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Class : 4 Sc 1 / Sc 2

SMK (P) METHODIST, PULAU PINANG PEPERIKSAAN PERTENGAHAN TAHUN 2012

CHEMISTRY 4541 Form Five 1 Hours 15 Minutes

JANGAN BUKA KERTAS SOALAN INI HINGGA DIBERITAHU 1. This question paper consists of 50 questions. 2. Answer all questions. 3. Answer each question by blackening the correct space on the answer sheet. 4. Blacken only one space for each question. 5. If you wish to change your answer, erase the blackened mark that you have made. Then blacken the space for the new answer. 6. The diagrams in the questions provided are not drawn to scale unless stated. 7. You may use a non-programmable scientific calculator.

Kertas soalan ini mengandungi ?? halaman bercetak

Section A: Answer all questions. (100 marks) 1. A gas jar that contains air is placed on top of a gas jar of bromine. After a period of time, a uniform colour is observed throughout both gas jars. What process has happened? A B C D Condensation Evaporation Diffusion Sublimation 5. Among the following compounds, which one contains particles bonded by strong electrostatic forces? A B C D Ammonia Naphthalene Carbon monoxide Sodium chloride

6. Which of the following has the same empirical formula as ethene, C2H4? A B C D C3H7 C4H11 C5H11 C6H12

7. The molar mass of astatine is 210 gmol-1. What is the relative atomic mass for astatine? Diagram 1 2. Diagram 1 shows the symbol of an atom copper. Proton number A B C D 29 35 64 29 Nucleon number 64 29 35 64 Number of electron 29 64 29 35 A B C D 100 110 210 120

8. Which of the following conducts electricity but does not undergo chemical changes? A B C D Molten lead(II) chloride Molten sulphur Molten magnesium Molten aluminium nitrate

3. Which of the following atomic models was proposed by Ernest Rutherford? A B C D The atom is the smallest particle. The atom is a positively charged sphere. The atom contains a nucleus that is surrounded by electrons moving a random. The atom contains a nucleus that is surrounded by electrons that move in certain orbitals.

9. Diagram 2 shows the set up of apparatus for the electrolysis of copper(II) sulphate solution.

4. From the position in the Periodic Table, we can predict many properties of an element and its compound. What property cannot be predicted? A B C D The formula of its oxide. The number of isotopes it has. The melting point. The freezing point.

Diagram 2 Which of the following solutions can be used to replace copper(II) sulphate solution? A B C D Ethyl ethanoate Potassium bromide solution Hexane Hexene

10. Diagram 3 shows the set-up of apparatus for electrolysis.

14. Which of the following shows the arrangement of atoms in an alloy?

Diagram 3 What is test would you use to confirm the product formed in test tube Y after electrolysis has been carried out for some time? A B C D A lighted wooden splinter Lime water A glowing splinter A moist litmus paper

11. Which of the following is NOT TRUE about the properties of acid? A Undergoes neutralisation with alkali. B Has a pH value lower than 7. C Reacts with ammonium salt and heated to produce ammonia gas. D Reacts with metal carbonates to produce hydrogen. 12. Latex can be kept in liquid state so that it can be transported to factories by adding A ethanoic acid B hydrochloric acid C ammonium hydroxide D ammonium sulphate 13. Which noble gas given below is used to fill airships and weather balloons? A B C D Argon Neon Helium Xenon

15. Diagram 4 shows a graph of a volume of gas against time. The rate of reaction is the highest at

Diagram 4

16. Diagram 5 below shows the formation of ammonia through Haber process.

Diagram 5 Which of the following represent catalyst A, temperature B and pressure C? Catalyst Temperature B, oC 450 450 200 550 Pressure C, atm 200 100 450 200

18. Calculate the volume of sodium hydroxide of concentration 0.5 mol dm-3 needed to neutralise 25.0 cm3 sulphuric acid of concentration 0.20 mol dm-3. A 10 cm3 B 20 cm3 C 25 cm3 D 50 cm3 19. The distilled water is added to 20 cm3 of 1.0 mol dm-3 sodium hydroxide solution to produce 250 cm3 of sodium hydroxide solution. What is the concentration of the sodium hydroxide solution produced? A B C D 0.08 mol dm-3 0.04 mol dm-3 0.06 mol dm-3 0.02 mol dm-3

A B C D

Iron Platinum Iron Vanadium(V) oxide

17. A reaction between sodium thiosulphate solution and dilute sulphuric acid will produce sulphur. Which of the following graphs shows the relationship between the concentration of sodium thiosulphate solution and the time taken to form sulphur?

