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Class: XII (AB) & SMS Date: 06-01-2013 Time: 3 Hours. Max.

Marks: 270
VERY IMPORTANT
A. The question paper consists of 3 section (Section-1 contains Mathematics, Section-2 contains Physics and Section-3
contains Chemistry). Please fill the OMR answer Sheet accordingly and carefully.
B. Each Section contains (30 questions in Part-A) and total number of pages are 24.
C. Please ensure that the Question Paper you have received contains ALL THE QUESTIONS in each Section
and PAGES. If you found some mistake like missing questions or pages then contact immediately to the
Invigilator.
INSTRUCTIONS
PART-A
1. Q.1 to Q.27 are single correct type questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct. For each question, you will be awarded 3 marks if you have darkened only the bubble
corresponding to the correct answer and zero mark if no bubble are darkened. In all other cases, minus one (1)
mark will be awarded.
2. Q.28 to Q.30 are Reasoning type questions, contains Statement-1 (Assertion) and Statement-2 (Reason).
Each question has four choices (A), (B), (C) and (D) out of which ONLY ONE is correct. For each question you will
be awarded 3 marks, if you have darkened only the bubble corresponding to the correct answer and zero mark if
no bubble are darkened. In all other cases, minus one (1) mark will be awarded.
3. Indicate the correct answer for each question by filling appropriate bubble in your answer sheet.
4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.
5. The answers of the questions must be marked by shading the circle against the question by dark Black Ball point Pen only.
FINAL TEST
PAPER - 1 (JEE MAINS)
USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14, Li = 7,
I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.5, Ti = 48, Ba = 137, U = 238,
Co= 59, B =11, F = 19, He = 4, Ne = 20, Ar = 40 , Mo = 96
[Take : ln 2 = 0.69, ln 3 = 1.09, e = 1.6 10
19
, m
e
= 9.1 10
31
kg ]
Take
0
= 8.85 10
12
, g = 10 m/s
2
unless otherwise stated
XII (AB) FINAL TEST [Paper-1_MAINS] Page # 2
MATHEMATICS
SPACE FOR ROUGH WORK
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.27 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.1 If the value of the definite integral dx 1
x 1
x sin
2 4
2 4
4 }
t
t
|
.
|

\
|
+
+
is equal to kt, then the value of k is
(A)
2
(B) 2 2 (C)
2 4
(D) 2 8
Q.2 If z
1
=
|
.
|

\
| t
+
t
4
sin i
4
cos 2 and z
2
=
|
.
|

\
| t
+
t
3
sin i
3
cos 3 , then | z
1
z
2
| is equal to
[ Note : i = 1 ]
(A) 6 (B) 3 2 + (C) 6 (D) 5
Q.3 Tangent to the ellipse 1
18
y
32
x
2 2
= + having slope
4
3
meet the coordinate axes in A and B.
The area of AAOB (O is origin) equals
(A) 12 (B) 8 (C) 24 (D) 32
Q.4 In which one of the following functions, Rolle's theorem is applicable?
(A) f(x) = | x |, in 2 s x s 2 (B) f(x) = tan x, in 0 s x s t
(C) f(x) = 1 +
3
2
) 2 x ( , in 1 s x s 3 (D) f(x) = x(x 2)
2
in 0 s x s 2
XII (AB) FINAL TEST [Paper-1_MAINS] Page # 3
MATHEMATICS
SPACE FOR ROUGH WORK
Q.5 A house of height 100 m subtends a right angle at the window of an opposite house. If the height of the
window is 64 m, then the distance between the two houses is
(A) 48 m (B) 36 m (C) 54 m (D) 72 m
Q.6 If the area of triangle on the argand plane formed by the complex numbers z, iz, z iz
(z = 0 and i =
1
) is 600, then | z | is equal to
(A) 10 (B) 20 (C) 30 (D) 40
Q.7 The distance between the origin and the normal to the curve y = e
2x
+ x
2
at x = 0, is
(A)
5
1
(B)
5
2
(C)
3
2
(D)
2
1
Q.8 A common tangent to 9x
2
16y
2
= 144 and x
2
+ y
2
= 9, is
(A) y =
7
15
x
7
3
+ (B) y =
7
15
x
7
2
3 +
(C) y = 2 7 15 x
7
3
+ (D) y =
7
15
x
7
3

