PHYSICAL CHEMISTRY

PHYSICAL CHEMISTRY
by:

By: Shailendra Kumar

SHAILENDRA KR.

Meq. Approach

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Topic: Application of Meq. Method

1. 8 g NaOH are present in 200 mL solution. The normality of the solution is : 8. How much water should be added to 100 mL of seminormal HCl solution to make it decinormal ? (a) 100 mL (c) 300 mL 9. (b) 200 mL (d) 400 mL

(a) 1 (d) 4
2.

(b) 2

(c) 3

The normality of concentrated sulphuric acid of specific gravity 1.80 and containing 98.0 percent H2SO4 by weight is :

The weight of CuSO4.5H2O (mol. wt. 249.5) present in 100 mL N/10 solution is : (a) 2.495 g (d) 4.5 g (b) 1.2475 g (e) 5 g (c) 3.475 g

(a)10 (d) 32
3.

(b) 30

(c) 25

The normality of 0.5 M-H3PO4 solution is :

(a)1 (d) 1.5

4.

(b) 2.5

(c) 3.5

10. 200 mL of 0.3 M-HCl were mixed with 100 mL of 0.3 MNaOH. The strenght of the resulting solution in terms of normality is :

(a) 0.5 (d) 0.1

(b) 0.4

(c) 0.3

8 g of sodium hydroxide were dissolved in 100 mL of water. The whole of this solution neutralises completely: (a)10 mL of 5N-H2SO4 (b) 20 mL of 5M-H2SO4 (c) 20 mL of 2.5M-H2SO4 (d) 30 mL of 5M- H2SO4

11. 25 mL of HCl liberates 10 mL of CO2 at S.T.P. when reacting with excess of CaCO3. The normality of HCl is:

(a) 0.03 (d) 0.057

(b) 0.0357

(c) 0.04

5.

To 100 mL M/10 HCl is added 100 mL M/10 Na2CO3. The resulting mixture will be : (a) acidic (c) alkaline (b) neutral (c) none of these

12. One molar 100 mL sodium hydroxide and 10 molar 10 mL of sulphuric acid are mixed together, the resulting solution will be : (a) acidic (c) neutral (b) basic (d) alkaline

6.

100 mL of 0.3 N-HCl was mixed with 200 mL of 0.6 NH2SO4. The normality of the resulting mixture was : (a) 0.5 (c) 1.5 (b) 1.0 (d) 2.0

13. How much anhydrous sodium carbonate should be weighed out for the preparation of 500 mL of 4 N-Na2CO3 solution ?

7.

One gram of a metal carbonate neutralises 200 mL of 0 . 1 N-HCl. The equivalent weight of the metal will be : (a) 50 (c) 20 (b) 40 (d) 100

(a) 5.3 g (d) 106 g

(b) 10.6 g

(c) 53 g

14. What is the normality of 7.3% (wt./vol.) hydrochloric acid solution (mol. wt. of HCl = 36.5) ?

(a) 1.5 (d) 2.0

(b) 3.0

(c) 4.0

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PHYSICAL CHEMISTRY
15. How much N/5 HCl solution would be required in react completely with 1 g of CaCO3 ? (a) 100 mL (d) 200 mL 16. The molecular weight of NaOH is 40, 25 mL of solution containing 4 g of NaOH in 500 mL will require for complete neutralisation : (a) 50 mL of N/10 HCl solution (b) 20 mL of N/10 HCl solution (c) 25 mL of N/10 HCl solution (d) 10 mL of N/10 HCl solution 17. 1 g of pure calcium carbonate is mixed with 200 mL of N/10 HCl. After the reaction is over : (a) excess of HCl is left (b) ureacted calcium carbonate is left (c) neither of calcium carbonate nor of HCl is left (d) None of these 18. 20 mL of N-HCl reacts completely with 0.4 g of a metal. The equivalent weight of the metal is : (a) 4 (d) 40 19. 100 mL of a dibasic acid solution contains 3.15 g of the acid. 10 mL of this solution neutralises 10 mL of 0.5 NNaOH solution. The molecular weight of acid is : (a) 63 (d) 30 20. 6.3 g of hydrated oxalic acid (H2C2O4.xH2O) is present in 100 mL, normal solution of the acid. The number of mole of water of crystallisation is : (a) 2 (d) 5 21. 0.82 g of metal was treated with 200 mL o N/2 H2SO4 till the metal dissolved completely. The resulting solution required 65 mL of (N) NaOH for neutralisation. The equivalent weight of the metal is : (a) 9 (c) 18 (b) 12 (d) 24 (b) 3 (c) 4 (b) 126 (c) 31.5 (b) 8 (c) 12 (b) 500 mL (c) 25 mL

