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Hydrogen Sulfide
Deadly Poison
Hydrogen sulfide is a deadly poison. When inhaled it goes through the lungs and enters the bloodstream. To protect itself the body tries to break down the hydrogen sulfide as fast as possible into a harmless compound. Poisoning occurs when the amount absorbed in the blood exceeds the rate at which it is eliminated. Exposure to high concentrations of hydrogen sulfide (acute exposure) can cause immediate coma and death from respiratory failure. Hydrogen sulfide builds up in the blood, paralyzes the nerve centres in the brain which stops the lungs from working. If not caught in time, acute poisoning is deadly.
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Sub-acute exposure (exposure to lower levels) may result in headaches, dizziness, loss of balance, agitation, nausea, diarrhea. Chronic poisoning (repeated exposure to low levels) may result in slowed pulse rate, fatigue, insomnia, cold sweat, eye infections, loss of weight, skin eruptions. If a worker is suffering from any of these symptoms, hydrogen sulfide may be responsible. The presence of hydrogen sulfide may be responsible. The presence of hydrogen sulfide should be suspected and tested for.
Who is at risk?
sewage treatment plant workers sewer workers workers in manholes tunnel workers well diggers workers in chemical laboratories Enclosed and confined spaces are the danger areas prone to the rapid buildup of hydrogen sulfide gas. A confined space is any workplace (not necessarily small) which is wholly or partially enclosed and from which immediate escape is difficult (sewers, manholes, pits, tunnels, vats, tanks, ovens, grain elevators and open-topped spaces more than 4 feet in depth). Enclosed areas (wet wells, grit chambers, pump stations valve chambers) although easier to get in and out of, are still as dangerous in the accumulation of deadly gas. A room or a building can be considered an enclosed space.
Levels of Exposure
Hydrogen sulfide is measured in parts per million (ppm). The American Conference of Governmental Industrial Hygienists (ACGIH) has recommended a Threshold Limit Value (TLV)-Time Wrighted Average (TWA) of 10 ppm. 10 ppm is equal to 0.001 per cent by volume, or only one-thousandth of one per cent of the total air volume. This is a time-weighted average exposure for a normal eight hour work day and a 40 hour work week to which nearly all workers may be repeatedly exposed without adverse effect. A Short Term Exposure Level (STEL) of 15 ppm is also recommended. This STEL is a 15 minute timeweighted average exposure which should not be exceeded at any time during a work day even if the 8-hour time-weighted average is within the TLV. Exposure at STEL should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. In many Canadian jurisdictions exposure limits are similar to the Threshold Limit Values recommended by the ACGIH. Other countries (Czechoslovakia and USSR) have accepted lower limits of 7 ppm.
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The recommended limit of 10 ppm does not guarantee worker safety. If should not be used as a guideline demarcating safe and dangerous concentrations of hydrogen sulfide. Because of wide variations in individual susceptibility some workers may experience problems at concentrations at or below the threshold limit. The safest exposure to Hydrogen sulfide is no exposure at all.
Effects of exposure
Hydrogen sulfide at low levels has a distinctive rotten-egg odour and workers mistakenly assume that the absence of smell means that they are not exposed to it. Smell is a poor warning sign of hydrogen sulfide. At higher concentrations a sweet smell may be noted, but at even greater concentrations, hydrogen sulfide can paralyze the sense of smell and the ability to smell is lost. Some workers are congenitally (by birth) unable to smell hydrogen sulfide. That is why the air should always be monitored by instruments designed to detect hydrogen sulfide.