Q.9 Let p be the statement '7 is not greater than 4' and q be the statement 'Paris is in France'.
Then ~ (p
v
q) is the statement
(A) 7 is greater than 4 or Paris is not in France (B) 7 is not greater than 4 and Paris is not in France
(C) 7 is greater than 4 and Paris is in France (D) 7 is greater than 4 and Paris is not in France
Q.10 Let f (t) = t
2
for 0 s t s 1 and g (t) = t
3
for 0 s t s 1. The value of c with 0 < c < 1
at which
) c ( ' g
) c ( ' f
) 0 ( g ) 1 ( g
) 0 ( f ) 1 ( f
=

, is
(A)
3
2
(B)
3
1
(C)
2
1
(D)
6
1
XII (AB) FINAL TEST [Paper-1_MAINS] Page # 4
MATHEMATICS
SPACE FOR ROUGH WORK
Q.11 Let A and B be two events such that ) B A ( P =
6
1
, P(A B) =
4
1
and ) A ( P =
4
1
, where A stands
for complement of event A. Then, events A and B are
(A) mutually exclusive and independent. (B) independent but not equally likely.
(C) equally likely but not independent. (D) equally likely and mutually exclusive.
Q.12 If the area of auxiliary circle of the ellipse
2
2
2
2
b
y
a
x
+ = 1 (a > b) is twice the area of the ellipse,
then the eccentricity of the ellipse is
(A)
2
1
(B)
2
3
(C)
3
1
(D)
2
1
Q.13 If I =
} t
+
1
0
2
x 1
dx
, then
(A) log
e
2 < I <
4
t
(B) log
e
2 > I (C) I =
4
t
(D) I = log
e
2
Q.14 The figure show a AAOB and the parabola y = x
2
.
The ratio of the area of the AAOB to the area of the
region AOB of the parabola y = x
2
, is equal to
O(0,0)
A
(a, a )
2
y
x
B
(a, a )
2
(A)
4
3
(B)
5
3
(C)
6
5
(D)
3
2
XII (AB) FINAL TEST [Paper-1_MAINS] Page # 5
MATHEMATICS
SPACE FOR ROUGH WORK
Q.15 If x
1
, x
2
, ........., x
18
are observations such that

=
=
18
1 j
j
9 ) 8 x ( and

=
=
18
1 j
2
j
45 ) 8 x ( ,
then the standard deviation of these observations is
(A)
34
18
(B) 5 (C) 5 (D)
2
3
Q.16 If xdy = y(dx + ydy), y(1) = 1 and y(x) > 0, then y(3) is equal to
(A) 1 (B) 2 (C) 3 (D) 4
Q.17 The function f(x) =
x cos x sin 1
x cos x sin 1
+ +
+
is not defined at x = t. The value of f(t), so that f(x) is
continuous at x = t, is
(A)
2
1
(B)
2
1
(C) 1 (D) 1
Q.18 The set S = {x e R: cos 2x + 2cos
2
x = 2}, is equal to
(A)
)
`

e
t
+ t I n :
3
n 2 (B)
)
`

e
t
t I n :
6
n (C)
)
`

e
t
+ t I n :
3
n (D)
)
`

e
t
t I n :
3
n 2
Q.19 The locus of P(z) where z = x + iy and satisfying
|
.
|

\
|

1 z
2 z
Re = 0 is
(A) {(x, y) e R
2
{(1, 0)}| x
2
+ y
2
3y + 2 = 0}
(B) {(x, y) e R
2
{(0, 1)} | x
2
+ y
2
3x + 2 = 0}
(C) {(x, y) e R
2
{(0, 1)} | x
2
+ y
2
+ 3x + 2 = 0}
(D){(x, y) e R
2
{(1, 0)} | x
2
+ y
2
3x + 2 = 0}
XII (AB) FINAL TEST [Paper-1_MAINS] Page # 6
MATHEMATICS
SPACE FOR ROUGH WORK
Q.20 Hat W contains two white balls and one black ball. Hat B contains two black balls and one white ball.
At random, one of the following strategies is selected :
Two different balls are drawn from hat W.
Two different balls are drawn from hat B.
One ball is drawn from each hat.
The probability of getting at least one white ball, is
(A)
2
1
(B)
4
1
(C)
27
22
(D)
27
21
Q.21 Let y = f(x) satisfies the differential equation (1 + x
2
)
dx
dy
+ 2xy = 2x and f(0) = 2.
Then the number of integers in the range of f(x) is
(A) 1 (B) 2 (C) 3 (D) 4
Q.22 On the set N of all natural numbers, define the relation R by a R b if and only if the greatest common
divisor of a and b is 2, then R is
(A) reflexive but not symmetric (B) symmetric only
(C) reflexive and transistive (D) equivalence
Q.23 Let a, b, c be non-zero real numbers. If the system of equations
y + z = a + 2x
x + z = b + 2y
x + y = c + 2z
is consistent and b = 4a +
4
c
, then the absolute value of sum of roots of the equation ax
2
+ bx + c = 0,
is equal to
(A) 1 (B) 2 (C) 3 (D) 4
Q.24 Let the term independent of x in the expansion of
9
2
x
1
x
|
.
|