By: Shailendra Kumar

sodium carbonate (anhydrous) reacts with 100 mL NHCl. The persentage of sodium chloride in the mixture is : (a) 40 (c) 60 (b) 50 (d) 80

24. 100 mL of N/10 H2SO4 is completely neutralised by 0.20 g of an oxide of the metal M. The equivalent weight of the metal M is : (a) 12 (c) 36 (b) 24 (d) 48

25. 75 mL of HCl solution required 125 mL of N/25 NaOH solution for complete neutralisation. The amount of HCl present in solution is given by : (a) 18.25 g (c) 0.1825 g (b) 1.825 g (d) 0.9125 g (b) 0.025 g-mole of HCl

26. 250 mL of 0.1 N solution of HCl contains : (a) 0.25 g-mole of HCl (c) 9.12 g-mole of HCl(d) 0.912 g-mole of HCl 27. 250 mL of N/10 sulphuric acid solution contains : (a) 1.225 g (d) 9.8 g 28. 10.0 mL of 0.1 M-H2SO4 will neutralise : (a) 10.0 mL of 0.1 M sodium hydroxide (b) 10.0 mL of 0.1 M sodium carbonate (c) 5.0 mL of 0.1 M sodium hydroxide (d) 5.0 mL of 0.1 M sodium carbonate 29. 100 mLof 0.5 N-NaOH solution is added to 20 mL of NHCl solution and 10 mL of 3N-H2SO4 solution. The solution will be : (a) strongly acidic (c) neutral (b) alkaline (d) faintly acidic (b) 2.450 g (c) 4.9 g

30. 100 mL of 0.2 M-H2SO4 is added to 100 mL of 0.2MNaOH. The resulting solution will be : (a) acidic slightly basic (b) basic (c) neutral (d)

31. What is the weight of sodium hydroxide required to neutralise 100 mL of 0.1-N-HCl ? (a) 4.0 g (d) 2.0 g 32. 100 mL of 0.4 N-HCl is mixed with 100 mL of 0.6 NH2SO4. What is the normality of the resulting solution ? (a) 0.5 (d) 0.4 (b) 0.2 (c) 0.3 (b) 0.04 g (c) 0.4 g

22. Certain weight of calcium carbonate reacts with 100 mL H2SO4 completely to give 224 mL CO2 at S.T.P. The normality of H2SO4 is : (a) N (d) N/5 23. 10.6 g of a mixture containing sodium chloride and (b) N/2 (c) N/3

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PHYSICAL CHEMISTRY
33. The formula of metallic hydroxide (equivalent weight = 150) is M(OH)2.xH2O. If the atomic weight of the metal is 176, then the value of x is : (a) 5 (c) 4 (b) 8 (d) 10 (a) 12.6 g (c) 4.5 g

By: Shailendra Kumar

(b) 6.3 g (d) 9 g

43. 4 g of solid sodium hydroxide was dissolved in 100 mL of water. The whole of this solution neutralises completely : (a) 10 mL of 5 N-H2SO4 (b) 20 mL of 2.5 M-H2SO4 (c) 30 mL of 5 M-H2SO4 (d) 40 mL of 10 M-H2SO4 44. 100 mL of 0.1 N-HCl is treated with excess of AgNO3. The weight of AgCl precipitated is : (a) 1.435 g (c) 7.175 g (b) 14.35 g (d) 3.65 g

