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Fumaric acid
47910 Fluka 607-146-00-X
1.2 2. 2.1
110-17-8 Relevant identified uses of the substance or mixture and uses advised against
Identified uses Laboratory chemicals, Manufacture of substances
HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Eye irritation (Category 2)
2.2
Irritating to eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
2.3 3. 3.1
Fumaric acid
CAS-No. EC-No. Index-No.
4. 4.1
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Further information
no data available
ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
6.3
6.4 7. 7.1
EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Immersion protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: > 480 min Material tested:Dermatril? ( Z677272, Size M) Splash protection Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: > 30 min Material tested:Dermatril? ( Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 873000, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an Industrial Hygienist familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
9. 9.1
PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties
a) b) c) d) e) Appearance Form: solid Odour no data available Odour Threshold no data available pH 2,1 at 4,9 g/l at 20 C Melting point/freezing Melting point/range: 298 - 300 C point f) Initial boiling point and 290 C at 760 hPa - DIN 53171 boiling range g) Flash point 230 C - closed cup - DIN 51755 Part 1 h) Evaporation rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits k) Vapour pressure l) Vapour density m) Relative density n) Water solubility o) Partition coefficient: noctanol/water p) Autoignition temperature q) Decomposition temperature r) Viscosity s) Explosive properties t) Oxidizing properties Upper explosion limit: 40 %(V) Lower explosion limit: 3 %(V) 2,2 hPa at 165 C no data available 1,635 g/cm3 at 20 C 4,9 g/l at 20 C log Pow: 0,3 no data available no data available no data available no data available no data available
9.2
Skin corrosion/irritation
Skin - rabbit - Mild skin irritation - 24 h
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Aspiration hazard
no data available
Potential health effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Ingestion May be harmful if swallowed. Skin May be harmful if absorbed through skin. May cause skin irritation. Eyes Causes serious eye irritation. Signs and Symptoms of Exposure
Gastrointestinal disturbance
Additional Information
RTECS: LS9625000
12. ECOLOGICAL INFORMATION 12.1 Toxicity Toxicity to fish mortality - Danio rerio (zebra fish) - 245 mg/l - 48 h
Method: DIN 38412 Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Growth inhibition EC50 - Desmodesmus subspicatus (green algae) - 41 mg/l 72 h EC50 - Daphnia magna (Water flea) - 73,6 mg/l - 24 h Method: DIN 38412
Contaminated packaging
Dispose of as unused product.
15.
REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
16.