\
|

has the value p and q be the sum of the
coefficients of its middle terms, then (p q) equals
(A) 0 (B) 2
9
C
4
(C)
9
C
5
(D)
9
C
3
XII (AB) FINAL TEST [Paper-1_MAINS] Page # 7
MATHEMATICS
SPACE FOR ROUGH WORK
Q.25 Consider the ten numbers
ar, ar
2
, ar
3
, .......... ar
10
.
If their sum is 18 and the sum of their reciprocals is 6 then the product of these ten numbers, is
(A) 324 (B) 343 (C) 243 (D) 729
Q.26 Let matrix A of order 3 is such that A
2
= 2A I where I is an identity matrix of order 3.
Then for n e N and n > 2, A
n
is equal to
(A) nA (n 1)I (B) nA I (C) 2
n 1
A (n 1)I (D) 2
n 1
A I
Q.27 If the derivative of the function f(x) is everywhere continuous and is given by
f(x) =

< +
> + +
1 x ; b ax
1 x ; 4 ax bx
2
2
, then
(A) a = 2, b = 3 (B) a = 3, b = 2 (C) a = 2, b = 3 (D) a = 3, b = 2
[REASONING TYPE]
Q.28 to Q.30 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.28 Statement-1: The value of ( ) ) x tan x ( ) 2 x ( tan ) 2 x ( Lim
1 1
x


+ + is equal to t.
Statement-2: If f(x) is derivable in [a, b] then - atleast one c e (a, b) such that
f '(c) =
a b
) a ( f ) b ( f

.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true
XII (AB) FINAL TEST [Paper-1_MAINS] Page # 8
MATHEMATICS
SPACE FOR ROUGH WORK
Q.29 Statement 1: Consider two curves
C
1
: 0 b z i iz z z = + +
and C
2
:
0 4 z ) i 1 ( z ) i 1 ( z z = + + +
where (b e R, z = x + iy and i = 1 ).
If C
1
and C
2
intersects orthogonally then b = 2.
Statement 2: If two curves intersects orthogonally then the angle between the tangents at all their
points of intersection is
2
t
.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true
Q.30 Statement 1: The circles x
2
+ y
2
= 9 and
( ) ( ) ( ) 0 6 y y 2 1 x 3 x 2 = +
touches each other
internally.
Statement 2: Circle described on the focal distance as diameter of the ellipse 8x
2
+ 9y
2
= 72
touches the auxiliary circle x
2
+ y
2
= 9 internally.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 9
PHYSICS
SPACE FOR ROUGH WORK
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.27 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.1 Time taken by the planet to cover path A B C is t
1
& time taken by the planet to cover path C D A is t
2
.
D
C
B
A
A
2
A
1
SUN
Planet
(A) t
1
= t
2
(B) t
2
> t
1
(C) t
1
> t
2
(D) cannot be determined
Q.2 A beam of light of wavelength 400nm and power 1.55mW is directed at the cathode of a photoelectric
cell. If only 10% of the incident photons effectively produce photoelectrons, find the current (approxi-
mate value) due to these electrons.
(A) 20 A (B) 50 A (C) 200 A (D) 500 A
Q.3 In which of the following cases, we would obtain an output of one.
x
y
z
Output
(A) x = 1, y = 1, z = 1 (B) x = 1, y = 1, z = 0
(C) x = 0, y = 1, z = 1 (D) x = 0, y = 0, z = 1
Q.4 The wavelength of the characteristic X-ray K
o
line emitted by a target element is 0.32 . What would
the wavelength of the K
|
line emitted by the same element?
(A) 0.37 (B) 0.57 (C) 0.27 (D) 0.13
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 10
PHYSICS
SPACE FOR ROUGH WORK
Q.5 Find the power dissipated in the circuit if the circular wire and its diameter has a resistance per unit
length. The radius of circle is a. The connecting wires are resistanceless.
(A)
ta
V 2
2
(B)
ta 2
V
2
(C)
+ t a 2 a 2
V
2
(D)
+ t a a
V
2
Q.6 Find the magnetic field at point O. Here curved part of wire has radius a & straight part of wire is very
long.
(A)
|
.
|