34. 500 mL of a 0.1N solution of AgNO3 are added to 500 mL of 0.1N solution of KCl. The concentration of nitrate ion in the resulting mixture is: (a) 0.05 N (c) 0.2 N (b) 0.01 N (d) 0.1 N

35. A solution containing 98 g of H2SO4 (formula weight = 98) per litre will be: (a) normal (c) centi-normal (b) molar (d) deci-normal

36. One gram of a metal carbonate neurtalises 200 mL of 0 . 1 N-HCl. The equivalent weight of the metal will be : (a) 50 (c) 20 (b) 40 (d) 100

45. 2.5 g of sodium hydroxide was dissolved in water and the volume was made to 50 mL. The volume of 5NH2SO4 required to neutralise the above alkali completely is : (a) 12.5 mL (d) 15 mL 46. One mole of sulphuric acid will be exactly neutralised by : (a) one mole of ammonia (b) one mole of barium hydroxide (c) two moles of calcium hydroxide (d) two moles of barium hydroxide 47. 30 mL of 0.2 N-NaOH solution is completly neutralised by 60 mL of hydrochloric acid. The normality of HCl is : (a) 0.8 N (d) 0.1 N 48. The molarity of water in pure water is : (a) 1 M (c) 55.5 M (b) 18 M (d) 1000 M (b) 450 g ( c ) (b) 0.4 N (c) 0.3 N (b) 25 mL (c) 30 mL

37. 75 mL of N/5 H2SO4, 10 mL of N/2 HCl and 30 mL of N/ 10 HNO3 are mixed together. The strength of the resulting acid mixture is : (a) 0.1 N (c) 0.3 N (b) 0.2 N (d) 0.4 N

38. What is the amount of NaOH required to neutralise 100 mL of 0.1 N-H2SO4 ? (a) 5.0 g (d) 0.8 g 39. 40 mL of 0.1 N-HCl are mixed with 20 mL of 0.1 MH2SO4. The strength of the resulting solution will be : (a) 0.4 N (c) 2N/15 (a) 0.5 (d) 2.0 41. How many millilitres of 0.02 M sodium hydroxide solution are needed to react completely with 100 mL of 0.01 M sulphuric acid ? (a) 200 mL (d) 50 mL 42. Oxalic acid is a dibasic acid having molecular formula (COOH)2.2H2O. What weight of oxalic acid is required to prepare 500 mL of 0.1 M solution ? (b) 150 mL (c) 100 mL (b) 0.3 N (d) 0.1 N (b) 1.0 (c) 1.5 (b) 4.0 g (c) 0.4 g

40. The normality 0.5 M-H2SO4 solution is :

49. The weight of H2SO4 in 2.5 litres of 2 M-H2SO4 is : (a) 400 g 480 g (d) 490 g 50. 1.0 g of a mixture of sodium chloride and anhydrous sodium carbonate is exactly neutrised by 50 mL of N/5 solution of an acid. The percentage of sodium chloride in the mixture is : (a) 53 (d) 70 (b) 47 (c) 80

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PHYSICAL CHEMISTRY
51. 10 mL of (N) HCl reacts with 0.12 g of a metal. The equivalent weight of metal is : (a) 8 (d) 20 52. Which of the following is independent of temperature ? (a) molarity (c) formality (b) molality (d) normality (b) 10 (c) 12

By: Shailendra Kumar

61. Which of the following should be done in order to prepare 0.40 M-NaCl starting with 100 mL of 0.30 MNaCl (mol. wt. of NaCl = 58.5) ? (a) add 5.85 g NaCl (b) add 20.0 mL water (c) add 0.01 mole NaCl (d) evaporate 10 mL water 62. The concentration of an aqueous solution of 0.01 MCH3OH solution is very nearly equal to : (a) 0.01% CH3OH (c) XCH3OH = 0.01 (b) 0.01 M-CH3OH (d) 0.99 M-H2O

