is pyrometric cone equivalent? How it is determined for a refractory? What is its
significance?(b) Write a short note on: i. porosity ii. Thermal Conductivity iii. Dimensional Stability.
iv. Strength
Week-22

Date of submission
Date of valuation of Assignment

UNIT-VII LUBRICANTS
1. Write a short note on principle and function of Lubricants
2. (a) Give the functions of lubricants. (b) Describe the mechanism of extreme pressure lubrication. c)
Week-23 How a viscous lubricant is converted into grease?
3. Write a note on lubricants with special reference to their classification, mode of action,
examples and uses.
1. Explain the various mechanisms of lubrication in detail.
2.Explain the following two theories for the mechanism of the lubricants.
Week-24 a) Boundary lubrication b) Extreme pressure lubrication
3. (a) Give the functions of lubricants. (b) Describe the mechanism of extreme
pressure lubrication. c) How a viscous lubricant is converted into grease?
1.
Define lubricant. Discuss the Classification and important properties of the lubricats

Week-25
Date of submission
Date of valuation of Assignment
UNIT-VIII FUELS & COMBUSTION
What is coal? How it is formed? Discuss the qualities of a good coal.
2. What is metallurgical coke? Describe any one method of manufacturing metallurgical coke.
3. a) Differentiate between proximate and ultimate analysis. b) Calculate
in calorific
Week-26
value of a fuel coal sample having composition? C-80%, H-3.5%, N-1.5%, Ash-7.2% a) What
is knocking? What are its adverse effects? How it is prevented? b) Define Octane and cetane Number. Explain
how it can be improved.
Explain how fuels are classified with suitable examples. (b) Explain the significance of the following
constituents present in coal. i. Moisture ii. Volatile matter iii. Ash and iv. Fixed carbon.
(a) Discuss the relative merits and demerits of solid, liquid and gaseous fuels.
Week-27
(b) Explain the significance of the following constituents present in coal. i. Total carbon ii. Hydrogen
iii. Nitrogen iv. Sulphur and v. Oxygen.

1) Write a short note on Refining. b What is meant by knocking in I.C engine? Explain the mechanism of
knocking in chemical terms.
2.(a) What do you understand by the term knocking in IC engines? Explain its relationship with
Week-28
chemical constituents of fuels. (b) A sample of coal contains 60% carbon, 33% Oxygen, 6.0%
Hydrogen, 0.5%
Sulphur, 0.2% Nitrogen and 0.3% Ash. Calculate GCV and NCV of coal
1Describe the experiment with a neat diagram . (b) Calculate gross and net calorific value of a gaseous fuel
from the following data. Vol of gaseous fuel burnt at STP- 0.09m3, wt of water used for cooling 25.0 kg, Temp
of inlet water 250C, temp of out let water 30.00C wt of water produced by steam condensation 0.02 kg latent
Week-29
heat of steam 587 Kcal/kg
2. With a neat diagram describe the Orsat’s gas analysis method. What are the special precautions to be taken in
the measurement? (a) How calorific value of a gaseous fuel is determined by Junker’s gas calorimeter.
Calculate gross and net calorific value of a gaseous fuel from the following data. Volume of gaseous fuel burnt
at STP – 0.09m3, weight of water used for cooling 25.0kg, temperature of inlet water 250C, temperature of
outlet water 30.00C, weight of water produced by steam condensation 0.02kg, latent heat of steam 587 kcal/kg.
2. (a) Explain Higher Calorific Value and Lower Calorific Value and distinguish the both.
(b) What are the characteristics of a good fuel?
Week-30
Date of submission

Date of valuation of Assignment

TUTORIAL / REVISION CLASSES

S.NO TUTORIAL CLASSES DETAILS

I Estimation hardness by EDTA method.

2 To study about external treatment of water

3 To study about factors influencing the corrosion

4 To study about types of protective coatings.

5 Preparation and properties of polyethylene, pvc, and bakelite.

6 To study about Criteria of a good refractory materials.

7 To study the properties of the lubricants.

8 To study the analysis of the coal.

9 To study about plastics and elastomers

10 Explain the following two theories for the mechanism of the

lubricants.
a) Boundary lubrication b) Extreme pressure lubrication
Tutorial [as many planned per unit]

UNIT-I
WATER TECHNOLOGY-I
1. Estimation hardness by EDTA method
UNIT-II
WATER TECHNOLOGY-II
1. To study about external treatment of water
UNIT-III
SCIENCE OF CORROSION
1. To study about factors influencing the corrosion & Control methods
UNIT-IV
PROTECTIVE COATINGS ANF THEIR APPLICATIONS
1. To study about types of protective coatings & applications.
UNIT-V

POLYMER SCIENCE AND TECHNOLOGY

1
Preparation and properties of polyethylene, pvc, and
bakelite and moulding techniques
UNIT-VI
Refractories & Insulators
1. To study about Criteria of a good refractory materials

UNIT-VII
LUBRICANTS
 1. To study the properties of the lubricants
UNIT-VIII
FUELS & COMBUSTION
1. To study analysis of coal and Orsat’s method