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Agenda
H&R a short Introduction Plasticizers some Basics Plasticizers in different Applications > PC Tyres > Truck Tyres > Transmission Belts > Profiles Conclusion
Introduction of H&R the Highlights 1919 - Foundation of H&R in Hamburg, Germany 1956 - Tudapetrol, the H&R production site 1985 - First production of TDAE under the control of H&R 1994 - Merge of the Salzbergen refinery (BASF) 1996 - First production of MES under the control of H&R 2004 - Merge of the Hamburg refinery (BP) Investment in a large plasticizer production 2005 - Start of the new TDAE production Enlargement of the international production (Thailand, China, Australia, South Africa, ) 2009 - First H&R production in North America
H&R, 2011, TRJ
Blend plant
Sales office
Today, H&R is producing more than 350.000 mt label free plasticizers for rubber applications plus Anti Ozone Waxes. From the top 10 of the tyre industry 10 are on H&Rs customer list. From the top 10 of the technical rubber good producers 10 are on H&Rs customer list.
80 70 60 50 40 30 20 10 0 0 10 20 30 40 50
Basics
50
DAE
40
TDAE
30 20 10 0 100 200 500 1.000 2.000 5.000 10.000
Basics
NAP
AR
HAR
Synth.
0,85
0,90
H&R, 2011, TRJ
0,95
1,00
Viskositt-Dichte-Konstante (VDK)
Basics
paraffinic BR NR/IR SBR naphthenic aromatic highly aromatic synthetic
TDAE
MES
NAP
RAE
0,85 0,90
H&R, 2011, TRJ
0,95
DAE
1,00
RUBBER
FILLER
OIL
CHEMICALS
Performance of PC Tyres
Productivity
110 100 90 80
DAE
Rolling Resistance
70 60
Performance of PC Tyres Commission Regulation (EC) 1907/2006 (formerly EU Directive 2005/69/EC) The ban of Polycyclic Aromatic Hydrocarbons starting 01.01.2010 Similar regulations in Japan and other countries This regulation affects more and more the production of technical rubber goods because more and more auto manufacturers require also cancer free TRG.
H&R, 2011, TRJ
Performance of PC Tyres
EU Tyre Labelling Regulation 1222/2009 starting 01.11.2012 Similar regulations in North America, Japan and other countries
Performance of PC Tyres
Productivity
110 100 90 80
70 60
Retreadability
85 80
Heat Dissipation
70 60
Life Time
H&R, 2011, TRJ
10
Profiles
Productivity
110 100 90 80
Aging Properties
70 60
Abrasion Loss
H&R, 2011, TRJ
Fatigue to Failure
Conclusion
paraffinic BR NR/IR SBR naphthenic aromatic highly aromatic synthetic
TDAE
MES
NAP
RAE
0,85 0,90
H&R, 2011, TRJ
0,95
DAE
1,00
11
EPDM
IIR
(X)IIR
BR
NR
SBR
CR
NBR
+ 0 +
+ 0 +
+ 0 0 0 0
+ + + 0 + 0 +
+ + + 0 + 0 +
+ + 0 0 0 0 -
+ + 0 0/+ -
0 0/+ -
12