53. A substance has its molecular weight 342. The molarity of a solution containing 6.84 g of a substance in 200 mL of solution is : (a) 0.1 M (c) 0.3 M (a) g / litre (c) mole / L (b) 0.2 M (d) 0.4 M (b) litre / mole (d) mole / 1000 g

54. Molarity is expressed as :

63. 0.45 g of a dibasic acid required 200 mL of N/20 NaOH solution for neutralisation. The molecular weight of the dibasic acid is : (a) 45 (d) 90 64. 0.84 g of metal carbonate reacts exactly with 40 mL of N/2 H2SO4 solution. The equivalent weight of the metal carbonate is (a) 21 (d) 42 65. Increasing the temperature of an aqueous solution will cause : (a) decrease in molality (b) decrease in molarity (c) decrease in mole fraction (d) dectrease in % (w/w) 66. The amount of HCl required to neutralise 20 mL of 0.5 N-NaOH is (a) 20 mL of 1.0 N-HCl (b) 10 mL of 1.0 N-HCl (c) 40 mL of 0.5 N-HCl (d) 10 mL of 0.1 N-HCl 67. 20 mL of a solution containing 6.5 g of a dibasic acid per litre neutralised 22.18 mL of a solution of NaOH. The same volume (20 mL) of N/10 HCl neutralised 21.5 mL of the same sodium hydroxide solution. The molecular weight of the acid is : (a) 120 (d) 100.32 68. 2 N-NaOH solution means that : (a) 2 g of NaOH is dissolved in 100 mL of water (b) 2 g of NaOH is dissolved in 100 mL of solution (c) 4 g of NaOH is dissolved in 100 mL of water (d) 8 g of NaOH is dissolved in 100 mL of solution (b) 126.0 (c) 128.02 (b) 30 (c) 40 (b) 60 (c) 70

55. One g-equivalent of potassium hydroxide is 56 g. Therefore, weight of KOH present in 500 mL of decinormal solution is : (a) 5.6 g (c) 28 g (b) 2.8 g (d) 11.2 g

56. 100 mL 0.3 N solution of NaOH was mixed with 200 mL of 0.3 M-H2SO4 solution. The normality of H2SO4 in the resulting solution is : (a) 0.9 N N (d) 0.4 N 57. The volume of N/5 HCl solution required to neutralise 2 g of CaCO3 is (Ca = 40, C = 12) : (a) 100 mL (d) 90 mL 58. 5.3 g of pure and anhydrous sodium carbonate is treated with 100 mL N/10 HCl. After the reaction is over : (a) excess of HCl is left (b) unreached sodium carbonate is left (c) neither of HCl nor of sodium carbonate is left (d) none of these 59. The normality of 73% HCl (density 1.2 g/mL) by weight would be : (a) 12 (d) 36 60. When 10 mL of 1M-KOH solution is mixed with 10 mL of M-H2SO4 solution, the resulting mixture will be : (a) acidic (d) strongly alkaline (b) alkaline (c) neutral (b) 18 (c) 24 (b) 200 mL (c) 50 mL (b) 0.3 N (c) 0.67

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PHYSICAL CHEMISTRY
69. 1.0 g of a piece of metal was allowed to react with 25 mL of 4 N-HCl. When the reaction was over, 100 mg of the metal remained unreacted. The equivalent weight of the metal is : (a) 9 (d) 24 70. A sample of Na2CO3.H2O weighing 0.62 g is added to 100 mL of 0.1 N-H2SO4 solution. The resulting solution is : (a) acidic (d) slightly acidic 71. Two litres of ammonia at 30C and 0.20 atm pressure neutralised 134 mL of a solution of sulphuric acid. The normality of the acid is : (a) 0.1 N (d) 0.14 N 72. One gram of a solid tribasic acid was dissolved in water and the solution was made to 250 mL. 19.2 mL of this solution required 10 mL of 1.1 N/10 NaOH solution for complete neutralisation. The molecular weight of the acid is : (a) 210 (c) 420 (b) 310 (d) 220 (b) 0.11 N (c) 0.12 N (b) basic (c) neutral (b) 12 (c) 18

