Q-2: Rakib performed some experiments with ammonia gas to justify the correctness of third corollary.

He observed that 2.7 gm of liquid ammonia occupies 3.557 litre volumes if it is vapourised at standard temperature and pressure. Besides these, its molar volume becomes 22.4 litres. a) What is meant by standard temperature and pressure? b) Molar volume of the gas is 22.4 litre - What do you mean by this? c) Prove the corollary which is justified by Rakib. d) Determine the molecular mass from the above stem and find out the volume of 50 gm gas. Q-3: Different scientists have lots of contribution for the development of the chemistry. These scientists have enough roles to explain the structure of atom of elements, differentiate between atom and molecule, combination laws etc. These postulates have also some defects. Avogadro law is the correction of Berzelius hypothesis. Avogadro differentiated for the first time between CO2 and H. a) Helium gas is how many atomic? b) Which main concept is used for the correction of Berzelius hypothesis? c) Show the differences between the two particles mentioned in the stem according to the first concept of Avogadro. d) Describe the correction of the Daltons postulates given by different scientists with showing appropriate arguments. Q-4: In a room two container of equal volumes are separately filled, one by hydrogen and another by an unknown gas X at 0oC and 1 atm pressure. Then the volume of each container becomes 1 litre and mass becomes 0.0898 g and 1.696 g respectively. 1 ml hydrogen gas reacts with 1 ml X gas and forms 2 ml of HX gas. It is notable that equal volume of all gases contains equal number of molecules and number of molecules in 1 mole of all gases are constant. a) How many molecules are present in 2 mole of gas? b) Explain the law that shows relation between the number of gas molecules and volume. c) Calculate the number of atoms in 2 mole of X gas. d) Identify the X gas. Q-5: Mr. Sowyed told that at STP one f the two balloon is filled by hydrogen and another is filled by X gas. Then the volume of each balloon become 1 L and their masses become 0.089 g and 1.25 g respectively 3 volume of hydrogen reacts with 1 volume of X gas to produce 2 volumes of a compound gas. a) What is the number of molecule in one mole of X gas? b) If n is the number of molecules, v is the volume of any gas, explain its mathematical expression. c) Deduce the number of atoms of X gas. d) Explain the equation with significance when the element X reacts with heated magnesium. Q-6: In laboratory, students form water by reacting oxygen and hydrogen. To find its molecular formula mass they got a relation with molecular mass and vapour density. They got a relation with molecular mass and vapour density. They also observe that, vapour density and density are different. a) What is vapour density? b) Write the above reaction and balance it. c) Calculate the density of oxygen gas at STP. d) Prove that M = 2 D (M = Molecular mass; D = vapour density)

Q-7: Scientist Avogadro first introduce the idea of molecules. He indicated dissimilarity between atoms and molecules. From the Avogadros law three corollaries are set up. One of the important corollaries form Avogadros law is molecular mass of a gas is twice its vapour density or relative density. a) What do you mean by vapour density of a gas? b) Do the density depend on temperature and pressure? c) If 2.7 g of liquid ammonia is allowed to evaporate the vapour occupies 3.557 litre at STP. Calculate the molecular mass of ammonia. d) At same temperature, reaction between 1 liter volume of a gaseous element and 2 liter volumes of another gaseous element produces a gaseous compound of 2 liters. The gases are diatomic. The symbols of the element is X and Y respectively if then deduces the formula of compounds. Q-8: Under same temperature and pressure molar volume of all gases are same. Again from Avogadros theory we get, under the same temperature and pressure equal volume of all gases contain same number of molecules. So, 1 mole of all gases contains same number of molecules. This number is called Avogadros number. The decision got from Avogadros theory is true for all solid and liquid substance. Avogadros theory and its corollaries are important for chemistry. a) What is the value of Avogadros number? b) Show that, 1 gm atom of all elements contains the Avogadros number of atom. c) Find out how many molecules are there in 2 g of water. d) State the third corollary of Avogadros law and prove it. Q-9: After publishing the Daltons atomic theory in 1803, the first four laws of chemical combination get the proof. But still Gay Lusacs law of gaseous volume remained in darkness. For that reason Berzelius proposed, Under similar conditions of temperature and pressure equal volumes o fall gases contain equal number of atoms. But it was wrong. Avogadro corrected Berzelius statement and gave a new formula, which is now known as Avogadros theory. a) State Avogadros law. b) Explain Avogadros law shortly. c) State the importance and application of Avogadros theory. d) Prove that molecules of H2 and Cl2 are diatomic. Q-10: Avogadros theory introduces the new era of chemistry. Some important corollaries are obtained from the theory. Easy solution of different mathematical problem of chemistry is possible using these corollaries. a) State the second corollaries of Avogadros law. b) State the value and significance of Avogadros number. c) The density of a gas at S.T.p is 3.954 g/litre. What is the molecular mass of this gas? d) Prove that, molecular density is two times greater than vapour density.