\
|
+
t 4
1 1
a
i
0
(B)
|
.
|

\
|
+
t 4
1 1
a 2
i
0
(C)
|
.
|

\
|
+
t 4
1 2
a
i
0
(D)
|
.
|

\
|

t 4
1 1
a 2
i
0
Q.7 A thin convex lens forms an image of a point object kept on its principal axis. The object is 50 cm away
from the lens and image is also 50 cm away from the lens. If a glass slab ( = 1.5, thickness = 6 cm) is
placed between the object and the lens, the image shifts by :
(A)
23
50
cm away (B)
23
25
cm away (C)
23
50
cm towards (D) none of these
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 11
PHYSICS
SPACE FOR ROUGH WORK
Q.8 A block of mass m is kept on a rough inclined plane with coefficient of friction . The force required to
just move the block up is
F
u
(A) mg cos u (B) mg sin u
(C) mg sin u + mg cos u (D) mg sin u mg cos u
Q.9 A particle is executing SHM with amplitude A. The displacement of the particle from the mean position
when its kinetic energy is equal to its potential energy is
(A)
2
A
(B)
2
A
(C)
2
A 3
(D) A
Q.10 An x-ray tube is operating at a voltage V. Which of the following wavelengths depend on V
(A) k
o
x-ray (B) k
|
x-ray
(C) minimum wavelength (D) maximum wavelength
Q.11 The critical angle of incidence for light travelling from medium A to B is u. If the speed of light in medium
A is v, then the speed in medium B is
(A) v sec u (B) v sin u (C) v cosec u (D) v cos u
Q.12 In a series LCR circuit connected to AC source, the power factor is 1. The angular frequency is 100t
rad/s. The inductance is 4H, the resistance is 100O. Then the capacitance is
(A) 2.5 F (B) 5 F (C) 4 F (D) 8 F
Q.13 If magnetic field in space is
i

T 1
, electric field is
i

C / N 10
, no gravitational field is present and a charged
particle is released from rest from origin, it will
(A) not move at all (B) move in a circular path
(C) move in a helical path (D) move on a straight line
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 12
PHYSICS
SPACE FOR ROUGH WORK
Q.14 A short circuited coil is kept on the ground and a magnet is
dropped on it as shown. The coil shows (when viewed from top)
(A) anticlockwise current that increases in magnitude
(B) anticlockwise current that remains constant
N
S
(C) clockwise current that remains constant
(D) clockwise current that increases in magnitude
Q.15 In an LR circuit shown below, at t = 0 switch is put on. the time after which the current becomes 1
ampere is
4H
4O
3V
(A) ln3 sec (B)
2
3 ln
sec. (C) 3ln2 sec. (D) never
Q.16 In a YDSE experiment = 540 nm, D = 1m, d = 1mm. A thin transparent film is pasted on upper slit and
the central maxima shifts to the point just in front of the upper slit. What is the effective path difference (in
air) at the centre of the screen ?
(A) 540 nm (B) 270 nm (C) 500 nm (D) 810 nm
Q.17 A freshly prepared sample of a certain radioactive isotope has an activity of 9.0 mCi. After 4.00 h, its
activity is 4.5 mCi. Find the half life.
(A) 8 hr (B) 16 hr (C) 4 hr (D) 24 hr
Q.18 A ball of mass m is revolving in a circle of radius R. It is connected to another ball of same mass hanging
vertically. If the hanging ball is in equilibrium, angular velocity of mass is
(A)
g
R
(B)
R
g
m
m
(C)
g
R 2
(D) gR
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 13
PHYSICS
SPACE FOR ROUGH WORK
Q.19 The interaction potential energy of a diatomic molecule is given by U =
12
r
A

6
r
B
. A and B are positive
constants. The distance r between them at equilibrium is
(A)
6 / 1
B
A
|
.
|

