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Safety Data Sheet

ZETAG 8858FSB
Revision date : 12.05.2010 Version: 1.1 Page: 1/6 (30478406/SDU_GEN_CA/EN)

1. Product and Company Identification


Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA 24 Hour Emergency Response Information CANUTEC (reverse charges): (613) 996-6666 BASF HOTLINE: (800) 454-COPE (2673)

2. Hazards Identification
Emergency overview

Signal word: Colour: Appearance: State of matter: Odour: Health: Physical/Chemical hazards:
Potential health effects

CAUTION ! colourless to white liquid, emulsion liquid of petroleum This product is corrosive to eyes., This product is a skin irritant. Slip hazard when wet.

Primary routes of entry: Skin, Eyes, Inhalation, Ingestion Chronic exposure: Corrosive. Causes eye burns. Repeated or prolonged contact may cause skin irritation or allergic skin reactions Acute exposure to petroleum distillate vapour may cause dizziness, drowsiness, headache, nausea, and irritation of the respiratory tract. Prolonged and repeated exposure may cause central nervous system damage, as well as heart and blood disorders. Aspiration of petroleum distillates may cause chemical pneumonitis.
Potential environmental effects

Releases to the environment are to be avoided.

3. Composition/Information on Ingredients
Chemical name Hexanedioic-acidCITRIC ACID ALCOHOLS, (C=12-14)-SECONDARY, CAS Number 124-04-9 77-92-9 84133-50-6 Content (Weight) 1.0 - 5.0 % 1.0 - 5.0 % 1.0 - 5.0 % Hazardous Y Y Y

Safety Data Sheet


ZETAG 8858FSB
Revision date : 12.05.2010 Version: 1.1 ETHOXYLATED Distillates (petroleum), hydrotreated light 64742-47-8 Page: 2/6 (30478406/SDU_GEN_CA/EN) 15.0 - 40.0 % Y

4. First-aid Measures
Inhalation: Remove to fresh air, if not breathing give artificial respiration. If breathing is difficult, give oxygen and get immediate medical attention. Skin: After contact with skin, wash immediately with plenty of water and soap. Get medical attention if irritation occurs. If clothing is contaminated, remove and launder before reuse. Eyes: Immediately flush the eye(s) with lukewarm, gently flowing water for 15 minutes or until the chemical is removed. Get immediate medical attention if irritation persists. Ingestion: Do not induce vomiting. If vomiting occurs naturally, have casualty lean forward to reduce the risk of aspiration. Seek medical attention immediately.

5. Fire-fighting Measures
Suitable extinguishing media: carbon dioxide, dry powder, foam, water spray Hazardous combustion products: Carbon and nitrogen oxides. Hazards during fire-fighting: The product is slippery when wet. Standard procedure for chemical fires. Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing.

6. Accidental Release Measures


Cleanup: Pick up with inert absorbent material (e.g. sand, earth etc.). Place into approved waste containers. Wear suitable protective equipment. Should not be released into the environment. Spills are very slippery.

7. Handling and Storage


Handling

General advice:

Safety Data Sheet


ZETAG 8858FSB
Revision date : 12.05.2010 Version: 1.1 Page: 3/6 (30478406/SDU_GEN_CA/EN) As with all industrial chemicals, use good industrial practices when handling. Avoid eye, skin, and clothing contact. Do not inhale. Do not taste or swallow. Use only with adequate ventilation. Avoid extremes of temperature. Keep from freezing.
Storage

General advice: Keep container tightly closed in a dry, cool and well-ventilated place. Avoid extremes of temperature. Keep from freezing. Temperature tolerance: Keep from freezing. > for industrial use only <

8. Exposure Controls and Personal Protection


Exposure Guidelines

Hexanedioic-acid- (124-04-9) Distillates (petroleum), hydrotreated light (64742-47-8) Engineering Controls:

ACGIH ACGIH

TWA value: 5 mg/m3 200 mg/m3

Work in well ventilated areas. Do not breathe vapors or mist. Ensure good ventilation and local exhaust.
Personal protective equipment

Respiratory protection: Wear a NIOSH-certified respirator as necessary. Eye protection: Tightly fitting safety goggles (splash goggles) (EN 166) Body protection: Wear chemical resistant gloves and protective clothing. General safety and hygiene measures: Eye wash station and safety shower should be available in immediate work area., Select additional protective equipment based upon potential for exposure.