By: Shailendra Kumar

77. The volume of water which must be added to 40 mL of 0.25 N oxalic acid solution in order to make it exactly decinormal is : (a) 40 mL (d) 60 mL 78. 25 mL of N solution of an acid was diluted to 250 mL. 10 mL of the solution was titrated with 0.05 N alkali solution. The volume of alkali solution required for complete neutralisation would be : (a) 100 mL (c) 5 mL (b) 20 mL (d) 10 mL (b) 30 mL (c) 20 mL

79. What volume of 0.2 N oxalic solution can be prepared from 63 g of oxalic acid ? (a) 0.2 litre (c) 2.5 litres (b) 0.5 litre (d) 5 litres

80. Hydrochloric acid solutions A and B have concentrations of 0.5 N and 0.1 N, respectively. The volumes of solutions A and B required to make 2.0 litres of 0.2 N-HCl are : (a) 0.5 L A + 1.5 L B (c) 1.0 L A + 1.0 L B (b) 1.5 L A + 0.5 L B (d) 0.75 L A + 1.25 L B

73. The normality of a 26% wt./vol. solution of ammonia is approximately : (a) 1.5 (c) 0.4 (b) 4.0 (d) 15.3

81. The equivalent weight of an unknown compound is 53. If 1.325 g of it be dissolved to make 250 mL of an aqueous solution of the compound, the normality of the solution is : (a) 0.1 N (d) 0.4 N 82. 0.12 g of pureMg ribbon completely reacts with 100 mL H2SO4. The normality of H2SO4 is : (a) N/10 (d) N/25 83. Suppose that 0.099 mole of solid sodium hydroxide is added to 100 mL of 1.0 M-HCl. The excess of mole of HCl present in solution than NaOH is : (a) 0.1 mole mole (d) 0.02 mole 84. The mole fraction of water in a 20% (w/w) aqueous solution of H2O2 is : (a) 77/68 (c) 20/80 (b) 68/77 (d) 80/20 (b) 0.01 mole (c)0.001 (b) N/15 (c) N/20 (b) 0.2 N (c) 0.3 N

74. 4 g of NaOH (mol. wt. = 40) were dissolved in water and the solution was made to 1000 mL. The whole of this will neutralize completely : (a) 100 mL of M-H2SO4 (b) 50 mL of 10 M-H2SO4 (c) 20 mL of 2.5 M-H2SO4 (d) 30 mL of 5 M-H2SO4 75. Commercial hydrochloric acid is 12 N. If 8.3 mL of this acid is dissolved in 991.7 mL of water, the normality of the resulting solution will be about : (a) 0.05 (c) 0.1 (b) 0.5 (c) 0.45

76. On dissolving 1.0 mole each of the following acids in 1.0 litre water, the acid that does not give a solution of strength 1.0 N is : (a) HCl (c) HNO3 (b) perchloric acid (d) phosphoric acid

85. If 5.85 g of NaCl is dissolved in 90 g of water, the mole fraction of NaCl is : (a) 0.1 (d) 0.0196 (b) 0.2 (c) 0.3

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PHYSICAL CHEMISTRY
86. What volume of CO2 at S.T.P. will be liberated by the action of 100 mL if 0.2 N-HCl on CaCO3 ? (a) 112 mL (c) 448 mL (b) 224 mL (d) 1120 mL (a) 1.5 (c) 0.5

By: Shailendra Kumar

chloride ions in the solution is : (b) 1.0 (d) 0.2

96. 100 mL of an N/10 acid will exactly neutralise : (a) 40 mL of N/4 alkali(b) 50 mL of N/10 alkali (c) 20 mL of N/5 alkali (d) 30 mL of N/6 alkali 97. The weight of BaCl2 that must be dissolved in 200 mL solution to produce chloride ion concentration as that present in solution containing 5.85 g NaCl per 100 mL, is : (Ba= 137) (a) 20.8 g (c) 41.6 g (b) 10.4 g (d) 10.4 g

