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Safety Data Sheet

ZETAG 7875FS40
Revision date : 2010/06/28 Version: 1.0 Page: 1/7 (30481530/SDS_GEN_CA/EN)

1. Product and Company Identification


Use: flocculation agent

Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA

24 Hour Emergency Response Information CANUTEC (reverse charges): (613) 996-6666 BASF HOTLINE: (800) 454-COPE (2673)

2. Hazards Identification
Emergency overview Eye irritant. Skin Irritant Caution - Slippery when wet!

CAUTION: Causes eye irritation. Sensitizing effects by skin contact. Repeated exposure may cause skin dryness or cracking. Vapors may irritate eyes and respiratory tract and result in headache or dizziness. Acute exposure to petroleum distillate vapour may cause dizziness, drowsiness, headache, nausea, and irritation of the respiratory tract. Prolonged and repeated exposure may cause central nervous system damage, as well as heart and blood disorders. Aspiration of petroleum distillates may cause chemical pneumonitis. Spills are very slippery.

State of matter: liquid Colour: off-white Odour: mineral oil-like Potential health effects Primary routes of entry: Skin Eyes Inhalation. Ingestion. Chronic toxicity: Carcinogenicity: None of the components in this product at concentrations greater than 0.1% are listed by IARC; NTP, OSHA or ACGIH as a carcinogen.

Safety Data Sheet


ZETAG 7875FS40
Revision date : 2010/06/28 Version: 1.0 Page: 2/7 (30481530/SDS_GEN_CA/EN)
Reproductive toxicity: No data available concerning reproduction toxicity.

Teratogenicity: No data available concerning teratogenic effects.

Genotoxicity: The chemical structure does not suggest a mutagenic effect.

3. Composition / Information on Ingredients


CAS Number 77-92-9 124-04-9 64742-47-8 64742-52-5 78330-23-1 Content (W/W) 1.0 - 5.0 % 1.0 - 5.0 % 1.0 - 5.0 % 15.0 - 40.0 % 3.0 - 7.0 % Hazardous ingredients Citric acid adipic acid Distillates (petroleum), hydrotreated light Distillates (petroleum), hydrotreated heavy naphthenic Alcohols, C11-14-iso-, C13-rich, ethoxylated propoxylated

4. First-Aid Measures
General advice: Immediately remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air. Assist in breathing if necessary. Consult a physician. If on skin: Wash thoroughly with soap and water. Remove contaminated clothing. If irritation develops, seek medical attention. If in eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Rinse mouth thoroughly with water, seek medical attention. Note to physician Treatment:

Treat according to symptoms (decontamination, vital functions), no known specific antidote. Aspiration hazard

Treatment:

5. Fire-Fighting Measures
Flash point: > 100 C

Suitable extinguishing media: dry powder, alcohol-resistant foam Unsuitable extinguishing media for safety reasons: water jet Additional information: If water is used, restrict pedestrian and vehicular traffic in areas where slip hazard may exist. Hazards during fire-fighting: harmful vapours

Safety Data Sheet


ZETAG 7875FS40
Revision date : 2010/06/28 Version: 1.0 Page: 3/7 (30481530/SDS_GEN_CA/EN)
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Spilled product is slippery underfoot. Very slippery when wet. Do not release chemically contaminated water into drains, soil or surface water. Sufficient measures must be taken to retain the water used for extinguishing. Dispose of contaminated water and soil according to local regulations. Protective equipment for fire-fighting: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations.

6. Accidental release measures


Personal precautions: Use personal protective clothing. Keep people away and stay on the upwind side. Spills are very slippery. Restrict pedestrian and vehicular traffic in area of spill until spill is thoroughly cleaned up. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Cleanup: Use common salt (sodium chloride) to aid removal of residues For large amounts: Pump off product. For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations. Further information: High risk of slipping due to leakage/spillage of product.

7. Handling and Storage


Handling General advice: High risk of slipping due to leakage/spillage of product. Breathing must be protected when large quantities are decanted without local exhaust ventilation. Protection against fire and explosion: Take precautionary measures against static discharges. Storage General advice: Keep container tightly closed and dry; store in a cool place. Avoid extremes of temperature, especially frost and freezing conditions. Storage stability: Storage temperature: >= 0 C

Temperature tolerance Product will freeze but should recover upon warming and mixing.