20. Which of the following solutions has the highest concentration of hydrogen ion? A B C D 50 cm3 of 1.0 mol dm-3 H2SO4 solution 150 cm3 of 1.0 mol dm-3 H2SO4 solution 100 cm3 of 1.0 mol dm-3 H2SO4 solution 50 cm3 of 2.0 mol dm-3 H2SO4 solution

21. An element M has proton number 12. It has the tendency of forming cation M2+. What is the electron arrangement of M2+? A 2.8.2 B 2.2 C 2.8 D 2.8.8.2

22. Which of the following substances has INCORRECT chemical formulae? Substance Formula A Sodium chloride NaCl B Copper(II) sulphate CuSO4 C Potassium oxide K2O D Ammonium nitrate NH4(NO3)2

26. The diagram 6 below shows the electron arrangement of atoms P, Q and R.

23. What is the number of oxygen atom in 0.1 mole of water? [Avogadro constant: 6.02 x 1023 mol-1] A B C D 6.02 x 1022 6.02 x 1023 60.2 x 1023 3.01 x 1023 Diagram 6 R can react with P and Q to form two different compounds. What are the formulae of the compounds formed? P and R P2R P2R PR PR2 Q and R QR2 QR QR2 QR2

24. Going down Group 18 of the Periodic Table of Element, I the boiling point of the elements increases.. II the size of the atom increases. III the forces of attraction between the particles increases. IV the solubility of the elements in water increases. A I and II only B II and III only C III and IV only D I, II and III only A B C D

27. When an electric current is flowed through molten lead(II) bromide, brown vapour can be seen on the anode of the carbon electrode. What is the reason? A Potassium is formed at the anode. B Potassium reacts with bromine at the carbon anode. C Bromide ion loses electron at the carbon anode to produce bromine. D Potassium bromide dissociates into potassium ions and bromide ions. 28. Both ethanoic acid and nitric acid of concentration 1 mol dm-3 have I II III IV the same concentration of hydrogen ions different degree of ionisation in water different pH value the same concentration of hydroxide ions

Aluminium oxide reacts with hydrochloric acid Aluminium oxide reacts with sodium hyroxide solution

25. The table above shows some information on aluminium oxide. From the in-formation above, which of the following is TRUE? A B C D Aluminium oxide is a base oxide. Aluminium oxide is an acid oxide. Aluminium oxide is an amphoteric oxide. Aluminium oxide is a metalloid oxide.

A I and II only B II and III only C III and IV only D I and IV only

29. A student added solution P to solution Q. He then filter the mixture and obtained salt R as residue and solution S as filtrate. Which of the following equations correctly represent the preparation of salt R? A B C D HCl + NaOH NaCl + H2O CuCl2 + Na2SO4 CuSO4 + 2NaCl MgCl2 + Na2CO3 MgCO3 + 2NaCl CuSO4 + 2KNO3 Cu(NO3)2 + K2SO4

32. Which of the following pairs of substances are not isomers? A Hexane and 2,3-dimethyl pentane B 1-butene and 2-methylpropene C Pentane and 2,2-dimethylpropane D 2-chloropentane and 3-chloropentane 33. A catalyst A B C D always slows down a chemical reaction is not used up in the chemical reaction can catalyst many chemical reactions always doubles the rate of a chemical reaction

30. Which of the following is the meaning of activation energy? A The maximum energy that the particles need to produce effective collision B The minimum amount of energy that particles must have in order to react C The amount of energy used by the particles during a collision D The amount of kinetic energy of molecules during a collision

34. Unsaturated fats can be converted to saturated fats through A hydrogenation B esterification C neutralization D fermentation 35. W, X, Y and Z are four metals. Consider the reactions below involving these metals: Z sulphate + X Z + X sulphate Z sulphate + W No reaction Y sulphate + W Y + W sulphate Arrange the metals W, X, Y and Z in decreasing order of reactivity. A B C D X, W, Z, Y Y, W, Z, X X, Z, W, Y Y, Z, W, X

31. Study the structural formula below in diagram 7.

36. The number of valence electrons in an atom of an element will determine .. I II III IV the stability of the atom. the chemical properties of the element. the group number of the element in the Periodic Table. the melting point and boiling point of the element. I and II only I and III only I, II and III only I, II, III and IV

Diagram 7 Based on the IUPAC system, what is the name of the compound having this structural formula? A B C D 2,4,4- trimethylpentane 2,4,4- trimethyloctane 2-ethyl-4-methylpentane 2,4-dimethylhexane

A B C D

37. The chemical formula for glucose is C6H12O6. This shows that ... I the empirical formula for glucose is CH2O. II each glucose molecule is made up of 6 carbon atoms, 12 hydrogen atoms and 6 oxygen atoms. III 1 mol of glucose contains a total of 144.48 x 1023 atoms. IV one glucose molecule has a mass of 180 times higher than the mass of 1 hydrogen atom (Use the information relative atomic mass for H =1, C =12 and O =16 Avogadro Constant = 6.02 X 1023 mol-1 ) A I and II only B I, III and IV only C II, III and IV only D I, II, III and IV

39. Diagram 8 shows set up apparatus for titration of potassium hydroxide with sulphuric acid.

38.

