Please read the paragraph carefully and answer the following questions with proper explanations.

A student was investigating the speed of reaction between limestone granules and different concentrations of hydrochloric acid. However after doing a whole series of experiments at different acid concentrations, there was no time to do the last planned experiment. The volume of carbon dioxide collected after 5 minutes in a 100 cm3 gas syringe was used to determine the rate of reaction. All the experiments were done in one lesson at a temperature of 22 C except for the last one. This was done in the next lesson, giving a carbon dioxide volume of 47.0 cm3 after 5 minutes, but at a higher temperature of 27 C (when in Kelvin call this T1, and the other temperature T2). To make the data analysis fair, all the gas volumes should be ideally measured at the same temperature, but a correction can be made for the last experiment. 1.The Volume the of 47.0 cm3 of gas at 27 C, would occupy at 22 C. (a) 45.6 cm3 (b) 46.5 cm3 (c) 46.2 cm3 (d) 42.6 cm3 2.If the temperature was ignored, what is the % error in the rate of reaction measurement? (a) +1.7% (b) -1.7% (c) +17% (d) - 17% 3.Would you need to do any correction for the volume of acid added to the limestone? (a) No correction needed for this at all. (b) Yes correction need for this at all. (c) Cant be predicted . (d) None of the above

4. A blown up balloon has a volume of 500ml at 278 K.The balloon is distended to its maximum stretching capacity.Determine the min temp above which it will brust.

5) In the arrhenius eqn which of the following statement is assumed (A) The fraction of efeective collisions having activation energy is equal to the fraction of total collisions having activation energy (B) The fraction of efeective collisions having activation energy is less thanl the fraction of total collisions having activation energy (C) The fraction of efeective collisions having activation energy is more than the fraction of total collisions having activation energy (D) The no of effective collisions are those collisions which lead to the formation of the product

6) Liquid ammonia ionizes to a little extent At -500 C , Its ionic product is KNH3 = [NH4+][NH2-] = 10-30

The no of amide ions present in 1 mm3 of pure liquid NH3 would be A) 10-15 ions/mm3 B) 600 ions/mm3

7) What is the pH of a solution prepared by mixing 0.0100 mol HA (with Ka = 1.00*10 -2) and 0.0100 mol of A- and diluting with water to 1.00 L?

HA

= 0.01

H+

A0.01 0.01(1+x)

t=teq. 0.01(1-x) 0.01x Ka = [H+][A-]/[HA]

=> 10-2 = 0.01x*0.01(1+x)/0.01(1-x) => 10-2 = 10-2 (x+x2)/(1-x) => 1-x = x+x2 => x2+2x-1=0 => x = 2 -1 So pH = -log(0.01x) = 2 - log(x) = 2 - log(0.414) = 2-(-0.38) = 2.38 8) If a cube is made such that small spheres are at the corners and large sphere is at the body centre of the cube, then what is the packing fraction of this system? 1. 0.68 2. 0.74 3. 0.52 4. 0.002

Packing fraction depends on the volume (solid volume).. So contribution of hollow sphere to the PF is negligible So total volume of smaller spheres in the cube = 8*1/8 (corner atoms so contribution of each to one

unit cell = 1/8)*Vsph = Vsph Now as it can be treated as BCC, a3 = 2(R+r) So u can get volume of cube as a3 PF = total volume of smaller spheres in the cube/volume of cube putting the values and taking R=10r we get PF = 0.002

9) Consider a large hollow sphere of radius 'R' in which small solid sphere of radius 'r' has to be placed in closest pascking. ( assume r=R/10) 10) Maximum no. of small spheres that can be filled into the large hollow sphere are : a)1000 b)500 c)250 d)740

11) If small spheres are to be placed in a square of edge R , then how many spheres ( whose centres will lie on or inside the square 0 are possible. ( assume the packing to be 2D square packing ) a) (R+10)2/100 b) R2/100 c) ( R+11)2 / 100 d) 99R2/100

12) If a cube is made such that small spheres are at the corners and large sphere is at the body centre of the cube , then whats the packing fraction of the system ? a)0.68 b) 0.74 c)0.52 d)o.002

13) Equivalent conductance== C of a C normal solution, so am I right in presuming that =C is the equivalent CONDUCTIVITY? If so , we have to plot vs C of a strong electrolyte I tried to proceed as follows : =0- bC, b= Kohlrausch's constant... thus, =C0- bC3/2 and so we have a cubic in C..

Now , I have assumed that =C is the equivalent conductivity of a C normal solution..is it right, if not..what is precisely equivalent conductivity(note: not equivalent conductance)? Besides if it were right, whats the equivalent conductivity at infinite dilution..is it o=C0=0x0=0? I seem to have been mistaken.... BTW, this is my first post at Target IIT, hurray...

Q14. peptization is a) evaporation of dispersed med b)precipiation of dispered phase c)disintegration of dipersed phase d)combined effect of dispersion medium on dispersed phase Actually, peptization is the dispersion of the precipitated material into colloidal solution. So, it involves first adsorption of the suitable ions and electrically charged particles then split frm precipitate as colloidal particles. thus , its c) disintegration of the dispersed phase.

Q15. Colloidal particles of water are coagulated effectively using a)NaCl b)(NH4)2SO4 c)alum d)gold chloride