\
|
(B)
6 / 1
B
A 2
|
.
|

\
|
(C)
6 / 1
B 2
A
|
.
|

\
|
(D) None of these
Q.20 A particle of mass m moves towards a smooth vertical wall with speed u. The wall is moving with speed
2u in opposite direction. The collision is head on elastic. The magnitude of impulse delivered to the
particle is
(A) 3 mu (B) 4 mu (C) 5 mu (D) 6 mu
Q.21 An air bubble of radius r rises steadily through a liquid of density with velocity v. The coefficient of
viscosity of liquid is
(A)
v
g r
9
2
2

(B)
v
g r
9
2
2
(C)
2
r
g v
9
2
(D)
2
vr
g
9
2
Q.22 A tuning fork of frequency 330 Hz is used to excite a resonance column. If speed of sound is 330 m/s,
length of resonance column at 1st resonance.
(A) 25 cm exactly (B) slightly less than 25 cm
(C) slightly more than 25 cm (D) slightly less than 50 cm
Q.23 A wave y = 3 cm sin |
.
|

\
| t
t
100
x 2
t 4 passes through a region. The maximum velocity of the particle of the
medium is given by (here t is in sec & x is in meter)
(A) 12t cm/s (B)
t 4
3
cm/s (C) 200 m/s (D) 0.5 cm/s
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 14
PHYSICS
SPACE FOR ROUGH WORK
Q.24 A cube of side a is pulled at the top as shown. At what value of F will it topple. Assume surface is so
rough that it does not slide.
mass
m
F
(A) mg (B) mg/2 (C) 2mg (D) 3mg/2
Q.25 A wire of linear mass density is being rotated about an axis passing through O and perpendicular to the
plane. Its moment of inertia is :
R
R R O
(A)
|
.
|

\
|
+ t
3
14
R
3
(B)
|
.
|

\
|
+ t
3
8
R
3
(C)
|
.
|

\
|
+ t
3
2
R
3
(D)
3
5
R
3
Q.26 If temperature versus density graph is a rectangular hyperbola, the process is (consider ideal gas &
number of moles of gas is constant).
(A) Isobaric (B) Isochoric (C) Adiabatic (D) Isothermal
Q.27 A certain radioactive sample is observed to undergo 10000 decays in 10 sec. In which of the following
cases can we say that decay rate during this time interval is approximately constant and equal to 1000
dps.
(A) t
1/2
= 10 sec (B) t
mean
= 10 sec (C) t
1/2
>> 10 sec (D) t
1/2
<< 10 sec
[REASONING TYPE]
Q.28 to Q.30 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.28 Statement-1 : The force due to atmosphere on our head is very large but we don't feel its effect.
Statement-2 : The molecules striking us are very tiny.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 15
PHYSICS
SPACE FOR ROUGH WORK
Q.29 Statement-1 : When a body rolls without slipping over a rough horizontal ground (without any net
external force), friction acting on it is not zero.
Statement-2 : When a body slips on rough ground, friction acting on it is kinetic.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
Q.30 Statement-1 : If we want to cross a uniformly flowing river in shortest time, we should swim (w.r.t.
river flow) in a direction perpendicular to river flow.
Statement-2 : Velocity is a vector and motion in x and y direction are independent of each other.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
CHEMISTRY
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 16
SPACE FOR ROUGH WORK
PART-A
[SINGLE CORRECT CHOICE TYPE]
Q.1 to Q.27 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.1 What happens when lyophillic sol is added to a lyophobic sol?
(A) A film of lyophillic sol is formed over lyophobic sol and lyophobic sol is stabilized.
(B) Lyophobic sol gets coagulated.
(C) Lyophillic sol gets coagulated.
(D) Lyophillic sol gets protected by the lyophobic sol.
Q.2 Which of the following does not exist?
(A) Tl [I
3
] (B) PBr
5
(C) SbCl
5
(D) BiBr
5
Q.3
O
O
O
is tautomer of
(A)
OH
O
O
(B)
OH
O
OH
(C)
OH
OH
OH
(D) All of these
Q.4 Which of the following statements regarding defects in crystalline solids is correct?
(A) Schottky defects exist in non-ionic substances and does not affect density of substance
(B) Frenkel defects increases the dielectric constant.
(C) Introduction of impurity defect in Si by insertion of Al will create n-type semiconductors.
(D) The formation of wustite is an example of metal excess defect.
CHEMISTRY
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 17
SPACE FOR ROUGH WORK
Q.5 If o, | and are the bond angles ( ZFAF where A is the central atom) in CF
4
, POF
3
and SO
2
F
2
respectively, the correct order is :
(A) o > | > (B) o < | < (C) o < < | (D) o > > |
Q.6 True statements regarding S
N
1 reaction is/are
(A) Perfect racemisation is observed
(B) Only Walden inversion is observed
(C) Total retention of configuartion is observed
(D) None of these
Q.7 200 ml of a very dilute aqueous solution of a protein contains 1.9gm of the protein. If osmotic rise of such
a solution at 300K is found to be 38 mm of solution then calculate molar mass of the protein.
(A) 24630 gm/mole (B) 123150 milli gm/mole
(C) 517230 gm/mole (D) 61575 gm/mole
Q.8 Which of the following reactions does not produce H
2
O
2
?
(A) BaO
2
+ H
2
S
4
(B) Na
2
O
2
+ H
2
O(ice cold)
(C) PbO
2
+ H
2
SO
4
(D) None of these
Q.9 Choose alkane that give more than one monochloro derivative upon reaction with chlorine in sun light.
(A) (B) (C) (D)
CHEMISTRY
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 18
SPACE FOR ROUGH WORK
Q.10 Which of the following statements regarding electrolytic conductance is not correct?
(A) The value of constant, 'A' in the equation for variation of molar conductance with square root of
concentration,
C A
0
m
C
m
=
for KCl and NaCl ) A & A (
NaCl KCl
aqueous solution will be
same at same temperature.
(B) The value of limiting molar conductivity (
0
m