9. Physical and Chemical Properties


Colour: Form: State of matter: Odour: pH value: Flash point: Freezing point: Boiling point: Density: % Volatiles: Solubility in water: colourless to white liquid, emulsion liquid of petroleum not determined > 93 C not determined not determined 1.03 g/cm3 23.9 % (EPA method 24/24A) dispersible

Safety Data Sheet


ZETAG 8858FSB
Revision date : 12.05.2010 Version: 1.1 Page: 4/6 (30478406/SDU_GEN_CA/EN)

10. Stability and Reactivity


Stability: Stable Conditions to avoid: Avoid temperature extremes, especially frost and freezing conditions.

Substances to avoid: Strong oxidizing agents., strong acids, strong bases Possibility of Hazardous Reactions: No hazardous reactions known. Hazardous decomposition products: No decomposition expected under normal storage conditions.

11. Toxicological Information


Acute oral toxicity:

not determined
Acute inhalation toxicity:

not determined
Acute dermal toxicity:

not determined
Skin irritation:

: Not tested Not tested May cause skin irritation Information on: ALCOHOLS, (C=12-14)-SECONDARY, ETHOXYLATED CAUSES SKIN IRRITATION. ---------------------------------Information on: Distillates (petroleum), hydrotreated light (Rabbits) Prolonged or repeated contact can cause defatting and drying of the skin resulting in skin irritation and dermatitis. ---------------------------------Eye irritation:

Corrosive. (Rabbits)

Skin Sensitization:

not determined Genetic toxicity: Not determined. Carcinogenicity: None of the components in this product at concentrations greater than 0.1% are listed by IARC; NTP, OSHA or ACGIH as a carcinogen. Reproductive toxicity: not determined Developmental toxicity/teratogenicity:

Safety Data Sheet


ZETAG 8858FSB
Revision date : 12.05.2010 Version: 1.1 not determined Page: 5/6 (30478406/SDU_GEN_CA/EN)

12. Ecological Information


Toxicity to fish: Oncorhynchus mykiss/96 h/LC50: 18 mg/l (under static conditions in the presence of humic acid) Toxicity to aquatic invertebrates: Daphnia magna/48 h/EC50: 12 mg/l (under static conditions in the presence of humic acid) Daphnia magna/NOEC (No observed effect concentration): < 3.1 mg/l (under static conditions in the presence of humic acid) Toxicity to aquatic plants: not determined

13. Disposal Considerations


Waste disposal of substance: Dispose of in accordance with national, state and local regulations.

14. Transport Information


TDG (Canada) Road transport

Special shipping information: Special shipping information: Special shipping information:

Not classified as a dangerous good under transport regulations. Not classified as a dangerous good under transport regulations. Not classified as a dangerous good under transport regulations.

International Air Transport Association (IATA) International Maritime Dangerous Goods Code (IMDG)

15. Regulatory Information


Canada: Domestic Substances List (DSL): US: Toxic Substances Control Act (TSCA): All components either exempt or listed on the DSL All component(s) comprising this product are either exempt or listed on the TSCA inventory

Canada Regulations

Workplace Hazardous Materials Information System (WHMIS Classification): D-2B Materials Causing Other Toxic Effects - Toxic material

This product is WHMIS controlled. Significant New Activity Conditions (SNAC): This product does not contain any components subject to a SNAC Notice.

Safety Data Sheet


ZETAG 8858FSB
Revision date : 12.05.2010 Version: 1.1
International Regulations

Page: 6/6 (30478406/SDU_GEN_CA/EN)

Chemical Weapons Convention: This product does not contain any component(s) listed under the Chemical Weapons Convention Schedule of Chemicals.

16. Other Information


Product Safety Contact: Prepared by: Phone number of preparer: Date / Revised: Terence Ma (905) 812-7280 12.05.2010

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

ZETAG 8858FSB is a registered trademark of BASF Canada or BASF SE Due to the merger of CIBA and BASF Group all Material Safety Data Sheets have been reassessed on the basis of consolidated information. This may have resulted in changes of the Material Safety Data Sheets. In case you have questions concerning such changes please contact us at the address mentioned in Section I. END OF DATA SHEET

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