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Lecture 1
1. 2. 3. 4. 5. 6. The phenomenon of superconductivity Superconducting materials Meissner effect London equations Magnetic field penetration depth Magnetic flux quantization
Phenomenon of superconductivity
resistance
TC temperature (K)
Discovered by Kamerlingh-Onnes in 1911: Hg,
Tc u 4 K
Phase diagram
of a superconductor on the H ? T plane: 2 H c T T = 1 ? Tc H c 0
1.2 1 0.8 0.6 0.4 0.2 0 0.2 0.4 0.6 0.8 1 1.2
T temperature T
Superconducting materials
material Al In Sn Pb Nb
T c , K H c , Oe
1.2 3.4 3.7 7.2 9.2 material 105 280 305 803 2060
T c , K H c , Oe
15 23 1.4 10 5 3.7 10 5 material
alloys
NbN Nb 3 Ge
Tc, K
35 93 94 125 150 D
La 1.85 Ba 0.15 CuO 4 ceramics YBa 2 Cu 3 O 7 Bi 2 Sr 2 CaCu 2 O 8+x Ta 2 Ba 2 Ca 2 Cu 3 O 10+x HgBa 2 Ca 2 Cu 3 O 8+x
D under pressure
Meissner effect
Walther Meissner and Robert Ochsenfeld in 1933
Example 1: a conductor
magnetic field
relaxation =L/R
Magnetic field induces a screening current (Lentz rule) which generates the opposite field in an ideal conductor: E = j _ = 0 /B according to Maxwells eq. 4 E = ? 1 c /t always B = const inside the conductor
lin
co o
ld fie
cooling
oli co
ng
conductor
g lin o co
superconductor
Levitation experiment
London equations
Derived by F. and H. London in 1935 Two-fluid model: electron density n = n s + n n n s density of superconducting electrons n n density of normal electrons
electron density
n ns
TC temperature (K)
London equations: / E = / C J s (1) t H = ?c 4 C J s (2) 4^ V 2 m C = n e 2 = c 2 L is a phenomenological parameter s m is the electron mass, e is the electron charge mc 2 V L = 4^ n e 2 1/2 is the London penetration depth
s
= eE ? m
v average drift velocity of electrons b their relaxation time (scattering on defects) Normal metal (steady state)
dv dt
= 0, v =
eb m
E, J = ne v =
ne 2 b m
E = aE
Ohms law
eE m
dJ s dt
= ne
dv s dt
ns e2 m
E =
For the 2nd London equation a naive way of derivation does not work: it relates to time-dependent fields important for the Meissner effect ^ Lets start from the Maxwells equation 4 H = 4c J
take curl
4 4 H = ?4 2 H
from 2nd London equation:
4 J = ? c1 C
1
4^ c
42H =
V2 L
H
V2 L
Thus, both E and H penetrate inside a superconductor to the distance V L which is called magnetic field (London) penetration depth
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Equation 4 2 H =
d2 dx 2
V2 L
H with H = 0, 0, H 0 gives
1
H?
V2 L
H = 0.
Using boundary conditions H0 = H 0 and HK = 0 we get a solution Hx = H 0 exp? VxL for the magnetic field.
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H 0 exp? VxL
temperature
T/T c
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Al Pb Nb crystal Nb films
50 nm 40 nm 47 nm 90 nm
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A .
14
We obtain a quantum-mechanical generalization of the 2nd London equation: 0 J s = n s ev s = c1 C 2^ 4 S ? A . where ic 0 = ^e = 2.06783461 10 ?15 Wb is the magnetic flux quantum.
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Integrating along C :
0 2^
[ 4 S dl = [ A dl
C C
where is the total flux inside C . Since the wave function must have a single value at any point expi S = expi S + 2^k , k = 0, 1, 2, ...
[ 4 S dl = 2^k
C
Similarity to the electron orbit quantization in atom t Interesting: F.London thought that 0 = 2 0 : he did not know about 2e t Experimental confirmation: Doll and Nbauer (1960)
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V2 L
H with H = 0, 0, H gives
1
H?
V2 L
H = 0.
d x H 0 cosh ?1 2V sinh VL L
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with current
JS
JS (x)
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Both H and J s are confined in the small V L -thick layer near the surface of the superconductor.
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