Forecast Question FiNaL SK 027

Sem II 08 / 09
Paper II (2 ½ Hours) FRIDAY 17 April 2009 (8.30 - 11.00 am)
Part A (40M) (answer ALL)
ALL)

Chapter 1 : Thermo (10M)

1) a) i) Definition of enthalpy combustion / formation / atomization / Hess Law
ii) Give equation, calculate Enthalpy ∆H (5M)

b) Construct Born Haber Cycle (BHC) e.g : KCl / Mg(OH)2

@ Label the Enthalpy ∆H (5M)

Chapter 4 : Intro & General Organic (10M)

2) a) Determine type of reaction e.g : EA, ES, NS, FRS etc (4M)
b) Define isomer
Draw a pair of enantiomers
@ simple reaction: give isomer, reagent used, product etc
Eg: nitration, Grignard reagent, Lucas test, oxidation & reduction (6M)

General Organic (10M)

3) a) Arrange increasing / decreasing BP e.g : C-C, R-X, NH2, OH and COOH (5M)
b) Arrange increasing / decreasing of acidity / basicity e.g: C6H6 , Phenol, aniline (5M)

General Organic (10M)

4) a) reaction of amine i.e 10 –NH2 and 20 –NH2 , Class of OH or COOH derivative (6M)
b) Write structure from simple diagram of reaction e.g: R-X, C6H6, OH, COOH or
NH2 (4M)

Part B (60M) (answer 4 (four

(four)) Q from 6 Q)

Chapter 2 : Electro Chem (15M)

5) Q = It
Calculate mass of metal formed / deposited at cathode electrode in unit gram
Molarity, time etc. (Faraday first Law: also consider defination)
P/s- 1 mol e = 96500C=1F
Galvanic cell
Calculate an ion [ ] that involve in the reaction using Nernst equation (15M)
* consider to draw diagram

Chapter 3 : Reaction Kinetic (15M)

6) a) Explain the factors of collision theory (5M)
b) Determine the order of reaction and rate constant,
constant, k from the table given (10M)
half life 1st order
* consider to plot graph and write DRE (differential rate of equation)
 General Organic (15M)
7) a) draw structure and write equation also observation
e.g: C=C, R-X, benzene, OH, C=O COOH or NH2 (7M)

b) Synthesis and write equation from R-X, benzene, OH, COOH or NH2 (8M)
*consider observation and naming the product

General Organic (15M) (essay question)

8) a) draw structure and write equation
C=O, OH, benzene or COOH
@ Give chemical test OH & Phenol, OH & C=C, 10 –NH2 & 20 –NH2 (7M)

b) Using Grignard Reagent R-Mg-X to produce alcohol (8M)

General Organic (15M)

9) a) Chem test, observation, write equation. (Iodoform / Tollen test) @ Lucas test
Hinsberg Test, HNO2 test (7M)
0
b) Synthesis e.g: i) CHO 2 OH
ii) Benzene phenyl acetic acid
iii) Toluene m-nitro benzoic acid @ σ-nitro benzoic acid (8M)

Chapter 19, 20 & 21 : Amine, AA & Protein, Polymer (15M)

10) a) Amine preparation & reaction (Hinsberg test @ HONO @ O=C-Cl) (5M)
b) zwitterions @ isoelectric point, draw structure e.g : peptide bond O=C-N (5M)
c) polimer define i) homopolymer
ii) copolymer
*write monomer from repeating unit

- Condensation polymerization (nylon-6,6) @ polyester / natural rubber

* used of synthetic polimer eg dacron, nylon, kevlar etc (5M)

Reminder

1) 4 chapter important in organic C=C, OH, C=O & COOH plus R-X, C6H6 & NH2
2) Naming structure is not necessary but if write and wrong… no mark given…!!!
given…!!!
3) Explain Boiling point step by step i.e explain for each compound
4) Deduce, describe and explain answer include elaboration
5) For questions that ask mechanism…
mechanism… arrow is very….very important…!!!
6) Synthesis / outline / convert only reagent and transition compound get
mark..!!
Important Summary

1) Synthesis (usually 2 or 3 steps only. Uncertain case 4 steps)

2) Chemical test (usually 4 marks given. Write equations properly…ok.)
3) Arrange boiling point / acidity / basicity…. Also explain
Warning : This is just forecast…ok my dear student.. please… please… I beg
to you my dear student…. Go s t u d y… study smart… not study hard.
Good Luck ‘4’ your F I N A L….!! Insya 4W1
ajarkanlah iLMu kimia dari K E Ikhlas a n hati sebagai Pensyarah yang mengajar
dan pohon lah k e berkat a n ilmu untuk anak didik Insya 4W1 mereka berjaya di dunia dan
akhirat
kimia itu m u d a h insya 4w1....... A..!!!!