87. 1 g of the carbonate of a metal was dissolved in 25 mL of N-HCl. The resulting liquid required 5 mL of N-NaOH for neutralisation. The eq. wt. of metal carbonate is : (a) 5 (d) 40 88. 0.1 mole of NaCl is added to 200 mL of M/10 AgNO3 solution. The molarity of nitrate ions in the solution will be : (a) 0.2 (c) 1.0 (b) 0.1 (d) 2.0 (b) 30 (c) 20

98. 100 mL 10% NaOH us mixed with 100 mL 10% H2SO4. The resulting solution is : (a) acidic (c) neutral (b)basic (d) slightly acidic

89. 1 g of pure magnesium ribbon reacts with 100 mL N/10 HCl. After the reaction is over : (a) excess of HCl is left (b) excess of magnesium is left (c) neither of magnesium nor of HCl is left (d) none of these 90. 1 g of a mixture of calcium carbonate and sodium chloride reacts completely with 100 mL N/10 HCl. The percentage of CaCO3 is the mixture is : (a) 40% (d) 80% 91. 200 mL M-NaNO3 and 200 mL M-Al(NO3)3 solutions are mixed. The molarity of nitrate ions in the mixture is : (a) 4 (c) 2 (b) 3 (d) 1 102. (b) 50% (c) 60% 101.

99. The volume of water that should be added to 400 mL of N/8 HCl to make it exactly N/12 is : (a) 100 mL (d) 400 mL 100. The mass of magnesium that must be added to 250 mL 1.2 M-HCl to reduce it to exactly 1.0 M-HCl is : (a) 1.2 g (c) 0.6 g (b) 1.0 g (d) 0.4 g (b) 200 mL (c) 300 mL

Equal volumes of 0.80 M-HCl, 0.50 M-KOH and 0.5 M-KCl are mixed. The molarity of resulting solution with regard to KCl is : (a) 1/2 M (c) 1/4 M (b) 1/3 M (d) 1.0 M

92. If 200 mL of N/10 HCl were added to 1 g of calcium carbonate. What would remain after the reaction ? (a) CaCO3 (b) HCl (c) neither of two (d) part of the both 93. The normality of 200 mL H 2 SO 4 solution that precipitates 2.33 g of BaSO4 when treated with excess of BaCl2 solution is: (a) 1 (c) 0.2 (b) 0.5 (d) 0.1

The volume of 0.25 M-MgCl2 that must be added to 320 mL of 0.25 M-NaCl to produce 0.3 M-Cl- in the mixture is : (a) 80 mL (c) 100 mL (b) 90 mL (d) 120 mL

103. 20 mL of NaOH solution converts 0.240 g NaH2PO4 in a solution to produce monohydrogen phosphate. The concentration of NaOH solution is : (a) 1 (c) 0.2 104. (b) 0.5 (d) 0.1

94. 100 mL of 0.2 M-H2SO4 is added to 100 mL of 0.3 MNaOH. The resulting solution will be : (a) acidic (d) slightly basic 95. A solution is prepared by dissolving 0.5 mole KCl and 0.5 mole BaCl2 in 1000 mL solution. The molarity of (b)basic (c) neutral

What volume of 0.5 N-HCl is required for the complete decomposition of 10 g of CaCO3 ? (a) 50 mL (c) 500 mL (b) 400 mL (d) 1000 mL

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PHYSICAL CHEMISTRY
105. The weight of iodine liberated when 100 mL 2 M CuSO4 solution is treted with excess of KI solution is : (a) 12.7 g (c) 1.27 g (b) 25.4 g (d) 2.54 g

By: Shailendra Kumar

(c) 1000 mL solution (d) 1000 g solution 116.The molarity of phosphoric acid is 0.5. Its reacts with Ca(OH)2 as Ca(OH)2 + H3PO4 = CaHPO4 +2H2O Its strength is : (a) 0.5 N (d) 3N 117.To 100 mL M/10 HCl, 100 mL M/10 Na2CO3 was added. The solution after the reaction is : (a) acidic (c) neutral (b) basic (d) none of these (b) 1N (c) 1.5 N

106. 25 mL of 0.5 M-H2SO4 is mixed with 30 mL of MNaOH solution. The volume of N/10 H2SO4 which will just neutralise the excess of alkali will be : (a) 5 mL (c) 10 mL 107. (b) 50 mL (d) 20 mL

Which of these solutions has the highest normality? (a) 8 g of KOH per 100 mL (b) 0.5 M-H2SO4 (c) N-phosphoric acid (d) 6 g of NaOH per 100 mL

108.

