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AKA photodetectors!
Photodetectors
Atoms in Solids
The lattice affects the structure of the energy levels of each atom we now have joint levels for the entire structure
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Band Theory
Lattice Bands
Conduction
In order for an electron to become free and participate in current flow, it must gain enough energy to jump over the forbidden band For semiconductors at room temperature, there is not enough energy to conduct. As temperature increases more electrons have the energy to jump the forbidden band
Resistivity decreases This is the opposite behavior of conductors
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Resistivity
Semiconductor R Conductor
Semiconductors
Intrinsic Semiconductor
Compound Semiconductors can be formed from two (or more) elements (e.g., GaAs)
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Extrinsic Semiconductors
A pure semiconductors where a small amount of another element is added to replace atoms in the lattice (doping).
The aim is to produce an excess of either electrons (n-type) or holes (p-type) Typical doping concentrations are one part in ten million Doping must be uniform throughout the lattice so that charges do not accumulate
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Photoelectric effect
Photons knock electrons into conduction band Band gap and work function
E = h (h is Plancks constant, is light frequency) Kmax = h - ( = Work Function, Kmax is max kinetic energy of freed electron)
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PN Junction Diode
A diode is formed by interfacing an n-type semiconductor with a p-type semiconductor. A pn junction is the interface between n and p regions.
Diode symbol
Photoresistors
CdS (Cadmium Sulfide) and CdSe (Cadmium Selenide) cells are common
( I ) Directly beneath the conduction band of the CdS crystal is a donor level and there is an acceptor level above the valence band. In darkness, the electrons and holes in each level are almost crammed in place in the crystal and the photoconductor is at high resistance. ( II ) When light illuminates the CdS crystal and is absorbed by the crystal, the electrons in the valence band are excited into the conduction band. This creates pairs of free holes in the valence band and free electrons in the conduction band, increasing the conductance. ( III ) Furthermore, near the valence band is a separate acceptor level that can capture free electrons only with difficulty, but captures free holes easily. This lowers the recombination probability of the electrons and holes and increases the number for electrons in the conduction band for N-type conductance
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Photodiodes
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Silicon has more than 2x response in IR Reverse bias lowers capacitance (makes device faster, extends sensitivity)
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Quantum Efficiency
Thinned silicon - More efficient, esp. at short - Rear illumination better, as the pads/traces in front get in the way
Quantum efficiency (QE) is a figure given for a photosensitive device (charge-coupled device (CCD), for example) which is the percentage of photons hitting the photoreactive surface that will produce an electron-hole pair. It is an accurate measurement of the device's sensitivity. 21
Signal-to-noise ratio is also important!!
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Photodiode ICs
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The Phototransistor
Like diodes, all transistors are light-sensitive. Phototransistors are designed specifically to take advantage of this fact. The most-common variant is an NPN bipolar transistor with an exposed base region. Here, light striking the base replaces what would ordinarily be voltage applied to the base -- so, a phototransistor amplifies variations in the light striking it. Note that phototransistors may or may not have a base lead (if they do, the base lead allows you to bias the phototransistor's light response. Phototransistors run in the photoconductive mode Theyre pretty slow, on average (e.g., Khz response) But give a fair amount of gain and are very easy to use.
Generally ground emitter and provide a collector resistor to set gain
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High voltage across detector produces avalanche gain (e.g., factor 300) Very Sensitive and Fast response (e.g., ns)
Vacuum Photodiodes
Accelerating, focused electric field acts as lens and provides avalanche gain at diode
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Photomultiplier Tubes
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Lens collects light over increased area Effective gain at optical wavelengths is roughly k = 0.92 (A/a)
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Also called photopots - photoelectrons create current that divides in proportion to position - Made by UDT, Hammamatsu, etc. - Somewhat expensive...
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Imagers
Large-arrayphotodetectors suitable for creating images
CCD = Charge Coupled Device CMOS = Complementary Metal Oxide SemiConductor CCD = specialized production plant and process CMOS = standard silicon production line
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Charge (Electrons)
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Light
Gate Opens
Charge Transfer from Photo Sensor to Vertical CCD Like Water Draining from a Dam
Charge (Electrons)
Vertical CCD
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CCD
CCD
CCD
CCD
Charge
Charge
Charge
Charge
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Voltage Generated on Surface of FD Output Amplifier Micro Wire Output Gate Horizontal CCD
Gate
Gate
Gate
Charge
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ON
Pixel-select Switch (e) Pixel Row (j) Column Signal Wire (f) (Micro Wire) Column-select Switch (g) Column Circuit (h)
ON
Charge
ON
ON
Output 37
Voltage Generated on Surface of Photo Sensor Like the Rising Water Level of a Bucket
0V Voltage
Charge
High
Photo Sensor
High
Photo Sensor 38
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CCD
Electron Packet Voltage (analog) Low High Low Lower Moderate High High Moderate to high high depends poor to excellent
CMOS
Voltage Bits (digital) Moderate Higher than expected High Higher slightly better low to Moderate Moderate higher low none
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CCD
CMOS
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Optical instrumentation
(a) General block diagram of an optical instrument. (b) Highest efficiency is obtained by using an intense lamp, lenses to gather and focus the light on the sample in the cuvette, and a sensitive detector. (c) Solid-state lamps and detectors may simplify the system.
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Detectors
Incandescent bulb Light emitting diode (LED) Gas and solid state lasers Arc lamp Fluorescent source
Thermal detector (pyroelectric) Photodiode Phototransistor Charge-coupled device (CCD) Photoconductive cell Photomultiplier tube43
Spectrophotometer
Block diagram of a single beam spectrophotometer. The prism serves as the dispersing device while the monochromator refers to the dispersing device (prism), entrance slit, and exit slit. The exit slit is moveable in the vertical direction so that those portions of the power spectrum produced by the power source (light source)44 that are to be used can be selected.
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