) of CH
3
COOH solution can not be obtained on
extrapolation of graph of
m
vs
C
.
(C) The correct order of limiting molar conductivity of H
+
, Na
+
and Mg
+2
follow the order,

0
Na m
0
Li m
0
H m
+ + +
> >
.
(D) For all weak electrolytes, K
eq
=
) (
C
C , m
0
m
0
m
2
C , m


, where K
eq
is the dissociation constant,
C , m
is
molar conductivity at any concentration and
0
m

is limiting molar conductivity..


Q.11 The reaction which is consistent with the fact that Cl
2
O
6
(s) exists as [ClO
2
+
][ClO
4

], would be
(A) Cl
2
O
6
+ NaOH NaClO
3
+ NaClO
4
+ H
2
O
(B) Cl
2
O
6
+ HF ClO
2
F + HClO
4
(C) 2HClO
4
+ P
2
O
5
2HPO
3
+ Cl
2
O
7
(D) 2ClO
2
+ 2O
3

C 0
Cl
2
O
6
+ 2O
2
CHEMISTRY
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 19
SPACE FOR ROUGH WORK
Q.12
NO
2
Cl

A

, Fe
Br
2
(X)
A

, OH CH
ONa CH
3
3
(Y)
Product (Y) of this reaction is
(A)
NO
2
OCH
3
Cl
(B)
NO
2
OCH
3
Br
(C)
NO
2
OCH
3
(D)
NO
2
OCH
3
Q.13 Calculate solubility of AgCN in a solution buffered at [H
+
] = 0.06 M if K
sp
of AgCN =6 10
17
and K
a
of HCN = 10
9
.
(A) 60 10
9
(B) 6 10
5
(C) 6 10
13
(D) 6 10
8
Q.14 The acidic strength of oxides of nitrogen follows the order:
(A) N
2
O < NO < N
2
O
3
< N
2
O
4
< N
2
O
5
(B) NO < NO
2
< N
2
O < N
2
O
3
< N
2
O
5
(C) NO < N
2
O < N
2
O
3
< N
2
O
5
< N
2
O
4
(D) NO < N
2
O < N
2
O
5
< N
2
O
3
< N
2
O
4
CHEMISTRY
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 20
SPACE FOR ROUGH WORK
Q.15 CH
3
C CCH
3
Product (A) & (B) respectively :
[E = Entegen; Z = Zusamen]
(A) E, E (B) E, Z (C) Z, Z (D) Z, E
Q.16 For a Vander Waal gas with a = 0.2463 atm lit
2
mol
1
and b = 0.01 lit mol
1
subjected to adiabatic free
expansion at an initial temperature of 650 K will show which of the following characteristics.
(A) q = 0, w = 0, AT = 0 (B) q = 0, w = 0, AT > 0
(C) q = 0, w = 0 , AT < 0 (D) q = 0, w = 0, AT = 0
Q.17 Which of the following processes of leaching / concentration is not correctly matched?
(A) Red bauxite Baeyer's process
(B) White/Brown bauxite Serpeck's process
(C) Bauxite Hall's process
(D) Heavy transition metal oxides Froth floatation process
Q.18 Which of the following will not produce same product when treated with dil.H
2
SO
4
with HgSO
4
or
when undergo hydroboration oxidation?
(A) (B)
H
(C)
H Ph (D) H Cl
3
C
CHEMISTRY
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 21
SPACE FOR ROUGH WORK
Q.19 Consider a first order gas phase reaction,
A
(g)
2B
(g)
+ C
(g)
The initial pressure taking only A in a rigid vessel was found to be P atm. After a lapse of 10 minutes, the
pressure of the system increases by x units and became P
10
atm. The rate constant for the reaction is
given by
(A) K =
1
min
x P
P
log
10
303 . 2