The strenght of NaOH solution is 5.1% (w/v), density 1.02 g/mL. Its strenght in w/w is : (a) 4% (c) 5% (b) 4.8% (d) 5.1%

118.4 g NaOH was dissolved in 50 mL water. The volume of (N) H2SO4 required for its complete neutralisation is : (a) 100 mL (d) 10 mL 119.The volume of HCl having concentration 18.25% by weight and specific gravity 1.2 for the preparation of 100 mL (N) solution is : (a) 18.25 mL (d) 16.66 mL 120. (b) 33.3 mL (d) 20.66 mL (c) 21.6 mL (b) 50 mL (c) 200 mL

109.

100 mL of N/10 (f = 1.08) HCl is diluted with distilled water to produce exactly decinormal solution. The volume of water required for the same is : (a) 108 mL (d) 80 mL (b) 100 mL (c) 8.0 mL

110.The strenght of a sodium hydroxide solution is 10% by wt. The mole fraction of water is : (a) 16/21 (c) 20/21 (b) 19/21 (d) none

10 g of a mixture of CaCO3 and MgCO3 (3% CaCO3 and 7% MgCO3) is allowed to react completely with 2.0 M-HCl. The volume of the acid required is : (a) 113.3 mL (c) 225 mL (b) 213.3 mL (d) 233 mL

121.

111. 100 mL 10% KOH is mixed with 100 mL 10% H2SO4. The resulting solution is : (a) acidic (c) neutral (b) basic (d) none 122.

1 g marble when reacted with (N) HCl acid required 19 mL for complete reaction leaving behind some sandy materials. The percentage purity of CaCO3 in the marble is : (a) 0.95 (d) 19 10 mL N/10 solution of a dibasic acid will completely neutralise N/10 solution of a monoacidic base if its volume added is : (a) 10 mL (d) 50 mL (b) 20 mL (c) 30 mL (b) 95 (c) 5

112.100 mL M-CH3COOH is mixed with 100 mL M-NaOH. The resulting solution is : (a) acidic (c) neutral (b) slightly basic (d) basic

113.The volume of 0.50 M BaCl2 that will contain 3.0 mole of chloride ions is : (a) 1.0 L (c) 3.0 L (b) 2.0 L (d) 1.5 L 123.

When excess of zinc reacts with 10 mL of H2SO4, 224 mL H2 is liberated at S.T.P. The strength of H2SO4 is (a) 10 N (b) 1 N (c) 2

114.The volume of 0.5 (N) sulphuric acid required to neutralise 200 mL of 0.2 (N) sodium carbonate is : (a) 23 mL (d) 100 mL 115.A solution is called normal if one gram-equivalent of solute is present in : (a) 1000 g water (b) 1000 mL water (b) 40 mL (c) 80 mL

N (d) 4 N

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PHYSICAL CHEMISTRY

By: Shailendra Kumar

A N S W E R S
1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. 73. 74. 75. 76. a e d b c a c d b e b a d d a a b e d b b b d a c c a d c c d 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 77. 78. 79. 80. 81. 82. 83. 84. 85. 86. 87. 88. 89. 90. 91. 92. a c e b a b e b a c b a b c a e b d a a a c b e b a d b b c c 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 93. 94. 95. 96. 97. 98. 99. 100. 101. 102. 103. 104. 105. 106. 107. 108. c a a a b c b c c b c b b a a d a a a a b b c b a d b b b d c
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