8. Exposure Controls and Personal Protection


Components with workplace control parameters adipic acid ACGIH TWA value 5 mg/m3 ;

Safety Data Sheet


ZETAG 7875FS40
Revision date : 2010/06/28 Version: 1.0
Distillates (petroleum), hydrotreated light ACGIH

Page: 4/7 (30481530/SDS_GEN_CA/EN)


TWA value 200 mg/m3 Non-aerosol (total hydrocarbon vapor); Application restricted to conditions in which there are negligible aerosol exposures. Skin Designation Non-aerosol (total hydrocarbon vapor); The substance can be absorbed through the skin. PEL 500 ppm 2,000 mg/m3 ;

Distillates (petroleum), OSHA hydrotreated heavy naphthenic Personal protective equipment

Respiratory protection: Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. Hand protection: Chemical resistant protective gloves Eye protection: Tightly fitting safety goggles (chemical goggles). Body protection: Impermeable protective clothing General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Handle in accordance with good industrial hygiene and safety practice. Eye wash fountains and safety showers must be easily accessible.

9. Physical and Chemical Properties


Form: Odour: Odour threshold: Colour: Boiling point: Density: Partitioning coefficient noctanol/water (log Pow): Solubility in water: liquid mineral oil-like No data available. off-white > 100 C approx. 1.1 g/cm3

( 20 C) not applicable dispersible

10. Stability and Reactivity


Conditions to avoid: No conditions known that should be avoided. Substances to avoid: strong oxidizing agents Hazardous reactions: No hazardous reactions when stored and handled according to instructions. Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Oxidizing properties: not fire-propagating

Safety Data Sheet


ZETAG 7875FS40
Revision date : 2010/06/28 Version: 1.0 Page: 5/7 (30481530/SDS_GEN_CA/EN)

11. Toxicological information


Acute toxicity Oral: Type of value: LD50 Value: > 2,000 mg/kg The product has not been tested. The statement has been derived from the properties of the individual components. Irritation / corrosion Skin: Species: rabbit Result: Irritant. The product has not been tested. The statement has been derived from products of a similar structure and composition. ---------------------------------Eye: Result: Irritant. The product has not been tested. The statement has been derived from products of a similar structure and composition. ---------------------------------Repeated dose toxicity Experimental/calculated data: No data available concerning repeated dose toxicity. ---------------------------------Other Information: not determined not determined not determined

12. Ecological Information


Fish Acute: static Fish/LC50 (96 h): 10 - 100 mg/l Aquatic invertebrates Acute: static Daphnia magna/EC50 (48 h): > 100 mg/l (under static conditions in the presence of 10 mg/L humic acid) Degradability / Persistence Biological / Abiological Degradation Test method: , activated sludge Evaluation: Not readily biodegradable.

Safety Data Sheet


ZETAG 7875FS40
Revision date : 2010/06/28 Version: 1.0 Page: 6/7 (30481530/SDS_GEN_CA/EN)

13. Disposal considerations


Waste disposal of substance: Dispose of in accordance with national, state and local regulations. Dispose of in accordance with national, state and local regulations. Do not discharge into drains/surface waters/groundwater. Container disposal: Packs that cannot be cleaned should be disposed of in the same manner as the contents. Uncontaminated packaging can be re-used.

14. Transport Information

Land transport TDG Not classified as a dangerous good under transport regulations

Sea transport IMDG Not classified as a dangerous good under transport regulations

Air transport IATA/ICAO Not classified as a dangerous good under transport regulations

15. Regulatory Information


Federal Regulations Registration status: Chemical DSL, CA

released / listed

WHMIS classification:

D2B: Materials Causing Other Toxic Effects - Toxic material

THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.

16. Other Information

We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our

Safety Data Sheet


ZETAG 7875FS40
Revision date : 2010/06/28 Version: 1.0 Page: 7/7 (30481530/SDS_GEN_CA/EN)
products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products.

MSDS Prepared by: BASF NA Product Regulations

msds@basf.com
MSDS Prepared on: 2010/06/28 ZETAG 7875FS40 is a registered trademark of BASF Canada or BASF SE Due to the merger of CIBA and BASF Group all Material Safety Data Sheets have been reassessed on the basis of consolidated information. This may have resulted in changes of the Material Safety Data Sheets. In case you have questions concerning such changes please contact us at the address mentioned in Section I. END OF DATA SHEET