AS Organic Chemistry 1 1. What is the IUPAC name of the following compound?

H H H H C C H H H H C H H H H C C H

2-methyl butane Ethyl propane 3- Methyl butane Pentane

2. What is the IUPAC name of the following compound? CH3 CH3 C CH2 CH3 3,3,4-trimethyl hexane 3,4,4- trimethyl hexane 4-Ethyl 3,4-dimethyl pentane 2-Ethyl-2,3-dimethyl pentane 3. Identify the functional group present in HCOCH2CH3 O HC CH3 CH C H2 CH3

O C O C O R

4. How many structural isomers are possible with molecular formula C6H14? 4 5 6 7 5. Which compound is a member of the same homologous series as 1-chloropropane? 1-Chloropropene 1-bromopropane 1-Chloropropane 1,1-Dichloropropane 6. Propane ,C3H8, undergoes incomplete combustion in a limited amount of air. Which products are most likely to be formed during this reaction? Carbon monoxide and water. Carbon monoxide and hydrogen. Carbon dioxide and hydrogen. Carbon dioxide and water. 7. Which are characteristics typical of a free radical? I. II. It has lone pair of electrons. It can be formed by the homolytic fission of a covalent bond?

III.

It is uncharged. I and II only. I and III only. II and III only. I, II and III .

8. When bromine water is shaken with a liquid organic compound, it is rapidly decolourised. What can be determined from this test? The compound is an alcohol. The compound is an alkane. The compound is an alkene The compound is an iodoalkane

9, What structural feature must a molecule have in order to undergo addition polymerization? Two functional groups. A carbon-carbon double bond. Carbon atoms singly bonded together. A polar covalent bond.

10. What type of reaction does the equation below represent? CH2==CH2 + Br2 Substitution Condensation Reduction Addition BrC H2C H2Br

11. Which reactions can ethene undergo? I. II. III. Addition Esterification Polymerization. I and II only. I and III only. II and III only. I, II and III . 12. Which statement about alcohols is correct? Primary alcohols can be obtained by the reduction of carboxylic acids or aldehydes. Secondary alcohols can be obtained by the oxidation of ketones. Tertiary alcohols can be obtained by the reduction of carboxylic acids or aldehydes. Alcohols can be obtained by the addition of water to alkanes using acid as catalyst, 13. Which of the following products could be formed from the oxidation of ethanol? I. II. III. Ethanal. Ethanoic Acid. Ethane. I and II only. I and III only. II and III only. I, II and III . 14. Which compound can not be easily oxidized using acidified potassium dichromate (VI) solution? CH3CH2CH2OH CH3CH(OH) CH3 (CH3 )2 CHCH2OH

(CH3 )3 C OH 15. Consider the following compounds; I. II. III. CH3 CH2CH(OH) CH3 CH3CH(CH3) CH2 OH (CH3 )3 C OH

The compounds are treated separately with acidified potassium dichromate (VI) solution. Which will produce a colour change from orange to green? I and II only. I and III only. II and III only. I, II and III . 16. Which compound is a tertiary halogenoalkane? (CH3 CH2 )2 CHBr CH3 (CH2)3 CH2 Br (CH3 )2 CHCH2 CH2 Br CH3 CH2 C (CH3)2Br !7. Which statement best describes the reaction mechanism involved in the single step conversion of chloroethane to ethanol? The reaction involves removal of HCl, followed by the addition of H2O. The reaction involves heterolytic fission of the CCl bond, followed by a reaction with H2O. The reaction involves nucleophilic attack of OH- in a bimolecular mechanism. The reaction mechanism involves a carbocation.

18. What is the reaction type when (CH3)3CBr reacts with aqueous solution of sodium hydroxide to form (CH3)3COH and NaBr.? Addition Elimination SN1 SN2