The relative atomic mass of metal K is 7 and the relative atomic mass of the metal L is 56.
Which of the following conclusions can be drawn from the above statement? I 1 mol of L has 8 times more atoms than 1 mol of K II 1 atom of L is 8 times heavier than 1 atom of K III 1 atom of L has the same number of protons with 8 atoms of K IV 56 g of L has the same number of atoms as in 7 g of K A I and III only B II and IV only C I, II and III only D I, II, III and IV

Diagram 8 What is total volume of the mixed solution in the conical flask at the end point of titration in diagram 8? A B C D 30 cm3 20 cm3 10 cm3 40 cm3

40. Table 9 shows the total volume of carbon dioxide gas collected at various time interval in a reaction of calcium carbonate with hydrochloric acid. Time/ s Volume of gas/ cm3 0 0.00 30 4.20 60 7.70 90 10.90

Time/ s Volume of gas/ cm3

120 13.70

150 15.20

180 16.00

210 16.00

Table 9 What is the average rate of reaction in the third minute? A B C D 0.128 cm3 s 1 0.100 cm3 s 1 0.114 cm3 s 1 0.088 cm3 s 1

41. An alloy is harder than its pure metal because the foreign atoms in the alloy A increases the bond strength between the atoms. B increases the empty spaces between the atoms. C reacts with the pure metal atoms to form a compound. D reduces the ability of the atoms to slide across each other. 42. An esterification reaction is given as follows :

44. An iron spoon is electroplated. The apparatus used is shown in diagram 11.

Propanoic acid + ethanol Q + H2O

What is the molecular formula of ester Q? Anode A B C D C3H7COOC2H5 C2H5COOC3H7 C2H5COOC2H5 C5H11COOH A B

Diagram 11 At the end of the electrolysis, it is observed that... Cathode Gas bubbles are released Brown deposits form

Brown deposits form Copper rod becomes thinner Brown deposits form

43. Positive terminal Lead Zinc Tin

C Negative terminal Magnesium Magnesium Zinc Table 10 Reading of the voltmeter/V 1.05 0.42 0.51

Copper rod becomes thicker Copper rod becomes thinner

Gas bubbles are released

45. The reaction between lead(II) nitrate and potassium iodide solution is represented by the equation below : Pb(NO3)2 (aq) + 2KI (aq) PbI2 (s) + 2KNO3 (aq) 25.0 cm3 of 1.0 mol dm-3 potassium iodide solution is mixed with 25.0 cm3 of 1.0 mol dm-3 lead(II) nitrate solution. What is the maximum mass of lead(II) iodide produced in this reaction? (Use the information relative atomic mass for I = 127 and Pb = 207) A 4.175 g B 5.76 g C 8.35 g D 11.52 g

Table 10 shows the reading of a voltmeter for each pair of metals which are immersed in a electrolyte that are connected with one salt bridge to form a simple voltaic cell. From the results, what is the reading of the voltmeter of a voltaic cell that consists of a pair of lead and tin metals? A B C D 0.12 V 0.63 V 0.93 V 1.98 V

46.

49. Diagram 13 shows the electron arrangement of a compound formed between element T and element Q.

Diagram 12 Consider the conversion in Diagram 12 and identify the substance Z. A 1-butanol B 2-methylpropanol C Butanoic acid D 2-methyl-2-butanol 47. Ceramic is made from A Silica, SiO2 B Cement C Marmar D Aluminosilicate hydrate 48. The following statements are about atom U and T. Electron arrangement of atom U is 1 Proton number of atom T is 6 Diagram 13 What group in the Periodic Table of Elements is element Q located? A B C D 2 8 16 18

What is the formula of the compound formed between U and T? A TU B TU2 C TU3 D TU4

50. Assuming that a new element called Sharine (symbol Sh) was discovered and it is above fluorine in Group 17 of the Periodic Table of Element, which are the CORRECT statements about Sharine? I It is a non-metal. II It is the most reactive element in Group 17. III It is the most electronegative element in the Group 17. IV It is the most probably in gaseous form at room conditions. A B C D I and II only II and III only I, II and III only I, II, III and IV

END OF QUESTION PAPER

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________________ (Cik Tan Phei Ling)

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