+
(B) K =
1
hr
2 / x P
P
log
10
303 . 2

(C) K = 2.303 6 log


1
10
hr
P P
P

(D) K = 2.303 6 log


10
P P 3
P 2

hr
1
Q.20 The anion which does not produce diatomic gas on treatment with hot and concentrated sulphuric is :
(A) Br

(B) I

(C) Cl

(D) None of these


Q.21


O H
3
(A) + (B) formed can be distinguished by
(A) Iodoform (B) Fehling (C) NaHSO
3
(D) 2,4-DNP
Q.22 How does the surface tension of a liquid vary with increase in temperature?
(A) Remains same (B) Increases (C) Decreases (D) No regular pattern
Q.23 The cation which gives white precipitate of its hydroxide when treated with aqueous ammonium sulphide
solution is :
(A) Pb
2+
(B) Al
3+
(C) Cr
3+
(D) Ni
2+
CHEMISTRY
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 22
SPACE FOR ROUGH WORK
Q.24
OH O C D 2
|
D
+ =

Cannizzaro
X and Y. Y.
X and Y will have structure :
(A)
O C D
| |
O

,
D
|
OH C D
|
D
(B)
O C D
| |
O

,
H
|
OH C D
|
D

(C)
O C H
| |
O

,
D
|
OH C D
|
D
(D) none is correct
Q.25 What volume of O
2(g)
measured at NTP will be formed by action of 200 ml of 0.4 M KMnO
4
of
hydrogen peroxide in acid solution.
(A) 4.48 litre (B) 2.24 litre (C) 8.96 litre (D) 1.12 litre
Q.26 CuSO
4
+ NH
4
OH Deep blue soluble
excess complex salt
The correct statement(s) regarding the complex is /are :
(A) It has square planar geometry.
(B) It is paramagnetic in nature.
(C) Unpaird electron present in p-orbital of copper.
(D) All the these
CHEMISTRY
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 23
SPACE FOR ROUGH WORK
Q.27
Cl
Cl

A

+
+
H
H ) ii (
Hg / Mg ) i (
Zn / O H ) ii (
O ) i (
ether Dry
Na
C B A
2
3
Product is
(A)
O
(B)
O
(C)
O
(D)
O
[REASONING TYPE]
Q.28 to Q.30 has four choices (A), (B), (C), (D) out of which ONLY ONE is correct.
Q.28 Statement-1 : In a hydrogen atom 2s and 2p orbital are degenerate where as in case of oxygen atom,
they are not.
Statement-2 : The repulsions between electrons are present in multielectron atoms which cause
change in energy of levels.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
Q.29 Statement-1 : Both CrO
4
2
and Cr
2
O
7
2
ions when treated with acidified H
2
O
2
solution gives blue
solution which turns green on standing.
Statement-2 : Blue solution of CrO
5
is stabilised in the presence of organic solvent e.g. ether,
pyridine etc.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
CHEMISTRY
XII (AB) FINAL TEST [Paper-I_MAINS] Page # 24
SPACE FOR ROUGH WORK
FOR AB
Q.30 Statement-1: Per molecule of D-Glucose consumes two molecule of PhNHNH
2
during formation
of osazone.
Statement-2: Structure of Glucose osazone is
C=NNHC H
6 5
CH OH
2
CH=NNHC H
6 5
HO
H
H
H
OH
OH
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.
FOR SMS
Q.30 Statement-1 :
C = N
Et
Me
OH

A

4 2
SO H . conc
Et NH C Me
| |
O

Statement-2 : During carbocation rearrangement Et a better migration than Me.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B)Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.