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A suitable breathing apparatus (one approved by the U.S. National Institute for Occupational Safety and Health NIOSH- or Canadian Standards Association C.S.A.- standard Z94.4) must be worn when entering a confined space. NIOSH recommends any supplied-air respirator or self-contained breathing apparatus for levels of hydrogen sulfide of 10 to 100 ppm; up to 250 ppm any supplied-air respirator with a full facepiece. Self contained respirators have air supplied from a cylinder worn on the back while supplied-air respirators have air supplied by a long line from a large stationary tank. When the atmosphere is dangerous workers should wear a self-contained breathing apparatus. Air purifying filter or cartridge respirators easily leak, have a limited lifetime and should not be used when the atmosphere is dangerous. Air supplied respirators with masks hooked up to an air hose connected to a blower are not suitable for tight areas and may foul or break. Appropriate respirators must always be used with proper fitting, be easily accessible, maintained and cleaned regularly. (See C.S.A. standard M1982 Selection, Care and Use of Respirators). 4. Record-keeping Air monitoring should be conducted at each location where hydrogen sulfide may be released and a survey log kept. If concentrations are below the recommended ceiling the records must contain the basis for this conclusion. 5. Training A comprehensive education/training program should be developed for workers which should include: knowledge of hazards from exposure; symptoms and how to deal with them; all emergency procedures (first aid, resuscitation, evacuation, meaning of alarms); training in the location of monitors, respirators. This training would be done quarterly and before a worker starts on the job. Workers should be certified as trained before being assigned to enter confined spaces. 6. Medical examinations Workers should be given medical examinations annually and prior to starting a job. Particular attention should be paid to eyes, nervous and respiratory systems. Checkups should include the ability to use respirators and hear to and see warnings. For further information contact: CUPE National Health and Safety Branch 1375 St. Laurent Boul. OTTAWA, Ontario K1G 0Z7 Tel.: (613) 237-1590 Fax: (613) 237-5508 Email: health_safety@cupe.ca (http://cupe.ca/mailto/urnygu_fnsrgl+phcr+pn) Website: http://cupe.ca/health-and-safety (http://cupe.ca/health-and-safety)
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Footnotes
1. Molly Coye, Hydrogen Sulfide: A powerful and deceptive killer, Oil, Chemical and Atomic Workers Union Health and Safety. 2. NIOSH: A Recommended Standard for Occupational Exposure to Hydrogen Sulfide states that Conclusive evidence of adverse health effects from chronic exposure to hydrogen sulfide at low concentrations is lacking. U.S. Department of Health, Education, and Welfare, National Institute for Occupational Safety and Health, p.1. In the OCAW published pamphlet Hydrogen Sulfide: A powerful and deceptive killer, Molly Coye, M.D., p.7, indicates that chronic poisoning may indeed occur. She notes that many of the symptoms are not specific to hydrogen sulfide and that other exposures may cause similar effects. Nevertheless hydrogen sulfide should be suspected. Publication No. 15, pp. 8-10 3. Coye, op. cit., pamphlet gives the example of the lethal concentration of 700 ppm: 700 ppm is equal to 0.07 per cent by volume, or only 7 one-hundredth of one per cent of the total air volume. Since 700 ppm = .07 per cent = 7 one-hundredth of one per cent, therefore, 10 ppm = .001 per cent = 1 one-thousandth of one per cent. 4. The chart is based on information from the main resources listed. Part of this chart is reproduced in the OCAW pamphlet, Hydrogen Sulfide: A powerful and deceptive killer, p.6. Also see, Chemical Hazard Summary, Canadian Centre for Occupational Health and Safety, Hamilton, No.12, August 29, 1985, pp.5 and 6. 5. Key, Henchel, Buxtler, et. al., Occupational Diseases a Guide to their Recognition, U.S. Department of Health, Education, and Welfare, National Institute for Occupational Safety and Health, Washington, 1977, p.424.
Abbreviations:
ACGIH American Conference of Governmental Industrial Hygienists NIOSH National Institute for Occupational Safety and Health ppm parts per million TLV Threshold Limit Value TWA Time Weighted Average STEL Short Term Exposure Level
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Chemical Hazard Summary: Hydrogen Sulfide, No.12, August 29, 1985, Canadian Centre for Occupational Health and Safety, Hamilton. Hydrogen Sulfide: A powerful and deceptive killer, Molly Coye, Oil, Chemical and Atomic Workers International Union Publication no.15, 1977. The Killer: H2S, Alberta Workers Health and Safety Compensation, Occupational Health and Safety Division. Occupation Diseases: A guide to Their Recognition, Key, Henschel, Butler, et al., U.S. Department of Health, Education, and Welfare, National Institute for Occupational Safety and Health, Washington, June 1977. NIOSH/OSHA: Occupational Health Guidelines for Chemical Hazards, National Institute for Occupational Safety and Health/Occupational Safety and Health Administration, January 1981. A Recommended Standard for Occupational Exposure to Hydrogen Sulfide, U.S. Department of Health, Education, and Welfare Public Health Service, National Institute for Occupational Safety and Health, Cincinnatti. Risky Business: An AFSCME Health and Safety Guide for Sewer, and Sewage Treatment Plant Workers, The American Federation of State, County and Municipal Employees, Washington, D.C.
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